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Set 5                                                          Manufactured Substances in Industry Perfect Score F4                                            2010


PAPER 2 : SRUCTURE

1       Ammonia is produced in mass quantities in industry through a process as shown in diagram 1
        below.


                        Nitrogen Gas                                                   Catalyst chamber                                      Ammonia gas


                      Hydrogen gas
                                                                                                         Diagram 1

        (a)   State the name of the process for the production of ammonia in industry.

              ...............................................................................................................................................................
                                                                                                                                                                     [1 mark]
        (b)   Write an equation for the process stated in (a)?

              ..............................................................................................................................................................
                                                                                                                                                                     [1 mark]
        (c)   State the catalyt used in this process?

              ...............................................................................................................................................................
                                                                                                                                                                     [1 mark]
        (d)   Other than the use of catalyst, state two conditions required for optimum production of ammonia.

              ...............................................................................................................................................................
                                                                                                                                                                     [1 mark]
        (e)   Ammonia react with sulphuric acid to form a fertilizer.Name the fertilizer.

              ...............................................................................................................................................................
                                                                                                                                                                     [1 mark]
        (f)   The reaction between ammonia and carbon dioxide produce urea, CO(NH2)2 and water.

              (i)       Write the equation for the reaction.

                        ......................................................................................................................................................
                                                                                                                                                                     [1 mark]
              (ii)      Determine the percentage by mass of nitrogen in urea.
                        [Relative atomic mass ; H,1; C,12; N,14; O,16 ]




                                                                                                         [2 marks]
        (g)   Aqueous ammonia can be used as a reagent to identify cations. State the observation when aqueous
              ammonia is slowly added until excess to a solution containing Cu2+ ion.

              ................................................................................................................................................................

              ...............................................................................................................................................................
                                                                                                                                                                    [2 marks]
Chemistry Perfect Score Module Form 4 2010 Set 5                                                                                                                                 82
Set 5                                                         Manufactured Substances in Industry Perfect Score F4                                         2010


2.      Diagram 2 shows a flow chart for the formation of Salt A through Process X and Process Y.



                                                                                Process
                Sulphur                        Sulphur dioxide                    X                      Sulphur trioxide

               Nitrogen

                                     Process                 Ammonia                                       Sulphuric Acid
              Hydrogen                 Y




                                                                                         Salt A
                                      Diagram 2


        (a)     Name

                (i)     Process X : ....................................................................................................

                (ii)    Process Y : ....................................................................................................
                                                                                                                                                              [2 marks ]

     (b)        (i)     Write the equation for the formation of sulphur trioxide in Process X

                          ....................................................................................................................................................
                                                                                                                                                                     [1 mark]
                (ii)      State the catalyst used in Process X

                          ...................................................................................................................................................
                                                                                                                                                                    [1 mark ]

     (c)        (i)     Write the equation for the formation of ammonia in Process Y

                         ...................................................................................................................................................
                                                                                                                                                                   [1 mark ]
                (ii)    State the optimum temperature and pressure for Process Y

                          Temperature:.................................... Pressure:...................................................
                                                                                                                                                               [1 mark ]

        (d)     (i)     Name salt A

                       .....................................................................................................................................................
                                                                                                                                                                    [1 mark ]
                (ii)   Write the formula for salt A

                       .....................................................................................................................................................
                                                                                                                                                                    [ 1 mark]

Chemistry Perfect Score Module Form 4 2010 Set 5                                                                                                                         83
Set 5                                                        Manufactured Substances in Industry Perfect Score F4                                          2010


              (iii)    Calculate the percentage of nitrogen by mass in salt A .
                       Given relative atomic mass H = 1, N = 14 , O = 16, S = 32




                                                                                                                                                               [2 mark ]
        (e)    State one use of sulphuric acid in everyday life..

               ..............................................................................................................................................................
                                                                                                                                                                    [1 mark ]

3       Table 3 shows certain polymers and monomers for a polymerization process.

                                          Monomer                                                            Polymer
                                          Amino acid

                                                                                                               Starch
                                              Ethene
                                         Chloroethene                                            Polychloroethene(PVC)

                                                                                                        Natural rubber

                                                                              Table 3

        (a)   What is meant by polymer?

              ................................................................................................................................................................
                                                                                                                                                                   [ 1 mark ]
        (b)   Complete Table 2 by writing the correct polymer or monomer for the respective monomer or polymer.

                                                                                                                                                               [4 marks]
        (c)   Draw the structural formula for the polymer formed from the polymerization of ethene.




                                                                                                                                                              [ 1 mark ]
        (d)   Diagram 3 shows the structural formula for the polymer polychloroethene or PVC.


                               H             H             H             H                 H             H
                               |              |            |              |                |              |
                               C             C             C             C                 C             C
                               |              |            |              |                |              |
                               H             Cl            H             Cl                H             Cl

                                                                Diagram 3

Chemistry Perfect Score Module Form 4 2010 Set 5                                                                                                                         84
Set 5                                                      Manufactured Substances in Industry Perfect Score F4                                       2010


              (i)     Draw the structural for the monomer of polychloroethene.




                                                                                                                                                         [ 1 mark ]

              (ii)    In the system for water supply to homes, PVC pipes are widely used to replace metal pipes.
                      State one advantage of using PVC pipes compared to using metal pipes in terms of their
                      chemical properties.


                    .....................................................................................................................................................
                                                                                                                                                               [ 1 mark ]
        (e)   Classify the polymers in Table 3 into natural polymers and synthetic polymers.

                                Natural polymer                                        Synthetic polymer




                                                                                                                                                        [ 2 marks ]

PAPER 2 : ESSAY
4.      (a)   Diagram 4 shows the arrangement of atoms in pure copper and an alloy of copper, brass.




              Pure copper                                                                      brass
                                                        Diagram 4
              (i)     Explain why is pure copper softer than its alloy.
                                                                                                                                                          [3 marks]
              (ii)    Explain why the alloy, brass is stronger than pure copper.
                                                                                                                                                          [3 marks]
              (iii)   State the aim of alloying.
                                                                                                                                                          [3 marks]




Chemistry Perfect Score Module Form 4 2010 Set 5                                                                                                                    85
Set 5                                            Manufactured Substances in Industry Perfect Score F4          2010


        (b)
               (i)       Explain why pure aluminium is not suitable for building bodies of planes.
                                                                                                                    [2 marks]
               (ii)      State the alloy suitable for building bodies of planes and give reasons for your answer
                                                                                                                    [4 marks]
        (c)    (i)       Malaysia is proud of the products from pewter as souvenirs for tourists.
                         Name the main metal and the foreign metal in pewter.
                                                                                                                    [2 marks]
               (ii) Besides hardness, state three advantages of the alloy pewter to its pure metal.
                                                                                                                   [ 3 marks]

5.      (a)    (i)       What is meant by the term ‘polymers’?.
               (ii)      Name two examples of synthetic polymers. For each example , state its monomer and
                         one common use.
                                                                                                                   [ 7 marks ]
        (b)    (i)       What is meant by the term ‘composite material’?.
               (ii)      Name two examples of composite materials and their respective uses.
                                                                                                                   [ 5 marks ]
        (c)   Diagram 5 shows the waste products from a factory which affect the quality
              of the environment.



              a. amples/uses
              b. pollution



                      Sulphur
                      dioxide
                      gas
                      Factory
                      actory
                      Building

                      Toxic
                      waste
                                                              Diagram 5

         Based on diagram 5, describe how the waste products affect the quality of the environment.

          Your description should include the following aspects:
          Source of pollutants
          Process
          Effect
                                                                                                                   [ 8 marks ]

Chemistry Perfect Score Module Form 4 2010 Set 5                                                                           86
Set 5                                          Manufactured Substances in Industry Perfect Score F4             2010


PAPER 3 : STRUCTURE

6.       Diagram 6 shows the set up of apparatus of an experiment to compare hardness of copper and brass. The
         steps of carrying out the experiment are as follows.


        1.A steel ball-bearing is taped onto a copper of
        block .

        2. A 1-kg weight is hung at a height of 50 cm
                                                                                                      1 kg
        above the copper block
        .                                                                                             weight
        3. The weight is allowed to drop onto the ball
        bearing.
                                                                                Metre
        4.The diameter of the dent produced by the ball
                                                                                ruler
        bearing on the copper block is measured.

        5. Steps 1 to 4 are repeated on other parts of the
        copper block to obtain an average value for the
        diameter of dents.
                                                                                                      Steel
        6. Experiment is repeated by using brass block to                                             ball
        replace copper block.                                                                         bearing




                                                                                       Copper block



                                                             Diagram 6

         Table 6 shows the results of the experiment

                          Experiment                           1         2         3            Average
                                                                                              diameter/ cm

           Diameter of dent on copper block/ cm               0.5        0.6      0.5

               Diameter of dent on brass block/cm             0.3        0.3      0.2

                                                              Table 6

         (a)     Based on Table 6, record the average diameter of dents in the space provided.
                                                                                                                  [3 marks]




Chemistry Perfect Score Module Form 4 2010 Set 5                                                                        87
Set 5                                        Manufactured Substances in Industry Perfect Score F4     2010


        (b)   Give a statement to describe the operational definition of the hardness based on this
              experiment.

               ………………………………..………...…………………………….………………………….…

               ………………………………..………...…………………………………………………….……
                                                        [3 marks]
        (c)   Complete table below.

                       Name of variables                                   Action to be taken
         (i) Manipulated variable:                         (i) The way to manipulate variable:

         …………………………………………………                                 …………………………………………………

         …………………………………………………          …………………………………………………
         (ii) Responding variable: (ii) Way to observe in the responding variable:

                                                             …………………………………………………
         …………………………………………………
                                   …………………………………………………
         …………………………………………………
         (iii) Fixed variable: (iii) The way to maintain the fixed variable:

         .. ………………………………………………                             …………………………………………………

         …………………………………………………                               …………………………………………………

                                                                                                        [6 marks]

        (d)   State the hypothesis for this experiment.

               ...……………………………...………………………………………………………………………

                                                                                                        [3 marks]
        (e)   Classify the following materials into pure metals and alloy.

                                  Iron, steel, copper, aluminium
                                        Duralumin, Bronze,

                                                                                                        [3 marks]




Chemistry Perfect Score Module Form 4 2010 Set 5                                                              88
Set 5                                       Manufactured Substances in Industry Perfect Score F4       2010


7.      Concrete and reinforced concrete are two types of composite materials. Diagram 7 shows an
        experiment to investigate the strength of concrete and reinforced concrete. The 10kg weight is dropped from
        a fixed height.




                                             10 kg weight



         .


                                     concrete                clamp




                                       Diagram 7
        (a)   What is concrete?

               ……………………………………………………………………………………………………….

               …………………………………………………………………………………………………….....
                                                                    [3 marks]
        (b)   What is the material used to reinforce concrete?
              Why is this material able to strengthen the concrete?

               …………………………………………………………………………..……………………….….

               ………………………………………………………………………….…..…………………….....

               …………………………………………………………………………….………………………...

              …………………………………………………………………………………………………........
                                                      [6 marks]
        (c ) State three uses of reinforced concrete.

               ………………………………………………………………………..…………………………….

               ………………………………………………………………………..………………………….....

               ………………………………………………………………………….………………………….

                                                                                                         [6 marks]



Chemistry Perfect Score Module Form 4 2010 Set 5                                                                89
Set 5                                        Manufactured Substances in Industry Perfect Score F4       2010


        (d) State the problem statement for this experiment.

               …………………………………………………………………………………….………………….

                …………………………………………………………………………………………………….....
                                                     [3 marks]
        (e)   Based on the experiment above, state
              (i)   the manipulated variable.

                      ...........…………………………………………………………………………………………..
              (ii)    the responding variable.

                      ...........………………………………………………………………………………………….
              (iii)   the fixed variable.

                    ..........…………………………………………………………………………………………
                                                                                                            [3 marks]
        (f)   What is the operational definition of strength of the composite material in this experiment..

              …………….……………………………………………………………………..……………………

             ……………………………………………………………….…………………..……………………
                                                                                                [3 marks]
        (g) A commonly used composite material is photochromic glass which is made by embedding
            glass with silver chloride.

              (i)     State two uses of photochromic glass.

                     …………………..................……………………………………………………...………………

                  …………………………………..................………………………………………...……………
                                                                                   [3 marks]
              (ii) Describe how silver chloride can be prepared in the laboratory.

                     ……………………….................…………………………………………….…………………

                     ………………………................……………………………………………..…………………

                     ……………………………................…………………………………………………………
                                                                     [3 marks]




Chemistry Perfect Score Module Form 4 2010 Set 5                                                                  90
Set 5                                        Manufactured Substances in Industry Perfect Score F4         2010


PAPER 3: ESSAY




                           Kitchen utensils such as pan, pots, spoons and forks rust easily if they
                           are made from iron. To overcome the problem of rusting, kitchen
                           utensils are made from steel.



8.      Referring to the explanation above, plan a laboratory experiment to compare the rusting of iron and steel.

        Your experiment should cove the following items:

        (a)   Statement of problem
        (b)   Variables
        (c)   Hypotheses
        (d)   List of materials and apparatus
        (e)   Experimental procedure
        (f)   Tabulation of data




Chemistry Perfect Score Module Form 4 2010 Set 5                                                                     91

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Chemistry perfect-score-module-form-4-set-5

  • 1. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 PAPER 2 : SRUCTURE 1 Ammonia is produced in mass quantities in industry through a process as shown in diagram 1 below. Nitrogen Gas Catalyst chamber Ammonia gas Hydrogen gas Diagram 1 (a) State the name of the process for the production of ammonia in industry. ............................................................................................................................................................... [1 mark] (b) Write an equation for the process stated in (a)? .............................................................................................................................................................. [1 mark] (c) State the catalyt used in this process? ............................................................................................................................................................... [1 mark] (d) Other than the use of catalyst, state two conditions required for optimum production of ammonia. ............................................................................................................................................................... [1 mark] (e) Ammonia react with sulphuric acid to form a fertilizer.Name the fertilizer. ............................................................................................................................................................... [1 mark] (f) The reaction between ammonia and carbon dioxide produce urea, CO(NH2)2 and water. (i) Write the equation for the reaction. ...................................................................................................................................................... [1 mark] (ii) Determine the percentage by mass of nitrogen in urea. [Relative atomic mass ; H,1; C,12; N,14; O,16 ] [2 marks] (g) Aqueous ammonia can be used as a reagent to identify cations. State the observation when aqueous ammonia is slowly added until excess to a solution containing Cu2+ ion. ................................................................................................................................................................ ............................................................................................................................................................... [2 marks] Chemistry Perfect Score Module Form 4 2010 Set 5 82
  • 2. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 2. Diagram 2 shows a flow chart for the formation of Salt A through Process X and Process Y. Process Sulphur Sulphur dioxide X Sulphur trioxide Nitrogen Process Ammonia Sulphuric Acid Hydrogen Y Salt A Diagram 2 (a) Name (i) Process X : .................................................................................................... (ii) Process Y : .................................................................................................... [2 marks ] (b) (i) Write the equation for the formation of sulphur trioxide in Process X .................................................................................................................................................... [1 mark] (ii) State the catalyst used in Process X ................................................................................................................................................... [1 mark ] (c) (i) Write the equation for the formation of ammonia in Process Y ................................................................................................................................................... [1 mark ] (ii) State the optimum temperature and pressure for Process Y Temperature:.................................... Pressure:................................................... [1 mark ] (d) (i) Name salt A ..................................................................................................................................................... [1 mark ] (ii) Write the formula for salt A ..................................................................................................................................................... [ 1 mark] Chemistry Perfect Score Module Form 4 2010 Set 5 83
  • 3. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 (iii) Calculate the percentage of nitrogen by mass in salt A . Given relative atomic mass H = 1, N = 14 , O = 16, S = 32 [2 mark ] (e) State one use of sulphuric acid in everyday life.. .............................................................................................................................................................. [1 mark ] 3 Table 3 shows certain polymers and monomers for a polymerization process. Monomer Polymer Amino acid Starch Ethene Chloroethene Polychloroethene(PVC) Natural rubber Table 3 (a) What is meant by polymer? ................................................................................................................................................................ [ 1 mark ] (b) Complete Table 2 by writing the correct polymer or monomer for the respective monomer or polymer. [4 marks] (c) Draw the structural formula for the polymer formed from the polymerization of ethene. [ 1 mark ] (d) Diagram 3 shows the structural formula for the polymer polychloroethene or PVC. H H H H H H | | | | | | C C C C C C | | | | | | H Cl H Cl H Cl Diagram 3 Chemistry Perfect Score Module Form 4 2010 Set 5 84
  • 4. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 (i) Draw the structural for the monomer of polychloroethene. [ 1 mark ] (ii) In the system for water supply to homes, PVC pipes are widely used to replace metal pipes. State one advantage of using PVC pipes compared to using metal pipes in terms of their chemical properties. ..................................................................................................................................................... [ 1 mark ] (e) Classify the polymers in Table 3 into natural polymers and synthetic polymers. Natural polymer Synthetic polymer [ 2 marks ] PAPER 2 : ESSAY 4. (a) Diagram 4 shows the arrangement of atoms in pure copper and an alloy of copper, brass. Pure copper brass Diagram 4 (i) Explain why is pure copper softer than its alloy. [3 marks] (ii) Explain why the alloy, brass is stronger than pure copper. [3 marks] (iii) State the aim of alloying. [3 marks] Chemistry Perfect Score Module Form 4 2010 Set 5 85
  • 5. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 (b) (i) Explain why pure aluminium is not suitable for building bodies of planes. [2 marks] (ii) State the alloy suitable for building bodies of planes and give reasons for your answer [4 marks] (c) (i) Malaysia is proud of the products from pewter as souvenirs for tourists. Name the main metal and the foreign metal in pewter. [2 marks] (ii) Besides hardness, state three advantages of the alloy pewter to its pure metal. [ 3 marks] 5. (a) (i) What is meant by the term ‘polymers’?. (ii) Name two examples of synthetic polymers. For each example , state its monomer and one common use. [ 7 marks ] (b) (i) What is meant by the term ‘composite material’?. (ii) Name two examples of composite materials and their respective uses. [ 5 marks ] (c) Diagram 5 shows the waste products from a factory which affect the quality of the environment. a. amples/uses b. pollution Sulphur dioxide gas Factory actory Building Toxic waste Diagram 5 Based on diagram 5, describe how the waste products affect the quality of the environment. Your description should include the following aspects:  Source of pollutants  Process  Effect [ 8 marks ] Chemistry Perfect Score Module Form 4 2010 Set 5 86
  • 6. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 PAPER 3 : STRUCTURE 6. Diagram 6 shows the set up of apparatus of an experiment to compare hardness of copper and brass. The steps of carrying out the experiment are as follows. 1.A steel ball-bearing is taped onto a copper of block . 2. A 1-kg weight is hung at a height of 50 cm 1 kg above the copper block . weight 3. The weight is allowed to drop onto the ball bearing. Metre 4.The diameter of the dent produced by the ball ruler bearing on the copper block is measured. 5. Steps 1 to 4 are repeated on other parts of the copper block to obtain an average value for the diameter of dents. Steel 6. Experiment is repeated by using brass block to ball replace copper block. bearing Copper block Diagram 6 Table 6 shows the results of the experiment Experiment 1 2 3 Average diameter/ cm Diameter of dent on copper block/ cm 0.5 0.6 0.5 Diameter of dent on brass block/cm 0.3 0.3 0.2 Table 6 (a) Based on Table 6, record the average diameter of dents in the space provided. [3 marks] Chemistry Perfect Score Module Form 4 2010 Set 5 87
  • 7. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 (b) Give a statement to describe the operational definition of the hardness based on this experiment. ………………………………..………...…………………………….………………………….… ………………………………..………...…………………………………………………….…… [3 marks] (c) Complete table below. Name of variables Action to be taken (i) Manipulated variable: (i) The way to manipulate variable: ………………………………………………… ………………………………………………… ………………………………………………… ………………………………………………… (ii) Responding variable: (ii) Way to observe in the responding variable: ………………………………………………… ………………………………………………… ………………………………………………… ………………………………………………… (iii) Fixed variable: (iii) The way to maintain the fixed variable: .. ……………………………………………… ………………………………………………… ………………………………………………… ………………………………………………… [6 marks] (d) State the hypothesis for this experiment. ...……………………………...……………………………………………………………………… [3 marks] (e) Classify the following materials into pure metals and alloy. Iron, steel, copper, aluminium Duralumin, Bronze, [3 marks] Chemistry Perfect Score Module Form 4 2010 Set 5 88
  • 8. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 7. Concrete and reinforced concrete are two types of composite materials. Diagram 7 shows an experiment to investigate the strength of concrete and reinforced concrete. The 10kg weight is dropped from a fixed height. 10 kg weight . concrete clamp Diagram 7 (a) What is concrete? ………………………………………………………………………………………………………. ……………………………………………………………………………………………………..... [3 marks] (b) What is the material used to reinforce concrete? Why is this material able to strengthen the concrete? …………………………………………………………………………..……………………….…. ………………………………………………………………………….…..……………………..... …………………………………………………………………………….………………………... …………………………………………………………………………………………………........ [6 marks] (c ) State three uses of reinforced concrete. ………………………………………………………………………..……………………………. ………………………………………………………………………..…………………………..... ………………………………………………………………………….…………………………. [6 marks] Chemistry Perfect Score Module Form 4 2010 Set 5 89
  • 9. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 (d) State the problem statement for this experiment. …………………………………………………………………………………….…………………. ……………………………………………………………………………………………………..... [3 marks] (e) Based on the experiment above, state (i) the manipulated variable. ...........………………………………………………………………………………………….. (ii) the responding variable. ...........…………………………………………………………………………………………. (iii) the fixed variable. ..........………………………………………………………………………………………… [3 marks] (f) What is the operational definition of strength of the composite material in this experiment.. …………….……………………………………………………………………..…………………… ……………………………………………………………….…………………..…………………… [3 marks] (g) A commonly used composite material is photochromic glass which is made by embedding glass with silver chloride. (i) State two uses of photochromic glass. …………………..................……………………………………………………...……………… …………………………………..................………………………………………...…………… [3 marks] (ii) Describe how silver chloride can be prepared in the laboratory. ……………………….................…………………………………………….………………… ………………………................……………………………………………..………………… ……………………………................………………………………………………………… [3 marks] Chemistry Perfect Score Module Form 4 2010 Set 5 90
  • 10. Set 5 Manufactured Substances in Industry Perfect Score F4 2010 PAPER 3: ESSAY Kitchen utensils such as pan, pots, spoons and forks rust easily if they are made from iron. To overcome the problem of rusting, kitchen utensils are made from steel. 8. Referring to the explanation above, plan a laboratory experiment to compare the rusting of iron and steel. Your experiment should cove the following items: (a) Statement of problem (b) Variables (c) Hypotheses (d) List of materials and apparatus (e) Experimental procedure (f) Tabulation of data Chemistry Perfect Score Module Form 4 2010 Set 5 91