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Chapter Menu Energy and Chemical Change Section 15.1 Energy Section 15.2   Heat Section 15.3   Thermochemical Equations Section 15.4   Calculating Enthalpy Change Section 15.5 Reaction Spontaneity Exit Click a hyperlink or folder tab to view the corresponding slides.
Section 15-1 Section 15.1  Energy ,[object Object],temperature:   a measure of the average kinetic energy of the particles in a sample of matter ,[object Object],[object Object],[object Object]
Section 15-1 Section 15.1  Energy  (cont.) energy law of conservation of energy chemical potential energy heat calorie joule specific heat Energy can change form and flow, but it is always conserved.
Section 15-1 The Nature of Energy ,[object Object],[object Object],[object Object],[object Object]
Section 15-1 The Nature of Energy  (cont.) ,[object Object]
Section 15-1 The Nature of Energy  (cont.) ,[object Object],[object Object],[object Object],[object Object]
Section 15-1 Measuring Heat ,[object Object],[object Object],[object Object]
Section 15-1 Measuring Heat  (cont.)
Section 15-1 Specific Heat ,[object Object],[object Object]
Section 15-1 Specific Heat  (cont.) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],Section 15-1 Section 15.1 Assessment The heat required to raise one gram of  a substance by one degree Celsius is called ____.  A. joule   B. calorie   C. specific heat   D. energy
[object Object],[object Object],[object Object],[object Object],Section 15-1 Section 15.1 Assessment Which of the following is an example of chemical potential energy?   A. the moon orbiting Earth   B. a car battery   C. a compressed spring   D. a roller coaster at the top of a hill
End of Section 15-1
Section 15-2 Section 15.2  Heat ,[object Object],pressure:   force applied per unit area ,[object Object]
Section 15-2 Section 15.2  Heat  (cont.) calorimeter thermochemistry system surroundings The enthalpy change for a reaction is the enthalpy of the products minus the enthalpy of the reactants. universe enthalpy enthalpy (heat) of reaction
Section 15-2 Calorimetry ,[object Object]
Section 15-2 Chemical Energy and the Universe ,[object Object],[object Object]
Section 15-2 Chemical Energy and the Universe  (cont.) ,[object Object],[object Object]
Section 15-2 Chemical Energy and the Universe  (cont.) ,[object Object],[object Object],[object Object],[object Object],[object Object]
Section 15-2 Chemical Energy and the Universe  (cont.) ,[object Object],[object Object]
Section 15-2 Chemical Energy and the Universe  (cont.)
Section 15-2 Chemical Energy and the Universe  (cont.)
[object Object],[object Object],[object Object],[object Object],Section 15-2 Section 15.2 Assessment In thermochemistry, the specific part  of the universe you are studying is  called ____.   A. system   B. area   C. enthalpy   D. surroundings
[object Object],[object Object],[object Object],[object Object],Section 15-2 Section 15.2 Assessment What is the heat content of a system at constant pressure called?  A. heat of reaction   B. heat of the system   C. enthalpy   D. entropy
End of Section 15-2
Section 15-3 Section 15.3  Thermochemical Equations ,[object Object],combustion reaction:   a chemical reaction that occurs when a substance reacts with oxygen, releasing energy in the form of heat and light  ,[object Object],[object Object]
Section 15-3 Section 15.3  Thermochemical Equations  (cont.) thermochemical equation enthalpy (heat) of combustion molar enthalpy (heat) of vaporization molar enthalpy (heat) of fusion Thermochemical equations express the amount of heat released or absorbed by chemical reactions.
Section 15-3 Writing Thermochemical Equations ,[object Object],[object Object]
Section 15-3 Writing Thermochemical Equations  (cont.)
Section 15-3 Changes of State ,[object Object],[object Object]
Section 15-3 Changes of State  (cont.)
Section 15-3 Changes of State  (cont.)
Section 15-3 Combustion Reactions ,[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],Section 15-3 Section 15.3 Assessment The amount of energy required to melt one mole of a solid is called ____.  A. molar enthalpy of vaporization   B. molar enthalpy of melting   C. molar enthalpy of fusion   D. molar enthalpy of condensation
[object Object],[object Object],[object Object],[object Object],Section 15-3 Section 15.3 Assessment A thermochemical equation specifies about changes in ____.  A. temperature   B. pressure   C. enthalpy   D. molar mass
End of Section 15-3
Section 15-4 Section 15.4  Calculating Enthalpy Change ,[object Object],allotrope:   one of two or more forms of an element with different structures and properties when they are in the same state  ,[object Object],[object Object],[object Object]
Section 15-4 Section 15.4  Calculating Enthalpy Change  (cont.) Hess’s law standard enthalpy (heat) of formation The enthalpy change for a reaction can be calculated using Hess’s law.
Section 15-4 Hess's Law ,[object Object]
Section 15-4 Hess's Law  (cont.)
Section 15-4 Standard Enthalpy (Heat) of Formation ,[object Object]
Section 15-4 Standard Enthalpy (Heat) of Formation  (cont.) ,[object Object],[object Object]
Section 15-4 Standard Enthalpy (Heat) of Formation  (cont.)
Section 15-4 Standard Enthalpy (Heat) of Formation  (cont.) ,[object Object],[object Object]
Section 15-4 Standard Enthalpy (Heat) of Formation  (cont.)
[object Object],[object Object],[object Object],[object Object],Section 15-4 Section 15.4 Assessment What is the enthalpy of oxygen in its standard state?  A. 0.00 kJ   B. 15.99 kJ   C. 100.0 kJ   D. 8.00 kJ
[object Object],[object Object],[object Object],[object Object],Section 15-4 Section 15.4 Assessment Two or more thermochemical reactions can be summed to determine the overall enthalpy changes based on what law?  A. Boyle’s law   B. Hess’s law   C. Gay-Lussac’s law   D. law of conservation of energy
End of Section 15-4
Section 15-5 Section 15.5  Reaction Spontaneity ,[object Object],vaporization:   the energy-requiring process by which a liquid changes to a gas or vapor  ,[object Object]
Section 15-5 Section 15.5  Reaction Spontaneity  (cont.) spontaneous process entropy second law of thermodynamics free energy Changes in enthalpy and entropy determine whether a process is spontaneous.
Section 15-5 Spontaneous Processes ,[object Object],[object Object]
Section 15-5 Spontaneous Processes  (cont.) ,[object Object]
Section 15-5 Spontaneous Processes  (cont.) ,[object Object],[object Object],[object Object]
Section 15-5 Spontaneous Processes  (cont.) ,[object Object],[object Object],[object Object]
Section 15-5 Spontaneous Processes  (cont.) ,[object Object],[object Object],[object Object]
Section 15-5 Entropy, the Universe, and Free Energy ,[object Object],[object Object],[object Object]
Section 15-5 Entropy, the Universe, and Free Energy  (cont.) ,[object Object],[object Object],[object Object]
Section 15-5 Entropy, the Universe, and Free Energy  (cont.) ,[object Object],[object Object]
Section 15-5 Entropy, the Universe, and Free Energy  (cont.) ,[object Object]
[object Object],[object Object],[object Object],[object Object],Section 15-5 Section 15.5 Assessment What is the measure of randomness in a system?  A. enthalpy   B. entropy   C. free energy   D. Gibbs free energy
[object Object],[object Object],[object Object],[object Object],Section 15-5 Section 15.5 Assessment Energy that is available to do work is ____.  A. enthalpy   B. entropy   C. random molecular motion   D. free energy
End of Section 15-5
Resources Menu Chemistry Online Study Guide Chapter Assessment Standardized Test Practice Image Bank Concepts in Motion
Study Guide 1 Section 15.1  Energy Key Concepts ,[object Object],[object Object],[object Object],[object Object]
Study Guide 2 Section 15.2  Heat Key Concepts ,[object Object],[object Object],[object Object]
Study Guide 3 Section 15.3  Thermochemical  Equations Key Concepts ,[object Object],[object Object],[object Object]
Study Guide 4 Section 15.4  Calculating Enthalpy  Change Key Concepts ,[object Object],[object Object]
Study Guide 5 Section 15.5  Reaction Spontaneity Key Concepts ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],Chapter Assessment 1 Which represents the larger amount of energy?  A. 1 calorie B. 1000 calories   C. 10 kilocalories   D. they are all equal
[object Object],[object Object],[object Object],[object Object],Chapter Assessment 2 What is the universe when using a bomb-calorimeter to measure heat absorbed by a substance in a process?   A. the substance in the calorimeter   B. the calorimeter itself   C. the water in the calorimeter   D. the calorimeter and all  its contents
[object Object],[object Object],[object Object],[object Object],Chapter Assessment 3 In which example is the Δ H ° positive?   A. an ice cube melting   B. condensation forming on  cold glass of water   C. molten lava cooling to  form solid rock   D. water vapor changing  directly into frost on windows
[object Object],[object Object],[object Object],[object Object],Chapter Assessment 4 The standard enthalpy of an element in its standard state is ____.  A. 0.00 calories   B. 0.00°C   C. 0.00 kilocalories   D. 0.00 kJ
[object Object],[object Object],[object Object],[object Object],Chapter Assessment 5 Spontaneous processes always result in:  A. an increase in entropy   B. a decrease in entropy   C. a decrease in randomness   D. an increase in enthalpy
[object Object],[object Object],[object Object],[object Object],STP 1 The specific heat of ethanol is 2.4 J/g ● C.  How many degrees Celsius can a 50.0g sample be raised with 2400 J of energy?   A. 10°   B. 20°   C. 30°   D. 40°
[object Object],[object Object],[object Object],[object Object],STP 2 What is the measure of the number of possible ways that the energy in a system can be distributed?   A. free energy  B. Hess's law C. enthalpy D. entropy
[object Object],[object Object],[object Object],[object Object],STP 3 Energy stored in chemical bonds is ____.  A. free energy   B. kinetic energy   C. specific heat   D. chemical potential energy
[object Object],[object Object],[object Object],[object Object],STP 4 The first law of thermodynamics states:  A. matter is neither created nor destroyed  in chemical reactions   B. energy is neither created nor  destroyed in chemical reactions   C. spontaneous processes always  proceed in such a way that the  entropy of the universe increases   D. free energy is random motion  of particles
[object Object],[object Object],[object Object],[object Object],STP 5 ____ energy is energy of motion.  A. Free   B. Kinetic   C. Enthalpy   D. Chemical potential
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CIM Figure 15.5	 Calorimetry Figure 15.10	Heat Flow in Endothermic and Exothermic Reactions Table 15.6	Reaction Spontaneity
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CHAPTER MENU ENERGY AND CHEMICAL CHANGE

  • 1.  
  • 2. Chapter Menu Energy and Chemical Change Section 15.1 Energy Section 15.2 Heat Section 15.3 Thermochemical Equations Section 15.4 Calculating Enthalpy Change Section 15.5 Reaction Spontaneity Exit Click a hyperlink or folder tab to view the corresponding slides.
  • 3.
  • 4. Section 15-1 Section 15.1 Energy (cont.) energy law of conservation of energy chemical potential energy heat calorie joule specific heat Energy can change form and flow, but it is always conserved.
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  • 9. Section 15-1 Measuring Heat (cont.)
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  • 16. Section 15-2 Section 15.2 Heat (cont.) calorimeter thermochemistry system surroundings The enthalpy change for a reaction is the enthalpy of the products minus the enthalpy of the reactants. universe enthalpy enthalpy (heat) of reaction
  • 17.
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  • 22. Section 15-2 Chemical Energy and the Universe (cont.)
  • 23. Section 15-2 Chemical Energy and the Universe (cont.)
  • 24.
  • 25.
  • 27.
  • 28. Section 15-3 Section 15.3 Thermochemical Equations (cont.) thermochemical equation enthalpy (heat) of combustion molar enthalpy (heat) of vaporization molar enthalpy (heat) of fusion Thermochemical equations express the amount of heat released or absorbed by chemical reactions.
  • 29.
  • 30. Section 15-3 Writing Thermochemical Equations (cont.)
  • 31.
  • 32. Section 15-3 Changes of State (cont.)
  • 33. Section 15-3 Changes of State (cont.)
  • 34.
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  • 39. Section 15-4 Section 15.4 Calculating Enthalpy Change (cont.) Hess’s law standard enthalpy (heat) of formation The enthalpy change for a reaction can be calculated using Hess’s law.
  • 40.
  • 41. Section 15-4 Hess's Law (cont.)
  • 42.
  • 43.
  • 44. Section 15-4 Standard Enthalpy (Heat) of Formation (cont.)
  • 45.
  • 46. Section 15-4 Standard Enthalpy (Heat) of Formation (cont.)
  • 47.
  • 48.
  • 50.
  • 51. Section 15-5 Section 15.5 Reaction Spontaneity (cont.) spontaneous process entropy second law of thermodynamics free energy Changes in enthalpy and entropy determine whether a process is spontaneous.
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  • 64. Resources Menu Chemistry Online Study Guide Chapter Assessment Standardized Test Practice Image Bank Concepts in Motion
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  • 80. IB Menu Click on an image to enlarge.
  • 81. IB 1
  • 82. IB 2
  • 83. IB 3
  • 84. IB 4
  • 85. IB 5
  • 86. IB 6
  • 87. IB 7
  • 88. IB 8
  • 89. IB 9
  • 90. IB 10
  • 91. IB 11
  • 92. IB 12
  • 93. IB 13
  • 94. IB 14
  • 95. CIM Figure 15.5 Calorimetry Figure 15.10 Heat Flow in Endothermic and Exothermic Reactions Table 15.6 Reaction Spontaneity
  • 96. Help Click any of the background top tabs to display the respective folder. Within the Chapter Outline, clicking a section tab on the right side of the screen will bring you to the first slide in each respective section. Simple navigation buttons will allow you to progress to the next slide or the previous slide. The “Return” button will allow you to return to the slide that you were viewing when you clicked either the Resources or Help tab. The Chapter Resources Menu will allow you to access chapter specific resources from the Chapter Menu or any Chapter Outline slide. From within any feature, click the Resources tab to return to this slide. To exit the presentation, click the Exit button on the Chapter Menu slide or hit Escape [Esc] on your keyboards while viewing any Chapter Outline slide.
  • 97. End of Custom Shows This slide is intentionally blank.