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Reaction kinetics
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],Rate = gradient =  conc   example units are mol s -1   time Now we find gradient at various concentrations and plot rate vs concentration [H 2 O 2} ] Time
rate concentration a) In this case the rate    concentration. When rate is directly proportional to the concentration we call this 1 st  order with respect to the concentration of the reactant we are monitoring
rate concentration b) In this case the rate is independent of the concentration.  We call this zero order with respect to the reactant we are monitoring
rate concentration c) We call this one 2 nd  order with respect to the reactant we are monitoring
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
2.4 x 10 -2 6 x 10 -3 4 x 10 -3 1.2 x 10 -2 6 x 10 -3 2 x 10 -3 3 x 10 -3  3 x 10 -3 2 x 10 -3 Initial rate mol/L/h Initial conc B mol/l Initial conc A mol/l
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]

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9 Reaction Kinetics

  • 2.
  • 3.
  • 4. rate concentration a) In this case the rate  concentration. When rate is directly proportional to the concentration we call this 1 st order with respect to the concentration of the reactant we are monitoring
  • 5. rate concentration b) In this case the rate is independent of the concentration. We call this zero order with respect to the reactant we are monitoring
  • 6. rate concentration c) We call this one 2 nd order with respect to the reactant we are monitoring
  • 7.
  • 8.
  • 9.
  • 10.
  • 11.
  • 12. 2.4 x 10 -2 6 x 10 -3 4 x 10 -3 1.2 x 10 -2 6 x 10 -3 2 x 10 -3 3 x 10 -3 3 x 10 -3 2 x 10 -3 Initial rate mol/L/h Initial conc B mol/l Initial conc A mol/l
  • 13.
  • 14.
  • 15.
  • 16.
  • 17.