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International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
185
EVAPORATION SUPPRESSION FROM WATER SURFACES USING
CHEMICAL FILMS
Dr. Umesh J. Kahalekar1
, Hastimal S. Kumawat2
1
(Professor and Head- Dept. of Civil Engineering, Government College of Engineering
Aurangabad-431005 (M.S.), India)
2
(Post Graduate Student- Government College of Engineering Aurangabad-431005 (M.S.),
India)
ABSTRACT
The extremely high rate of Evaporation from water surfaces day by day is reducing
the optimal utilization of water reservoirs. The work presented in this study aims to investing
the use of Chemical films as Evapo Suppretants for reduction of evaporation from the open
water surface so as to increase the storage efficiency. Particular emphasis will be on practical
procedures and techniques that professionals can use to estimate and/or to suppress
evaporation from shallow water bodies. The natural evaporation loss taking place from pan
evaporimeters of two alcohols were observed and compared. The important meteorological
factors affecting the natural evaporation such as Temperature, Relative Humidity, Wind
Velocity, Sunshine Hours, etc. were also observed.
Cetyl and Stearyl Alcohols were selected to reduce the evaporation during the study
period in Aurangabad region with two US Class-A evaporation pans. Different concentrations
of Cetyl and Stearyl alcohols were used in different pans. First pan EP1 was filled with water
without adding chemical while in pan EP2 alcohols was added. The preliminary results of the
study indicated that evaporation rate from surface water was reduced overall upto 28% in pan
EP2 as compared to pan EP1 while the Cetyl alcohol individually gives the average reduction
is 27% and the Stearyl alcohol gives 27% and Both Cetyl and Stearyl Alcohol combine gives
the average reduction is 30%. The Penman’s Equation is used to compare the evaporation
values in evaporation pan 1.
Keywords: Cetyl & Stearyl Alcohols, Class-A Pan, Evaporation Reduction, Evaporation
Suppression, Penman’s equation
INTERNATIONAL JOURNAL OF CIVIL ENGINEERING AND
TECHNOLOGY (IJCIET)
ISSN 0976 – 6308 (Print)
ISSN 0976 – 6316(Online)
Volume 4, Issue 3, May - June (2013), pp. 185-196
© IAEME: www.iaeme.com/ijciet.asp
Journal Impact Factor (2013): 5.3277 (Calculated by GISI)
www.jifactor.com
IJCIET
© IAEME
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
186
1. INTRODUCTION
Water is one of the nature’s precious gifts, which sustains life on earth. Civilizations
over the world have prospered or perished depending upon the availability of this vital
resource. Water has been worshiped for life nourishing properties in all the scriptures. Vedas
have unequivocally eulogized water in all its virtuous properties.
The total water resources on earth are estimated to be around 1360 Million cubic km.
Out of which only about (33.5 Million cubic km) is fresh water. India possesses only 4% of
total average runoff of the rivers of the world although it sustains 16% of the world’s
population. The per capita availability of water in the country is only 1820 m3
/year, compared
to 40855 m3
/year in Brazil, 8902 m3
/year in USA, 2215 m3
/year in China, 2808 m3
/year in
Spain, 18162 m3
/year in Australia, 3351 m3
/year in France, 3614 m3
/year in Mexico and 3393
m3
/year in Japan. The total water resources of India are estimated to be around 1,869 Billion
cubic meters. Due to topographic, hydrological and other constraints, only about 690 BCM of
total surface water is considered as utilizable [1].
Due to high temperatures and arid conditions in about one third of the country, the
evaporation losses have been found to be substantial. Therefore, it is imperative to minimise
evaporation losses in the storages/water bodies.
Evaporation losses from on-farm storage can potentially be large, particularly in
irrigation areas in where up to 40% of storage volume can be lost each year to evaporation.
Reducing evaporation from water storage would allow additional crop production, water
trading or water for the environment. The need for prevention of enormous evaporation losses
assumes greater significance, in view of the predictable scarcity of water; the country will be
facing in future. It has been assessed that against the utilizable water resources of the order of
1123 BCM, the requirement by 2025 AD to be met from surface water resources will be
around 1093 BCM, thereby surplus by just 30 BCM[1, 2].
Due to intense agricultural practices, rapid increase in population, industrialization
and urbanization etc., scarcity of water is being increasingly felt. In the present scenario of
utmost strain on the water resources, of the country, it becomes necessary to conserve water
by reducing evaporation losses. National Water Policy-2002 under Para 19.1 emphasises that
evaporation losses should be minimised in drought-prone areas [1].
The internet was also browsed to search the information on any new researches or
identification of any new technology / chemicals to retard the evaporation rate. The search on
internet, resulted in finding some case studies done in this field in other countries, however,
the chemicals / technology used is the same. Some websites are from the manufacturers of
WER chemicals such as Hexadecanol or Octadecanol or Acilol claiming to have conducted
experiments in other countries towards evaporation control [3, 4, 5].
Chemical substances such as Cetyl and Stearyl alcohols can be sprayed periodically
on water surface to reduce evaporation. After a detailed review of the available evaporation
reduction methods, surface water cover technique was selected using Cetyl and Stearyl
alcohol emulsion substances to form a thin monomolecular film over water surface to reduce
evaporation [6]. This method has several advantages over other methods. It is economically
feasible due to low cost of substances and easily available. It mixes with water easily and
when added to large water surface; it forms a thin invisible film that reduces evaporation
considerably. It decomposes easily and doesn't dissolve in water.
There are several methods to measure evaporation from free water surfaces through
(US weather class-A pan), or more accurately by using energy balance equations. Due to
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
187
several factors including air movement and fluctuations of water surface, which affect the
accuracy of measurement of evaporation depth therefore, standard and well recognized
method of (US weather class-A pan) was selected for the present study [7].
The present study was conducted to measure the reduction of evaporation on
relatively small and controlled water surface of two pans (US weather class-A pan) with
continuous measurement of air temperature, relative humidity, wind velocity and evaporation
rates and evaluated the results in terms of efficiency in reducing evaporation. The evaporation
pan 2 was added with Cetyl and Stearyl alcohols as thin film on water surface to reduce
evaporation. Based on material safety data sheet, the substance does not have any harmful
effects on human beings, animals or plants however; further study is required to determine
the potential environmental, health and ecological impacts of the substance on aquatic
animals and plants [8,9,10].
2. MATERIALS AND METHODOLOGY
The study was conducted at Aurangabad (Marathwada region of M.S.) with the help
of a fully operated meteorological station with sensors to measure sunshine hours, air
temperature, wind velocity and relative humidity. Two US weather class-A pans were used
with an accurate measuring tool to measure daily water depth in the pans. A protection cover
was constructed to protect the pans from birds and other animals.
The amount of chemical films (Cetyl and Stearyl alcohols) added to the two
evaporation pans was calculated and applied to one of the pan for fifteen days duration. No
chemical was added to pan (EP1) to measure natural evaporation rate due to ambient
conditions and for comparison. In pan (EP2), 50 mg per m2
of water surface per day, to make
the effective substance in pan (EP2) is 58.35mg/day and as that of 100mg and 150 mg is
calculated.
A monolayer is formed on a water surface when long-chained alcohols such as Cetyl
alcohol (Hexadecanol) are spread across the water. The chemical spreads spontaneously
across the surface resulting in a layer only one molecule thick (about two millionths of a
millimetre). The molecules of the monolayer ‘stand’ on the surface because they are
amphiphilic i.e. they have a soluble end and an opposing insoluble end (Fig.1).
Figure 1 Monolayer molecules ‘standing’ on the water surface (courtesy Geoff Barnes,
University of Queensland)
Duration the entire study period (Jan-Sept 2012), Cetyl and Stearyl Alcohols was
sprayed daily in evaporation pan EP2 and meteorological parameters including air
temperature, relative humidity, wind speed and sunshine hours as well as water levels in two
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
188
pans were measured. The standard procedure was strictly followed and maintained during
measurements of the readings for accuracy and consistency of the results throughout the
duration of the study. All the pans were cleaned regularly to remove sediments from pans, if
any.
3. RESULTS AND DISCUSSION
The results of the study indicated that air temperature ranges from 15.0-41.0°C with
average of 34.5°C, while wind velocity ranges from 0.4-12 km/hr with average of 3.9 km/hr.
The relative humidity ranges from 25-95% with average of 66.8%. Similarly, the daily pan
evaporation rates ranges from 1-9.7 mm/day with average of 6.4 mm/day. The pan
evaporation rate reached its peak in June and it reached 9.7 mm/day.
Table1. Summary of the experiment results of the daily reduction of pan evaporation rates
for different months
Table 2. Summary of the experiment results - chemical wise reduction in percentage
Reduction using only
cetyl alcohol
Reduction using only
stearyl alcohol
Reduction using cetyl +
stearyl alcohol
23.13 22.66 25.28
27.07 26.73 29.67
33.85 31.98 41.88
21.06 24.48 25.73
26.17 28.01 25.21
Average
Reduction
26.26%
Average
Reduction
26.77%
Average
Reduction
29.55%
Table 1 shows the daily average evaporation rate for 8 months from January to
September. In table 2 the chemical wise reduction is shown. The average reduction recorded
using only Cetyl alcohol is about 26.26%. The average reduction recorded using only Stearyl
alcohol is about 26.77%. The average reduction recorded using Cetyl and Stearyl alcohol is
about 29.55%.
Duration
Evaporation
mm/day (EP1)
Evaporation
mm/day (EP2)
%
Reduction
16 Jan -31 Jan 5.41 4.16 23.13
01 Feb - 29 Feb 5.72 4.36 23.97
01 Mar -31 Mar 6.15 4.40 28.37
01 Apr - 30 Apr 7.55 5.26 30.29
01 May - 31 May 8.15 5.14 36.93
01 June - 21 June 7.11 5.40 23.76
22 Aug - 31 Aug 3.68 2.68 25.69
01 Sept -12 Sept 3.89 2.76 28.01
Average 5.96 4.27 27.52
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
189
Chemical and concentration wise reduction in percentage is shown in table 3.It is
cleared from this table as the concentration is increased the reduction is also increased while
the cetyl and stearyl alcohols combine perform better than other two concentrations and
chemicals. In table 4 the reduction in percent concentration wise is shown.
Table 3. Summary of the experiment results - chemical and concentration wise reduction in
percentage
Reduction using only cetyl alcohol
23.13 for
50mg/m2
/day
27.07 for
100mg/m2
/day
-- for
150mg/m2
/day21.06 26.17 33.85
22.09 Average 26.62 Average 33.85 Average
Reduction using only stearyl alcohol
22.66 for
50mg/m2
/day
26.73 for
100mg/m2
/day
-- for
150mg/m2
/day24.48 28.01 31.98
23.57 Average 27.37 Average 31.98 Average
Reduction using cetyl + stearyl alcohol
25.28 for
50mg/m2
/day
29.67 for
100mg/m2
/day
-- for
150mg/m2
/day25.73 25.21 41.88
25.51 Average 27.44 Average 41.88 Average
Table 4. Summary of the experiment results - concentration wise reduction in percentage
for 50mg/m2
/day for 100mg/m2
/day for 150mg/m2
/day
23.13 27.07 33.85
25.28 29.67 41.88
22.66 26.73 31.98
21.06 26.17 --
24.48 25.21 --
25.73 28.01 --
Avg. 23.72 Avg. 27.14 Avg. 35.90
Difference Between 50mg/m2
/day and 100mg/m2
/day: 3.42
Difference Between 100mg/m2
/day and 150mg/m2
/day: 8.76
The daily average pan evaporation rate for 4 summer months (March, April, May and
June) was measured as 6.15, 7.55, 8.15 and 7.11 mm/day, respectively. Thus, middle four
months (March to June) witnessed the highest evaporation rates due to high temperature and
low humidity.
The readings are validated with help of Penman’s equation for evaporation [11], the
following equation were used.
( )
0.00061 .
0.00061
n
a
e
Q
P E
L
E
P
∆
+
=
∆ +
 
 
  (1)
where,
Qnis the net solar radiation used in evaporation in cal/sq.cm
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
190
Qn= Qi (1– r) – Qb (2)
Qi is the incoming solar radiation
0
0.55i
n
Q Q a
N
= +
 
 
 
(3)
Q0 is the radiation in cal/cm2
/dayreceived at the top of the atmosphere
a = 0.29 cosθ (4)
θ is the latitude of the place
nis the actual number of sunshine hours in the day,
N is the maximum possible hours of bright sunshine
ris called the reflection coefficient or the albedo whose value may be taken as 0.05 for water
surface
Qbis the net outgoing longwave radiation
( )4
0.56 0.09 0.1 0.9b a
n
Q T e
N
σ= − +
 
 
 
(5)
σ is the Stefan-Boltzman constant
σ = 118.944 x 10-9
cal/cm2
/day/°K (6)
T is the mean daily temperature in °K
eais the actual vapour pressure of air in mm of mercury
100
. .
s
a
e
e
R H
= (7)
R. H. is the Relative Humidity in %
∆ is the slope of saturation vapour pressure curve at air temperature t in mb/°C
( )
2
4098
237.3
s
e
t
∆ =
+
(8)
esis the saturated vapour pressure corresponding to the mean daily air temperature
17.27
6.11exp
237.3
s
T
e
T
=
+
 
 
 
(9)
t is the air temperature in °C
Le is the latent heat of vaporization of water in cal/g which varies with the temperature and
can be obtained from
Le = 597.3 – 0.564 t (10)
P is the atmospheric pressure in kPa
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
191
5.26
293 0.0065
101.3
293
z
P
−
=
 
 
 
(11)
z is the elevation above sea level in m
Eais the evaporation from the water surface when water and air temperatures are equal
Ea= 0.35(0.5 + 0.54 V) (es - ea) (12)
V is in m/s measured at a height of 2 m above the free surface
The regression model is shown in Fig. 2 is drawn for the study period 16 January to
21 June. The data is best fitting by the regression analysis. The best fit for EP1got from model
is 45.94%. The best fit for using Penman’s equation got from model is about 46.1% and that
of EP2the best fit get from model is about 32.52%. These regression models are showing the
linearity of recorded data and Penman’s equation data.
The regression model shown in Fig. 3 indicates the study period between 16 Jan to 12
Sept. firstly it decided to check the efficiency of cetyl and Stearyl alcohols in summer
therefore the reading were taken for the period 16 Jan to 21 June. Whatever readings were not
available in the graph that is due to evaporation reading and other data are not recorded for
period 22 June to 21 Aug. the reading and other data were continues after this gap and
respective regression model is drawn for remaining period upto 12 Sept.
Figure 2. Linear regression model showing EP1, EP2 and evaporation using Penman's eqn
(depth in mm) {16 Jan -21 June}
y = 0.019x - 780.3
R² = 0.459
y = 0.01x - 406.1
R² = 0.325
y = 0.026x - 1078.
R² = 0.461
2.8
3.6
4.4
5.2
6.0
6.8
7.6
8.4
9.2
10.0
10.8
16/01/12
23/01/12
30/01/12
06/02/12
13/02/12
20/02/12
27/02/12
05/03/12
12/03/12
19/03/12
26/03/12
02/04/12
09/04/12
16/04/12
23/04/12
30/04/12
07/05/12
14/05/12
21/05/12
28/05/12
04/06/12
11/06/12
18/06/12
25/06/12
02/07/12
Evaporationmm/day
Days
Evaporation mm/day (EP1) Evaporation mm/day (EP2)
Evaporation Using Penman's Eqn Linear (Evaporation mm/day (EP1))
Linear (Evaporation mm/day (EP2)) Linear (Evaporation Using Penman's Eqn)
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
192
Figure 3. Linear regression model showing EP1, EP2 and evaporation using Penman's eqn
(depth in mm) {16 Jan -12 Sept}
After these observed data the respective regression models is plotted. From this model
it is observed that the model is not fitting to that extent. So, from all these studies it is
concluded that the films are not that much efficient in rainy season as that of in summer
season.
It is observed that splashing or overflowing of the pan may cause the flowing of
chemical film with it. The high wind velocity breaks or may breaks therefore no layer is form
and therefore water gets evaporated. Again the rain droplets may reduce the efficiency of the
chemical films.
The relationship of air temperature, wind velocities and relative humidity with the
evaporation was determined with the help of linear regression analysis of daily observed data.
A linear regression model for best fit of observed data for daily air temperature and daily
evaporation depth in mm for both pans (EP1and EP2) was developed as in Fig. 4.
y = -0.003x + 137.4
R² = 0.017
y = -0.003x + 151.1
R² = 0.050
y = 0.004x - 175.9
R² = 0.026
1.4
2.2
3.0
3.8
4.6
5.4
6.2
7.0
7.8
8.6
9.4
10.2
11.0 16/01/12
23/01/12
30/01/12
06/02/12
13/02/12
20/02/12
27/02/12
05/03/12
12/03/12
19/03/12
26/03/12
02/04/12
09/04/12
16/04/12
23/04/12
30/04/12
07/05/12
14/05/12
21/05/12
28/05/12
04/06/12
11/06/12
18/06/12
25/06/12
02/07/12
09/07/12
16/07/12
23/07/12
30/07/12
06/08/12
13/08/12
20/08/12
27/08/12
03/09/12
10/09/12
Evaporationmm/day
Days
Evaporation mm/day (EP1) Evaporation mm/day (EP2) Evaporation Using Penman's Eqn
Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2)) Linear (Evaporation Using Penman's Eqn)
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
193
Figure 4.Linear regression model for daily air temperature and daily evaporation
{16 Jan- 12 Sept}
The model indicated that there is a direct correlation between air temperatures with
the daily pan evaporation rates. Similarly, a linear regression model for best fit of observed
data for wind velocity and daily evaporation depth (mm) was developed as in Fig. 5.
Figure 5.Linear regression model for daily wind velocity and daily evaporation
{16 Jan- 12 Sept}
The model indicated that there is a direct correlation between wind velocities with the
daily pan evaporation rates. In addition, a simple regression model for best fit of observed
data for daily relative humidity and daily evaporation depth (mm) was developed as in Fig. 6.
y = 0.258x - 2.491
R² = 0.556
y = 0.144x - 0.420
R² = 0.412
0.0
2.0
4.0
6.0
8.0
10.0
12.0
0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0
Evaporationmm/day
Temperature °C
Evaporation mm/day (EP1) Evaporation mm/day (EP2)
Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2))
y = -0.296x + 7.565
R² = 0.179
y = -0.207x + 5.356
R² = 0.207
0.0
2.0
4.0
6.0
8.0
10.0
12.0
0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
Evaporationmm/day
Wind Velocity km/hr
Evaporation mm/day (EP1) Evaporation mm/day (EP2)
Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2))
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May
Figure 6.Linear regression model for daily relative humid
The model indicated that pan evaporation rates decreases as humidity increases and
that there is an inverse correlation between average daily relative humidity with the daily pan
evaporation rates. The results of
chemical film solution with different concentrations and without application in two different
evaporation pans from January to September is presented in
Figure 7.Cumulative daily evaporation
Similarly daily average gross evaporation rates for different months for two pans were
compared and the evaporation reductions in percentage were calculated. Table 1 show that
the average daily average gross evaporation rates and percentage of reduction of evaporation
rate for different months for two pans.
y =
y = -0.024x + 6.197
R² = 0.144
0.0
2.0
4.0
6.0
8.0
10.0
12.0
0.0 10.0 20.0 30.0
Evaporationmm/day
Evaporation mm/day (EP1)
Linear (Evaporation mm/day (EP1))
4.0
12.0
20.0
28.0
36.0
44.0
52.0
60.0
68.0
76.0
84.0
92.0
16-31
Jan
01-15
Feb
16-29
Feb
01-16
Mar
17
Evaporationmm
Evaporation mm/day (EP1)
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976
6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
194
Linear regression model for daily relative humidity and daily evaporation
{16 Jan- 12 Sept}
The model indicated that pan evaporation rates decreases as humidity increases and
that there is an inverse correlation between average daily relative humidity with the daily pan
evaporation rates. The results of the pan evaporation control experiment after adding
chemical film solution with different concentrations and without application in two different
evaporation pans from January to September is presented in Fig. 7.
Cumulative daily evaporation depth (mm) measured for two pans (EP
{16 Jan - 12 Sept}
Similarly daily average gross evaporation rates for different months for two pans were
compared and the evaporation reductions in percentage were calculated. Table 1 show that
ily average gross evaporation rates and percentage of reduction of evaporation
rate for different months for two pans.
y = -0.036x + 8.836
R² = 0.131
30.0 40.0 50.0 60.0 70.0 80.0
Relative Humidity %
Evaporation mm/day (EP2)
Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2))
17-31
Mar
01-15
Apr
16-30
Apr
01-16
May
17-31
May
01-07
June
08-14
June
15-21
June
22-28
Aug
Months
Evaporation mm/day (EP1) Evaporation mm/day (EP2)
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
June (2013), © IAEME
ity and daily evaporation
The model indicated that pan evaporation rates decreases as humidity increases and
that there is an inverse correlation between average daily relative humidity with the daily pan
the pan evaporation control experiment after adding
chemical film solution with different concentrations and without application in two different
depth (mm) measured for two pans (EP1 and EP2)
Similarly daily average gross evaporation rates for different months for two pans were
compared and the evaporation reductions in percentage were calculated. Table 1 show that
ily average gross evaporation rates and percentage of reduction of evaporation
90.0 100.0
Linear (Evaporation mm/day (EP2))
28 29 Aug-
4 Sept
05-12
Sept
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May
The pan evaporation rates are smaller in winter as compared to the summer months.
In general, evaporation rate from pan EP
when the recommended concentration was applied. Similarly, in table 4 the reduction in
percent concentration wise. The concentration where used as per recommendations it is
observed that 23.72 % reduction is achieved. If this
% average reduction is possible. If this quantity is tripled then the results are tremendously
increased i.e. about 35.90 % reduction is possible.
These findings confirmed that there is a significant reduction in
water surfaces when we applied the chemical films
highly feasible and cost effective to use the substance to reduce evaporation.
Figure 5.Monthly evaporation depth in mm {16 Jan
4. CONCLUSION
As the duration of rainy season and quantity of rainfall is reduced, the demand of
water is day by day increasing due to increase in population and Industrialization therefore,
the economic value also increases. Therefore the government should adopt the st
for storage and maximum utilization of rainwater. Protecting the stored water in water bodies
(Dams, Reservoirs, Lakes, etc.) from evaporation remains an integral part of sustainable
planning, especially during the summer hot months, when temperature is high and humidity
is low, which leads to extremely high rate evaporation from water surfaces. Chemical films
such as Cetyl and Stearyl alcohols are one of most feasible and cost effective evaporation
retardants which reduces evaporation significantly. The present study has confirmed that a
chemical film produces an invisible thin monomolecular film over water surface that
significantly reduces evaporation. The experimental study was conducted to demonstrate the
effectiveness of evaporation reduction on US weather class
different concentrations of 50, 100 and 150 mg/m
was reduced up to 28% as compared to without addition of chemical films. Therefore, these
chemicals are highly feasible and cost effective to apply the present evaporation reduction
technique on a large scale to a large number of reservoirs of
the water loss through evaporation from water surfaces.
2.4
3.0
3.6
4.2
4.8
5.4
6.0
6.6
7.2
7.8
8.4
16-31
Jan
01-15
Feb
16-29
Feb
01-16
Mar
17
Mar
Evaporationmm
Evaporation mm/day (EP1)
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976
6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
195
The pan evaporation rates are smaller in winter as compared to the summer months.
In general, evaporation rate from pan EP1 is reduced by 27.52% as compared to pan EP
when the recommended concentration was applied. Similarly, in table 4 the reduction in
percent concentration wise. The concentration where used as per recommendations it is
observed that 23.72 % reduction is achieved. If this quantity is doubled i.e. 100mg then 27.14
% average reduction is possible. If this quantity is tripled then the results are tremendously
about 35.90 % reduction is possible.
These findings confirmed that there is a significant reduction in evaporation from free
water surfaces when we applied the chemical films i.e. Cetyl and Stearyl alcohols and it is
highly feasible and cost effective to use the substance to reduce evaporation.
Monthly evaporation depth in mm {16 Jan - 12 Sept}
As the duration of rainy season and quantity of rainfall is reduced, the demand of
water is day by day increasing due to increase in population and Industrialization therefore,
the economic value also increases. Therefore the government should adopt the st
for storage and maximum utilization of rainwater. Protecting the stored water in water bodies
.) from evaporation remains an integral part of sustainable
planning, especially during the summer hot months, when temperature is high and humidity
is low, which leads to extremely high rate evaporation from water surfaces. Chemical films
d Stearyl alcohols are one of most feasible and cost effective evaporation
retardants which reduces evaporation significantly. The present study has confirmed that a
chemical film produces an invisible thin monomolecular film over water surface that
icantly reduces evaporation. The experimental study was conducted to demonstrate the
n reduction on US weather class-A pans adding chemical films of
different concentrations of 50, 100 and 150 mg/m2
/day. The study concluded that
was reduced up to 28% as compared to without addition of chemical films. Therefore, these
chemicals are highly feasible and cost effective to apply the present evaporation reduction
technique on a large scale to a large number of reservoirs of the Marathwada region to reduce
the water loss through evaporation from water surfaces.
17-31
Mar
01-15
Apr
16-30
Apr
01-16
May
17-31
May
01-07
June
08-14
June
15-21
June
22-28
Aug
Months
Evaporation mm/day (EP1) Evaporation mm/day (EP2)
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
June (2013), © IAEME
The pan evaporation rates are smaller in winter as compared to the summer months.
27.52% as compared to pan EP2
when the recommended concentration was applied. Similarly, in table 4 the reduction in
percent concentration wise. The concentration where used as per recommendations it is
100mg then 27.14
% average reduction is possible. If this quantity is tripled then the results are tremendously
evaporation from free
Cetyl and Stearyl alcohols and it is
As the duration of rainy season and quantity of rainfall is reduced, the demand of
water is day by day increasing due to increase in population and Industrialization therefore,
the economic value also increases. Therefore the government should adopt the strategic plans
for storage and maximum utilization of rainwater. Protecting the stored water in water bodies
.) from evaporation remains an integral part of sustainable
planning, especially during the summer hot months, when temperature is high and humidity
is low, which leads to extremely high rate evaporation from water surfaces. Chemical films
d Stearyl alcohols are one of most feasible and cost effective evaporation
retardants which reduces evaporation significantly. The present study has confirmed that a
chemical film produces an invisible thin monomolecular film over water surface that
icantly reduces evaporation. The experimental study was conducted to demonstrate the
A pans adding chemical films of
/day. The study concluded that evaporation
was reduced up to 28% as compared to without addition of chemical films. Therefore, these
chemicals are highly feasible and cost effective to apply the present evaporation reduction
the Marathwada region to reduce
28
Aug
29 Aug-
4 Sept
05-12
Sept
International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308
(Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME
196
REFERENCES
[1] R. Kumar, R. D. Singh and K. D. Sharma, Water resources of India, Current
Science89(5), 2005, 794-811.
[2] M. E. Jensen, Estimating Evaporation from Water Surfaces, CSU/ARS
Evapotranspiration Workshop, Fort Collins, CO, 2010, 1-27.
[3] W. J. Roberts, Evaporation Suppression from Water Surfaces, American Geophysical
Union, 38(5), 1957, 740-744.
[4] J. Walter, The use of Monomolecular Films to Reduce Evaporation, International Union
of Geodesy and Geophysics Assembly, Berkely, California, 1963, 39-48.
[5] E. H. Hobbs, Evaporation Reduction by Monomolecular Films the Influence of Water
Temperature and Application Rate on the Effectiveness of Cetyl Alcohol, 17-19.
[6] I. Craig, E. Schmidt and M. Scobie, Evaporation Control using Covers – some realistic
solutions for the irrigation industry National Centre for Engineering in Agriculture
(NCEA), University of Southern Queensland.
[7] Mohammed I. Al-Saud, Reduction of Evaporation from Water Surfaces-Preliminary
Assessment for Riyadh Region, Kingdom of Saudi Arabia, Research Journal of Soil and
Water Management, 1(1), 2010, 5-9.
[8] F. S. Ikweiri , H. Gabril , M. Jahawi and Y. Almatrdi, Evaluating the Evaporation
Water Loss from the Omar Muktar Open Water Reservoir, 12th
International Water
Technology Conference, IWTC12, Alexandria, Egypt, 2008, 893-899.
[9] G.T. Barnes, The potential for monolayers to reduce the evaporation of water from
large water storages, 95, 2008, 339-353.
[10] D.McJannet, F. Cook, J. Knight and S. Burn, Evaporation Reduction by Monolayers:
Overview, Modelling and Effectiveness, Urban Water Security Research Alliance
Technical Report, 6, 2008, 1-32.
[11] P. J. Rami Reddy, A text book of Hydrology (University Science Press, 2008) 207-233.
[12] U. J. Kahalekar, H. S. Kumawat, Evaporation suppression from water surfaces using
chemical films,International Conference on Sustainable Innovative Techniques in Civil
and Environmental Engineering, SITCEE – 2013, New Delhi, India, 2013, 38-43.
[13] Abdur Rahman, M. A. Zafor and Shantanu Kar, “Analysis and Comparision of Surface
Water Quality Parameters in and Around Dhaka City”, International Journal of Civil
Engineering & Technology (IJCIET), Volume 3, Issue 2, 2012, pp. 7 - 15,
ISSN Print: 0976 – 6308, ISSN Online: 0976 – 6316.
[14] C. P. Pise and Dr. S. A. Halkude, “Blend of Natural and Chemical Coagulant for
Removal of Turbidity in Water”, International Journal of Civil Engineering &
Technology (IJCIET), Volume 3, Issue 2, 2012, pp. 188 - 197, ISSN Print:
0976 – 6308, ISSN Online: 0976 – 6316.

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Evaporation suppression from water surfaces using chemical films

  • 1. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 185 EVAPORATION SUPPRESSION FROM WATER SURFACES USING CHEMICAL FILMS Dr. Umesh J. Kahalekar1 , Hastimal S. Kumawat2 1 (Professor and Head- Dept. of Civil Engineering, Government College of Engineering Aurangabad-431005 (M.S.), India) 2 (Post Graduate Student- Government College of Engineering Aurangabad-431005 (M.S.), India) ABSTRACT The extremely high rate of Evaporation from water surfaces day by day is reducing the optimal utilization of water reservoirs. The work presented in this study aims to investing the use of Chemical films as Evapo Suppretants for reduction of evaporation from the open water surface so as to increase the storage efficiency. Particular emphasis will be on practical procedures and techniques that professionals can use to estimate and/or to suppress evaporation from shallow water bodies. The natural evaporation loss taking place from pan evaporimeters of two alcohols were observed and compared. The important meteorological factors affecting the natural evaporation such as Temperature, Relative Humidity, Wind Velocity, Sunshine Hours, etc. were also observed. Cetyl and Stearyl Alcohols were selected to reduce the evaporation during the study period in Aurangabad region with two US Class-A evaporation pans. Different concentrations of Cetyl and Stearyl alcohols were used in different pans. First pan EP1 was filled with water without adding chemical while in pan EP2 alcohols was added. The preliminary results of the study indicated that evaporation rate from surface water was reduced overall upto 28% in pan EP2 as compared to pan EP1 while the Cetyl alcohol individually gives the average reduction is 27% and the Stearyl alcohol gives 27% and Both Cetyl and Stearyl Alcohol combine gives the average reduction is 30%. The Penman’s Equation is used to compare the evaporation values in evaporation pan 1. Keywords: Cetyl & Stearyl Alcohols, Class-A Pan, Evaporation Reduction, Evaporation Suppression, Penman’s equation INTERNATIONAL JOURNAL OF CIVIL ENGINEERING AND TECHNOLOGY (IJCIET) ISSN 0976 – 6308 (Print) ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), pp. 185-196 © IAEME: www.iaeme.com/ijciet.asp Journal Impact Factor (2013): 5.3277 (Calculated by GISI) www.jifactor.com IJCIET © IAEME
  • 2. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 186 1. INTRODUCTION Water is one of the nature’s precious gifts, which sustains life on earth. Civilizations over the world have prospered or perished depending upon the availability of this vital resource. Water has been worshiped for life nourishing properties in all the scriptures. Vedas have unequivocally eulogized water in all its virtuous properties. The total water resources on earth are estimated to be around 1360 Million cubic km. Out of which only about (33.5 Million cubic km) is fresh water. India possesses only 4% of total average runoff of the rivers of the world although it sustains 16% of the world’s population. The per capita availability of water in the country is only 1820 m3 /year, compared to 40855 m3 /year in Brazil, 8902 m3 /year in USA, 2215 m3 /year in China, 2808 m3 /year in Spain, 18162 m3 /year in Australia, 3351 m3 /year in France, 3614 m3 /year in Mexico and 3393 m3 /year in Japan. The total water resources of India are estimated to be around 1,869 Billion cubic meters. Due to topographic, hydrological and other constraints, only about 690 BCM of total surface water is considered as utilizable [1]. Due to high temperatures and arid conditions in about one third of the country, the evaporation losses have been found to be substantial. Therefore, it is imperative to minimise evaporation losses in the storages/water bodies. Evaporation losses from on-farm storage can potentially be large, particularly in irrigation areas in where up to 40% of storage volume can be lost each year to evaporation. Reducing evaporation from water storage would allow additional crop production, water trading or water for the environment. The need for prevention of enormous evaporation losses assumes greater significance, in view of the predictable scarcity of water; the country will be facing in future. It has been assessed that against the utilizable water resources of the order of 1123 BCM, the requirement by 2025 AD to be met from surface water resources will be around 1093 BCM, thereby surplus by just 30 BCM[1, 2]. Due to intense agricultural practices, rapid increase in population, industrialization and urbanization etc., scarcity of water is being increasingly felt. In the present scenario of utmost strain on the water resources, of the country, it becomes necessary to conserve water by reducing evaporation losses. National Water Policy-2002 under Para 19.1 emphasises that evaporation losses should be minimised in drought-prone areas [1]. The internet was also browsed to search the information on any new researches or identification of any new technology / chemicals to retard the evaporation rate. The search on internet, resulted in finding some case studies done in this field in other countries, however, the chemicals / technology used is the same. Some websites are from the manufacturers of WER chemicals such as Hexadecanol or Octadecanol or Acilol claiming to have conducted experiments in other countries towards evaporation control [3, 4, 5]. Chemical substances such as Cetyl and Stearyl alcohols can be sprayed periodically on water surface to reduce evaporation. After a detailed review of the available evaporation reduction methods, surface water cover technique was selected using Cetyl and Stearyl alcohol emulsion substances to form a thin monomolecular film over water surface to reduce evaporation [6]. This method has several advantages over other methods. It is economically feasible due to low cost of substances and easily available. It mixes with water easily and when added to large water surface; it forms a thin invisible film that reduces evaporation considerably. It decomposes easily and doesn't dissolve in water. There are several methods to measure evaporation from free water surfaces through (US weather class-A pan), or more accurately by using energy balance equations. Due to
  • 3. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 187 several factors including air movement and fluctuations of water surface, which affect the accuracy of measurement of evaporation depth therefore, standard and well recognized method of (US weather class-A pan) was selected for the present study [7]. The present study was conducted to measure the reduction of evaporation on relatively small and controlled water surface of two pans (US weather class-A pan) with continuous measurement of air temperature, relative humidity, wind velocity and evaporation rates and evaluated the results in terms of efficiency in reducing evaporation. The evaporation pan 2 was added with Cetyl and Stearyl alcohols as thin film on water surface to reduce evaporation. Based on material safety data sheet, the substance does not have any harmful effects on human beings, animals or plants however; further study is required to determine the potential environmental, health and ecological impacts of the substance on aquatic animals and plants [8,9,10]. 2. MATERIALS AND METHODOLOGY The study was conducted at Aurangabad (Marathwada region of M.S.) with the help of a fully operated meteorological station with sensors to measure sunshine hours, air temperature, wind velocity and relative humidity. Two US weather class-A pans were used with an accurate measuring tool to measure daily water depth in the pans. A protection cover was constructed to protect the pans from birds and other animals. The amount of chemical films (Cetyl and Stearyl alcohols) added to the two evaporation pans was calculated and applied to one of the pan for fifteen days duration. No chemical was added to pan (EP1) to measure natural evaporation rate due to ambient conditions and for comparison. In pan (EP2), 50 mg per m2 of water surface per day, to make the effective substance in pan (EP2) is 58.35mg/day and as that of 100mg and 150 mg is calculated. A monolayer is formed on a water surface when long-chained alcohols such as Cetyl alcohol (Hexadecanol) are spread across the water. The chemical spreads spontaneously across the surface resulting in a layer only one molecule thick (about two millionths of a millimetre). The molecules of the monolayer ‘stand’ on the surface because they are amphiphilic i.e. they have a soluble end and an opposing insoluble end (Fig.1). Figure 1 Monolayer molecules ‘standing’ on the water surface (courtesy Geoff Barnes, University of Queensland) Duration the entire study period (Jan-Sept 2012), Cetyl and Stearyl Alcohols was sprayed daily in evaporation pan EP2 and meteorological parameters including air temperature, relative humidity, wind speed and sunshine hours as well as water levels in two
  • 4. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 188 pans were measured. The standard procedure was strictly followed and maintained during measurements of the readings for accuracy and consistency of the results throughout the duration of the study. All the pans were cleaned regularly to remove sediments from pans, if any. 3. RESULTS AND DISCUSSION The results of the study indicated that air temperature ranges from 15.0-41.0°C with average of 34.5°C, while wind velocity ranges from 0.4-12 km/hr with average of 3.9 km/hr. The relative humidity ranges from 25-95% with average of 66.8%. Similarly, the daily pan evaporation rates ranges from 1-9.7 mm/day with average of 6.4 mm/day. The pan evaporation rate reached its peak in June and it reached 9.7 mm/day. Table1. Summary of the experiment results of the daily reduction of pan evaporation rates for different months Table 2. Summary of the experiment results - chemical wise reduction in percentage Reduction using only cetyl alcohol Reduction using only stearyl alcohol Reduction using cetyl + stearyl alcohol 23.13 22.66 25.28 27.07 26.73 29.67 33.85 31.98 41.88 21.06 24.48 25.73 26.17 28.01 25.21 Average Reduction 26.26% Average Reduction 26.77% Average Reduction 29.55% Table 1 shows the daily average evaporation rate for 8 months from January to September. In table 2 the chemical wise reduction is shown. The average reduction recorded using only Cetyl alcohol is about 26.26%. The average reduction recorded using only Stearyl alcohol is about 26.77%. The average reduction recorded using Cetyl and Stearyl alcohol is about 29.55%. Duration Evaporation mm/day (EP1) Evaporation mm/day (EP2) % Reduction 16 Jan -31 Jan 5.41 4.16 23.13 01 Feb - 29 Feb 5.72 4.36 23.97 01 Mar -31 Mar 6.15 4.40 28.37 01 Apr - 30 Apr 7.55 5.26 30.29 01 May - 31 May 8.15 5.14 36.93 01 June - 21 June 7.11 5.40 23.76 22 Aug - 31 Aug 3.68 2.68 25.69 01 Sept -12 Sept 3.89 2.76 28.01 Average 5.96 4.27 27.52
  • 5. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 189 Chemical and concentration wise reduction in percentage is shown in table 3.It is cleared from this table as the concentration is increased the reduction is also increased while the cetyl and stearyl alcohols combine perform better than other two concentrations and chemicals. In table 4 the reduction in percent concentration wise is shown. Table 3. Summary of the experiment results - chemical and concentration wise reduction in percentage Reduction using only cetyl alcohol 23.13 for 50mg/m2 /day 27.07 for 100mg/m2 /day -- for 150mg/m2 /day21.06 26.17 33.85 22.09 Average 26.62 Average 33.85 Average Reduction using only stearyl alcohol 22.66 for 50mg/m2 /day 26.73 for 100mg/m2 /day -- for 150mg/m2 /day24.48 28.01 31.98 23.57 Average 27.37 Average 31.98 Average Reduction using cetyl + stearyl alcohol 25.28 for 50mg/m2 /day 29.67 for 100mg/m2 /day -- for 150mg/m2 /day25.73 25.21 41.88 25.51 Average 27.44 Average 41.88 Average Table 4. Summary of the experiment results - concentration wise reduction in percentage for 50mg/m2 /day for 100mg/m2 /day for 150mg/m2 /day 23.13 27.07 33.85 25.28 29.67 41.88 22.66 26.73 31.98 21.06 26.17 -- 24.48 25.21 -- 25.73 28.01 -- Avg. 23.72 Avg. 27.14 Avg. 35.90 Difference Between 50mg/m2 /day and 100mg/m2 /day: 3.42 Difference Between 100mg/m2 /day and 150mg/m2 /day: 8.76 The daily average pan evaporation rate for 4 summer months (March, April, May and June) was measured as 6.15, 7.55, 8.15 and 7.11 mm/day, respectively. Thus, middle four months (March to June) witnessed the highest evaporation rates due to high temperature and low humidity. The readings are validated with help of Penman’s equation for evaporation [11], the following equation were used. ( ) 0.00061 . 0.00061 n a e Q P E L E P ∆ + = ∆ +       (1) where, Qnis the net solar radiation used in evaporation in cal/sq.cm
  • 6. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 190 Qn= Qi (1– r) – Qb (2) Qi is the incoming solar radiation 0 0.55i n Q Q a N = +       (3) Q0 is the radiation in cal/cm2 /dayreceived at the top of the atmosphere a = 0.29 cosθ (4) θ is the latitude of the place nis the actual number of sunshine hours in the day, N is the maximum possible hours of bright sunshine ris called the reflection coefficient or the albedo whose value may be taken as 0.05 for water surface Qbis the net outgoing longwave radiation ( )4 0.56 0.09 0.1 0.9b a n Q T e N σ= − +       (5) σ is the Stefan-Boltzman constant σ = 118.944 x 10-9 cal/cm2 /day/°K (6) T is the mean daily temperature in °K eais the actual vapour pressure of air in mm of mercury 100 . . s a e e R H = (7) R. H. is the Relative Humidity in % ∆ is the slope of saturation vapour pressure curve at air temperature t in mb/°C ( ) 2 4098 237.3 s e t ∆ = + (8) esis the saturated vapour pressure corresponding to the mean daily air temperature 17.27 6.11exp 237.3 s T e T = +       (9) t is the air temperature in °C Le is the latent heat of vaporization of water in cal/g which varies with the temperature and can be obtained from Le = 597.3 – 0.564 t (10) P is the atmospheric pressure in kPa
  • 7. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 191 5.26 293 0.0065 101.3 293 z P − =       (11) z is the elevation above sea level in m Eais the evaporation from the water surface when water and air temperatures are equal Ea= 0.35(0.5 + 0.54 V) (es - ea) (12) V is in m/s measured at a height of 2 m above the free surface The regression model is shown in Fig. 2 is drawn for the study period 16 January to 21 June. The data is best fitting by the regression analysis. The best fit for EP1got from model is 45.94%. The best fit for using Penman’s equation got from model is about 46.1% and that of EP2the best fit get from model is about 32.52%. These regression models are showing the linearity of recorded data and Penman’s equation data. The regression model shown in Fig. 3 indicates the study period between 16 Jan to 12 Sept. firstly it decided to check the efficiency of cetyl and Stearyl alcohols in summer therefore the reading were taken for the period 16 Jan to 21 June. Whatever readings were not available in the graph that is due to evaporation reading and other data are not recorded for period 22 June to 21 Aug. the reading and other data were continues after this gap and respective regression model is drawn for remaining period upto 12 Sept. Figure 2. Linear regression model showing EP1, EP2 and evaporation using Penman's eqn (depth in mm) {16 Jan -21 June} y = 0.019x - 780.3 R² = 0.459 y = 0.01x - 406.1 R² = 0.325 y = 0.026x - 1078. R² = 0.461 2.8 3.6 4.4 5.2 6.0 6.8 7.6 8.4 9.2 10.0 10.8 16/01/12 23/01/12 30/01/12 06/02/12 13/02/12 20/02/12 27/02/12 05/03/12 12/03/12 19/03/12 26/03/12 02/04/12 09/04/12 16/04/12 23/04/12 30/04/12 07/05/12 14/05/12 21/05/12 28/05/12 04/06/12 11/06/12 18/06/12 25/06/12 02/07/12 Evaporationmm/day Days Evaporation mm/day (EP1) Evaporation mm/day (EP2) Evaporation Using Penman's Eqn Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2)) Linear (Evaporation Using Penman's Eqn)
  • 8. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 192 Figure 3. Linear regression model showing EP1, EP2 and evaporation using Penman's eqn (depth in mm) {16 Jan -12 Sept} After these observed data the respective regression models is plotted. From this model it is observed that the model is not fitting to that extent. So, from all these studies it is concluded that the films are not that much efficient in rainy season as that of in summer season. It is observed that splashing or overflowing of the pan may cause the flowing of chemical film with it. The high wind velocity breaks or may breaks therefore no layer is form and therefore water gets evaporated. Again the rain droplets may reduce the efficiency of the chemical films. The relationship of air temperature, wind velocities and relative humidity with the evaporation was determined with the help of linear regression analysis of daily observed data. A linear regression model for best fit of observed data for daily air temperature and daily evaporation depth in mm for both pans (EP1and EP2) was developed as in Fig. 4. y = -0.003x + 137.4 R² = 0.017 y = -0.003x + 151.1 R² = 0.050 y = 0.004x - 175.9 R² = 0.026 1.4 2.2 3.0 3.8 4.6 5.4 6.2 7.0 7.8 8.6 9.4 10.2 11.0 16/01/12 23/01/12 30/01/12 06/02/12 13/02/12 20/02/12 27/02/12 05/03/12 12/03/12 19/03/12 26/03/12 02/04/12 09/04/12 16/04/12 23/04/12 30/04/12 07/05/12 14/05/12 21/05/12 28/05/12 04/06/12 11/06/12 18/06/12 25/06/12 02/07/12 09/07/12 16/07/12 23/07/12 30/07/12 06/08/12 13/08/12 20/08/12 27/08/12 03/09/12 10/09/12 Evaporationmm/day Days Evaporation mm/day (EP1) Evaporation mm/day (EP2) Evaporation Using Penman's Eqn Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2)) Linear (Evaporation Using Penman's Eqn)
  • 9. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 193 Figure 4.Linear regression model for daily air temperature and daily evaporation {16 Jan- 12 Sept} The model indicated that there is a direct correlation between air temperatures with the daily pan evaporation rates. Similarly, a linear regression model for best fit of observed data for wind velocity and daily evaporation depth (mm) was developed as in Fig. 5. Figure 5.Linear regression model for daily wind velocity and daily evaporation {16 Jan- 12 Sept} The model indicated that there is a direct correlation between wind velocities with the daily pan evaporation rates. In addition, a simple regression model for best fit of observed data for daily relative humidity and daily evaporation depth (mm) was developed as in Fig. 6. y = 0.258x - 2.491 R² = 0.556 y = 0.144x - 0.420 R² = 0.412 0.0 2.0 4.0 6.0 8.0 10.0 12.0 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0 40.0 45.0 Evaporationmm/day Temperature °C Evaporation mm/day (EP1) Evaporation mm/day (EP2) Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2)) y = -0.296x + 7.565 R² = 0.179 y = -0.207x + 5.356 R² = 0.207 0.0 2.0 4.0 6.0 8.0 10.0 12.0 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0 Evaporationmm/day Wind Velocity km/hr Evaporation mm/day (EP1) Evaporation mm/day (EP2) Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2))
  • 10. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May Figure 6.Linear regression model for daily relative humid The model indicated that pan evaporation rates decreases as humidity increases and that there is an inverse correlation between average daily relative humidity with the daily pan evaporation rates. The results of chemical film solution with different concentrations and without application in two different evaporation pans from January to September is presented in Figure 7.Cumulative daily evaporation Similarly daily average gross evaporation rates for different months for two pans were compared and the evaporation reductions in percentage were calculated. Table 1 show that the average daily average gross evaporation rates and percentage of reduction of evaporation rate for different months for two pans. y = y = -0.024x + 6.197 R² = 0.144 0.0 2.0 4.0 6.0 8.0 10.0 12.0 0.0 10.0 20.0 30.0 Evaporationmm/day Evaporation mm/day (EP1) Linear (Evaporation mm/day (EP1)) 4.0 12.0 20.0 28.0 36.0 44.0 52.0 60.0 68.0 76.0 84.0 92.0 16-31 Jan 01-15 Feb 16-29 Feb 01-16 Mar 17 Evaporationmm Evaporation mm/day (EP1) International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 194 Linear regression model for daily relative humidity and daily evaporation {16 Jan- 12 Sept} The model indicated that pan evaporation rates decreases as humidity increases and that there is an inverse correlation between average daily relative humidity with the daily pan evaporation rates. The results of the pan evaporation control experiment after adding chemical film solution with different concentrations and without application in two different evaporation pans from January to September is presented in Fig. 7. Cumulative daily evaporation depth (mm) measured for two pans (EP {16 Jan - 12 Sept} Similarly daily average gross evaporation rates for different months for two pans were compared and the evaporation reductions in percentage were calculated. Table 1 show that ily average gross evaporation rates and percentage of reduction of evaporation rate for different months for two pans. y = -0.036x + 8.836 R² = 0.131 30.0 40.0 50.0 60.0 70.0 80.0 Relative Humidity % Evaporation mm/day (EP2) Linear (Evaporation mm/day (EP1)) Linear (Evaporation mm/day (EP2)) 17-31 Mar 01-15 Apr 16-30 Apr 01-16 May 17-31 May 01-07 June 08-14 June 15-21 June 22-28 Aug Months Evaporation mm/day (EP1) Evaporation mm/day (EP2) International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 June (2013), © IAEME ity and daily evaporation The model indicated that pan evaporation rates decreases as humidity increases and that there is an inverse correlation between average daily relative humidity with the daily pan the pan evaporation control experiment after adding chemical film solution with different concentrations and without application in two different depth (mm) measured for two pans (EP1 and EP2) Similarly daily average gross evaporation rates for different months for two pans were compared and the evaporation reductions in percentage were calculated. Table 1 show that ily average gross evaporation rates and percentage of reduction of evaporation 90.0 100.0 Linear (Evaporation mm/day (EP2)) 28 29 Aug- 4 Sept 05-12 Sept
  • 11. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May The pan evaporation rates are smaller in winter as compared to the summer months. In general, evaporation rate from pan EP when the recommended concentration was applied. Similarly, in table 4 the reduction in percent concentration wise. The concentration where used as per recommendations it is observed that 23.72 % reduction is achieved. If this % average reduction is possible. If this quantity is tripled then the results are tremendously increased i.e. about 35.90 % reduction is possible. These findings confirmed that there is a significant reduction in water surfaces when we applied the chemical films highly feasible and cost effective to use the substance to reduce evaporation. Figure 5.Monthly evaporation depth in mm {16 Jan 4. CONCLUSION As the duration of rainy season and quantity of rainfall is reduced, the demand of water is day by day increasing due to increase in population and Industrialization therefore, the economic value also increases. Therefore the government should adopt the st for storage and maximum utilization of rainwater. Protecting the stored water in water bodies (Dams, Reservoirs, Lakes, etc.) from evaporation remains an integral part of sustainable planning, especially during the summer hot months, when temperature is high and humidity is low, which leads to extremely high rate evaporation from water surfaces. Chemical films such as Cetyl and Stearyl alcohols are one of most feasible and cost effective evaporation retardants which reduces evaporation significantly. The present study has confirmed that a chemical film produces an invisible thin monomolecular film over water surface that significantly reduces evaporation. The experimental study was conducted to demonstrate the effectiveness of evaporation reduction on US weather class different concentrations of 50, 100 and 150 mg/m was reduced up to 28% as compared to without addition of chemical films. Therefore, these chemicals are highly feasible and cost effective to apply the present evaporation reduction technique on a large scale to a large number of reservoirs of the water loss through evaporation from water surfaces. 2.4 3.0 3.6 4.2 4.8 5.4 6.0 6.6 7.2 7.8 8.4 16-31 Jan 01-15 Feb 16-29 Feb 01-16 Mar 17 Mar Evaporationmm Evaporation mm/day (EP1) International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 195 The pan evaporation rates are smaller in winter as compared to the summer months. In general, evaporation rate from pan EP1 is reduced by 27.52% as compared to pan EP when the recommended concentration was applied. Similarly, in table 4 the reduction in percent concentration wise. The concentration where used as per recommendations it is observed that 23.72 % reduction is achieved. If this quantity is doubled i.e. 100mg then 27.14 % average reduction is possible. If this quantity is tripled then the results are tremendously about 35.90 % reduction is possible. These findings confirmed that there is a significant reduction in evaporation from free water surfaces when we applied the chemical films i.e. Cetyl and Stearyl alcohols and it is highly feasible and cost effective to use the substance to reduce evaporation. Monthly evaporation depth in mm {16 Jan - 12 Sept} As the duration of rainy season and quantity of rainfall is reduced, the demand of water is day by day increasing due to increase in population and Industrialization therefore, the economic value also increases. Therefore the government should adopt the st for storage and maximum utilization of rainwater. Protecting the stored water in water bodies .) from evaporation remains an integral part of sustainable planning, especially during the summer hot months, when temperature is high and humidity is low, which leads to extremely high rate evaporation from water surfaces. Chemical films d Stearyl alcohols are one of most feasible and cost effective evaporation retardants which reduces evaporation significantly. The present study has confirmed that a chemical film produces an invisible thin monomolecular film over water surface that icantly reduces evaporation. The experimental study was conducted to demonstrate the n reduction on US weather class-A pans adding chemical films of different concentrations of 50, 100 and 150 mg/m2 /day. The study concluded that was reduced up to 28% as compared to without addition of chemical films. Therefore, these chemicals are highly feasible and cost effective to apply the present evaporation reduction technique on a large scale to a large number of reservoirs of the Marathwada region to reduce the water loss through evaporation from water surfaces. 17-31 Mar 01-15 Apr 16-30 Apr 01-16 May 17-31 May 01-07 June 08-14 June 15-21 June 22-28 Aug Months Evaporation mm/day (EP1) Evaporation mm/day (EP2) International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 June (2013), © IAEME The pan evaporation rates are smaller in winter as compared to the summer months. 27.52% as compared to pan EP2 when the recommended concentration was applied. Similarly, in table 4 the reduction in percent concentration wise. The concentration where used as per recommendations it is 100mg then 27.14 % average reduction is possible. If this quantity is tripled then the results are tremendously evaporation from free Cetyl and Stearyl alcohols and it is As the duration of rainy season and quantity of rainfall is reduced, the demand of water is day by day increasing due to increase in population and Industrialization therefore, the economic value also increases. Therefore the government should adopt the strategic plans for storage and maximum utilization of rainwater. Protecting the stored water in water bodies .) from evaporation remains an integral part of sustainable planning, especially during the summer hot months, when temperature is high and humidity is low, which leads to extremely high rate evaporation from water surfaces. Chemical films d Stearyl alcohols are one of most feasible and cost effective evaporation retardants which reduces evaporation significantly. The present study has confirmed that a chemical film produces an invisible thin monomolecular film over water surface that icantly reduces evaporation. The experimental study was conducted to demonstrate the A pans adding chemical films of /day. The study concluded that evaporation was reduced up to 28% as compared to without addition of chemical films. Therefore, these chemicals are highly feasible and cost effective to apply the present evaporation reduction the Marathwada region to reduce 28 Aug 29 Aug- 4 Sept 05-12 Sept
  • 12. International Journal of Civil Engineering and Technology (IJCIET), ISSN 0976 – 6308 (Print), ISSN 0976 – 6316(Online) Volume 4, Issue 3, May - June (2013), © IAEME 196 REFERENCES [1] R. Kumar, R. D. Singh and K. D. Sharma, Water resources of India, Current Science89(5), 2005, 794-811. [2] M. E. Jensen, Estimating Evaporation from Water Surfaces, CSU/ARS Evapotranspiration Workshop, Fort Collins, CO, 2010, 1-27. [3] W. J. Roberts, Evaporation Suppression from Water Surfaces, American Geophysical Union, 38(5), 1957, 740-744. [4] J. Walter, The use of Monomolecular Films to Reduce Evaporation, International Union of Geodesy and Geophysics Assembly, Berkely, California, 1963, 39-48. [5] E. H. Hobbs, Evaporation Reduction by Monomolecular Films the Influence of Water Temperature and Application Rate on the Effectiveness of Cetyl Alcohol, 17-19. [6] I. Craig, E. Schmidt and M. Scobie, Evaporation Control using Covers – some realistic solutions for the irrigation industry National Centre for Engineering in Agriculture (NCEA), University of Southern Queensland. [7] Mohammed I. Al-Saud, Reduction of Evaporation from Water Surfaces-Preliminary Assessment for Riyadh Region, Kingdom of Saudi Arabia, Research Journal of Soil and Water Management, 1(1), 2010, 5-9. [8] F. S. Ikweiri , H. Gabril , M. Jahawi and Y. Almatrdi, Evaluating the Evaporation Water Loss from the Omar Muktar Open Water Reservoir, 12th International Water Technology Conference, IWTC12, Alexandria, Egypt, 2008, 893-899. [9] G.T. Barnes, The potential for monolayers to reduce the evaporation of water from large water storages, 95, 2008, 339-353. [10] D.McJannet, F. Cook, J. Knight and S. Burn, Evaporation Reduction by Monolayers: Overview, Modelling and Effectiveness, Urban Water Security Research Alliance Technical Report, 6, 2008, 1-32. [11] P. J. Rami Reddy, A text book of Hydrology (University Science Press, 2008) 207-233. [12] U. J. Kahalekar, H. S. Kumawat, Evaporation suppression from water surfaces using chemical films,International Conference on Sustainable Innovative Techniques in Civil and Environmental Engineering, SITCEE – 2013, New Delhi, India, 2013, 38-43. [13] Abdur Rahman, M. A. Zafor and Shantanu Kar, “Analysis and Comparision of Surface Water Quality Parameters in and Around Dhaka City”, International Journal of Civil Engineering & Technology (IJCIET), Volume 3, Issue 2, 2012, pp. 7 - 15, ISSN Print: 0976 – 6308, ISSN Online: 0976 – 6316. [14] C. P. Pise and Dr. S. A. Halkude, “Blend of Natural and Chemical Coagulant for Removal of Turbidity in Water”, International Journal of Civil Engineering & Technology (IJCIET), Volume 3, Issue 2, 2012, pp. 188 - 197, ISSN Print: 0976 – 6308, ISSN Online: 0976 – 6316.