Vystar presentation at the July 2011 International Latex Conference in Akron on the many different uses for Vytex Natural Rubber Latex. The low protein and low non-rubber form of latex
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International Latex Conference Presentation on Vytex NRL.
1. Further Development of Vytex Natural Rubber
Latex Leads to Strong Niche Market
Advances
Matt Clarka (Speaker), Travis Honeycutta, Gunalan Narayananb,
William Doylea, Joanne Kearneya
aVystar® Corporation, 3235 Satellite Boulevard, Building 400, Suite 290, Duluth, GA 30096 USA
bStratoshift Technologies SDN. BHD., No 24, Jalan SS21/42A, Damansara Utama, 47400 Peltaling Jaya, Senlangor, Malaysia
2. What is Vytex® Natural Rubber Latex?
A fully commercialized source material, using a multi-patented
process and green chemistry to significantly reduce non-rubber
components, including antigenic proteins, for a more
consistent, stable and cleaner natural rubber latex
3. Vytex® NRL Technology
FW
L
P FW
L
FW
L P
L P FW P L FW
FW
FW P FW
P L L P
L P FW FW
FW
L
L L L
FW P L L L
FW P FW P FW
P
L P L P
L P
5. New Standard of Latex
Vytex® NRL Meets the New ASTM D1076-10 Category 5 Standard
“Centrifuged Hevea natural latex treated with aluminum hydroxide or by
other means, preserved with ammonia……containing less than
0.5 % non-rubber content.”
Categories
1–4
Max. 2.0%
6. Vytex® NRL Advancements: Specialty Gloves
Clean Room and Specialty Gloves
Clean room gloves made with Vytex® require
~ 50% less leaching to remove non-rubbers
and chemical particles
• Lower product rejection rates due to extensive alkaline washes
• Decreased energy, water and waste usage
Vytex® use with common antimicrobials is superior to NRL- will not
react and de-stabilize
7. Protein Results in Clean Room Gloves
Using Comparative Leaching Processes
Powder Free Powdered
Vytex® NRL Trials Modified Lowry Modified Lowry
Using Normal Established (µg/dm²) (µg/dm²)
Parameters Size Spec: < 50 µg/dm2 Size Spec: < 200 µg/dm2
Trial #1 – Normal Process L 17.87 XXXS 20.68
2 pre-leach; 2 post-leach
Trial #2 XL 19.32 L 43.29
2 pre-leach; 1 post-leach
Trial #3 S 18.30 S 68.61
2 pre-leach only
Trial #4 XXXS 14.89 L 67.07
1 pre-leach only
Trial #5 L 15.46 S 142.57
No post or pre-leach
Testing conducted by Malaysian Glove Manufacturer
8. Vytex® NRL Advancements: Condoms
Naturally whiter, more translucent
condoms
Condoms made with Vytex® NRL
contained 35% fewer nitrosamines than traditional latex*
Significantly reduced odor compared to NRL
US FDA protein claim “less than 2 µg/dm2 antigenic protein”
* Customer Test Data
9. Vytex® NRL Advancements: Balloons
Vytex® Control
Whiter, cleaner balloons for brighter,
truer colors with less pigment usage
Reduced usage of pigments and
whiteners (TiO2)
Better air and helium retention in balloons
Vytex® Control
10. Vytex® NRL Balloons: Stay Inflated Longer
80 Helium Retention Over Time Normal Air Retention Over Time
70
Circumference (cm)
60
50
40
30
20
10
0
12 24 36 48 60 72 84 96 108 120
Hours Vytex NRL
Control NRL
11. Vytex® NRL Advancements: Adhesives
Spray Adhesives
Less non-rubber debris for cleaner spray
Absence of non-rubber debris reduces spray-head clogging;
decreased equipment/line downtime
Cleaner adhesives flow easily; allowing for gravity-fed system
vs. pump system using propellants
~ 40% faster tack time in some formulations compared to
traditional latex
12. Antigenic Protein Results in Adhesives
Vytex® NRL vs. Standard NRL
ELISA D6499-07 (µg/g)
Source Sample 1 Sample 2
Vytex® NRL 1.6 2.4
Control A 624.5 76.3
Testing conducted by LEAP Testing Services, Sayre, PA, USA
13. How Vytex® NRL is Helping to Solve Customer Product
Development Challenges:
Adhesives for Personal Care Products
Goal:
Safe and effective skin adhesive which can be easily and
safely removed
Result:
Material with excellent adhesive quality
Low levels of protein
Adhesive can easily be removed with soap
14. Vytex® NRL Advancements: Foam Products
Virtually Odor Free
Significantly reduced leaching
No fragrances required to mask or eliminate odor
Vytex® process eliminates microbial food sources that
break down to cause odor and accelerated aging
Whiter, Cleaner Foams
15. How Vytex® NRL is Helping to Solve Customer Product
Development Challenges:
Customized Foams
Goal: a greener, naturally based foam with slow recovery properties
4.00%
3.50%
3.00%
2.50%
Typical NRL**
2.00%
Vytex NRL*
1.50%
Typical Polyurethane**
1.00%
0.50%
0.00%
compression set
* Internal test results
**Carey, R.H. and Rogers, E.A. (1956) Modern Plastics, 33 (12), 139.
16. Vytex® NRL Threads: Physical Property Testing
Physical Properties
Antigenic
Modulusa Tenacitya Protein
% Straina
(g/denier) (g/denier) ELISAb
Source (µg/dm2)
Vytex® NRL 929.5 0.0088 0.31 3.8
(± 48.8) (±0.0007) (±0.02)
NRL Control 771.3 0.0144 0.33 14.1
(±90.1) (±0.0016) (±0.02)
Spandex 755.7 0.0781 0.87 n/a
(±160.1) (±0.0111) (±0.07)
aTesting conducted by North Carolina State University, College of Textiles, Raleigh, NC USA; bLEAP Testing Services.
17. Vytex® NRL Threads: Lower Modulus/Higher Elongation
Easier Donning and Greater Comfort
Tenacity vs. % Strain Curves
1.00
0.80
Tenacity (gf/denier)
0.60
Natural Rubber Latex Control
Spandex
0.40
Vytex NRL
0.20
0.00
0 200 400 600 800 1000
Strain (%)
Testing conducted by North Carolina State University, College of Textiles
18. How Vytex® NRL is Helping to Solve Customer Product
Development Challenges:
Specialty Fabrics for Personal Protection Products
Goal:
• Latex based apparel that can worn daily
• Fabric must retain fluids to prevent leakage
• Fabric must be easy to don and comfortable to wear
• Production process does not include a leaching step
Result:
• Low levels of antigenic proteins
• Tight film structure minimizes leakage
• Low modulus material for easy donning
19. Opportunities for Further Enhancements to Vytex® NRL
No Ammonia Alternative
Ammonia Preserved CL 60 is the Industry Standard
• Current low ammonia levels to 0.20 – 0.35%
• However, TMTD used as a preservative and therefore CL60 is not
Nitrosamine-free
Growing demand for improved lattices:
• Low VOCs for use in enclosed factory spaces
• Specialty end use applications such as body paints, adhesives, etc.
• Without ammonia or TMTD used at any stage of preservation
Very Low Ammonia Vytex NRLO5 (<.05% ammonia) currently available
20. Conclusions
Vytex® NRL Multi-patented Process
Physically removes non-rubbers, including proteins,
from liquid natural latex
Meets new Category 5 standards of ASTM D1076-10
21. Conclusions
Products Made with Vytex® NRL
Exam gloves and condoms: FDA 510(k) allowances of protein claims
Foams: naturally whiter with minimal latex odor
Balloons: truer colors and better air/helium retention
Dipped goods: less leaching/improved environmental impact
Vystar R&D focuses on addressing our customers’ varied
product and production challenges