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A.NITROGEN 1.Pengertian Nitrogen Nitrogen adalah unsur kimia dalam table periodik yang memiliki lambang N dan nomor atom 7. Biasanya ditemukan sebagai gas tanpa warna, tanpa bau, tanpa rasa dan merupakan gas diatomik bukan logam yang stabil, sangat sulit bereaksi dengan unsur atau senyawa lainnya. Dinamakan zat lemas karena zat ini bersifat malas, tidak aktif bereaksi dengan unsur lainnya. Nitrogen mengisi 78,08 % atmosfir bumi dan terdapat dalam banyak jaringan hidup. Zat lemas membentuk banyak senyawa penting seperti asam amino, amoniak, asam nitrat dan sianida. 2. Sifat-Sifat Nitrogen a.Sifat Fisis Nitrogen 1) Berupa gas diatomic N2 tidak berbau, tidak berasa, tidak berwarna, dan sedikit larut dalam air. 2) Bersifat non polar sehingga gaya Van Deer Waals antar molekul sangat kecil 3) Sifat fisik nitrogen yang lain Titi didih 77,36 K Titik lebur 63,15 K Berat jenis relative 0,97 Berat molekul 28,013 Kalor peleburan 0,720 kJ/mol Kalor penguapan 5,57 kJ/mo Kapasitas kalor dalm suhu kamar 29,124 J/mol K b. Sifat kimia 1) Molekul N2 berikatan kovalen rangkap tiga, memiliki energy ikatan yang relative besar yaitu 946 kJ/mol sehingga sangat stabil atau sukar bereaksi pada suhu tinggi (endoterm) dengan bantuan katalis. 2) Pada suhu ruangan N2 bereaksi sangat lambat dengan logam Li menghasilkan Li3N. Sedangakan dengan logam-logam lain, dapat dilakukan dengan cara mengerjakan loncatan bunga api listrik melalui gas nitrogen yang bertekanan rendah, proses ini dikatalisasi oleh adanya oksigen homo terbentuk nitrogen aktif (N2 menjadi 2N) yang dapat membentuk senyawa nitrida dengan logam-logam tertentu. 3) Nitrogen bereaksi dengan hydrogen atau aksigen pada suhu yang tinggi seperti dalam loncatan bunga api listrik, membentuk gas NH3 dan NO3 . 3.Pembuatan nitrogen 1. Di laboratorium dari dekomposisi termal senyawa amonium CNH4 NO2 dengan cara dipanaskan. Reaksinya seperti berikut : CNH4 NO2(s ) → N2 + 2H2 O 2. Dalam industri, dengan cara destruksi bertingkat dan pencairan (destilasi udara cair) karena N2 mempunyai titik didih rendah daripada O2 maka ia lebih dahulu menguap sebagai fraksi pertama 3. Secara spektroskop N2 murni di buat dengan dekomposisi termal Natrium Barium Azida. Berikut reaksinya: 2NaN3 → 2Na + 3N2 4. Pemanasan NH4 NO2 melalui reaksi sebagai berikut : NH4 NO2 → N2 + 2H2 O 5. Oksidasi NH3 melalui reaksi sebagai berikut : 2NH3 + 3CuO → N2+ 3Cu + 3H2O 6. Destilasi (penyulingan ) bertingkat dari udara cair yaitu udara bersih kita masukkan ke dalam kompresor,kemudian didinginkan dengan pendinginan. Udara dingin mengembun melalui celah dan hasilnya adalah udara yang suhunya sangat dingin sehingga udara mencair. Setelah itu, udara cair kita saring untuk memisahkan gas CO2 dan hidrokarbon, selanjutnya disuling. Udara cair masuk ke bagian puncak kolom tempat nitrogen, komponen yang paling mudah menguap, keluar sebagai gas. Pada pertengahan kolom, gas
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Nitrogen Project
1.
Nitrogen An All –
Purpose Element
2.
What is Nitrogen? Trivalent
Bond
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Periodic Table
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The Nitrogen Cycle
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The Haber Process
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Trinitrotoluene
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Liquid Nitrogen
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The Leidenfrost Effect
9.
Other Uses
