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22/01/2014 
1 
Coating Overview 
Audrey BERGERON 
Bangkok – January 23rd 2014 
1 
2 
About the instructor 
Title Coating specialist 
Region / Entity Asia Pacific / TPS 
Business segment Subsea – Onshore Offshore 
Education Meng./ Chemical Engineering 
Contact abergeron@technip.com
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3 
About Technip Singapore 
• Shallow to deep water 
(3000 m) 
• S-laying 
• Rigidd pipes (4” to 60 “) 
• Piggy-backed pipeline 
installation 
• Pipe-in-pipe, CRA 
OFFSHORE 
PIPELINE 
INSTALLATION 
• Lifting up to 1200 tons 
• Installation of 
platform, subsea 
structures, skids, 
modules, etc. 
OFFSHORE 
STRUCTURE 
INSTALLATION, 
HEAVY LIFTING 
4 
About Technip Singapore 
• Spools 
• Risers 
• Buckle Initiator Structures 
• PLEM 
• Manifolds 
• Skids 
• Crossing Structures 
• Installation Aids 
FABRICATION 
SERVICES 
• Full-time divers 
• Saturation to 300m 
• Pipelines, platform, SCM 
de-commissioning / 
removal 
DIVING, IMR, 
DECOMMIS-SIONING
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5 
About Technip Singapore 
G1201 - 3rd Generation DP Pipelay Vessel incl. 1200MT Pedestal Crane 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
6
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7 
Abbreviations 
3LPP/PE: 
CS: 
CUI: 
CWC: 
FBE: 
FJC: 
GSPU: 
HP/HT: 
HSS: 
MLPP/PE: 
PE: 
PFP: 
PP: 
PU: 
SPU: 
SS: 
TSA: 
Three Layer PolyPropylene / PolyEthylene 
Carbon Steel 
Corrosion Under Insulation 
Concrete Weight Coating 
Fusion-Bonded Epoxy 
Field Joint Coating 
Glass Syntactic PolyUrethane 
High Pressure/ High Temperature 
Heat Shrinkable Sleeves 
Multi-Layer PolyPropylene / PolyEthylene 
PolyEthylene 
Passive Fire Protection 
PolyPropylene 
PolyUrethane 
Syntactic PolyUrethane 
Stainless Steel 
Thermal Spray Aluminum 
8 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
8
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1. HSE moment 
Find the difference: 
9 
1. HSE moment 
10
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11 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
11 
2. Reason for coating 
Why do we need coating? What kind of coating? 
Corrosion protection 
 Anti corrosion paint 
Passive Fire Protection (PFP) 
 Intumescent Epoxy 
 Cementitious coating 
Fouling release 
 Anti fouling paint 
12
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2. Reason for coating 
Mechanical protection 
 Polyolefin coatings 
Negative buoyancy 
 Concrete weight coating 
Prevent CUI 
(corrosion under insulation) 
 Metallizing 
(Thermal spray aluminum) 
13 
2. Reason for coating 
Anti slip 
 Paint + natural aggregate 
Insulation 
 PU foam 
Aesthetic aspect 
 Polyurethane, Acrylic 
14
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15 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
15 
16 
3. Introduction to corrosion 
According to NACE: “ Corrosion is a deterioration of a material because 
of reaction with its environment.” 
Liquid water is in contact with metal 
AND 
corrosive agent is present in the water 
CORROSION =
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17 
3. Introduction to corrosion 
 Corrosion impact: 
o Safety: unsafe corroded structures / equipment 
o Cost: For the US, the annual cost of corrosion worldwide is 
around 3% of GDP (US$ 250 Billion) 
18 
3. Introduction to corrosion 
 Different types of corrosion 
 Uniform corrosion 
o Uniform loss of mass for external surfaces. Concerns 
mainly carbon steel and cast iron. 
o Solution: corrosion allowance (3 to 6 mm), painting, 
cathodic protection. 
 Galvanic corrosion 
o Creation of an electric current between 2 materials with 
different potential. 
o Common cases: aluminum/stainless steel, carbon 
steel/stainless steel. 
o Solution: isolation joints, cathodic protection, coating 
 Erosion corrosion 
o Erosion (abrasion): removal of metal by mechanical 
action of liquids (or solids). Erosion-corrosion :removal of 
corrosion products by mechanical action of liquids ( or 
solids). 
o Solution: improve flow by design of the piece, change for 
better material, corrosion allowance
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19 
3. Introduction to corrosion 
Different types of corrosion 
 Pitting corrosion 
o High chloride concentration leads to passivation layer 
breakdown. 
o Affects stainless steel, aluminum, titanium 
o Solution: increase molybdenum content in SS (CRA), 
coating 
 Chloride stress corrosion cracking 
o Combined action of seawater and mechanical stress 
o 316 Austenitic stainless steels subject to CSCC if 
chloride concentration > 50 ppm and temperature > 
50Ԩ 
o Solution: coating, change material grade (316 SS to 
22Cr or 25Cr) 
20 
3. Introduction to corrosion 
Design 
Corrosion 
prevention 
Coating 
Chemical 
treatment 
Material 
selection 
Cathodic 
protection
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21 
3. Introduction to corrosion 
How to prevent corrosion? 
 Design: avoid water retention, moisture / salts entrapment 
 Inhibitors: chemical added into a fluid to decrease corrosion rate 
 Material selection. Examples: 
o SS 304L very sensitive to CSCC in offshore environment. SS 316L, 22Cr 
duplex or Inconel 625 are preferred. 
o Carbon Steel can be selected for offshore structures, provided it is protected 
by coating and cathodic protection. 
 Cathodic protection: protection of the surface by another “sacrificial” 
metal (Zn, Al, Mg, …) who has a more electronegative potential. 
 Protective coating 
22 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
22
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4. Surface preparation 
Surface preparation: The key step to the coating success 
Clean the surface from contaminant 
Create roughness for coating adhesion. 
objectives 
grease dust 
mill scale 
oil 
Soluble 
salts 
Former 
coating 
contaminants 
Long term stability 
to the coating 
Did you know? 75% of premature coating failures are caused by 
inadequate or improper surface preparation 
23 
4. Surface preparation 
Selection of the method depends on: 
Substrate: carbon steel, stainless steel, Aluminum, galvanized 
steel … 
Degree of cleanliness required (paint system type and thickness) 
Geometry of the piece (area difficult to access with machines) 
Place where surface is prepared (on site, applicator’s plant) 
24
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4. Surface preparation 
1. Prior to commencement 
• check for fabrication or welding defaults: rough 
edges, cuts and welds shall be rounded to a 
2mm radius to improve coating coverage and 
adhesion on the surface. 
• remove weld spatters. 
2. Solvent cleaning. 
Degrease and remove oil, grease, soluble contaminants with solvent 
cleaning (fresh water, emulsion cleaners, detergents, organic solvents, 
petroleum based solvents, alkaline cleaners). Does not remove 
Chlorides, mill scale or other inorganic materials. 
3. Abrasive blasting or other method 
Remove chlorides and sulfates, create desired surface profile for 
primer adhesion, create a uniform aspect. 
25 
4. Surface preparation 
steel shot or grit (carbon steel 
surfaces), 
aluminum oxide or garnet 
sand (stainless steel or carbon 
steel surfaces). 
Projection of abrasive 
particles to remove rust 
and other contaminant and 
create a rough surface 
Abrasive blast cleaning 
26
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4. Surface preparation 
Abrasive blasting 
equipment 
27 
Surface preparation: other methods 
Power tool cleaning (hand or 
mechanical). Example: rotary wire brush. 
Water jetting. Only to remove previous 
coating, does not create roughness. 
Pickling. Dipping of steel in an 
acid bath 
4. Surface preparation 
28
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4. Surface preparation 
Substrate Type of system Cleanliness (ISO 8501-1 or 
SSPC) 
Profile 
surface 
(ISO 8503) 
Carbon steel – external 
surfaces 
Typical paint system 
with DFT > 200μm 
Sa 2 ½ eq. to SSPC SP10 50-75 μm 
Carbon steel – internal 
surfaces 
Internal coating 
(“lining”) 
Sa 3 eq. to SSPC SP5 or Sa 2 ½ 
eq. to SSPC SP10 
50-75 μm 
Stainless steel, 
Galvanized steel 
Typical paint system Sweep blasting eq. to SSPC SP7 20-40 μm 
- Carbon steel 
- Stainless steel 
TSA - Sa 3 eq. to SSPC SP5 
- Sweep blasting eq. to SSPC SP7 
70-120 μm 
29 
30 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
30
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5.1 Corrosion protection 
coatings 
31 
 Definition 
 Application 
 Selection 
 Protection mode 
 Specification 
32 
5.1. Corrosion protection coatings - Definition 
PAINT 
= A+B 
Pigments 
+ fillers 
Binder 
(polymer) 
Solvent 
Additives 
Reactive 
+ solvent 
Component A 
Component B
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5.1. Corrosion protection coatings - Definition 
Major paint used for corrosion protection purpose 
• 2 component- thermoset coatings 
• Excellent adhesion, chemical and water resistance 
• Shall be top-coated by UV-resistant topcoat 
EPOXY 
• 2 component 
• POLYURETHANE Resistant to UV, good gloss and color retention 
• 2 component – min. zinc content 85% 
• Very high substrate adhesion – good chemical resistance 
• Max thickness 80 μm, subject to mud-cracking -careful with 
repairs 
INORGANIC ZINC 
• Cure at ambient temp. or with help of heat 
SILICONES • For heat resistance up to 600 Ԩ, or foul release 
• 2 component coatings 
• Very good for immersion service 
• Suitable up to 230 Ԩ 
PHENOLIC 
EPOXIES 
• 2 component – used as linings – very resistant to chemicals and 
temp. 
• High thickness (2 x 1000 μm) VINYL ESTER 
•2 component – short pot life (45 min at 20 Ԩ) - Glass flake reinforced 
•Excellent resistance to abrasion, water and moisture – good for salt 
and fresh water environment and walkways 
POLYESTER 
5.1. Corrosion protection coatings – Application 
Spray application : Air spray vs Airless spray 
Air spray 
- Spray pattern 
easily adjusted 
- High quality of 
finishes 
(automotive) 
- Overspray 
causes high loss of 
coating 
- Add solvent to 
improve 
atomization but 
leads to low 
thickness 
Airless spray 
- Less overspray 
- Heavier film built 
- Better production 
rates 
-Little control of 
coating quantity 
- Speed makes it 
difficult for small 
pieces 
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5.1. Corrosion protection coatings – Application 
Brush application 
 Brush is only for 
o Small areas not easily 
accessible by spray 
o Repairs and touch-up 
o Stripe coats, corner, edges, 
welds, bolting, flanges 
o When environmental conditions 
prohibit the use of spray 
- Helps coating to have 
a good adhesion on 
substrate (for primers 
and underwater 
coatings) 
- Good penetration into 
surfaces that cannot be 
properly cleaned 
Roller application 
 Do not use roller unless specific client approval 
- Slow application (can 
be an advantage in 
some cases) 
- Low DFT achieved 
35 
5.1. Corrosion protection coatings – Protection 
mode 
Finish coat (polyurethane) 
Intermediate coat (Epoxy based) 
Zinc rich primer (inorganic zinc, zinc 
rich epoxy) 
Primer with inibitors (zinc phosphate) 
1 – Barrier 
2 – Galvanic 
3 – Inhibition 
36 Steel 
• Impermeability to water vapor, oxygen and salts 
(Chloride), thick film, electric resistance  
pigmented epoxies (high solid content, mica 
flakes) 
1. Barrier 
effect 
• Primer contains a metallic pigment with a more 
electronegative potential  inorganic zinc 
silicates and zinc rich organic primers (epoxies) 
2. Galvanic 
effect 
• Isolation of the substrate surface by addition of a 
metallic compound chemically bonded to the 
surface  zinc phosphate pigment 
3. Inhibition
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5.1. Corrosion protection coatings - Selection 
Selection of coating depends on: 
Atmospheric corrosivity of environment (marine C5M, 
industrial C5I, high C4, …) 
Substrate (carbon steel, stainless steel, galvanized 
steel, aluminum, CRA, …) 
Equipment operating temperature 
Durability of the coating / installation 
1 
2 
3 
4 
37 
5.1. Corrosion protection coatings – Specification 
Frequently encountered coating systems – Onshore offshore systems 
Substrate System DFT (μm) 
CS operating below 120 Ԩ 
(Uninsulated) 
Zinc rich primer (epoxy or inorganic zinc) 
Epoxy high build 
Polyurethane topcoat 
50-75 
150-200 
50 
CS operating between 120Ԩ and 450 Ԩ 
(Uninsulated) 
Inorganic zinc primer 
Al pigmented silicone 
Al pigmented silicone 
50-75 
25 
25 
SS operating below 120 Ԩ 
(Uninsulated) 
Epoxy primer, zinc free 
Epoxy high build 
Polyurethane topcoat 
50 
150-200 
50 
SS operating between 120Ԩ and 600 Ԩ 
(Uninsulated) 
Al pigmented silicone 
Al pigmented silicone 
25 
25 
Insulated CS and SS operating below 200 
Ԩ 
Epoxy phenolic 
Epoxy phenolic 
100 
100 
Insulated CS and SS operating between 
200 Ԩ and 600 Ԩ 
TSA 
Sealer (silicone) 
250 
40 
Bulk items (any substrate, any 
temperature, valves, piping, …) 
Universal coating, inorganic copolymer 
(compatible with PU topcoat for color 
marking) 
As per 
manufacturer 
38
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5.1. Corrosion protection coatings – Specification 
Frequently encountered coating systems – Onshore offshore systems 
Internal coatings (Carbon steel surfaces) 
Application System DFT (μm) 
Potable water below 60 Ԩ Solvent free epoxy 
Solvent free epoxy 
300 
300 
Crude oil, diesel, condensate, below 60 Ԩ: 
bottom up to 1m + roof and upper 1m of wall 
Abrasion resistant epoxy 
Abrasion resistant epoxy 
150-180 
150-180 
methanol, MEG below 80 Ԩ Inorganic zinc primer 60 
Process vessel below 120 Ԩ Solvent free epoxy Novolac 300-600 
Galvanized surfaces 
Substrate System DFT (μm) 
Galvanized steel operating below 120 Ԩ Epoxy primer, zinc free 
High build epoxy 
Polyurethane 
50 
100 
50 
39 
5.1. Corrosion protection coatings – Specification 
Antiskid surfaces 
Substrate System DFT (μm) 
Carbon steel Epoxy primer 
Frequently encountered coating systems – Subsea systems 
Substrate System DFT (μm) 
CS and SS in splash zone 
Abrasion resistant epoxy (glass flakes) 
300 
operating below 100 Ԩ 
Abrasion resistant epoxy (glass flakes) 
300 
CS and SS immersed 
operating below 100 Ԩ 
Abrasion resistant epoxy or high build epoxy 
Abrasion resistant epoxy or high build epoxy 
175 
175 
Ultra high build epoxy + non-skid aggregates 
Polyurethane 
50 
600-3000 
60 
Note: 1. Surface friction coefficient may need to be indicated. 
2. Use of Aluminum oxide (and other non-ferrous irregular surfaces) is preferred 
40
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5.1. Corrosion protection coatings – Specification 
Checks and Quality Controls 
Before painting application 
o Operator and inspector Qualification certificates 
o Instrumentation device calibration certificates 
 Surface preparation 
o Environmental conditions (Dew Point, surface T°C and Ambient T°C measurement), 
o Abrasive contamination, 
o Grade of cleanliness + surface roughness, 
o Chloride content + dust level 
 Painting application 
o Wet and dry film thickness, 
o Visual inspection 
 After painting application 
o Curing of inorganic zinc, 
o Adhesion test 
o Pinhole detection (only for immersed, underground and internal coatings) 
5.2 Specific coatings 
42 
 Metallizing 
 Passive Fire Protection 
 Fouling-release coatings
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5.2 Specific coatings: Metallizing (TSA) 
Thermal Spray Aluminum 
 Spraying of molten Aluminum wire by flame spray or arc spray 
 Good for immersion and CUI prevention. 
 Applied on Carbon steel or Stainless steel operating up to 600 Ԩ 
- Excellent corrosion 
protection properties 
- Excellent resistance to 
mechanical damages 
- Very high durability (up 
to 50 years) 
- Zero VOC. 
- Porous: need to apply a 
sealer on top (epoxy or 
silicone). 
- Cost effective process 
- HSE rules must be strictly 
followed. 
- Critical surface 
preparation: high degree 
of cleanliness required 
43 
5.2 Specific coatings: Metallizing (TSA) 
TSA coating systems 
Substrate System DFT (μm) 
CS and SS operating below 
TSA 
250 
120 Ԩ 
Epoxy sealer compatible with TSA 
40 
CS and SS operating above 
120Ԩ 
TSA 
Silicone sealer compatible with TSA 
250 
40 
Application examples 
 Bulk valves (all temperatures, CS and SS) 
 Offshore or immersed structures 
 Flare top 
TSA applicators 
 Norimax 
 WASCO 
 MTM Metalization 
44
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5.2 Specific coatings: Metallizing (TSA) 
Splitter column Turret component 
45 
5.2 Specific coatings: Metallizing 
Other Thermal Spray Coatings: 
 Zinc 
 Al-Zn 
 Stainless steel 
 Inconel 
 Copper Nickel 
 Monel 
 Hastelloy 
Harder material  Higher operating temperature gun 
46
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5.2 Specific coatings: PFP 
 Steel begins to lose strength as its temperature rises in a fire  structural collapse. 
 PFP is designed to protect structures supporting high risk and valuable equipment. 
 Objective: prevent the substrate to rise in temperature during a fire to avoid steel to collapse: 
o Jet fire 
o Hydrocarbon fire 
o Cellulosic fire 
1400 
1200 
1000 
800 
600 
400 
200 
0 
Fire Curves 
0 30 60 90 120 150 180 
Temperature °C 
Time (minutes) 
Cellulosic 
Hydrocarbon 
Jet Fire 
Jet fire: Release of hydrocarbon fuel 
under pressure through a relatively 
small opening such as a crack or hole 
 high levels of turbulence, “erosion” 
of the PFP coating. 
Pool fire: Hydrocarbon fuel burning 
under atmospheric pressure. 
47 
48 
5.2 Specific coatings: PFP 
Organic coatings: Intumescent epoxy 
They are inert at ambient temperature but react when exposed to 
temperatures above about 200ºC. The reacted coating forms a thick carbon 
based char. Applied with reinforcement mesh 
- Provides corrosion 
protection 
- Low DFT for 2h 
protection (2-10 
mm) 
- Low density 
- Requires the use 
of skilled applicators 
- Cost effective
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49 
Spray application equipment 
Source: PPG 
Typical Plural Component 
Pump 
Typical plural component 
mixing block and spray gun 
5.2 Specific coatings: PFP 
 Thickness of PFP is determined by: 
o Size, shape of steel section to protect (beams, hollow section) 
o Critical failure temperature 
o Duration of protection needed 
 Calculation of DFT with Hp/A value. 
The higher Hp/A value, the higher PFP thickness will be required. 
High Hp 
Low A 
Fast Heating 
Low Hp 
High A 
Slow Heating 
Source: PPG 
Hp = heated perimeter 
exposed to fire 
A = cross-section area of steel 
element 
5.2 Specific coatings: PFP 
50
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5.2 Specific coatings: PFP 
52 
5.2 Specific coatings: PFP 
Inorganic coatings: Cementitious 
Lightweight with nominal density around 500 kg/m3. 
Must be topcoated with a high water vapor permeability 
coating. Must also be applied with mesh reinforcement. 
- Cheap, easy to install 
and repair 
- Hard and durable 
- Heavy 
- Thickness around 25 mm 
for a 2h fire protection 
- Poor flexibility 
- Risk of hidden corrosion in 
reinforcement by water 
ingress
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5.2 Specific coatings: PFP 
PFP systems 
Substrate System DFT (μm) 
Fireproofed carbon steel 
surfaces 
Zinc rich epoxy or inorganic zinc silicate 
Intumescent PFP epoxy 
Polyurethane 
50 
As calculated 
50 
Fireproofed stainless steel 
surfaces 
Zinc free epoxy primer 
Intumescent PFP epoxy 
Polyurethane 
50 
As calculated 
50 
Fireproofed carbon steel 
surfaces 
Zinc rich epoxy or inorganic zinc silicate 
High build epoxy 
Cementitious PFP 
50 
150 
As calculated 
Fireproofed stainless steel 
surfaces 
Zinc free epoxy primer 
High build epoxy 
Cementitious PFP 
50 
150 
As calculated 
5.2 Specific coatings: Fouling release coatings 
Objective: prevent formation of biofouling on vessels and 
structures (mussels, barnacles, algae, etc.). 
2 mechanisms: fouling release coatings and antifouling 
coatings (biocide release). 
Fouling release coatings: 
- Silicones 
- Fluoro-polymer 
Prevent attachment of micro-organisms on the structure 
by creating a smooth finish with low surface tension. 
Source: PPG 
TBT-based coatings are prohibited 
54
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55 
5.2 Specific coatings: Fouling release coatings 
Fouling release system 
Substrate System DFT (μm) 
Any (riser, structure, hull, etc.) Epoxy primer 
Foul release coat (1 or 2 coats) 
Finish coat 
50-100 
200-600 
100-150 
Note: Fouling release systems depend on each coating manufacturer; all products of the system should 
be compatible with each other. The proposed system is for example only. 
56 
5.2 Specific coatings: Shop primers 
 Thin film inorganic zinc primer applied on applicator’s plant 
for more accurate control of application process. 
 Typical application: steel plates for tank storage. 
 Purpose: Protect against corrosion and environment during 
transport and before erection. 
 Primer is applied automatically or not at 15-30 μm. 
Source: TOTAL – GTS presentation
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57 
5.2 Specific coatings: Shop primers 
Source: TOTAL – GTS presentation 
58 
5.2 Specific coatings: Shop primers 
Source: TOTAL – GTS presentation
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59 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
59 
6.1 Pipe coating 
60 
 Selection 
 Properties 
 Standards 
 Systems 
 Subcontractors 
 Futures challlenges
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6.1. Pipe coating - Selection 
Pipeline protection = Combination of 
 Adequate protective coating, 
 Supplementary cathodic protection 
Selection of the coating system depends on: 
o Pipe material characteristics 
o Service / design temperature 
o Pipeline design thermal profile 
o Maximum water depth 
o Specific properties requirement (cathodic disbondment, elongation, strength, …) 
o Laying method 
61 
6.1. Pipe coating - Properties 
Properties for Corrosion protection coating 
Main properties 
o Strong adhesion to the pipe 
o Corrosion properties 
o Strong resistance to cathodic 
disbondment 
o Durability for design life of the 
pipe 
o Good mechanical strength 
62
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6.1. Pipe coating - Properties 
Properties for Thermal insulation coating 
 Pipes are insulated to prevent hydrate formation, waxing and to satisfy separator 
arrival temperature. 
Main properties 
o Thermal conductivity 
o Density 
o Adhesion to base material 
Properties for Weight coating 
Main properties 
o Density 
o Compressive strength 
63 
 Types of pipe coatings 
o Fusion Bonded Epoxy (FBE), Liquid epoxy 
o 3-layer Polyethylene (3LPE) / Polypropylene (3LPP) 
o MLPP Foam / syntactic 
o GSPU, SPU 
o Concrete Weight Coating (CWC) 
Corrosion 
protection 
Flow 
assurance 
Negative 
buoyancy 
6.1. Pipe coating - Properties 
64
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65 
6.1. Pipe coating - Standards 
International standards in pipe coating: ISO 21809 
 3LPE/PP: ISO 21809 - 1 
 FBE: ISO 21809 - 2 
 CWC: ISO 21809 - 5 
ISO 21809 replaces DIN (German), NF (French), CSA (Canadian) 
Other standards or specifications 
 AWWA (American Water Works Association): AWWA C213-07 (FBE) 
 DNV-RP-F106 (FBE, 3LPP, 3LPE) 
 NACE RP0394-2002 (FBE) 
 DNV-OS-F101 (CWC) 
 NO STANDARD FOR INSULATION COATING 
6.1. Pipe coating - Systems 
 Liquid coating 
- Mainly used for buried pipe operating at elevated temperature, where 3LPE and 3LPP cannot be 
considered. 
- Generally a high built coating applied by airless spray with DFT up to 3000 μm. 
- Maximum service temperature can go up to 200Ԩ , depending on the type of resin (epoxy, epoxy 
novolac, phenolic epoxy, vinyl ester). 
- Can be reinforced with glass flakes to improve moisture and mechanical resistance. 
- Can be applied as an internal lining to protect against corrosive fluid. In this case, thickness up to 
300 μm. 
66
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67 
6.1. Pipe coating - Systems 
 Fusion Bonded Epoxy (FBE) 
Coating system description Single layer fusion bonded epoxy 
Type of protection Corrosion protection 
Typical coating thickness 350-500 μm 
Design temperature 90Ԩ 
Water depth limit Unlimited 
Major characteristics - Excellent long term corrosion resistance to steel, 
- Cathodic disbondment resistance (reduce cost of 
cathodic protection) 
- Good chemical resistance. 
68 
6.1. Pipe coating - Systems 
 FBE coating process 
Source: Bredero Shaw
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69 
6.1. Pipe coating - Systems 
 Three Layer Polypropylene (3LPP) 
Coating system description FBE + PP Adhesive + Solid PP 
Type of protection Corrosion protection 
Mechanical protection 
Typical coating thickness 2- 4.5 mm 
Design temperature 110Ԩ (up to 130 Ԩ with high temperature FBE) 
Water depth limit Unlimited 
Major characteristics - High film thickness 
- Good PP flexibility  mechanical protection to the 
pipe. 
- Good impact strength 
70 
6.1. Pipe coating - Systems 
 3LPP coating process 
Source: Bredero Shaw
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71 
6.1. Pipe coating - Systems 
 Three Layer Polyethylene (3LPE) 
Coating system 
description 
FBE + PE Adhesive + Solid PE 
Type of protection Corrosion protection 
Mechanical protection 
Typical coating 
thickness 
2- 4.5 mm 
Design temperature 80Ԩ 
Water depth limit Unlimited 
Major characteristics - Cheaper than 3LPP, but does not have as good mechanical 
characteristics as 3LPP. 
3LPE process is the same as 3LPP 
72 
6.1. Pipe coating - Systems 
 Multilayer PP (MLPP) – Foam MLPP 
Coating system 
description 
FBE + PP Adhesive + (Solid PP) + PP Foam + Solid PP 
Type of protection Corrosion protection + Mechanical protection + Thermal 
insulation 
Typical coating 
thickness 
Depends on thermal requirements 
Design temperature 120Ԩ 
Water depth limit 600 m 
Major characteristics K-value around 0.17 W/m.K, density 600-800 kg/m3 
1. FBE 
2. 2. PP adhesive 
3. Solid PP 
4. PP foam 
5. Outer PP shield 
Source: Bredero Shaw
22/01/2014 
37 
73 
6.1. Pipe coating - Systems 
 Multilayer (MLPP) – Glass syntactic MLPP 
Coating system 
description 
FBE + PP Adhesive + (Solid PP) + GSPP + Solid PP 
Type of protection Corrosion protection + Mechanical protection + Thermal 
insulation 
Typical coating 
thickness 
Depends on thermal requirements 
Design temperature 130Ԩ 
Water depth limit 3000 m 
Major characteristics K-value around 0.16 W/m.K, density 650-700 kg/m3 
Hydrostatic pressure resistance is reinforced by glass 
microspheres added into the PP matrix. 
74 
6.1. Pipe coating - Systems 
 Syntactic PU - polymer syntactic (sPU) 
Coating system 
FBE + sPU 
description 
Type of protection Corrosion protection + Thermal insulation 
Typical coating 
Depends on thermal requirements 
thickness 
Design temperature 115Ԩ 
Water depth limit 300 m 
Major characteristics - K-value around 0.12 W/m.K, density 600-700 kg/m3 
- Thin wall + low polymer mechanical properties decrease 
compression resistance of the foam.
22/01/2014 
38 
75 
6.1. Pipe coating - Systems 
 Syntactic PU - Glass syntactic (GSPU) 
Coating system 
FBE + GSPU 
description 
Type of protection Corrosion protection + Thermal insulation 
Typical coating 
Depends on thermal requirements 
thickness 
Design temperature 130Ԩ 
Water depth limit 3000 m 
Major characteristics - K-value around 0.16 W/m.K, density 800 kg/m3 
- Hydrostatic pressure resistance reinforced by glass 
microspheres added into the PU matrix. 
- Grade of glass influences the collapse pressure and 
theoretical maximum water depth. 
76 
6.1. Pipe coating - Systems 
 Injection moulding PU process 
Source: Bredero Shaw
22/01/2014 
39 
 Concrete Weight Coating (CWC) 
 Purpose: provide negative buoyancy 
and mechanical protection to the pipe. 
 Mixture of cement, iron ore and wire wrap 
 Main properties: 
o Density (1900-3700 kg/m3): varies iron ore 
quantity. 
o Compressive strength: depends on cement 
and water content. 
o Thickness: depends on pipe diameter. 
o Water absorption: ISO standard recommend 
a maximum of 5% vol. 
 Reinforcement 
o Rigid preformed cages 
o Wire mesh fabric 
Source: Bredero Shaw 
6.1. Pipe coating - Systems 
77 
78 
6.1. Pipe coating - Systems 
 Concrete Weight coating 
Type of protection Negative buoyancy + Mechanical protection 
Typical coating thickness Depends on pipe diameter 
Design temperature N/A 
Water depth limit Unlimited 
Major characteristics Density (1900-3700 kg/m3): varies with iron ore quantity.
22/01/2014 
40 
79 
6.1. Pipe coating - Systems 
Concrete Weight Coating (CWC) 
 Impingement method 
Source: Bredero Shaw 
80 
6.1. Pipe coating - Systems 
Concrete Weight Coating (CWC) 
 Wrap-on method 
Source: Bredero Shaw
22/01/2014 
41 
81 
6.1. Pipe coating - Systems 
 Elastomer coatings (Neoprene, EPDM, butyl rubber, etc.) 
Mainly used for splash 
zone protection 
Be careful of chamfering 
 can cause failure of 
the bond 
Source: Yadana riser – F. Duesso 
82 
6.1. Pipe coating - Subcontractors 
APAC 
 Bredero Shaw 
 WASCO Energy 
Americas 
 Bredero Shaw 
 CRC Evans 
EMEA 
 Bredero Shaw 
 Eupec 
 Socotherm 
 Tenaris
22/01/2014 
42 
83 
Operators - Gap analysis with ISO 21809-1: Microsoft Excel 
Worksheet 
6.1. Pipe coating - Operators 
84 
6.1. Pipe coating - Operators 
Microsoft Excel 
Worksheet Operators - Gap analysis with ISO 21809-1: 
 ENI = based on ISO 
 TOTAL SHELL and PETRONAS: more stringent on different tests
22/01/2014 
43 
85 
6.1. Pipe coating – Future challenges 
 HT/HP 
- R&D programm in different pipe coating applicators and manufacturers 
to test different materials like glass syntactic silicones 
 Arctic 
- Bredero Shaw involved in JIP for new material in arctic conditions 
 Flexible weight coating 
 Ultra deep waters – thermal insulation 
6.2 Field joint coating 
86 
 Definition 
 Selection 
 Standards 
 Systems 
 S-Lay installation 
 Subcontractors
22/01/2014 
44 
6.2. Field joint coatings - Definition 
Field joint definition: Part of pipe left bare for welding prior to installation 
 Purpose of FJC: anticorrosion or thermal insulation. 
 Field joint is the weak point in a pipe coating system. 
 Welded joints are highly sensitive to corrosion. 
3LPP 
coating 
pipe 
 Cut back length shall be predetermined and mainly 
depends on type of FJC. 
 Properties shall be the same as the parent coating 
(pipe coating). 
 FJC are mostly applied in field  application shall 
be easy, fast and reliable. 
FJC 
 FJC = FBE, HSS, Polyolefin tapes, IMPP, IMPU, PE, PP, liquid resins 
87 
6.2. Field joint coatings - Selection 
Line pipe working conditions 
• density, thermal conductivity (if thermal 
insulation), coating breakdown factor 
Pipe laying environment 
• mechanical protection expected 
(impact strength, abrasion, 
compressive strength, flexibility, water 
absorption, curing time) 
Parent coating 
Parent coating FJC possibilities 
FBE FBE 
Heat Shrinkable Sleeves 
Liquid coating 
Polyethylene HSS 
Liquid coating 
PE flame spray 
Polypropylene PP flame spray / tapes 
IMPU 
IMPP 
Liquid coating 
Concrete coating HSS + HDPUF 
88
22/01/2014 
45 
6.2. Field joint coatings - Standards 
International standards in field joint coating: ISO 21809 
 ISO 21809 - 3 
Other standards or specifications 
 DNV-RP-F102 
 NACE RP0303 - HSS 
 EN 12068 – tapes and HSS 
 NO STANDARD FOR INSULATION COATING 
89 
6.2. Field joint coatings - Systems 
 FBE 
Coating system 
description 
FBE 
Type of protection Corrosion protection 
Typical coating 
350-500 μm 
thickness 
Design temperature 90Ԩ, modified epoxies can withstand higher temperatures 
Water depth limit Unlimited 
Major characteristics - The most widely used coating 
- Good chemical resistance 
- Very good corrosion protection 
- Very common and easy to find subcontractors 
- Low impact resistance 
Overlap on parent 
coating 
50 mm 
90
22/01/2014 
46 
6.2. Field joint coatings - Systems 
 Heat Shrink Sleeves: 2-layers (mastic HSS) 
Coating system 
description 
Mastic adhesive + Polyolefin backing on St3 steel 
Type of protection Corrosion protection 
Typical coating 
2 mm 
thickness 
Design temperature Up to 100Ԩ (depending on product: PE or PP) 
Water depth limit 3000 m 
Major characteristics Manual application with gas torch 
Example of HSS system PE: 
- KLNN Canusa 
- WPC 100M (Berry Plastic) 
PP: 
- GTS PP 100 
Overlap on parent 
coating 
100 mm 
91 
6.2. Field joint coatings - Systems 
 Heat Shrink Sleeves: 3-layers (hot-melt HSS) 
Coating system 
description 
Liquid epoxy + hot-melt adhesive + Polyolefin backing on Sa 
21/2 steel 
Type of protection Corrosion protection 
Typical coating thickness 2 mm 
Design temperature > 100Ԩ (depending on product: PE or PP) 
Water depth limit 3000 m 
Major characteristics Manual application with gas torch 
Example of HSS system PE: 
- GTS 80 (Canusa) 
- HTLP80 (Berry Plastic) 
PP: 
- GTS PP (Canusa) 
Overlap on parent 
coating 
100 mm 
92
22/01/2014 
47 
6.2. Field joint coatings - Systems 
 PP tape wrap 
Coating system 
description 
FBE + Adhesive PP + PP tape 
Type of protection Corrosion protection 
Typical coating 
3 mm 
thickness 
Design temperature 110Ԩ 
Water depth limit 3000 m 
Major characteristics - Applied in spiral or wrapped by hand or by wrapster 
with the determined overlap (50% recommended). 
- Only compatible with 3LPP pipeline coating 
Example of tape wrap 
system 
FBE: Scotchkote 226N (3M) 
Adhesive: Hifax EP 510/60m (Basell) 
PP tape: Hifax EP 510/60 (Basell) 
Overlap on parent 
coating 
70 mm 
93 
6.2. Field joint coatings - Systems 
 Flame spray PP 
Coating system 
description 
FBE + Adhesive PP + PP powder 
Type of protection Corrosion protection 
Typical coating 
3 mm 
thickness 
Design temperature 110Ԩ 
Water depth limit 3000 m 
Major characteristics Similar to tape wrap 
Overlap on parent 
70 mm 
coating 
94
22/01/2014 
48 
6.2. Field joint coatings - Systems 
 Injection moulded polyurethane (IMPU) 
Coating system 
description 
FBE + Solid PU or PU primer + Solid PU 
Type of protection Corrosion protection + thermal insulation 
Typical coating 
+4 mm 
thickness 
Design temperature Up to 130Ԩ 
Water depth limit 3000 m 
Example of system FBE: Scotchkote 226N (3M) 
Solid PU: Hyperlast FJ302 (DOW) 
Overlap on parent 
coating 
70 mm 
95 
6.2. Field joint coatings - Systems 
 Injection moulded polypropylene (IMPP) 
Coating system 
description 
FBE + PP adhesive + Moulded PP 
Type of protection Corrosion protection + thermal insulation 
Typical coating 
4-10 mm 
thickness 
Design temperature Up to 110Ԩ (130Ԩ with high temp. FBE) 
Water depth limit 3000 m 
Example of system FBE: Scotchkote 226N (3M) 
Adhesive: BB 127E (Borealis) or Hifax EP5 10/60 (Basell) 
Solid PP: EA 165E (Borealis) or CA 197 (Basell) 
Overlap on parent 
coating 
70 mm 
96
22/01/2014 
49 
6.2. Field joint coatings – S-lay installation 
S-lay: 
 Firing line is horizontal 
 Pipeline is support by a stinger to avoid high bending stress. 
97 
6.2. Field joint coatings – S-lay installation 
98
22/01/2014 
50 
6.2. Field joint coatings – Subcontractors 
Bredero 
Shaw 
Canusa CPS 
PIH 
OJS 
FBE, IMPU, IMPP 
HSS, liquid epoxy, tape wrap 
FBE, flame spray PP & PE, HSS, IMPU, IMPP, PU 
foam infill 
HDPUF, HSS 
99 
10 
0 
Summary 
1. HSE moment 
2. Reason for coating 
3. Corrosion prevention - Generality 
4. Surface preparation 
5. Painting & coating 
6. Pipe & field joint coating 
7. Coating qualification – process and requirement 
100
22/01/2014 
51 
7. Coating qualification 
101 
 Painting 
 Pipe and field joint coatings 
7. Coating qualification - Painting 
Norsok M501 rev.6 
CS surfaces operating < 120 Ԩ 
Ballast water tanks/ seawater filled 
vessels 
Anti-slip for walkways, escape 
routes, lay down areas 
Intumescent epoxy + cementitious 
PFP 
Splash zone and immersed surfaces 
1 
3B 
4 
5 
7 
102
22/01/2014 
52 
7. Coating qualification - Painting 
Norsok M501 rev.6 
Test (acc. to ISO 20340) Assessment method Acceptance criteria 
Seawater immersion 
ISO 4624- pull-off test 
5MPa 
- 4200h 
ISO 4628-3,4,5,6 
No defect 
- For system 3B, 7A, 7B, 7C and 1 
when used in tidal or splash zone 
Ageing 
- 4200h 
- For system 1, 3B, 4, 5A, 5B, 7A 
ISO 4624- pull-off test 
ISO 4628 
5MPa 
No defect 
Cathodic disbonding 
- 4 weeks 
- For system 3B, 7A, 7B, 7C, 1 when 
used in splash or tidal zone 
ISO 15711 Max. 20 mm 
103 
7. Coating qualification 
Shell systems that need to be qualified as per DEP 
TSA (DEP 30.48.40.31) 
DFT checking 
Ballast water tanks/ seawater filled 
vessels 
Anti-slip for walkways, escape 
routes, lay down areas 
Intumescent epoxy + cementitious 
PFP 
Splash zone and immersed surfaces 
104
22/01/2014 
53 
7. Coating qualification 
Shell systems that need to be qualified as per DEP - TSA 
Test Assessment 
method 
Measurement Acceptance criteria 
Visual examination ISO 14918 100% surface Uniform appearance, no defect 
or blisters 
Coating thickness ISO 2808 Min. 5 Min. 250 μm 
Coating adhesion ISO 4624 Min. 3 > 7 MPa 
Overall quality Bend test (DEP) Min. 3 Minor cracks 
Sealer Visual inspection 100% surface No open pores at the surface 
 Check every step of the ITP. 
 The process leads to qualification of: 
o operators (blasters, sprayers), 
o equipment, 
o subcontractor coating procedure. 
 Example of PQT done for Prelude FLNG 
Microsoft Word 
7 - 2003 Documen 
Adobe Acrobat 
Document 
105 
7. Coating qualification – Pipe & FJC 
Qualification of 3LPE and 3LPP as per ISO 21809-1: Adobe Acrobat 
Document 
Properties 3LPE 3LPP 
Continuity Zero defect Zero defect 
Impact strength > 7 J/mm > 10 J/mm 
Indentation at 23 Ԩ 
< 0.2 mm 
< 0.1 mm 
Indentation at max temp. 
< 0.4 mm 
< 0.4 mm 
Elongation at break > 400 % > 400 % 
Peel strength at 23 Ԩ 
> 15 N/mm 
Peel strength at max. Temp. 
> 3 N/mm 
> 25 N/mm 
> 4 N/mm 
Cathodic disbondment 23 Ԩ, 28 d 
Cathodic disbondment 65 Ԩ, 24 h 
Cathodic disbondment max. temp., 28 d 
< 7 mm 
< 7 mm 
< 15 mm 
< 7 mm 
< 7 mm 
< 15 mm 
Hot water immersion test (80 Ԩ, 48h) Average < 2 mm and 
max. < 3 mm 
Average < 2 mm and 
max. < 3 mm 
Flexibilitty No cracking at 2° angle No cracking at 2° angle 
Curing of epoxy As per manufacturer As per manufacturer 
106
22/01/2014 
54 
Sources 
Bibliography: 
[1] NACE CIP 1 Manual 
[2] Encyclopedie de la peinture: formuler, fabriquer, appliquer, tome 1 
[3] ISO 8501-1 
[4] ISO 21809-1 to 5 
[5] PPG – PFP and Fouling release coating presentation 
Websites: 
[6] www.nace.com 
[7] http://www.corrosion-doctors.org/Seawater/Fouling.htm 
[8] www.brederoshaw.com 
107 
Thank you 
108

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Coating presentation tp bangkok 23 jan 2014

  • 1. 22/01/2014 1 Coating Overview Audrey BERGERON Bangkok – January 23rd 2014 1 2 About the instructor Title Coating specialist Region / Entity Asia Pacific / TPS Business segment Subsea – Onshore Offshore Education Meng./ Chemical Engineering Contact abergeron@technip.com
  • 2. 22/01/2014 2 3 About Technip Singapore • Shallow to deep water (3000 m) • S-laying • Rigidd pipes (4” to 60 “) • Piggy-backed pipeline installation • Pipe-in-pipe, CRA OFFSHORE PIPELINE INSTALLATION • Lifting up to 1200 tons • Installation of platform, subsea structures, skids, modules, etc. OFFSHORE STRUCTURE INSTALLATION, HEAVY LIFTING 4 About Technip Singapore • Spools • Risers • Buckle Initiator Structures • PLEM • Manifolds • Skids • Crossing Structures • Installation Aids FABRICATION SERVICES • Full-time divers • Saturation to 300m • Pipelines, platform, SCM de-commissioning / removal DIVING, IMR, DECOMMIS-SIONING
  • 3. 22/01/2014 3 5 About Technip Singapore G1201 - 3rd Generation DP Pipelay Vessel incl. 1200MT Pedestal Crane Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 6
  • 4. 22/01/2014 4 7 Abbreviations 3LPP/PE: CS: CUI: CWC: FBE: FJC: GSPU: HP/HT: HSS: MLPP/PE: PE: PFP: PP: PU: SPU: SS: TSA: Three Layer PolyPropylene / PolyEthylene Carbon Steel Corrosion Under Insulation Concrete Weight Coating Fusion-Bonded Epoxy Field Joint Coating Glass Syntactic PolyUrethane High Pressure/ High Temperature Heat Shrinkable Sleeves Multi-Layer PolyPropylene / PolyEthylene PolyEthylene Passive Fire Protection PolyPropylene PolyUrethane Syntactic PolyUrethane Stainless Steel Thermal Spray Aluminum 8 Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 8
  • 5. 22/01/2014 5 1. HSE moment Find the difference: 9 1. HSE moment 10
  • 6. 22/01/2014 6 11 Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 11 2. Reason for coating Why do we need coating? What kind of coating? Corrosion protection  Anti corrosion paint Passive Fire Protection (PFP)  Intumescent Epoxy  Cementitious coating Fouling release  Anti fouling paint 12
  • 7. 22/01/2014 7 2. Reason for coating Mechanical protection  Polyolefin coatings Negative buoyancy  Concrete weight coating Prevent CUI (corrosion under insulation)  Metallizing (Thermal spray aluminum) 13 2. Reason for coating Anti slip  Paint + natural aggregate Insulation  PU foam Aesthetic aspect  Polyurethane, Acrylic 14
  • 8. 22/01/2014 8 15 Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 15 16 3. Introduction to corrosion According to NACE: “ Corrosion is a deterioration of a material because of reaction with its environment.” Liquid water is in contact with metal AND corrosive agent is present in the water CORROSION =
  • 9. 22/01/2014 9 17 3. Introduction to corrosion  Corrosion impact: o Safety: unsafe corroded structures / equipment o Cost: For the US, the annual cost of corrosion worldwide is around 3% of GDP (US$ 250 Billion) 18 3. Introduction to corrosion  Different types of corrosion  Uniform corrosion o Uniform loss of mass for external surfaces. Concerns mainly carbon steel and cast iron. o Solution: corrosion allowance (3 to 6 mm), painting, cathodic protection.  Galvanic corrosion o Creation of an electric current between 2 materials with different potential. o Common cases: aluminum/stainless steel, carbon steel/stainless steel. o Solution: isolation joints, cathodic protection, coating  Erosion corrosion o Erosion (abrasion): removal of metal by mechanical action of liquids (or solids). Erosion-corrosion :removal of corrosion products by mechanical action of liquids ( or solids). o Solution: improve flow by design of the piece, change for better material, corrosion allowance
  • 10. 22/01/2014 10 19 3. Introduction to corrosion Different types of corrosion  Pitting corrosion o High chloride concentration leads to passivation layer breakdown. o Affects stainless steel, aluminum, titanium o Solution: increase molybdenum content in SS (CRA), coating  Chloride stress corrosion cracking o Combined action of seawater and mechanical stress o 316 Austenitic stainless steels subject to CSCC if chloride concentration > 50 ppm and temperature > 50Ԩ o Solution: coating, change material grade (316 SS to 22Cr or 25Cr) 20 3. Introduction to corrosion Design Corrosion prevention Coating Chemical treatment Material selection Cathodic protection
  • 11. 22/01/2014 11 21 3. Introduction to corrosion How to prevent corrosion?  Design: avoid water retention, moisture / salts entrapment  Inhibitors: chemical added into a fluid to decrease corrosion rate  Material selection. Examples: o SS 304L very sensitive to CSCC in offshore environment. SS 316L, 22Cr duplex or Inconel 625 are preferred. o Carbon Steel can be selected for offshore structures, provided it is protected by coating and cathodic protection.  Cathodic protection: protection of the surface by another “sacrificial” metal (Zn, Al, Mg, …) who has a more electronegative potential.  Protective coating 22 Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 22
  • 12. 22/01/2014 12 4. Surface preparation Surface preparation: The key step to the coating success Clean the surface from contaminant Create roughness for coating adhesion. objectives grease dust mill scale oil Soluble salts Former coating contaminants Long term stability to the coating Did you know? 75% of premature coating failures are caused by inadequate or improper surface preparation 23 4. Surface preparation Selection of the method depends on: Substrate: carbon steel, stainless steel, Aluminum, galvanized steel … Degree of cleanliness required (paint system type and thickness) Geometry of the piece (area difficult to access with machines) Place where surface is prepared (on site, applicator’s plant) 24
  • 13. 22/01/2014 13 4. Surface preparation 1. Prior to commencement • check for fabrication or welding defaults: rough edges, cuts and welds shall be rounded to a 2mm radius to improve coating coverage and adhesion on the surface. • remove weld spatters. 2. Solvent cleaning. Degrease and remove oil, grease, soluble contaminants with solvent cleaning (fresh water, emulsion cleaners, detergents, organic solvents, petroleum based solvents, alkaline cleaners). Does not remove Chlorides, mill scale or other inorganic materials. 3. Abrasive blasting or other method Remove chlorides and sulfates, create desired surface profile for primer adhesion, create a uniform aspect. 25 4. Surface preparation steel shot or grit (carbon steel surfaces), aluminum oxide or garnet sand (stainless steel or carbon steel surfaces). Projection of abrasive particles to remove rust and other contaminant and create a rough surface Abrasive blast cleaning 26
  • 14. 22/01/2014 14 4. Surface preparation Abrasive blasting equipment 27 Surface preparation: other methods Power tool cleaning (hand or mechanical). Example: rotary wire brush. Water jetting. Only to remove previous coating, does not create roughness. Pickling. Dipping of steel in an acid bath 4. Surface preparation 28
  • 15. 22/01/2014 15 4. Surface preparation Substrate Type of system Cleanliness (ISO 8501-1 or SSPC) Profile surface (ISO 8503) Carbon steel – external surfaces Typical paint system with DFT > 200μm Sa 2 ½ eq. to SSPC SP10 50-75 μm Carbon steel – internal surfaces Internal coating (“lining”) Sa 3 eq. to SSPC SP5 or Sa 2 ½ eq. to SSPC SP10 50-75 μm Stainless steel, Galvanized steel Typical paint system Sweep blasting eq. to SSPC SP7 20-40 μm - Carbon steel - Stainless steel TSA - Sa 3 eq. to SSPC SP5 - Sweep blasting eq. to SSPC SP7 70-120 μm 29 30 Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 30
  • 16. 22/01/2014 16 5.1 Corrosion protection coatings 31  Definition  Application  Selection  Protection mode  Specification 32 5.1. Corrosion protection coatings - Definition PAINT = A+B Pigments + fillers Binder (polymer) Solvent Additives Reactive + solvent Component A Component B
  • 17. 22/01/2014 17 33 5.1. Corrosion protection coatings - Definition Major paint used for corrosion protection purpose • 2 component- thermoset coatings • Excellent adhesion, chemical and water resistance • Shall be top-coated by UV-resistant topcoat EPOXY • 2 component • POLYURETHANE Resistant to UV, good gloss and color retention • 2 component – min. zinc content 85% • Very high substrate adhesion – good chemical resistance • Max thickness 80 μm, subject to mud-cracking -careful with repairs INORGANIC ZINC • Cure at ambient temp. or with help of heat SILICONES • For heat resistance up to 600 Ԩ, or foul release • 2 component coatings • Very good for immersion service • Suitable up to 230 Ԩ PHENOLIC EPOXIES • 2 component – used as linings – very resistant to chemicals and temp. • High thickness (2 x 1000 μm) VINYL ESTER •2 component – short pot life (45 min at 20 Ԩ) - Glass flake reinforced •Excellent resistance to abrasion, water and moisture – good for salt and fresh water environment and walkways POLYESTER 5.1. Corrosion protection coatings – Application Spray application : Air spray vs Airless spray Air spray - Spray pattern easily adjusted - High quality of finishes (automotive) - Overspray causes high loss of coating - Add solvent to improve atomization but leads to low thickness Airless spray - Less overspray - Heavier film built - Better production rates -Little control of coating quantity - Speed makes it difficult for small pieces 34
  • 18. 22/01/2014 18 5.1. Corrosion protection coatings – Application Brush application  Brush is only for o Small areas not easily accessible by spray o Repairs and touch-up o Stripe coats, corner, edges, welds, bolting, flanges o When environmental conditions prohibit the use of spray - Helps coating to have a good adhesion on substrate (for primers and underwater coatings) - Good penetration into surfaces that cannot be properly cleaned Roller application  Do not use roller unless specific client approval - Slow application (can be an advantage in some cases) - Low DFT achieved 35 5.1. Corrosion protection coatings – Protection mode Finish coat (polyurethane) Intermediate coat (Epoxy based) Zinc rich primer (inorganic zinc, zinc rich epoxy) Primer with inibitors (zinc phosphate) 1 – Barrier 2 – Galvanic 3 – Inhibition 36 Steel • Impermeability to water vapor, oxygen and salts (Chloride), thick film, electric resistance  pigmented epoxies (high solid content, mica flakes) 1. Barrier effect • Primer contains a metallic pigment with a more electronegative potential  inorganic zinc silicates and zinc rich organic primers (epoxies) 2. Galvanic effect • Isolation of the substrate surface by addition of a metallic compound chemically bonded to the surface  zinc phosphate pigment 3. Inhibition
  • 19. 22/01/2014 19 5.1. Corrosion protection coatings - Selection Selection of coating depends on: Atmospheric corrosivity of environment (marine C5M, industrial C5I, high C4, …) Substrate (carbon steel, stainless steel, galvanized steel, aluminum, CRA, …) Equipment operating temperature Durability of the coating / installation 1 2 3 4 37 5.1. Corrosion protection coatings – Specification Frequently encountered coating systems – Onshore offshore systems Substrate System DFT (μm) CS operating below 120 Ԩ (Uninsulated) Zinc rich primer (epoxy or inorganic zinc) Epoxy high build Polyurethane topcoat 50-75 150-200 50 CS operating between 120Ԩ and 450 Ԩ (Uninsulated) Inorganic zinc primer Al pigmented silicone Al pigmented silicone 50-75 25 25 SS operating below 120 Ԩ (Uninsulated) Epoxy primer, zinc free Epoxy high build Polyurethane topcoat 50 150-200 50 SS operating between 120Ԩ and 600 Ԩ (Uninsulated) Al pigmented silicone Al pigmented silicone 25 25 Insulated CS and SS operating below 200 Ԩ Epoxy phenolic Epoxy phenolic 100 100 Insulated CS and SS operating between 200 Ԩ and 600 Ԩ TSA Sealer (silicone) 250 40 Bulk items (any substrate, any temperature, valves, piping, …) Universal coating, inorganic copolymer (compatible with PU topcoat for color marking) As per manufacturer 38
  • 20. 22/01/2014 20 5.1. Corrosion protection coatings – Specification Frequently encountered coating systems – Onshore offshore systems Internal coatings (Carbon steel surfaces) Application System DFT (μm) Potable water below 60 Ԩ Solvent free epoxy Solvent free epoxy 300 300 Crude oil, diesel, condensate, below 60 Ԩ: bottom up to 1m + roof and upper 1m of wall Abrasion resistant epoxy Abrasion resistant epoxy 150-180 150-180 methanol, MEG below 80 Ԩ Inorganic zinc primer 60 Process vessel below 120 Ԩ Solvent free epoxy Novolac 300-600 Galvanized surfaces Substrate System DFT (μm) Galvanized steel operating below 120 Ԩ Epoxy primer, zinc free High build epoxy Polyurethane 50 100 50 39 5.1. Corrosion protection coatings – Specification Antiskid surfaces Substrate System DFT (μm) Carbon steel Epoxy primer Frequently encountered coating systems – Subsea systems Substrate System DFT (μm) CS and SS in splash zone Abrasion resistant epoxy (glass flakes) 300 operating below 100 Ԩ Abrasion resistant epoxy (glass flakes) 300 CS and SS immersed operating below 100 Ԩ Abrasion resistant epoxy or high build epoxy Abrasion resistant epoxy or high build epoxy 175 175 Ultra high build epoxy + non-skid aggregates Polyurethane 50 600-3000 60 Note: 1. Surface friction coefficient may need to be indicated. 2. Use of Aluminum oxide (and other non-ferrous irregular surfaces) is preferred 40
  • 21. 22/01/2014 21 41 5.1. Corrosion protection coatings – Specification Checks and Quality Controls Before painting application o Operator and inspector Qualification certificates o Instrumentation device calibration certificates  Surface preparation o Environmental conditions (Dew Point, surface T°C and Ambient T°C measurement), o Abrasive contamination, o Grade of cleanliness + surface roughness, o Chloride content + dust level  Painting application o Wet and dry film thickness, o Visual inspection  After painting application o Curing of inorganic zinc, o Adhesion test o Pinhole detection (only for immersed, underground and internal coatings) 5.2 Specific coatings 42  Metallizing  Passive Fire Protection  Fouling-release coatings
  • 22. 22/01/2014 22 5.2 Specific coatings: Metallizing (TSA) Thermal Spray Aluminum  Spraying of molten Aluminum wire by flame spray or arc spray  Good for immersion and CUI prevention.  Applied on Carbon steel or Stainless steel operating up to 600 Ԩ - Excellent corrosion protection properties - Excellent resistance to mechanical damages - Very high durability (up to 50 years) - Zero VOC. - Porous: need to apply a sealer on top (epoxy or silicone). - Cost effective process - HSE rules must be strictly followed. - Critical surface preparation: high degree of cleanliness required 43 5.2 Specific coatings: Metallizing (TSA) TSA coating systems Substrate System DFT (μm) CS and SS operating below TSA 250 120 Ԩ Epoxy sealer compatible with TSA 40 CS and SS operating above 120Ԩ TSA Silicone sealer compatible with TSA 250 40 Application examples  Bulk valves (all temperatures, CS and SS)  Offshore or immersed structures  Flare top TSA applicators  Norimax  WASCO  MTM Metalization 44
  • 23. 22/01/2014 23 5.2 Specific coatings: Metallizing (TSA) Splitter column Turret component 45 5.2 Specific coatings: Metallizing Other Thermal Spray Coatings:  Zinc  Al-Zn  Stainless steel  Inconel  Copper Nickel  Monel  Hastelloy Harder material  Higher operating temperature gun 46
  • 24. 22/01/2014 24 5.2 Specific coatings: PFP  Steel begins to lose strength as its temperature rises in a fire  structural collapse.  PFP is designed to protect structures supporting high risk and valuable equipment.  Objective: prevent the substrate to rise in temperature during a fire to avoid steel to collapse: o Jet fire o Hydrocarbon fire o Cellulosic fire 1400 1200 1000 800 600 400 200 0 Fire Curves 0 30 60 90 120 150 180 Temperature °C Time (minutes) Cellulosic Hydrocarbon Jet Fire Jet fire: Release of hydrocarbon fuel under pressure through a relatively small opening such as a crack or hole  high levels of turbulence, “erosion” of the PFP coating. Pool fire: Hydrocarbon fuel burning under atmospheric pressure. 47 48 5.2 Specific coatings: PFP Organic coatings: Intumescent epoxy They are inert at ambient temperature but react when exposed to temperatures above about 200ºC. The reacted coating forms a thick carbon based char. Applied with reinforcement mesh - Provides corrosion protection - Low DFT for 2h protection (2-10 mm) - Low density - Requires the use of skilled applicators - Cost effective
  • 25. 22/01/2014 25 49 Spray application equipment Source: PPG Typical Plural Component Pump Typical plural component mixing block and spray gun 5.2 Specific coatings: PFP  Thickness of PFP is determined by: o Size, shape of steel section to protect (beams, hollow section) o Critical failure temperature o Duration of protection needed  Calculation of DFT with Hp/A value. The higher Hp/A value, the higher PFP thickness will be required. High Hp Low A Fast Heating Low Hp High A Slow Heating Source: PPG Hp = heated perimeter exposed to fire A = cross-section area of steel element 5.2 Specific coatings: PFP 50
  • 26. 22/01/2014 26 51 5.2 Specific coatings: PFP 52 5.2 Specific coatings: PFP Inorganic coatings: Cementitious Lightweight with nominal density around 500 kg/m3. Must be topcoated with a high water vapor permeability coating. Must also be applied with mesh reinforcement. - Cheap, easy to install and repair - Hard and durable - Heavy - Thickness around 25 mm for a 2h fire protection - Poor flexibility - Risk of hidden corrosion in reinforcement by water ingress
  • 27. 22/01/2014 27 53 5.2 Specific coatings: PFP PFP systems Substrate System DFT (μm) Fireproofed carbon steel surfaces Zinc rich epoxy or inorganic zinc silicate Intumescent PFP epoxy Polyurethane 50 As calculated 50 Fireproofed stainless steel surfaces Zinc free epoxy primer Intumescent PFP epoxy Polyurethane 50 As calculated 50 Fireproofed carbon steel surfaces Zinc rich epoxy or inorganic zinc silicate High build epoxy Cementitious PFP 50 150 As calculated Fireproofed stainless steel surfaces Zinc free epoxy primer High build epoxy Cementitious PFP 50 150 As calculated 5.2 Specific coatings: Fouling release coatings Objective: prevent formation of biofouling on vessels and structures (mussels, barnacles, algae, etc.). 2 mechanisms: fouling release coatings and antifouling coatings (biocide release). Fouling release coatings: - Silicones - Fluoro-polymer Prevent attachment of micro-organisms on the structure by creating a smooth finish with low surface tension. Source: PPG TBT-based coatings are prohibited 54
  • 28. 22/01/2014 28 55 5.2 Specific coatings: Fouling release coatings Fouling release system Substrate System DFT (μm) Any (riser, structure, hull, etc.) Epoxy primer Foul release coat (1 or 2 coats) Finish coat 50-100 200-600 100-150 Note: Fouling release systems depend on each coating manufacturer; all products of the system should be compatible with each other. The proposed system is for example only. 56 5.2 Specific coatings: Shop primers  Thin film inorganic zinc primer applied on applicator’s plant for more accurate control of application process.  Typical application: steel plates for tank storage.  Purpose: Protect against corrosion and environment during transport and before erection.  Primer is applied automatically or not at 15-30 μm. Source: TOTAL – GTS presentation
  • 29. 22/01/2014 29 57 5.2 Specific coatings: Shop primers Source: TOTAL – GTS presentation 58 5.2 Specific coatings: Shop primers Source: TOTAL – GTS presentation
  • 30. 22/01/2014 30 59 Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 59 6.1 Pipe coating 60  Selection  Properties  Standards  Systems  Subcontractors  Futures challlenges
  • 31. 22/01/2014 31 6.1. Pipe coating - Selection Pipeline protection = Combination of  Adequate protective coating,  Supplementary cathodic protection Selection of the coating system depends on: o Pipe material characteristics o Service / design temperature o Pipeline design thermal profile o Maximum water depth o Specific properties requirement (cathodic disbondment, elongation, strength, …) o Laying method 61 6.1. Pipe coating - Properties Properties for Corrosion protection coating Main properties o Strong adhesion to the pipe o Corrosion properties o Strong resistance to cathodic disbondment o Durability for design life of the pipe o Good mechanical strength 62
  • 32. 22/01/2014 32 6.1. Pipe coating - Properties Properties for Thermal insulation coating  Pipes are insulated to prevent hydrate formation, waxing and to satisfy separator arrival temperature. Main properties o Thermal conductivity o Density o Adhesion to base material Properties for Weight coating Main properties o Density o Compressive strength 63  Types of pipe coatings o Fusion Bonded Epoxy (FBE), Liquid epoxy o 3-layer Polyethylene (3LPE) / Polypropylene (3LPP) o MLPP Foam / syntactic o GSPU, SPU o Concrete Weight Coating (CWC) Corrosion protection Flow assurance Negative buoyancy 6.1. Pipe coating - Properties 64
  • 33. 22/01/2014 33 65 6.1. Pipe coating - Standards International standards in pipe coating: ISO 21809  3LPE/PP: ISO 21809 - 1  FBE: ISO 21809 - 2  CWC: ISO 21809 - 5 ISO 21809 replaces DIN (German), NF (French), CSA (Canadian) Other standards or specifications  AWWA (American Water Works Association): AWWA C213-07 (FBE)  DNV-RP-F106 (FBE, 3LPP, 3LPE)  NACE RP0394-2002 (FBE)  DNV-OS-F101 (CWC)  NO STANDARD FOR INSULATION COATING 6.1. Pipe coating - Systems  Liquid coating - Mainly used for buried pipe operating at elevated temperature, where 3LPE and 3LPP cannot be considered. - Generally a high built coating applied by airless spray with DFT up to 3000 μm. - Maximum service temperature can go up to 200Ԩ , depending on the type of resin (epoxy, epoxy novolac, phenolic epoxy, vinyl ester). - Can be reinforced with glass flakes to improve moisture and mechanical resistance. - Can be applied as an internal lining to protect against corrosive fluid. In this case, thickness up to 300 μm. 66
  • 34. 22/01/2014 34 67 6.1. Pipe coating - Systems  Fusion Bonded Epoxy (FBE) Coating system description Single layer fusion bonded epoxy Type of protection Corrosion protection Typical coating thickness 350-500 μm Design temperature 90Ԩ Water depth limit Unlimited Major characteristics - Excellent long term corrosion resistance to steel, - Cathodic disbondment resistance (reduce cost of cathodic protection) - Good chemical resistance. 68 6.1. Pipe coating - Systems  FBE coating process Source: Bredero Shaw
  • 35. 22/01/2014 35 69 6.1. Pipe coating - Systems  Three Layer Polypropylene (3LPP) Coating system description FBE + PP Adhesive + Solid PP Type of protection Corrosion protection Mechanical protection Typical coating thickness 2- 4.5 mm Design temperature 110Ԩ (up to 130 Ԩ with high temperature FBE) Water depth limit Unlimited Major characteristics - High film thickness - Good PP flexibility  mechanical protection to the pipe. - Good impact strength 70 6.1. Pipe coating - Systems  3LPP coating process Source: Bredero Shaw
  • 36. 22/01/2014 36 71 6.1. Pipe coating - Systems  Three Layer Polyethylene (3LPE) Coating system description FBE + PE Adhesive + Solid PE Type of protection Corrosion protection Mechanical protection Typical coating thickness 2- 4.5 mm Design temperature 80Ԩ Water depth limit Unlimited Major characteristics - Cheaper than 3LPP, but does not have as good mechanical characteristics as 3LPP. 3LPE process is the same as 3LPP 72 6.1. Pipe coating - Systems  Multilayer PP (MLPP) – Foam MLPP Coating system description FBE + PP Adhesive + (Solid PP) + PP Foam + Solid PP Type of protection Corrosion protection + Mechanical protection + Thermal insulation Typical coating thickness Depends on thermal requirements Design temperature 120Ԩ Water depth limit 600 m Major characteristics K-value around 0.17 W/m.K, density 600-800 kg/m3 1. FBE 2. 2. PP adhesive 3. Solid PP 4. PP foam 5. Outer PP shield Source: Bredero Shaw
  • 37. 22/01/2014 37 73 6.1. Pipe coating - Systems  Multilayer (MLPP) – Glass syntactic MLPP Coating system description FBE + PP Adhesive + (Solid PP) + GSPP + Solid PP Type of protection Corrosion protection + Mechanical protection + Thermal insulation Typical coating thickness Depends on thermal requirements Design temperature 130Ԩ Water depth limit 3000 m Major characteristics K-value around 0.16 W/m.K, density 650-700 kg/m3 Hydrostatic pressure resistance is reinforced by glass microspheres added into the PP matrix. 74 6.1. Pipe coating - Systems  Syntactic PU - polymer syntactic (sPU) Coating system FBE + sPU description Type of protection Corrosion protection + Thermal insulation Typical coating Depends on thermal requirements thickness Design temperature 115Ԩ Water depth limit 300 m Major characteristics - K-value around 0.12 W/m.K, density 600-700 kg/m3 - Thin wall + low polymer mechanical properties decrease compression resistance of the foam.
  • 38. 22/01/2014 38 75 6.1. Pipe coating - Systems  Syntactic PU - Glass syntactic (GSPU) Coating system FBE + GSPU description Type of protection Corrosion protection + Thermal insulation Typical coating Depends on thermal requirements thickness Design temperature 130Ԩ Water depth limit 3000 m Major characteristics - K-value around 0.16 W/m.K, density 800 kg/m3 - Hydrostatic pressure resistance reinforced by glass microspheres added into the PU matrix. - Grade of glass influences the collapse pressure and theoretical maximum water depth. 76 6.1. Pipe coating - Systems  Injection moulding PU process Source: Bredero Shaw
  • 39. 22/01/2014 39  Concrete Weight Coating (CWC)  Purpose: provide negative buoyancy and mechanical protection to the pipe.  Mixture of cement, iron ore and wire wrap  Main properties: o Density (1900-3700 kg/m3): varies iron ore quantity. o Compressive strength: depends on cement and water content. o Thickness: depends on pipe diameter. o Water absorption: ISO standard recommend a maximum of 5% vol.  Reinforcement o Rigid preformed cages o Wire mesh fabric Source: Bredero Shaw 6.1. Pipe coating - Systems 77 78 6.1. Pipe coating - Systems  Concrete Weight coating Type of protection Negative buoyancy + Mechanical protection Typical coating thickness Depends on pipe diameter Design temperature N/A Water depth limit Unlimited Major characteristics Density (1900-3700 kg/m3): varies with iron ore quantity.
  • 40. 22/01/2014 40 79 6.1. Pipe coating - Systems Concrete Weight Coating (CWC)  Impingement method Source: Bredero Shaw 80 6.1. Pipe coating - Systems Concrete Weight Coating (CWC)  Wrap-on method Source: Bredero Shaw
  • 41. 22/01/2014 41 81 6.1. Pipe coating - Systems  Elastomer coatings (Neoprene, EPDM, butyl rubber, etc.) Mainly used for splash zone protection Be careful of chamfering  can cause failure of the bond Source: Yadana riser – F. Duesso 82 6.1. Pipe coating - Subcontractors APAC  Bredero Shaw  WASCO Energy Americas  Bredero Shaw  CRC Evans EMEA  Bredero Shaw  Eupec  Socotherm  Tenaris
  • 42. 22/01/2014 42 83 Operators - Gap analysis with ISO 21809-1: Microsoft Excel Worksheet 6.1. Pipe coating - Operators 84 6.1. Pipe coating - Operators Microsoft Excel Worksheet Operators - Gap analysis with ISO 21809-1:  ENI = based on ISO  TOTAL SHELL and PETRONAS: more stringent on different tests
  • 43. 22/01/2014 43 85 6.1. Pipe coating – Future challenges  HT/HP - R&D programm in different pipe coating applicators and manufacturers to test different materials like glass syntactic silicones  Arctic - Bredero Shaw involved in JIP for new material in arctic conditions  Flexible weight coating  Ultra deep waters – thermal insulation 6.2 Field joint coating 86  Definition  Selection  Standards  Systems  S-Lay installation  Subcontractors
  • 44. 22/01/2014 44 6.2. Field joint coatings - Definition Field joint definition: Part of pipe left bare for welding prior to installation  Purpose of FJC: anticorrosion or thermal insulation.  Field joint is the weak point in a pipe coating system.  Welded joints are highly sensitive to corrosion. 3LPP coating pipe  Cut back length shall be predetermined and mainly depends on type of FJC.  Properties shall be the same as the parent coating (pipe coating).  FJC are mostly applied in field  application shall be easy, fast and reliable. FJC  FJC = FBE, HSS, Polyolefin tapes, IMPP, IMPU, PE, PP, liquid resins 87 6.2. Field joint coatings - Selection Line pipe working conditions • density, thermal conductivity (if thermal insulation), coating breakdown factor Pipe laying environment • mechanical protection expected (impact strength, abrasion, compressive strength, flexibility, water absorption, curing time) Parent coating Parent coating FJC possibilities FBE FBE Heat Shrinkable Sleeves Liquid coating Polyethylene HSS Liquid coating PE flame spray Polypropylene PP flame spray / tapes IMPU IMPP Liquid coating Concrete coating HSS + HDPUF 88
  • 45. 22/01/2014 45 6.2. Field joint coatings - Standards International standards in field joint coating: ISO 21809  ISO 21809 - 3 Other standards or specifications  DNV-RP-F102  NACE RP0303 - HSS  EN 12068 – tapes and HSS  NO STANDARD FOR INSULATION COATING 89 6.2. Field joint coatings - Systems  FBE Coating system description FBE Type of protection Corrosion protection Typical coating 350-500 μm thickness Design temperature 90Ԩ, modified epoxies can withstand higher temperatures Water depth limit Unlimited Major characteristics - The most widely used coating - Good chemical resistance - Very good corrosion protection - Very common and easy to find subcontractors - Low impact resistance Overlap on parent coating 50 mm 90
  • 46. 22/01/2014 46 6.2. Field joint coatings - Systems  Heat Shrink Sleeves: 2-layers (mastic HSS) Coating system description Mastic adhesive + Polyolefin backing on St3 steel Type of protection Corrosion protection Typical coating 2 mm thickness Design temperature Up to 100Ԩ (depending on product: PE or PP) Water depth limit 3000 m Major characteristics Manual application with gas torch Example of HSS system PE: - KLNN Canusa - WPC 100M (Berry Plastic) PP: - GTS PP 100 Overlap on parent coating 100 mm 91 6.2. Field joint coatings - Systems  Heat Shrink Sleeves: 3-layers (hot-melt HSS) Coating system description Liquid epoxy + hot-melt adhesive + Polyolefin backing on Sa 21/2 steel Type of protection Corrosion protection Typical coating thickness 2 mm Design temperature > 100Ԩ (depending on product: PE or PP) Water depth limit 3000 m Major characteristics Manual application with gas torch Example of HSS system PE: - GTS 80 (Canusa) - HTLP80 (Berry Plastic) PP: - GTS PP (Canusa) Overlap on parent coating 100 mm 92
  • 47. 22/01/2014 47 6.2. Field joint coatings - Systems  PP tape wrap Coating system description FBE + Adhesive PP + PP tape Type of protection Corrosion protection Typical coating 3 mm thickness Design temperature 110Ԩ Water depth limit 3000 m Major characteristics - Applied in spiral or wrapped by hand or by wrapster with the determined overlap (50% recommended). - Only compatible with 3LPP pipeline coating Example of tape wrap system FBE: Scotchkote 226N (3M) Adhesive: Hifax EP 510/60m (Basell) PP tape: Hifax EP 510/60 (Basell) Overlap on parent coating 70 mm 93 6.2. Field joint coatings - Systems  Flame spray PP Coating system description FBE + Adhesive PP + PP powder Type of protection Corrosion protection Typical coating 3 mm thickness Design temperature 110Ԩ Water depth limit 3000 m Major characteristics Similar to tape wrap Overlap on parent 70 mm coating 94
  • 48. 22/01/2014 48 6.2. Field joint coatings - Systems  Injection moulded polyurethane (IMPU) Coating system description FBE + Solid PU or PU primer + Solid PU Type of protection Corrosion protection + thermal insulation Typical coating +4 mm thickness Design temperature Up to 130Ԩ Water depth limit 3000 m Example of system FBE: Scotchkote 226N (3M) Solid PU: Hyperlast FJ302 (DOW) Overlap on parent coating 70 mm 95 6.2. Field joint coatings - Systems  Injection moulded polypropylene (IMPP) Coating system description FBE + PP adhesive + Moulded PP Type of protection Corrosion protection + thermal insulation Typical coating 4-10 mm thickness Design temperature Up to 110Ԩ (130Ԩ with high temp. FBE) Water depth limit 3000 m Example of system FBE: Scotchkote 226N (3M) Adhesive: BB 127E (Borealis) or Hifax EP5 10/60 (Basell) Solid PP: EA 165E (Borealis) or CA 197 (Basell) Overlap on parent coating 70 mm 96
  • 49. 22/01/2014 49 6.2. Field joint coatings – S-lay installation S-lay:  Firing line is horizontal  Pipeline is support by a stinger to avoid high bending stress. 97 6.2. Field joint coatings – S-lay installation 98
  • 50. 22/01/2014 50 6.2. Field joint coatings – Subcontractors Bredero Shaw Canusa CPS PIH OJS FBE, IMPU, IMPP HSS, liquid epoxy, tape wrap FBE, flame spray PP & PE, HSS, IMPU, IMPP, PU foam infill HDPUF, HSS 99 10 0 Summary 1. HSE moment 2. Reason for coating 3. Corrosion prevention - Generality 4. Surface preparation 5. Painting & coating 6. Pipe & field joint coating 7. Coating qualification – process and requirement 100
  • 51. 22/01/2014 51 7. Coating qualification 101  Painting  Pipe and field joint coatings 7. Coating qualification - Painting Norsok M501 rev.6 CS surfaces operating < 120 Ԩ Ballast water tanks/ seawater filled vessels Anti-slip for walkways, escape routes, lay down areas Intumescent epoxy + cementitious PFP Splash zone and immersed surfaces 1 3B 4 5 7 102
  • 52. 22/01/2014 52 7. Coating qualification - Painting Norsok M501 rev.6 Test (acc. to ISO 20340) Assessment method Acceptance criteria Seawater immersion ISO 4624- pull-off test 5MPa - 4200h ISO 4628-3,4,5,6 No defect - For system 3B, 7A, 7B, 7C and 1 when used in tidal or splash zone Ageing - 4200h - For system 1, 3B, 4, 5A, 5B, 7A ISO 4624- pull-off test ISO 4628 5MPa No defect Cathodic disbonding - 4 weeks - For system 3B, 7A, 7B, 7C, 1 when used in splash or tidal zone ISO 15711 Max. 20 mm 103 7. Coating qualification Shell systems that need to be qualified as per DEP TSA (DEP 30.48.40.31) DFT checking Ballast water tanks/ seawater filled vessels Anti-slip for walkways, escape routes, lay down areas Intumescent epoxy + cementitious PFP Splash zone and immersed surfaces 104
  • 53. 22/01/2014 53 7. Coating qualification Shell systems that need to be qualified as per DEP - TSA Test Assessment method Measurement Acceptance criteria Visual examination ISO 14918 100% surface Uniform appearance, no defect or blisters Coating thickness ISO 2808 Min. 5 Min. 250 μm Coating adhesion ISO 4624 Min. 3 > 7 MPa Overall quality Bend test (DEP) Min. 3 Minor cracks Sealer Visual inspection 100% surface No open pores at the surface  Check every step of the ITP.  The process leads to qualification of: o operators (blasters, sprayers), o equipment, o subcontractor coating procedure.  Example of PQT done for Prelude FLNG Microsoft Word 7 - 2003 Documen Adobe Acrobat Document 105 7. Coating qualification – Pipe & FJC Qualification of 3LPE and 3LPP as per ISO 21809-1: Adobe Acrobat Document Properties 3LPE 3LPP Continuity Zero defect Zero defect Impact strength > 7 J/mm > 10 J/mm Indentation at 23 Ԩ < 0.2 mm < 0.1 mm Indentation at max temp. < 0.4 mm < 0.4 mm Elongation at break > 400 % > 400 % Peel strength at 23 Ԩ > 15 N/mm Peel strength at max. Temp. > 3 N/mm > 25 N/mm > 4 N/mm Cathodic disbondment 23 Ԩ, 28 d Cathodic disbondment 65 Ԩ, 24 h Cathodic disbondment max. temp., 28 d < 7 mm < 7 mm < 15 mm < 7 mm < 7 mm < 15 mm Hot water immersion test (80 Ԩ, 48h) Average < 2 mm and max. < 3 mm Average < 2 mm and max. < 3 mm Flexibilitty No cracking at 2° angle No cracking at 2° angle Curing of epoxy As per manufacturer As per manufacturer 106
  • 54. 22/01/2014 54 Sources Bibliography: [1] NACE CIP 1 Manual [2] Encyclopedie de la peinture: formuler, fabriquer, appliquer, tome 1 [3] ISO 8501-1 [4] ISO 21809-1 to 5 [5] PPG – PFP and Fouling release coating presentation Websites: [6] www.nace.com [7] http://www.corrosion-doctors.org/Seawater/Fouling.htm [8] www.brederoshaw.com 107 Thank you 108