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Chapter 4 QBA Miguel A. Castro R.


               How are elements
               organized?
Chapter 4… An introduction
Patterns in Element Properties

 Pure  elements at room temperature
  and atmospheric pressure can be
  solids, liquids, or gases.
 Some elements are colorless. Others
  are colored.
 Despite the differences between
  elements, groups of elements share
  certain properties.
Newlands’ Law

 In 1865, John Newlands arranged the
  elements by atomic mass and noticed
  that physical properties repeated every
  eighth element.

 This   is called the Law of Octaves.
Mendeleev

 In 1869, Dmitri Mendeleev used
  Newlands’s observation and other
  information to produce the first orderly
  arrangement, or periodic table, of all 63
  elements known at the time.
 Mendeleev wrote the symbol for each
  element, along with the physical and
  chemical properties and the relative
  atomic mass of the element, on a card.
Mendeleev

 Mendeleev  started a new row each
 time the properties of the elements
 repeated.

 Mendeleev predicted the properties of
 the missing elements.
Beyond Mendeleev

 About 40 years after Mendeleev published
 his periodic table, an English chemist named
 Henry Moseley found a different physical
 basis for the arrangement of elements.

 Moseley  studied the lines in the X-ray
 spectra of 38 different elements, he found
 that the wavelengths of the lines in the
 spectra decreased in a regular manner as
 atomic mass increased.
Beyond Mendeleev

 When the elements were arranged by
 increasing atomic number, the discrepancies
 in Mendeleev’s table disappeared.

 Moseley’s  work led to both the modern
 definition of atomic number, and showed that
 atomic number, not atomic mass, is the basis
 for the organization of the periodic table
Periodic Law

 Mendeleev’s  principle of chemical periodicity
 is known as the periodic law, which states
 that when the elements are arranged
 according to their atomic numbers, elements
 with similar properties appear at regular
 intervals.

 Elements  in each column of the periodic
 table have the same number of electrons in
 their outer energy level (Valence Electrons).
Periodic Law

 Valence electrons are found in the
 outermost shell of an atom and that
 determines the atom’s chemical
 properties.

 Elements with the same number of
 valence electrons tend to react in
 similar ways.
Blocks of the Periodic Table




Do not draw this! Page 119 in Holt Chemistry!
Periodic Law

A  vertical column on the periodic table
 is called a group. Elements in a group
 share chemical properties.

A horizontal row on the periodic table is
 called a period. Elements in the same
 period have the same number of
 occupied energy levels.
The Periodic Law, continued
Organization of the Periodic Table, continued
Chapter 4



    Tour of the Periodic
    Table
Main Group Elements

•   Elements in groups 1, 2, and 13–18 are
    known as the main-group elements.
    Main-group elements are in the s- and
    p-blocks of the periodic table.
    –   alkali metals (Group 1)
    –   alkaline-earth metals (Group 2)
    –   halogens (Group 17)
    –   noble gases (Group 18)
Main Group Properties



Brainiac: The Alkali Metals
A class by itself

 Hydrogen   is the most common element
  in the universe.
 Because it consists of just one proton
  and one electron, hydrogen behaves
  unlike any other element.
 With its one electron, hydrogen can
  react with many other elements,
  including oxygen.
Metals

 The
    majority of elements, including
 many main-group ones, are metals.

 Metalsare recognized by its shiny
 appearance, but some nonmetal
 elements, plastics, and minerals are
 also shiny.
Transition Metals

 The transition metals constitute Groups 3
 through 12 and are sometimes called the
 d-block elements because of their position
 in the periodic table.

A transition metal may lose one, two, or
 even three valence electrons depending
 on the element with which it reacts.
Chapter 4



    Trends in the
    Periodic Table
Trends are easy to find

 You will be responsible for working on
 the graphing periodic trends lab on
 your own time.

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HOW ARE ELEMENTS ORGANIZED?

  • 1. Chapter 4 QBA Miguel A. Castro R. How are elements organized?
  • 2. Chapter 4… An introduction
  • 3. Patterns in Element Properties  Pure elements at room temperature and atmospheric pressure can be solids, liquids, or gases.  Some elements are colorless. Others are colored.  Despite the differences between elements, groups of elements share certain properties.
  • 4.
  • 5. Newlands’ Law  In 1865, John Newlands arranged the elements by atomic mass and noticed that physical properties repeated every eighth element.  This is called the Law of Octaves.
  • 6. Mendeleev  In 1869, Dmitri Mendeleev used Newlands’s observation and other information to produce the first orderly arrangement, or periodic table, of all 63 elements known at the time.  Mendeleev wrote the symbol for each element, along with the physical and chemical properties and the relative atomic mass of the element, on a card.
  • 7. Mendeleev  Mendeleev started a new row each time the properties of the elements repeated.  Mendeleev predicted the properties of the missing elements.
  • 8. Beyond Mendeleev  About 40 years after Mendeleev published his periodic table, an English chemist named Henry Moseley found a different physical basis for the arrangement of elements.  Moseley studied the lines in the X-ray spectra of 38 different elements, he found that the wavelengths of the lines in the spectra decreased in a regular manner as atomic mass increased.
  • 9. Beyond Mendeleev  When the elements were arranged by increasing atomic number, the discrepancies in Mendeleev’s table disappeared.  Moseley’s work led to both the modern definition of atomic number, and showed that atomic number, not atomic mass, is the basis for the organization of the periodic table
  • 10. Periodic Law  Mendeleev’s principle of chemical periodicity is known as the periodic law, which states that when the elements are arranged according to their atomic numbers, elements with similar properties appear at regular intervals.  Elements in each column of the periodic table have the same number of electrons in their outer energy level (Valence Electrons).
  • 11. Periodic Law  Valence electrons are found in the outermost shell of an atom and that determines the atom’s chemical properties.  Elements with the same number of valence electrons tend to react in similar ways.
  • 12. Blocks of the Periodic Table Do not draw this! Page 119 in Holt Chemistry!
  • 13. Periodic Law A vertical column on the periodic table is called a group. Elements in a group share chemical properties. A horizontal row on the periodic table is called a period. Elements in the same period have the same number of occupied energy levels.
  • 14. The Periodic Law, continued Organization of the Periodic Table, continued
  • 15. Chapter 4 Tour of the Periodic Table
  • 16. Main Group Elements • Elements in groups 1, 2, and 13–18 are known as the main-group elements. Main-group elements are in the s- and p-blocks of the periodic table. – alkali metals (Group 1) – alkaline-earth metals (Group 2) – halogens (Group 17) – noble gases (Group 18)
  • 17. Main Group Properties Brainiac: The Alkali Metals
  • 18. A class by itself  Hydrogen is the most common element in the universe.  Because it consists of just one proton and one electron, hydrogen behaves unlike any other element.  With its one electron, hydrogen can react with many other elements, including oxygen.
  • 19. Metals  The majority of elements, including many main-group ones, are metals.  Metalsare recognized by its shiny appearance, but some nonmetal elements, plastics, and minerals are also shiny.
  • 20. Transition Metals  The transition metals constitute Groups 3 through 12 and are sometimes called the d-block elements because of their position in the periodic table. A transition metal may lose one, two, or even three valence electrons depending on the element with which it reacts.
  • 21. Chapter 4 Trends in the Periodic Table
  • 22. Trends are easy to find  You will be responsible for working on the graphing periodic trends lab on your own time.