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11. When you look through a diffraction grating at a tube of hydrogen gas activated by a high
voltage, you see three or four discrete colors rather than the rainbow you would see when
looking at a white light bulb. Explain why this is, and why you don't see more than three or four
colors
Solution
The lines in the hydrogen emission spectrum form regular patterns and can be represented by a
(relatively) simple equation. Each line can be calculated from a combination of simple whole
numbers.
Why does hydrogen emit light when it is excited by being exposed to a high voltage and what is
the significance of those whole numbers?
When nothing is exciting it, hydrogen's electron is in the first energy level - the level closest to
the nucleus. But if you supply energy to the atom, the electron gets excited into a higher energy
level - or even removed from the atom altogether.
The high voltage in a discharge tube provides that energy. Hydrogen molecules are first broken
up into hydrogen atoms (hence the atomic hydrogen emission spectrum) and electrons are then
promoted into higher energy levels.
Suppose a particular electron was excited into the third energy level. This would tend to lose
energy again by falling back down to a lower level. It could do this in two different ways.
It could fall all the way back down to the first level again, or it could fall back to the second level
- and then, in a second jump, down to the first level.
With each fall the electron emits lights (where "light" includes UV and IR as well as visible)
These are the reasons why we don't see more than three or four colours.
11- When you look through a diffraction grating at a tube of hydrogen.docx

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11- When you look through a diffraction grating at a tube of hydrogen.docx

  • 1. 11. When you look through a diffraction grating at a tube of hydrogen gas activated by a high voltage, you see three or four discrete colors rather than the rainbow you would see when looking at a white light bulb. Explain why this is, and why you don't see more than three or four colors Solution The lines in the hydrogen emission spectrum form regular patterns and can be represented by a (relatively) simple equation. Each line can be calculated from a combination of simple whole numbers. Why does hydrogen emit light when it is excited by being exposed to a high voltage and what is the significance of those whole numbers? When nothing is exciting it, hydrogen's electron is in the first energy level - the level closest to the nucleus. But if you supply energy to the atom, the electron gets excited into a higher energy level - or even removed from the atom altogether. The high voltage in a discharge tube provides that energy. Hydrogen molecules are first broken up into hydrogen atoms (hence the atomic hydrogen emission spectrum) and electrons are then promoted into higher energy levels. Suppose a particular electron was excited into the third energy level. This would tend to lose energy again by falling back down to a lower level. It could do this in two different ways. It could fall all the way back down to the first level again, or it could fall back to the second level - and then, in a second jump, down to the first level. With each fall the electron emits lights (where "light" includes UV and IR as well as visible) These are the reasons why we don't see more than three or four colours.