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Presented by:
Parth kapoor
Dft-09b
Roll no:17/1054
VARIOUS TYPES OF
ADHESIVES
1.Latex Adhesive
2.Neoprene Adhesive
3.Polyurethane Adhesive
4.Hot-Melt Adhesive
5.Pressure Sensitive Adhesive
The Main Classes Of
Adhesive Used In Footwear
Industry
1.Vegatable Pastes
2.Rubber Latex
3.Natural Rubber Solution
5.Neoprene or Polychloropene Adhesives
6.Polyurethane Adhesive
7.Hot-Melt Adhesive
8.Nitrocellulose Adhesive
1.Vegetable Pastes: It is made from starch or dextrin,
  are mainly used in the trade for labeling boxes.
2.Rubber Latex: It is an aqueous emulsion of natural or
  synthetic rubber stabilised with ammonia . It normally
  contains 40 to 60 % solids. In sole attaching, this adhesive
  is used mostly to the bond leather temporarily to natural
  crepe.
3.Natural Rubber Solution: which is a solution of a
  natural rubber dissolve in solvents such as carbon
  tetrachloride or benzene, can be used for making
  permanent bonds of crepe to crepe.
4.Neoprene Adhesive: are more correctly called
  polychlro-prene adhesive because Neoprene is the trade
  name of DU Pont for polychlro-prene.
5.Poly-urethe Adhesive: It have different properties,
  depending on their molecular structure . Although
  aqueous poly-urethe emulsion are now being develop for
  sole bonding, of resin but with some stabilizers.
6.Hot-Melt Adhesive: It have a plastics material rather
  than synthetic rubber as their basic material. The most
  successful are polyester or polyamide resins and, to a
  lesser extent,EVA,a co-polymer of polyethylene and vinyl
  acetate.
7.Nitrocellulose Adhesives: are made from nitro-
  cellulose dissolve in strong solvents of the acetone group
  .these adhesive were the first synthetic adhesive used in
  the footwear industry but really never satisfactory . They
  have long since been replace by neoprene & polyurethane
  adhesives.
The Selection Of Best
Adhesive
The main points to be considered when selecting
  adhesives for footwear manufacture are:
1.Cost
2.Strength
3.Sutability for use with shoe materials
4.Sutability for shoe in processes
5.Shelf & pot life
6.General Considerations
PRECAUTIONS ON USE OF
ADHESIVES
 Many adhesives are available for specific end use. one has
  to find out an ideal adhesive for specific requirements.
 The adhesive manufacturers have to educate the users
  about the limitations on the use of individual adhesive and
  train the operators on the proper use of adhesive materials.
 Testing and establishment of realistic quantity control
  procedures.
 Safety in handling of materials,before,during and after use.
 Customer service satisfaction requires a close working
  relationship between the supplier and user.
Neoprene Adhesive
It is the generic term for synthetic rubber-like polymers
   of- chlorobutadience(chloroprene),or copolymers with
   chlorobutadience as the main constitutent.These are
   usually dissolve in blends of aromatic aliphatic hydro-
   carbons & polar solvents such as MEK . The blends of
   solvents give adhesives with varying viscosities &
   drying rates
             As with more solvent baseadhesive,neoprene
   can be applied by machine as well as by hand.
POLYURETHANE ADHESIVE
 Polyurethane(P.U) is produced when a disocyanate
 having two isocyanine groups is reacted with a diol
 having two hydroxyl groups.


                    INGREDIENTS
Polyols having a molecular weight 1000.The polyols may
 be polyether, polyester or polybutadiene based.
Diisocyanate:This is either toluene disocyanate(TDI)or
 methylene bis (4,4;phenyl isocyanine)MDI.
Curing agent may be a short chain diol or triol for MDI
 and an aromatic diamine for TDI.
HOT MELT ADHESIVE
 These are of cent percent solid content and are free from
solvents. The availability of a variety of polymers with a
broad spectrum of properties tailored for a specific end
use, is an added advantage. Today hot melt formulations
are available for temporary as well as permanent
attachment in shoe manufacture.
 Usually supplied to footwear industry in the form of
granules and rods (in coils).When these adhesives
heated to high temperature, they melt rapidly into a
fluid, flow freely on bonding sites, wet the surfaces,
quickly cool, solidify to a crystalline solid and thereby
adhere to give good bond strength between the two
surfaces.
HOT MELT ADHESIVE
 USED IN THERMOFOLDING MACHINES
 AMBER COLOURED
 STITCHED AS IT IS NOT A PERMANENT
 BOND
PROPERTIES
Amber coloured.
Polyamide is used instead of polyester due to its
 flexibility, low melting point and availability in either
 granular, rod or block form.
Toe puffs,stiifeners,backing cloths and lining material,
 for lamination could be precoated (either overall,or
 splattered)with hot melt adhesives and they attached by
 pressing under heated plates(hand iron, laminating
 press).
It must be stitched as it’s not a permanent bond.
USAGE
 Hot melt adhesives are used in shoe upper assembly for
attaching linings to uppers and edge bonding. Textile
linings with thermo cement coatings or film adhesives is
kept on the upper and attached by ironing. Bonded
surface presents a clean, uniform and neat appearance
with a rapid setting. The cement is also extruded as in
the thermocementing,folding and attaching machine.
TESTS FOR ADHESIVES
 VISCOSITY: The object of this test is to get an idea of information
  regarding the age,quality,stability,solids content, molecular weight
  and specific gravity of the adhesive.

 DRYING TIME: The adhesive is applied by the brush to the surface
  of the material. The time at which the adhesive film develops
  tackiness as its starts sticking to the finger.

 TACK: The force required to separates two surfaces, one of which
  has been coated with an adhesive after they have been in contact
  over a specified area at a specified pressure for a specified time.
  Tensile testing machine is used and the results are given in
  pounds/sq inch required to part the test blocks.
SHELF LIFE: The viscosity of the same adhesive sample is
 determined periodically at the regular intervals of time,the
 results are compared with that of the value of a fresh sample
 or original shape.
POT LIFE: It is determined by noting down the changes in
 viscosity or bond strength, but the test methods should be as
 agreeable between the adhesive manufacturer and the user
PEEL STRENGTH: Peel strength of an adhesive in kg./cm
 width obtained by peeling the two surfaces and recording the
 adhesive strength. The objective of this test is to get an
 information as to the behavior of the adhesive to an
 andherend i.e., bond strength.
SEAM TAPES
 THERMOPLASTIC ADHESIVE FILM APPLIED TO
  SEWN SEAMS OF FABRICS TO PREVENT WATER
  FROM LEAKING THROUGH THE SEAMS
 APPLIED BY USING AIR TAPING MACHINES, LASER
  OR ULTRA SONIC MACHINERY.
 E.g. CREPE PAPER TAPE, LIGHT/MEDIUM COTTON
  SHEETING ETC.
strap and stripping
reinforcement

 NYLON COATED CUT TAPE: COATED 1 OR BOTH
  SIDE(S) FOR STRAP AND STRIPPING
  APPLICATIONS
 NYLON CUT TAPE: COATED BOTH SIDES FOR
  BUCKLE HOLES IN WIDER STRAPS
 NON-WOVEN TAPE: COATED 1 OR 2 SIDE(S) RAW
  EDGE STRAPS ETC
FACING AND TRIM REINFORCEMENT

 COATED LIGHT COTTON DRILL TAPE: FLEXIBLE AND
    HIGH QUALITY
   COATED COMPRESSED PAPER TAPE: GOOD
    RESISTANCE TO COMPRESSION AND USED IN EYELET
    ATTACHMENT
   COATED NON-WOVEN POLYPROPYLENE TAPE:
    LIGHT WEIGHT WITH GOOD TEAR RESISTANCE AND
    IT HAS HIGH STRENGTH
   COATED NON-WOVEN POLYESTER TAPE: HIGH
    PERFORMANCE AND USED FOR ALL METALLIC
    FASTENINGS.
                                    THANK YOU.

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Adhesive

  • 1.
  • 3.
  • 4. VARIOUS TYPES OF ADHESIVES 1.Latex Adhesive 2.Neoprene Adhesive 3.Polyurethane Adhesive 4.Hot-Melt Adhesive 5.Pressure Sensitive Adhesive
  • 5. The Main Classes Of Adhesive Used In Footwear Industry 1.Vegatable Pastes 2.Rubber Latex 3.Natural Rubber Solution 5.Neoprene or Polychloropene Adhesives 6.Polyurethane Adhesive 7.Hot-Melt Adhesive 8.Nitrocellulose Adhesive
  • 6. 1.Vegetable Pastes: It is made from starch or dextrin, are mainly used in the trade for labeling boxes. 2.Rubber Latex: It is an aqueous emulsion of natural or synthetic rubber stabilised with ammonia . It normally contains 40 to 60 % solids. In sole attaching, this adhesive is used mostly to the bond leather temporarily to natural crepe. 3.Natural Rubber Solution: which is a solution of a natural rubber dissolve in solvents such as carbon tetrachloride or benzene, can be used for making permanent bonds of crepe to crepe.
  • 7. 4.Neoprene Adhesive: are more correctly called polychlro-prene adhesive because Neoprene is the trade name of DU Pont for polychlro-prene. 5.Poly-urethe Adhesive: It have different properties, depending on their molecular structure . Although aqueous poly-urethe emulsion are now being develop for sole bonding, of resin but with some stabilizers. 6.Hot-Melt Adhesive: It have a plastics material rather than synthetic rubber as their basic material. The most successful are polyester or polyamide resins and, to a lesser extent,EVA,a co-polymer of polyethylene and vinyl acetate.
  • 8. 7.Nitrocellulose Adhesives: are made from nitro- cellulose dissolve in strong solvents of the acetone group .these adhesive were the first synthetic adhesive used in the footwear industry but really never satisfactory . They have long since been replace by neoprene & polyurethane adhesives.
  • 9. The Selection Of Best Adhesive The main points to be considered when selecting adhesives for footwear manufacture are: 1.Cost 2.Strength 3.Sutability for use with shoe materials 4.Sutability for shoe in processes 5.Shelf & pot life 6.General Considerations
  • 10. PRECAUTIONS ON USE OF ADHESIVES  Many adhesives are available for specific end use. one has to find out an ideal adhesive for specific requirements.  The adhesive manufacturers have to educate the users about the limitations on the use of individual adhesive and train the operators on the proper use of adhesive materials.  Testing and establishment of realistic quantity control procedures.  Safety in handling of materials,before,during and after use.  Customer service satisfaction requires a close working relationship between the supplier and user.
  • 11. Neoprene Adhesive It is the generic term for synthetic rubber-like polymers of- chlorobutadience(chloroprene),or copolymers with chlorobutadience as the main constitutent.These are usually dissolve in blends of aromatic aliphatic hydro- carbons & polar solvents such as MEK . The blends of solvents give adhesives with varying viscosities & drying rates As with more solvent baseadhesive,neoprene can be applied by machine as well as by hand.
  • 12. POLYURETHANE ADHESIVE Polyurethane(P.U) is produced when a disocyanate having two isocyanine groups is reacted with a diol having two hydroxyl groups. INGREDIENTS Polyols having a molecular weight 1000.The polyols may be polyether, polyester or polybutadiene based. Diisocyanate:This is either toluene disocyanate(TDI)or methylene bis (4,4;phenyl isocyanine)MDI. Curing agent may be a short chain diol or triol for MDI and an aromatic diamine for TDI.
  • 13.
  • 14. HOT MELT ADHESIVE These are of cent percent solid content and are free from solvents. The availability of a variety of polymers with a broad spectrum of properties tailored for a specific end use, is an added advantage. Today hot melt formulations are available for temporary as well as permanent attachment in shoe manufacture. Usually supplied to footwear industry in the form of granules and rods (in coils).When these adhesives heated to high temperature, they melt rapidly into a fluid, flow freely on bonding sites, wet the surfaces, quickly cool, solidify to a crystalline solid and thereby adhere to give good bond strength between the two surfaces.
  • 15. HOT MELT ADHESIVE  USED IN THERMOFOLDING MACHINES  AMBER COLOURED  STITCHED AS IT IS NOT A PERMANENT BOND
  • 16. PROPERTIES Amber coloured. Polyamide is used instead of polyester due to its flexibility, low melting point and availability in either granular, rod or block form. Toe puffs,stiifeners,backing cloths and lining material, for lamination could be precoated (either overall,or splattered)with hot melt adhesives and they attached by pressing under heated plates(hand iron, laminating press). It must be stitched as it’s not a permanent bond.
  • 17. USAGE Hot melt adhesives are used in shoe upper assembly for attaching linings to uppers and edge bonding. Textile linings with thermo cement coatings or film adhesives is kept on the upper and attached by ironing. Bonded surface presents a clean, uniform and neat appearance with a rapid setting. The cement is also extruded as in the thermocementing,folding and attaching machine.
  • 18. TESTS FOR ADHESIVES  VISCOSITY: The object of this test is to get an idea of information regarding the age,quality,stability,solids content, molecular weight and specific gravity of the adhesive.  DRYING TIME: The adhesive is applied by the brush to the surface of the material. The time at which the adhesive film develops tackiness as its starts sticking to the finger.  TACK: The force required to separates two surfaces, one of which has been coated with an adhesive after they have been in contact over a specified area at a specified pressure for a specified time. Tensile testing machine is used and the results are given in pounds/sq inch required to part the test blocks.
  • 19. SHELF LIFE: The viscosity of the same adhesive sample is determined periodically at the regular intervals of time,the results are compared with that of the value of a fresh sample or original shape. POT LIFE: It is determined by noting down the changes in viscosity or bond strength, but the test methods should be as agreeable between the adhesive manufacturer and the user PEEL STRENGTH: Peel strength of an adhesive in kg./cm width obtained by peeling the two surfaces and recording the adhesive strength. The objective of this test is to get an information as to the behavior of the adhesive to an andherend i.e., bond strength.
  • 20.
  • 21. SEAM TAPES  THERMOPLASTIC ADHESIVE FILM APPLIED TO SEWN SEAMS OF FABRICS TO PREVENT WATER FROM LEAKING THROUGH THE SEAMS  APPLIED BY USING AIR TAPING MACHINES, LASER OR ULTRA SONIC MACHINERY.  E.g. CREPE PAPER TAPE, LIGHT/MEDIUM COTTON SHEETING ETC.
  • 22. strap and stripping reinforcement  NYLON COATED CUT TAPE: COATED 1 OR BOTH SIDE(S) FOR STRAP AND STRIPPING APPLICATIONS  NYLON CUT TAPE: COATED BOTH SIDES FOR BUCKLE HOLES IN WIDER STRAPS  NON-WOVEN TAPE: COATED 1 OR 2 SIDE(S) RAW EDGE STRAPS ETC
  • 23. FACING AND TRIM REINFORCEMENT  COATED LIGHT COTTON DRILL TAPE: FLEXIBLE AND HIGH QUALITY  COATED COMPRESSED PAPER TAPE: GOOD RESISTANCE TO COMPRESSION AND USED IN EYELET ATTACHMENT  COATED NON-WOVEN POLYPROPYLENE TAPE: LIGHT WEIGHT WITH GOOD TEAR RESISTANCE AND IT HAS HIGH STRENGTH  COATED NON-WOVEN POLYESTER TAPE: HIGH PERFORMANCE AND USED FOR ALL METALLIC FASTENINGS.  THANK YOU.