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PLOTS SPECTROSCOPE



 webcam + DVD + slit + case + software
                   =
         Digital Spectroscope
Desktop kit uses a webcam ($40)




                                  Clip on device for smartphone ($10)


                Public Laboratory
                 (and kickstarter)
Spectral Workshop




•Online (share camera)
•Offline (no longer supported, but available)

•Allows calibration of spectra captured by camera
•Uses CFL spectra (mercury lines)
CALIBRATION
    CFL spectrum overlaid with intensity




436nm blue line       546nm green line
Some Captured Spectra

Calibration using CFL – standard spectra   Mercury discharge lamp




              Solar spectrum                  Green laser 484nm




             Osram Biolux lamp                       Halogen




             Strontium chloride                 Red Bull (for absorbance)
Photosynthetically Active Radiation (PAR)
http://publiclaboratory.org/notes/cfastie/3-16-2013/par




 Absorbance using halogen
 (probably) as source lamp
 (baseline) and subtracting light
 transmitted by chlorophyll solution
Beer’s Law




  Does coffee obey Beer’s Law (500nm absorbance)
http://publiclaboratory.org/notes/akjeff91/3-28-2013/does-coffee-obey-beers-law
Fraunhofer’s Lines in Solar Spectrum




http://publiclaboratory.org/notes/cfastie/3-2-2013/fraunhofer
Flame Emission Spectrography




                  Injecting metal salt solutions into bunsen venturi
                             and analysing the spectra



http://publiclaboratory.org/notes/straylight/10-14-2012/classroom-flame-spectroscopy
Wine Analysis By Absorption




              Wine in petri dish over incandescent light source
              baseline, analysed for absorption characteristics

http://publiclaboratory.org/notes/warren/1-19-2012/wine-spectroscopy-adam-hasler
Energy Drink Artificial Colouring




http://publiclaboratory.org/notes/natalieorms/3-28-2013/qualitative-comparison-
percent-transmittance-three-energy-drinks-do-conc
More Applications
•   Black Body Radiation
•   LED colour analysis
•   Halogen vs Incandescent vs LED lighting
•   Stage 2 physics (Balmer Series)
•   Stage 2 chemistry
http://publiclaboratory.org/wiki/spectral-analysis
Sample Spectra
  (not from spectral workbench)




http://www.ausetute.com.au/emissions.html
Building The Spectroscope
• Make a slit for the end of the box
• Put some DVD plastic over the camera lens
• Put the camera in the box, opposite the slit, at
  about 45°
• Install the software, plug in the camera
• Select view
• Calibrate
• Use
DVD Plastic Diffraction Grating
                                   The DVD plastic from a blank
                                   DVD (+/- R) has almost parallel
                                   lines printed at 740nm spacing.

                                   These provide a cheap and
                                   effective transmission diffraction
                                   grating. First order maxima of
                                   interference pattern is at around
                                   60 degrees.

                                   The camera and DVD are
                                   angled around 50 degrees to
                                   introduce an incident angle,
                                   which makes the pattern
                                   asymmetric. One side of the
                                   pattern is now centred in the
The DVD “grooves” run vertically   middle of the camera field of
                                   view.
The Slit
• Aluminium Foil stuck
  to a microscope slide
• Sticky tape !
• Smaller slit = better
  resolution
• 0.5mm is good
• Any old slit works !
Camera and Slit
        Arrangement
Cover is off the box

The slit to camera distance is
dependant on the minimum
focusing range of the camera.
The longer the distance, the
better the resolution
Camera Angle
      •About 45-60 degrees
      works well

      •Align with slit opening

      •Blu Tak is your friend

      •Reversing the angle
      reverses the spectrum
      order

      •Changing the angle also
      spreads out the spectrum
      a bit
Spectral Workbench - Offline
•   Windows Installation Instructions

•   You need
          Spectral Workbench Master (folder 35MB)
          Apple Quicktime (Quicktime Installer – Use default settings)
          WinVDIG_101 (installer – Use default settings note that only
    version 1.01 works, not newer versions)


•   After installing quicktime, you need to:
          copy C:Program Files (x86)QuickTimeQTSystemQTJava.zip
          to C:Program Files (x86)Javajre6libextQTJava.zip

•   After Installing WinVDIG_101 run QTCap, which is a video or webcam
    stream that allows spectral workbench to capture your webcam through
    quicktime (QTCap)
•   Follow the instructions for QTCap on the next slide, this gets you a webcam
    feed
WinVDIG - QTCap



Source should be “USB Video Device WDM”




                               Preview should be “compressed”
                The webcam video should come up in the boxes
Run Spectral Workbench
• “Spectral workbench
  master/spectrometry_kit/application.windows/sp
  ectrometry_kit.exe”
• You should see a grey screen and the QTCap
  window again
• Select the webcam source and preview
  “compressed”
• Click 'OK'.
• In a few seconds, spectral workbench will fire up
Getting The Picture




Adjust sample row by click and drag vertically. It is clumsy !
Getting a Nice Spectra




• Two green lines + sharp blue + many reds
• No overexposure
• Small slit = good resolution
Troubleshooting
•Grey Screen of Death means WinVDIG or
quicktime aren’t set up properly

•Try using the ‘scope with a big slit to get
an idea of where the spectrum lies
                                               Mercury Discharge Lamp
•Don’t clean the DVD plastic, the purple
layer has the lines on it !

•Use the “Adjust Sample Row” to see
everything the camera sees, then angle the
camera to get the image.

•Reducing reflections inside the box helps
the camera auto exposure work

•Don’t be afraid to play with the apparatus,
turn the camera or move stuff around
Want to Know More ?
• http://spectralworkbench.org/capture
• https://github.com/jywarren/spectral-
  workbench

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Plots spectroscope sasta presentation 2013

  • 1. PLOTS SPECTROSCOPE webcam + DVD + slit + case + software = Digital Spectroscope
  • 2. Desktop kit uses a webcam ($40) Clip on device for smartphone ($10) Public Laboratory (and kickstarter)
  • 3. Spectral Workshop •Online (share camera) •Offline (no longer supported, but available) •Allows calibration of spectra captured by camera •Uses CFL spectra (mercury lines)
  • 4. CALIBRATION CFL spectrum overlaid with intensity 436nm blue line 546nm green line
  • 5. Some Captured Spectra Calibration using CFL – standard spectra Mercury discharge lamp Solar spectrum Green laser 484nm Osram Biolux lamp Halogen Strontium chloride Red Bull (for absorbance)
  • 6. Photosynthetically Active Radiation (PAR) http://publiclaboratory.org/notes/cfastie/3-16-2013/par Absorbance using halogen (probably) as source lamp (baseline) and subtracting light transmitted by chlorophyll solution
  • 7. Beer’s Law Does coffee obey Beer’s Law (500nm absorbance) http://publiclaboratory.org/notes/akjeff91/3-28-2013/does-coffee-obey-beers-law
  • 8. Fraunhofer’s Lines in Solar Spectrum http://publiclaboratory.org/notes/cfastie/3-2-2013/fraunhofer
  • 9. Flame Emission Spectrography Injecting metal salt solutions into bunsen venturi and analysing the spectra http://publiclaboratory.org/notes/straylight/10-14-2012/classroom-flame-spectroscopy
  • 10. Wine Analysis By Absorption Wine in petri dish over incandescent light source baseline, analysed for absorption characteristics http://publiclaboratory.org/notes/warren/1-19-2012/wine-spectroscopy-adam-hasler
  • 11. Energy Drink Artificial Colouring http://publiclaboratory.org/notes/natalieorms/3-28-2013/qualitative-comparison- percent-transmittance-three-energy-drinks-do-conc
  • 12. More Applications • Black Body Radiation • LED colour analysis • Halogen vs Incandescent vs LED lighting • Stage 2 physics (Balmer Series) • Stage 2 chemistry http://publiclaboratory.org/wiki/spectral-analysis
  • 13. Sample Spectra (not from spectral workbench) http://www.ausetute.com.au/emissions.html
  • 14. Building The Spectroscope • Make a slit for the end of the box • Put some DVD plastic over the camera lens • Put the camera in the box, opposite the slit, at about 45° • Install the software, plug in the camera • Select view • Calibrate • Use
  • 15. DVD Plastic Diffraction Grating The DVD plastic from a blank DVD (+/- R) has almost parallel lines printed at 740nm spacing. These provide a cheap and effective transmission diffraction grating. First order maxima of interference pattern is at around 60 degrees. The camera and DVD are angled around 50 degrees to introduce an incident angle, which makes the pattern asymmetric. One side of the pattern is now centred in the The DVD “grooves” run vertically middle of the camera field of view.
  • 16. The Slit • Aluminium Foil stuck to a microscope slide • Sticky tape ! • Smaller slit = better resolution • 0.5mm is good • Any old slit works !
  • 17. Camera and Slit Arrangement Cover is off the box The slit to camera distance is dependant on the minimum focusing range of the camera. The longer the distance, the better the resolution
  • 18. Camera Angle •About 45-60 degrees works well •Align with slit opening •Blu Tak is your friend •Reversing the angle reverses the spectrum order •Changing the angle also spreads out the spectrum a bit
  • 19. Spectral Workbench - Offline • Windows Installation Instructions • You need Spectral Workbench Master (folder 35MB) Apple Quicktime (Quicktime Installer – Use default settings) WinVDIG_101 (installer – Use default settings note that only version 1.01 works, not newer versions) • After installing quicktime, you need to: copy C:Program Files (x86)QuickTimeQTSystemQTJava.zip to C:Program Files (x86)Javajre6libextQTJava.zip • After Installing WinVDIG_101 run QTCap, which is a video or webcam stream that allows spectral workbench to capture your webcam through quicktime (QTCap) • Follow the instructions for QTCap on the next slide, this gets you a webcam feed
  • 20. WinVDIG - QTCap Source should be “USB Video Device WDM” Preview should be “compressed” The webcam video should come up in the boxes
  • 21. Run Spectral Workbench • “Spectral workbench master/spectrometry_kit/application.windows/sp ectrometry_kit.exe” • You should see a grey screen and the QTCap window again • Select the webcam source and preview “compressed” • Click 'OK'. • In a few seconds, spectral workbench will fire up
  • 22. Getting The Picture Adjust sample row by click and drag vertically. It is clumsy !
  • 23. Getting a Nice Spectra • Two green lines + sharp blue + many reds • No overexposure • Small slit = good resolution
  • 24. Troubleshooting •Grey Screen of Death means WinVDIG or quicktime aren’t set up properly •Try using the ‘scope with a big slit to get an idea of where the spectrum lies Mercury Discharge Lamp •Don’t clean the DVD plastic, the purple layer has the lines on it ! •Use the “Adjust Sample Row” to see everything the camera sees, then angle the camera to get the image. •Reducing reflections inside the box helps the camera auto exposure work •Don’t be afraid to play with the apparatus, turn the camera or move stuff around
  • 25. Want to Know More ? • http://spectralworkbench.org/capture • https://github.com/jywarren/spectral- workbench