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International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 1049
EMISSION REDUCTION BY COMBINATION EFFECT OF PERMANENT
MAGNETS AND UREA INJECTION
Suyog Khillare1, Kiran Hiware2, Sandeep Imale3, Chirag Patil4
1,2,3Student, Dept. of Mechanical Engineering, Jawaharlal Nehru Engineering College, Aurangabad, Maharashtra,
India
4Student, Dept. of Master of Business Administration and Engineering, Hochschule für Technik und Wirtschaft,
Berlin, Germany
---------------------------------------------------------------------***----------------------------------------------------------------------
Abstract - Atmospheric pollution is oneofthe majorproblems
that whole world can be facing. Large air pollution is
produced by manmade activities like burning of combustible
gases, inorganic or organic waste, recyclable materials etc. In
last few years, the problem of environmental pollution is
raised to significant level because of increase in usage of
vehicle throughout the world. Having high thermal efficiency
is one of the best advantages of using Diesel Engine, but along
with this it has a serious drawback of emitting larger amount
of harmful exhaust gases when compared with gasoline
engine. The half of total nitrogen oxides and more than two
thirds of particulate matter can be emitted by vehicle using
diesel as a fuel. Nitrogen oxides emitted by diesel engine
results into the formation of ground level ozone, which
irritates the respiratory system, causing coughing, choking,
and other lung disorder. When nitrogen oxides and
hydrocarbon emissions combine in the presence of sunlight
gives ozone pollution which results into a health hazardsboth
for adults and individualssufferingfromrespiratoryproblems.
The emission of large particulate matters due to incomplete
combustion of fuel causes health problemslike irritationin the
eyes, throat and lungs which leads to various disorders.)
Key Words: Magnetic emission filter, Urea injection,
Emission Reduction, Diesel Engine
1. INTRODUCTION
Nowadays, automotive catalytic converter has been used to
reduce the automotive vehicles emissions. Exhaust catalytic
converters were introduced, because most of the countries
recognized restricting laws related to emissions of carbon
monoxide, hydrocarbons andnitrogenoxidesbytheengines.
These emissions generated by the combustion process of
internal combustion engines are very harmful to health and
the surroundings. The CO emissions join withhemoglobin in
the bloodstream promotes the reduction of oxygen-active
sites which arises asphyxia. Nitrogen oxides (NOx)
contribute to acid rain and photochemical smog which give
irritation to the eyes and skin. The Three-Way Catalysts are
advanced system for emission treatmentofgasolinevehicles
that significantly reduce the emissions of carbon monoxide
(CO), hydrocarbons (HC) and nitrogen oxides (NOx) in
atmosphere.
Main aim is to reduce the emissions like CO, NOx, and HC
from exhaust of diesel engine using combined effect of
magnetic emission filter and urea injection. Environmental
pollution is one of the biggest problems faced by human
beings in the past decades and in generations to come.
Approximately 1/3 of the air pollutionisfrombyautomobile
fleet. It is substantial to control automotive pollutions to
achieve the goal of cleaner air, which should help for
reduction of greenhouse gases. Exhaust pollutants from the
automobile’s engines have negative impact on air quality as
well as on human health. Current study focuses on newly
developed setup of magnetic emission filter and urea
injection as a catalytic converter, because existing available
catalytic converters suffer from various problems like;
poisoning, fracture, melting & higher cost. The objective of
this paper is to develop cost effective magnetic emission
filter as a catalytic converter to be used on a diesel engine.
2. EXPERIMENTAL SET-UP
A magnetic emission filter with urea injection unit
schematic diagram
Fig -1: Schematic Diagram of Magnetic emission filter with
Urea Injection Unit
Magnetic emission filter construction is as follows:-
It consists of a cylindrical filter (meshed from inside for
transfer of exhaust gases), urea injection unit, Neodymium
magnets (placed on the periphery of the cylindrical filter)
Working principle: -
The harmful exhaust gases from enginepassfromtheinletof
the filter device which contains nitrogen oxides (NOx),
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 1050
carbon monoxide (CO), Hydrocarbons (HC), particulate
matter (PM).
Following chemical reactions were takes place inside the
filter:
Table -1: Chemical Reactions of Emission Gases
NOx reactions:
N2+ O₂ = NO + NO₂
CO reaction:
CO+ ½ O2 = CO₂ + Heat
HC reaction:
HC + O2 = H₂O + CO₂
PM reaction:
PM + O2 = CO₂ + H₂O
Urea reactions with NOx :
6NO2+ 8NH₃= 7N₂ + 12H₂O
6NO+ 4NH₃ = 5N₂+ 6H₂O
NO+ NO2 + 2NH3 = 2N2+ 3H2O
2.1 Reduction of NOx
NOx is produced by the reaction of nitrogen and oxygen
gases during combustion, especially at higher temperatures.
In regions of dense vehicle transportation, significant air
pollution caused due to nitrogen oxides emission. Most of
this will be nitrogen oxide (NO), with a small amount of
nitrogen dioxide (NO2) and remaining of other nitrogen-
oxygen combinations. NOx is considered as an undesirable
emission and regulations for restriction of this compound
are getting stringent. Photochemical smog formation is
mainly occurring when NOx reactswithozone,whichisquite
harmful for health. NOx is generally createdfromnitrogenin
the air. Atmospheric nitrogen exists as a stable diatomic
molecule at low temperatures, however, at the very high
temperatures like that in combustion chamber of an engine,
few of the diatomic nitrogen (N2)breaksdowntomonatomic
nitrogen (N) which is reactive. A significant amount of
monoatomic nitrogen can be formed as the temperature in
combustion chamber is around 2500°C in an engine. Other
gases that are relatively stable at low temperatures like
oxygen and water vapor become reactive at high
temperature which contributes in the formation of NOx. For
the purpose of NOx reduction, we have used the urea
injection unit. In urea injection a fine atomized spray of urea
blend which consist of 40% Urea and 60% water is sprayed
into the setup resulting in mixing of the flue gases with the
atomized spray. For the purpose of atomizing, the fine spray
of urea injection is required and for that carburetor is used.
The flue gas is let in instead of the fresh air and urea blend is
let in instead of fuel. This carburetor has efficiently worked,
and a perfect atomization of the urea blend is obtained
continuously. The urea blend is stored in a tank through
which continuous passage of the liquid flow takes place.The
liquid can be refilled easily once it gets over.
2.2 Reduction of Particulate Matter
A magnetic field generated by permanent earth magnets is
used for reducing pollutants, mainly HC from exhaust gases.
A housing having an inlet for receiving exhaust gases with
pollutants, and an outlet for the exit to the exhaust gases
which is free from pollutants. A magnetic filter element
defines a plurality of flow paths for exhaust gases between
inlet and the outlet; during this inlet through flow paths to
outlet pollutants in exhaust gases are substantially reduced.
To apply magnetic field applied in the pathways of exhaust
gases is created by pass strong permanent magnets, due to
that magnetic field hydrocarbon changes their orientation
and convert from para state to ortho state. In ortho state
inter molecular force is reduced to a considerable and
increase space between hydrogen. This hydrogen of fuel
reacts with oxygen producing a complete burn in the
combustion chamber
Fig -2: Magnetic Field Effect on Outlet Emission Gases
For the filter permanent magnets are used as their magnetic
properties are stronger than other normal magnets, So,
Neodymium magnets are used based on their low cost and
easy availability.
Fig -3: Magnetic Field Effect on Outlet Emission Gases
Actual Magnetic Pollution filter set-up:
Fig -3: Actual magnetic emission filter setup
3. RESULTS AND DISCUSSION
The results were taken by the following method:
Firstly, we measured the emission levels without the setup
and then with the setup on same engine
International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056
Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072
© 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 1051
Table -2: Engine specifications
Table -3: Comparison of Measured Emission with and
Without Magnetic Pollution Filter Setup
Chart -1: Comparison of before and after setup emission
parameters
It is evident from the above data that NOx is reduced to
about 53% and CO is reduced from 2.034 to 0.58% and the
oxygen content has increased from 13.2 to 18.4% which
gives quite a clear picture of emission reduction with the
help of the setup.
4. CONCLUSION
The harmful emissive gases tend to pollute the environment
so there is need to reduce them if not eliminate them from
the surrounding. Above research work concludethattheuse
of magnetic filter as catalytic converter is effective in
reducing the harmful content from emissionwhenusedwith
a diesel engine. Use of magnetic filterwithurea injectionunit
can be used as a substitute to other after treatment devices
as it is more cost effective. With neodymium magnets along
with urea dosing unit best results of reduced pollutants can
be achieved
ACKNOWLEDGEMENT
The authors sincerely thank Jawaharlal Nehru Engineering
College, for the resources and support provided for the
study.
REFERENCES
[1] Engr. Okoronkwo C. A ,Engr. Dr. Nwachukwu, C.C,Engr.
Dr. Ngozi –Olehi L.C and Engr. Igbokwe, J.O, The effectof
electromagnetic flux density on the ionization and the
combustion of fuel (An economy design project)” in
AMERICAN JOURNAL OF SCIENTIFIC AND INDUSTRIAL
RESEARCH
[2] Piyush M Patel, Prof. Gaurav P Rathod ,Prof. Tushar M
Patel, “Effect of magnetic field on performance and
emission of single cylinder four stroke diesel engine” in
IOSR Journal of Engineering (IOSRJEN)Vol. 04, Issue 05
(May. 2014)
Type
Single Cylinder, Naturally Aspirated
Air Cooled, Diesel engine
Displacement (CC) 436 CC
Max. Power 5.52 kW @ 3600 rpm+ 50rpm
Max. Torque 18 Nm @ 2400 – 2200 rpm
Sr
No.
Parameter
Emissions
measured
without setup
Emissions
measured with
setup
1. Oxygen 13.2% 18.4%
2. Fuel temp 95 ˚C 33 ˚C
3. CO 2.034% 0.58%
4. Nitric oxide 239 ppm 112 ppm
5. Methane 2.35% 1.25%
6. CO2 3.28% 1.06%
7. Excess air
ratio
84.54 560.30
8. Heat loss in
dry flue gas
3.28% 0.48%
9. Total heat
loss
27.33% 5.89%
10. Overall
efficiency
72.67% 94.09 %

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IRJET- Emission Reduction by Combination Effect of Permanent Magnets and Urea Injection

  • 1. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 1049 EMISSION REDUCTION BY COMBINATION EFFECT OF PERMANENT MAGNETS AND UREA INJECTION Suyog Khillare1, Kiran Hiware2, Sandeep Imale3, Chirag Patil4 1,2,3Student, Dept. of Mechanical Engineering, Jawaharlal Nehru Engineering College, Aurangabad, Maharashtra, India 4Student, Dept. of Master of Business Administration and Engineering, Hochschule für Technik und Wirtschaft, Berlin, Germany ---------------------------------------------------------------------***---------------------------------------------------------------------- Abstract - Atmospheric pollution is oneofthe majorproblems that whole world can be facing. Large air pollution is produced by manmade activities like burning of combustible gases, inorganic or organic waste, recyclable materials etc. In last few years, the problem of environmental pollution is raised to significant level because of increase in usage of vehicle throughout the world. Having high thermal efficiency is one of the best advantages of using Diesel Engine, but along with this it has a serious drawback of emitting larger amount of harmful exhaust gases when compared with gasoline engine. The half of total nitrogen oxides and more than two thirds of particulate matter can be emitted by vehicle using diesel as a fuel. Nitrogen oxides emitted by diesel engine results into the formation of ground level ozone, which irritates the respiratory system, causing coughing, choking, and other lung disorder. When nitrogen oxides and hydrocarbon emissions combine in the presence of sunlight gives ozone pollution which results into a health hazardsboth for adults and individualssufferingfromrespiratoryproblems. The emission of large particulate matters due to incomplete combustion of fuel causes health problemslike irritationin the eyes, throat and lungs which leads to various disorders.) Key Words: Magnetic emission filter, Urea injection, Emission Reduction, Diesel Engine 1. INTRODUCTION Nowadays, automotive catalytic converter has been used to reduce the automotive vehicles emissions. Exhaust catalytic converters were introduced, because most of the countries recognized restricting laws related to emissions of carbon monoxide, hydrocarbons andnitrogenoxidesbytheengines. These emissions generated by the combustion process of internal combustion engines are very harmful to health and the surroundings. The CO emissions join withhemoglobin in the bloodstream promotes the reduction of oxygen-active sites which arises asphyxia. Nitrogen oxides (NOx) contribute to acid rain and photochemical smog which give irritation to the eyes and skin. The Three-Way Catalysts are advanced system for emission treatmentofgasolinevehicles that significantly reduce the emissions of carbon monoxide (CO), hydrocarbons (HC) and nitrogen oxides (NOx) in atmosphere. Main aim is to reduce the emissions like CO, NOx, and HC from exhaust of diesel engine using combined effect of magnetic emission filter and urea injection. Environmental pollution is one of the biggest problems faced by human beings in the past decades and in generations to come. Approximately 1/3 of the air pollutionisfrombyautomobile fleet. It is substantial to control automotive pollutions to achieve the goal of cleaner air, which should help for reduction of greenhouse gases. Exhaust pollutants from the automobile’s engines have negative impact on air quality as well as on human health. Current study focuses on newly developed setup of magnetic emission filter and urea injection as a catalytic converter, because existing available catalytic converters suffer from various problems like; poisoning, fracture, melting & higher cost. The objective of this paper is to develop cost effective magnetic emission filter as a catalytic converter to be used on a diesel engine. 2. EXPERIMENTAL SET-UP A magnetic emission filter with urea injection unit schematic diagram Fig -1: Schematic Diagram of Magnetic emission filter with Urea Injection Unit Magnetic emission filter construction is as follows:- It consists of a cylindrical filter (meshed from inside for transfer of exhaust gases), urea injection unit, Neodymium magnets (placed on the periphery of the cylindrical filter) Working principle: - The harmful exhaust gases from enginepassfromtheinletof the filter device which contains nitrogen oxides (NOx),
  • 2. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 1050 carbon monoxide (CO), Hydrocarbons (HC), particulate matter (PM). Following chemical reactions were takes place inside the filter: Table -1: Chemical Reactions of Emission Gases NOx reactions: N2+ O₂ = NO + NO₂ CO reaction: CO+ ½ O2 = CO₂ + Heat HC reaction: HC + O2 = H₂O + CO₂ PM reaction: PM + O2 = CO₂ + H₂O Urea reactions with NOx : 6NO2+ 8NH₃= 7N₂ + 12H₂O 6NO+ 4NH₃ = 5N₂+ 6H₂O NO+ NO2 + 2NH3 = 2N2+ 3H2O 2.1 Reduction of NOx NOx is produced by the reaction of nitrogen and oxygen gases during combustion, especially at higher temperatures. In regions of dense vehicle transportation, significant air pollution caused due to nitrogen oxides emission. Most of this will be nitrogen oxide (NO), with a small amount of nitrogen dioxide (NO2) and remaining of other nitrogen- oxygen combinations. NOx is considered as an undesirable emission and regulations for restriction of this compound are getting stringent. Photochemical smog formation is mainly occurring when NOx reactswithozone,whichisquite harmful for health. NOx is generally createdfromnitrogenin the air. Atmospheric nitrogen exists as a stable diatomic molecule at low temperatures, however, at the very high temperatures like that in combustion chamber of an engine, few of the diatomic nitrogen (N2)breaksdowntomonatomic nitrogen (N) which is reactive. A significant amount of monoatomic nitrogen can be formed as the temperature in combustion chamber is around 2500°C in an engine. Other gases that are relatively stable at low temperatures like oxygen and water vapor become reactive at high temperature which contributes in the formation of NOx. For the purpose of NOx reduction, we have used the urea injection unit. In urea injection a fine atomized spray of urea blend which consist of 40% Urea and 60% water is sprayed into the setup resulting in mixing of the flue gases with the atomized spray. For the purpose of atomizing, the fine spray of urea injection is required and for that carburetor is used. The flue gas is let in instead of the fresh air and urea blend is let in instead of fuel. This carburetor has efficiently worked, and a perfect atomization of the urea blend is obtained continuously. The urea blend is stored in a tank through which continuous passage of the liquid flow takes place.The liquid can be refilled easily once it gets over. 2.2 Reduction of Particulate Matter A magnetic field generated by permanent earth magnets is used for reducing pollutants, mainly HC from exhaust gases. A housing having an inlet for receiving exhaust gases with pollutants, and an outlet for the exit to the exhaust gases which is free from pollutants. A magnetic filter element defines a plurality of flow paths for exhaust gases between inlet and the outlet; during this inlet through flow paths to outlet pollutants in exhaust gases are substantially reduced. To apply magnetic field applied in the pathways of exhaust gases is created by pass strong permanent magnets, due to that magnetic field hydrocarbon changes their orientation and convert from para state to ortho state. In ortho state inter molecular force is reduced to a considerable and increase space between hydrogen. This hydrogen of fuel reacts with oxygen producing a complete burn in the combustion chamber Fig -2: Magnetic Field Effect on Outlet Emission Gases For the filter permanent magnets are used as their magnetic properties are stronger than other normal magnets, So, Neodymium magnets are used based on their low cost and easy availability. Fig -3: Magnetic Field Effect on Outlet Emission Gases Actual Magnetic Pollution filter set-up: Fig -3: Actual magnetic emission filter setup 3. RESULTS AND DISCUSSION The results were taken by the following method: Firstly, we measured the emission levels without the setup and then with the setup on same engine
  • 3. International Research Journal of Engineering and Technology (IRJET) e-ISSN: 2395-0056 Volume: 06 Issue: 10 | Oct 2019 www.irjet.net p-ISSN: 2395-0072 © 2019, IRJET | Impact Factor value: 7.34 | ISO 9001:2008 Certified Journal | Page 1051 Table -2: Engine specifications Table -3: Comparison of Measured Emission with and Without Magnetic Pollution Filter Setup Chart -1: Comparison of before and after setup emission parameters It is evident from the above data that NOx is reduced to about 53% and CO is reduced from 2.034 to 0.58% and the oxygen content has increased from 13.2 to 18.4% which gives quite a clear picture of emission reduction with the help of the setup. 4. CONCLUSION The harmful emissive gases tend to pollute the environment so there is need to reduce them if not eliminate them from the surrounding. Above research work concludethattheuse of magnetic filter as catalytic converter is effective in reducing the harmful content from emissionwhenusedwith a diesel engine. Use of magnetic filterwithurea injectionunit can be used as a substitute to other after treatment devices as it is more cost effective. With neodymium magnets along with urea dosing unit best results of reduced pollutants can be achieved ACKNOWLEDGEMENT The authors sincerely thank Jawaharlal Nehru Engineering College, for the resources and support provided for the study. REFERENCES [1] Engr. Okoronkwo C. A ,Engr. Dr. Nwachukwu, C.C,Engr. Dr. Ngozi –Olehi L.C and Engr. Igbokwe, J.O, The effectof electromagnetic flux density on the ionization and the combustion of fuel (An economy design project)” in AMERICAN JOURNAL OF SCIENTIFIC AND INDUSTRIAL RESEARCH [2] Piyush M Patel, Prof. Gaurav P Rathod ,Prof. Tushar M Patel, “Effect of magnetic field on performance and emission of single cylinder four stroke diesel engine” in IOSR Journal of Engineering (IOSRJEN)Vol. 04, Issue 05 (May. 2014) Type Single Cylinder, Naturally Aspirated Air Cooled, Diesel engine Displacement (CC) 436 CC Max. Power 5.52 kW @ 3600 rpm+ 50rpm Max. Torque 18 Nm @ 2400 – 2200 rpm Sr No. Parameter Emissions measured without setup Emissions measured with setup 1. Oxygen 13.2% 18.4% 2. Fuel temp 95 ˚C 33 ˚C 3. CO 2.034% 0.58% 4. Nitric oxide 239 ppm 112 ppm 5. Methane 2.35% 1.25% 6. CO2 3.28% 1.06% 7. Excess air ratio 84.54 560.30 8. Heat loss in dry flue gas 3.28% 0.48% 9. Total heat loss 27.33% 5.89% 10. Overall efficiency 72.67% 94.09 %