Heat changes in chemical reactions

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ianthi

Educação Negócios Tecnologia

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Physical Chemists have known that Poisson Boltzmann theories (including Debye Huckel) are poor descriptions of the properties of ionic solutions at reasonable concentrations, or in mixtures or containing divalent ions. Since all of life occurs in ionic solutions that are quite concentrated, and involve calcium, Poisson Boltzmann theories are of limited use in biology. These facts seem not to be widely known in the biochemical and biophysical community or among applied mathematicians and theoretical chemists. Thus, the title of this paper

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MB3 is the block in which we will study Mass Balances in Multiple Phases. Phases include: vapor-liquid equilibrium, liquid-liquid systems and solid-liquid systems Extraction, Humidification, Distillation, Absorption, Crystallization are some examples of the processes involving these type of processes. SECTION 1 -Single Phase Theory (Phase-Diagrams) --Phase Diagram --Phase Change --Boiling point (T,P); Sublimation point (T,P); Freezing point (T,P) --L-S, L-G, G-S Equilibrium lines -Vapor Pressure (Antoine and Clapyeron Eqn) --Vapor pressure definition --Volatility --Latent heat of vaporization --Vapor Pressure estimation/calculation -Gibbs Phase Rule --DOF for systems (intensive properties) SECTION 2 -Gas-Liquid Systems (1 condensable) --Only one substance condenses --Evaporation, Drying, Humidity --Examples: Air-Humidity -Gas-Liquid Systems (multi-condensable) --Raoult Law --Henry Law --Dew/Bubble points --Txy & Pxy Diagrams --Examples: Ethanol-Water SECTION 3 -Solid-Liquid Systems --Crystallization --Solubility and Saturation --Hydrated Salts -Liquid-Liquid Systems --Miscibility and Extraction � Problems and Exercises in my webpage www.ChemicalEngineeringGuy.com Suscribe to my channel: www.youtube.com/ChemEngineeringGuy Visit my Facebook Page: www.facebook.com/Chemical.Engineering.Guy e-Mail me: chemical.engineering.guy@gmail.com

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