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The Periodic Table Chapter 12
Why is the Periodic Table important to me? ,[object Object],[object Object]
Pre-Periodic Table Chemistry … ,[object Object],[object Object],[object Object],[object Object],[object Object]
Elements ,[object Object],[object Object]
The History of the Modern Periodic Table
During the nineteenth century, chemists began to categorize the elements according to similarities in their physical and chemical properties.  The end result of these studies was our modern periodic table.
Johann Dobereiner 1780 - 1849 Model of triads In 1829, he classified some elements into groups of three, which he called triads. The elements in a triad had similar chemical properties and orderly physical properties. (ex. Cl, Br, I and Ca, Sr, Ba)
John Newlands 1838 - 1898 Law of Octaves In 1863, he suggested that elements be arranged in “octaves” because he noticed (after arranging the elements in order of increasing atomic mass) that certain properties repeated every 8th element.
John Newlands 1838 - 1898 Law of Octaves Newlands' claim to see a repeating pattern was met with savage ridicule on its announcement. His classification of the elements, he was told, was as arbitrary as putting them in alphabetical order and his paper was rejected for publication by the Chemical Society.
John Newlands 1838 - 1898 Law of Octaves His law of octaves failed beyond the element calcium. WHY? Would his law of octaves work today with the first 20 elements?
Dmitri Mendeleev 1834 - 1907 In 1869 he published a table of the elements organized by increasing atomic mass.
Lothar Meyer 1830 - 1895 At the same time, he published his own table of the elements organized by increasing atomic mass.
[object Object],[object Object],So why is Mendeleev called the “father of the modern periodic table” and not Meyer, or both?
[object Object],[object Object],Mendeleev...
After the discovery of these unknown elements between 1874 and 1885, and the fact that Mendeleev’s predictions for Sc, Ga, and Ge were amazingly close to the actual values, his table was generally accepted.
However, in spite of Mendeleev’s great achievement, problems arose when new elements were discovered and more accurate atomic weights determined.  By looking at our modern periodic table, can you identify what problems might have caused chemists a headache? Ar and K Co and Ni Te and I Th and Pa
Henry Moseley 1887 - 1915 In 1913, through his work with X-rays, he determined the actual nuclear charge (atomic number) of the elements*.  He rearranged the elements in order of increasing atomic number. *“There is in the atom a fundamental quantity which increases by regular steps as we pass from each element to the next.  This quantity can only be the charge on the central positive nucleus.”
Henry Moseley His research was halted when the British government sent him to serve as a foot soldier in WWI.  He was killed in the fighting in Gallipoli by a sniper’s bullet, at the age of 28.  Because of this loss, the British government later restricted its scientists to noncombatant duties during WWII.
Glenn T. Seaborg After co-discovering 10 new elements, in 1944 he moved 14 elements out of the main body of the periodic table to their current location below the Lanthanide series.  These became known as the Actinide series. 1912 - 1999
Glenn T. Seaborg He is the only person to have an element named after him while still alive. 1912 - 1999 "This is the greatest honor ever bestowed upon me - even better, I think, than winning the Nobel Prize."
Periodic Table ,[object Object],[object Object],[object Object]
The Current Periodic Table ,[object Object],[object Object],[object Object],[object Object]
Groups…Here’s Where the Periodic Table Gets Useful!! ,[object Object],[object Object],[object Object],[object Object],[object Object]
Periodic Law When elements are arranged in order of increasing atomic number, there is a periodic pattern in their physical and chemical properties.
 
 
Properties of Non-Metals ,[object Object],[object Object],[object Object],[object Object],[object Object],Sulfur
Properties of Metalloids/Semiconductors ,[object Object],[object Object],[object Object],[object Object],Silicon
Families  Periods ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Families on the Periodic Table ,[object Object],[object Object],[object Object]
Hydrogen ,[object Object],[object Object],[object Object],[object Object]
Hydrogen ,[object Object],[object Object],[object Object]
Alkali Metals ,[object Object],[object Object],[object Object]
Alkali Metals ,[object Object],[object Object]
Alkali Metals ,[object Object],[object Object],[object Object]
Alkaline Earth Metals ,[object Object],[object Object],[object Object]
Alkaline Earth Metals ,[object Object],[object Object],[object Object]
Transition Metals ,[object Object],[object Object],[object Object],[object Object]
Transition Metals ,[object Object],[object Object],[object Object]
 
Transition Elements ,[object Object],[object Object]
Boron Family ,[object Object],[object Object]
Boron Family ,[object Object],[object Object],[object Object],[object Object]
Carbon Family ,[object Object],[object Object],[object Object],[object Object]
Carbon Family ,[object Object],[object Object],[object Object]
Nitrogen Family ,[object Object],[object Object],[object Object],[object Object]
 
Oxygen Family or Chalcogens ,[object Object],[object Object],[object Object]
Oxygen Family ,[object Object],[object Object],[object Object]
Halogens ,[object Object],[object Object],[object Object],[object Object]
Halogen Family ,[object Object],[object Object],Halogen atoms only need to gain 1 electron to fill their outermost energy level. They react with alkali metals to form salts.
The Noble Gases
The Noble Gases ,[object Object],[object Object],[object Object],[object Object],[object Object]
Noble Gases ,[object Object],[object Object],[object Object],[object Object],[object Object]
Rare Earth Elements ,[object Object],[object Object]
The Octet Rule ,[object Object],To determine if an atom has a  stable  arrangement, we will modify our electron arrangement drawings to include only the outer electrons.  This is called the  Lewis Dot Structure  and some examples follow:                                                                                        
We begin by imagining a box around the symbol, and add one electron to each side (exception: He).  If there are more than 4 electrons, the next time around the box, they pair up, see N for example .  First, we use the atomic number. For N, that is _______. Therefore the number of  valence  electrons is ______.  We should also note which family N is in.  In that family all members have ________ outer electrons. Stability and the Octet Rule N • • • • • 5  6  7  full
More Lewis Dot Examples P • • • • • Cl • • • • • • • What does P need for a  stable,  noble-gas-like   arrangement? What does Cl need? 5  6  7  full
Stability and the Octet Rule ,[object Object],[object Object],[object Object]
** Because they already have a full valence energy level. ** The  noble gases  are  stable   meaning they seldom form bonds with other atoms.  Why not?
Stop and Think ,[object Object],[object Object],[object Object],How does an atom of Cl get  stable? Once it’s  stable  it is no longer  neutral.  Let’s see why.
Becoming stable ,[object Object],[object Object],[object Object],[object Object],• -1 An atom with a charge is called an  ion.

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Chapter 12

  • 1. The Periodic Table Chapter 12
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  • 5. The History of the Modern Periodic Table
  • 6. During the nineteenth century, chemists began to categorize the elements according to similarities in their physical and chemical properties. The end result of these studies was our modern periodic table.
  • 7. Johann Dobereiner 1780 - 1849 Model of triads In 1829, he classified some elements into groups of three, which he called triads. The elements in a triad had similar chemical properties and orderly physical properties. (ex. Cl, Br, I and Ca, Sr, Ba)
  • 8. John Newlands 1838 - 1898 Law of Octaves In 1863, he suggested that elements be arranged in “octaves” because he noticed (after arranging the elements in order of increasing atomic mass) that certain properties repeated every 8th element.
  • 9. John Newlands 1838 - 1898 Law of Octaves Newlands' claim to see a repeating pattern was met with savage ridicule on its announcement. His classification of the elements, he was told, was as arbitrary as putting them in alphabetical order and his paper was rejected for publication by the Chemical Society.
  • 10. John Newlands 1838 - 1898 Law of Octaves His law of octaves failed beyond the element calcium. WHY? Would his law of octaves work today with the first 20 elements?
  • 11. Dmitri Mendeleev 1834 - 1907 In 1869 he published a table of the elements organized by increasing atomic mass.
  • 12. Lothar Meyer 1830 - 1895 At the same time, he published his own table of the elements organized by increasing atomic mass.
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  • 15. After the discovery of these unknown elements between 1874 and 1885, and the fact that Mendeleev’s predictions for Sc, Ga, and Ge were amazingly close to the actual values, his table was generally accepted.
  • 16. However, in spite of Mendeleev’s great achievement, problems arose when new elements were discovered and more accurate atomic weights determined. By looking at our modern periodic table, can you identify what problems might have caused chemists a headache? Ar and K Co and Ni Te and I Th and Pa
  • 17. Henry Moseley 1887 - 1915 In 1913, through his work with X-rays, he determined the actual nuclear charge (atomic number) of the elements*. He rearranged the elements in order of increasing atomic number. *“There is in the atom a fundamental quantity which increases by regular steps as we pass from each element to the next. This quantity can only be the charge on the central positive nucleus.”
  • 18. Henry Moseley His research was halted when the British government sent him to serve as a foot soldier in WWI. He was killed in the fighting in Gallipoli by a sniper’s bullet, at the age of 28. Because of this loss, the British government later restricted its scientists to noncombatant duties during WWII.
  • 19. Glenn T. Seaborg After co-discovering 10 new elements, in 1944 he moved 14 elements out of the main body of the periodic table to their current location below the Lanthanide series. These became known as the Actinide series. 1912 - 1999
  • 20. Glenn T. Seaborg He is the only person to have an element named after him while still alive. 1912 - 1999 "This is the greatest honor ever bestowed upon me - even better, I think, than winning the Nobel Prize."
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  • 24. Periodic Law When elements are arranged in order of increasing atomic number, there is a periodic pattern in their physical and chemical properties.
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  • 57. We begin by imagining a box around the symbol, and add one electron to each side (exception: He). If there are more than 4 electrons, the next time around the box, they pair up, see N for example . First, we use the atomic number. For N, that is _______. Therefore the number of valence electrons is ______. We should also note which family N is in. In that family all members have ________ outer electrons. Stability and the Octet Rule N • • • • • 5 6 7 full
  • 58. More Lewis Dot Examples P • • • • • Cl • • • • • • • What does P need for a stable, noble-gas-like arrangement? What does Cl need? 5 6 7 full
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  • 60. ** Because they already have a full valence energy level. ** The noble gases are stable meaning they seldom form bonds with other atoms. Why not?
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