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Allotropic forms of carbon CARBON Crystalline Amorphous Diamond Graphite Fullerene Coal Charcoal Lampblack
 
Electronic configuration of Carbon ,[object Object],[object Object],[object Object],1s 2s 2p C atoms in graphite are sp 2  hybridized
Sp 2  Carbon sp 2  carbon has three hybrid orbitals at 120 o  angle in one plane (forming sigma bonds with three such carbons) and a hybridized orbital at right angles to the plane.
Now each of these sp 2  hybridized carbons combine with each other to form a sheet of hexagonal arranged network.
Each C atom contains an unhybridized p orbital. Together due to resonance they form rings of delocalized electrons.
[object Object],[object Object],[object Object]
1.42 A o 3.4 A o
The delocalised electrons in the unhybridized p orbital are free to move anywhere within the sheet - each electron is no longer fixed to a particular carbon atom.  Because of these free electrons graphite is a good conductor of electricity.  There is, however, no direct contact between the delocalised electrons in one sheet and those in the neighbouring sheets.  Layer of C-atoms Delocalized electrons
Properties of graphite ,[object Object],[object Object],[object Object],[object Object]
Allotropic forms of carbon CARBON Crystalline Amorphous Diamond Graphite Fullerene Coal Charcoal Lampblack
 
Discovery ,[object Object],[object Object],[object Object]
Structure ,[object Object],[object Object]
Structure ,[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],A soccer ball is a model of the Buckminsterfullerene C 60
70-fullerene graph   60-fullerene graph
Properties ,[object Object],[object Object],[object Object],[object Object],[object Object]
Properties ,[object Object],[object Object],[object Object]
Applications ,[object Object],[object Object],[object Object],[object Object],[object Object]
Singled Walled Carbon Nanotube (SWCNT) ,[object Object],[object Object],[object Object]
Types of CNT ,[object Object],[object Object],[object Object],[object Object],[object Object],Achiral Chiral
 
Synthesis Of Carbon Nanotube ,[object Object],[object Object],[object Object]
Electric Arc Discharge ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Chemical Vapour Deposition
Laser Ablation

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Graphite,Fullerene And Carbon Nanotubules

  • 1.  
  • 2. Allotropic forms of carbon CARBON Crystalline Amorphous Diamond Graphite Fullerene Coal Charcoal Lampblack
  • 3.  
  • 4.
  • 5. Sp 2 Carbon sp 2 carbon has three hybrid orbitals at 120 o angle in one plane (forming sigma bonds with three such carbons) and a hybridized orbital at right angles to the plane.
  • 6. Now each of these sp 2 hybridized carbons combine with each other to form a sheet of hexagonal arranged network.
  • 7. Each C atom contains an unhybridized p orbital. Together due to resonance they form rings of delocalized electrons.
  • 8.
  • 9. 1.42 A o 3.4 A o
  • 10. The delocalised electrons in the unhybridized p orbital are free to move anywhere within the sheet - each electron is no longer fixed to a particular carbon atom. Because of these free electrons graphite is a good conductor of electricity. There is, however, no direct contact between the delocalised electrons in one sheet and those in the neighbouring sheets. Layer of C-atoms Delocalized electrons
  • 11.
  • 12. Allotropic forms of carbon CARBON Crystalline Amorphous Diamond Graphite Fullerene Coal Charcoal Lampblack
  • 13.  
  • 14.
  • 15.
  • 16.
  • 17.
  • 18. 70-fullerene graph 60-fullerene graph
  • 19.
  • 20.
  • 21.
  • 22.
  • 23.
  • 24.  
  • 25.
  • 26.