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         Code No: RR220805
                                                                                          Set No. 1
            II B.Tech II Semester Supplimentary Examinations, Apr/May 2008
                   MATERIAL SCIENCE FOR CHEMICAL ENGINEERING
                                        (Chemical Engineering)
         Time: 3 hours                                                                      Max Marks: 80
                                     Answer any FIVE Questions
                                   All Questions carry equal marks



           1. Sketch a (110) plane in a unit cell of cubic crystal. Show all the (111) directions
               that lie on this plane, giving Miller indices of each one of them. [16]

           2. Write about :

                (a) Ionic structures.
                (b) Covalent structures.
                                                                                                       [8+8]

           3. (a) What is meant by the term ‘solid phase’?
                (b) Give some examples of single phase and multiphase materials and state why
                     they are so called?                                                              [6+10]

           4. (a) How the stability of a dislocation loop can be determined?
                (b) Give a brief note on the origin of dislocations?                                   [8+8]

           5. (a) By taking logarithm on both sides of the equation * + [ ( )]n -Q/RT ,
                     show that the condition for plotting data involving * and to obtain a straight
                     line
                (b) Explain why a decrease in temperature should cause the line to shift to the
                     right.                                                                           [10+6]

           6. Distinguish between the term “recovery” and “recrystallization” involved in the
              pro cess of heating cold-worked metals?                                                   [16]

           7. What is meant by ductile-brittle transition temperature? Name a few materials
              which are susceptible to brittle transition? State some of the factors responsible
              for brittle transition?                                                                   [16]

           8. Draw the free energy curves versus composition for the solid and liquid phases in
              a protective system at

                (a) A temperature above protective temperature Tp, where a solid phase is present.
                (b) Tp

                (c) A temperature below Tp where a liquid phase is present. [16]
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         Code No: RR220805
                                                                                 Set No. 2
            II B.Tech II Semester Supplimentary Examinations, Apr/May 2008
                   MATERIAL SCIENCE FOR CHEMICAL ENGINEERING
                                        (Chemical Engineering)
         Time: 3 hours                                                                  Max Marks: 80
                                     Answer any FIVE Questions
                                   All Questions carry equal marks



           1. How many atoms are there per square millimeter on:

               (a) (100) Plane of copper
               (b) (110) Plane

               (c) (111) Pane?                                                                        [5+5+6]

           2. State the usual methods used in determining the structure of a crystal. State also
               how to determine lattice parameters of a cubic crystal by the di raction metho d.
                                                                                                         [16]

           3. (a) What is meant by the term ‘solid phase’?
               (b) Give some examples of single phase and multiphase materials and state why
                    they are so called?                                                                [6+10]

           4. Derive an expression for the energy per unit length of an edge dislocation? [16]

           5. What is engineering stress and strain? What is meant by true stress and true strain?
              State where each of them are particularly used and suitable? In mathematical
              terms, which of these is the independent variable?                                         [16]

           6. If a bar of metal is quenched from a high temperature, the surface layers are found
               to contain compressive stresses and the center portion tensile stresses. Explain the
               phenomena?                                                                                [16]

           7. Explain the mechanism of

               (a) fatigue failure
               (b) Creep failure.
                                                                                                        [8+8]

           8. De ne grain boundary and account for its character.                                        [16]
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         Code No: RR220805
                                                                                          Set No. 3
            II B.Tech II Semester Supplimentary Examinations, Apr/May 2008
                   MATERIAL SCIENCE FOR CHEMICAL ENGINEERING
                                        (Chemical Engineering)
         Time: 3 hours                                                                        Max Marks: 80
                                     Answer any FIVE Questions
                                   All Questions carry equal marks



           1. (a) Sketch the ve, two dimensional (plane) lattices.
                (b) Explain why each is a distinct distribution of points in two dimension.
                (c) Why is “entered square” not a separate plane lattice. [10+3+3]
           2. Calculate the atomic density (number of atoms for unit area) in (111),(110),(100)
              planes of copper (F.C.C.) with the lattice parameter of 3.61 A0. Can you pack
              atoms more closely than in (111) plane?                                                     [16]

           3. Why is inter solubility possible in a substitutional solid solution but not in a inter-
              stitial solid solution?                                                                     [16]

           4. Discuss :

                (a) How solute atoms a ect dislocation motion?
                (b) How precipitate particles a ect dislocation motion?                                  [8+8]

           5. (a) By taking logarithm on both sides of the equation * + [ ( )]n -Q/RT ,
                     show that the condition for plotting data involving * and to obtain a straight
                     line
                (b) Explain why a decrease in temperature should cause the line to shift to the
                     right.                                                                             [10+6]

           6. A pure iron sheet 0.10 inch thick is annealed before cold-rolling it to 0.08inch
              (negligible change in width).

                (a) What would be the ductility of the iron after cold-rolling?
                (b) Estimate the approximate temperature of recrystallization for this iron?

                (c) Give two reasons why the recrystallization temperature of any metal is not
                     xed?                                                                                     [16]

           7. The fracture strength of a sample of glass is 40 MN/ 2. Estimate the Gri th’s
               crack length in this sample assuming E=60,000MN/ 2.and = 0.2 J/ 2. [16]

           8. Explain why the rate of transformation of austenite to pearlite goes through a
              maximum (the nose of the TTT as the reaction temperature is lowered below A1)
              (Supply TTT diagram in the examination).                                                    [16]
www.studentyogi.com                                                                                www.studentyogi.com

         Code No: RR220805
                                                                                      Set No. 4
            II B.Tech II Semester Supplimentary Examinations, Apr/May 2008
                   MATERIAL SCIENCE FOR CHEMICAL ENGINEERING
                                        (Chemical Engineering)
         Time: 3 hours                                                                           Max Marks: 80
                                     Answer any FIVE Questions
                                   All Questions carry equal marks



           1. (a) A sodium chloride crystal is used to measure the wave length of some X rays.
                    The di raction angle is 5 20 for d111 spacing of chloride ions. What is the
                    wavelength? (The lattice constant is 5.63 0) d111.

               (b) Write tin is bct with equivalent points at 0,0,0 and 1
                                                                                2 , 1 , 12
                                                                                    2        and lattice constants
                    of a 5.820 A and c =3.175 A. The unit cell however has four atoms (at 0,0,0;
                    1
                    2 , 12, 1 2; 0, 1 4, 14 and 0, 1   2, 3 4 )
               (c) What is the linear density of equivalent points in
                       i. (111) and
                      ii. (201)directions?                                                                  [5+5+6]

           2. Give detailed explanation for powder method.                                                       [16]

           3. Explain the di erence between edge and screw dislo cation.                                         [16]

           4. Explain clearly the role of dislocations in crystal growth?                                        [16]

           5. (a) What is the di erence between slip in single crystals and slip in polycrystalline
                   metals?
               (b) Explain with neat sketches the mechanism for dislocation in plastic deforma-
                    tion.                                                                                      [6+10]

           6. Cite ve engineering applications where metal is cold-worked to increase the tensile
              strength?                                                                                          [16]

           7. What is fracture? State the causes of fracture in a material? [16]

           8. (a) What is meant by eutectoid, hypo eutectoid, hypereutectoid steels?
               (b) What is the relationship between them?                                                      [12+4]

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M A T E R I A L S C I E N C E F O R C H E M I C A L E N G I N E E R I N G J N T U M O D E L P A P E R{Www

  • 1. www.studentyogi.com www.studentyogi.com Code No: RR220805 Set No. 1 II B.Tech II Semester Supplimentary Examinations, Apr/May 2008 MATERIAL SCIENCE FOR CHEMICAL ENGINEERING (Chemical Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. Sketch a (110) plane in a unit cell of cubic crystal. Show all the (111) directions that lie on this plane, giving Miller indices of each one of them. [16] 2. Write about : (a) Ionic structures. (b) Covalent structures. [8+8] 3. (a) What is meant by the term ‘solid phase’? (b) Give some examples of single phase and multiphase materials and state why they are so called? [6+10] 4. (a) How the stability of a dislocation loop can be determined? (b) Give a brief note on the origin of dislocations? [8+8] 5. (a) By taking logarithm on both sides of the equation * + [ ( )]n -Q/RT , show that the condition for plotting data involving * and to obtain a straight line (b) Explain why a decrease in temperature should cause the line to shift to the right. [10+6] 6. Distinguish between the term “recovery” and “recrystallization” involved in the pro cess of heating cold-worked metals? [16] 7. What is meant by ductile-brittle transition temperature? Name a few materials which are susceptible to brittle transition? State some of the factors responsible for brittle transition? [16] 8. Draw the free energy curves versus composition for the solid and liquid phases in a protective system at (a) A temperature above protective temperature Tp, where a solid phase is present. (b) Tp (c) A temperature below Tp where a liquid phase is present. [16]
  • 2. www.studentyogi.com www.studentyogi.com Code No: RR220805 Set No. 2 II B.Tech II Semester Supplimentary Examinations, Apr/May 2008 MATERIAL SCIENCE FOR CHEMICAL ENGINEERING (Chemical Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. How many atoms are there per square millimeter on: (a) (100) Plane of copper (b) (110) Plane (c) (111) Pane? [5+5+6] 2. State the usual methods used in determining the structure of a crystal. State also how to determine lattice parameters of a cubic crystal by the di raction metho d. [16] 3. (a) What is meant by the term ‘solid phase’? (b) Give some examples of single phase and multiphase materials and state why they are so called? [6+10] 4. Derive an expression for the energy per unit length of an edge dislocation? [16] 5. What is engineering stress and strain? What is meant by true stress and true strain? State where each of them are particularly used and suitable? In mathematical terms, which of these is the independent variable? [16] 6. If a bar of metal is quenched from a high temperature, the surface layers are found to contain compressive stresses and the center portion tensile stresses. Explain the phenomena? [16] 7. Explain the mechanism of (a) fatigue failure (b) Creep failure. [8+8] 8. De ne grain boundary and account for its character. [16]
  • 3. www.studentyogi.com www.studentyogi.com Code No: RR220805 Set No. 3 II B.Tech II Semester Supplimentary Examinations, Apr/May 2008 MATERIAL SCIENCE FOR CHEMICAL ENGINEERING (Chemical Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. (a) Sketch the ve, two dimensional (plane) lattices. (b) Explain why each is a distinct distribution of points in two dimension. (c) Why is “entered square” not a separate plane lattice. [10+3+3] 2. Calculate the atomic density (number of atoms for unit area) in (111),(110),(100) planes of copper (F.C.C.) with the lattice parameter of 3.61 A0. Can you pack atoms more closely than in (111) plane? [16] 3. Why is inter solubility possible in a substitutional solid solution but not in a inter- stitial solid solution? [16] 4. Discuss : (a) How solute atoms a ect dislocation motion? (b) How precipitate particles a ect dislocation motion? [8+8] 5. (a) By taking logarithm on both sides of the equation * + [ ( )]n -Q/RT , show that the condition for plotting data involving * and to obtain a straight line (b) Explain why a decrease in temperature should cause the line to shift to the right. [10+6] 6. A pure iron sheet 0.10 inch thick is annealed before cold-rolling it to 0.08inch (negligible change in width). (a) What would be the ductility of the iron after cold-rolling? (b) Estimate the approximate temperature of recrystallization for this iron? (c) Give two reasons why the recrystallization temperature of any metal is not xed? [16] 7. The fracture strength of a sample of glass is 40 MN/ 2. Estimate the Gri th’s crack length in this sample assuming E=60,000MN/ 2.and = 0.2 J/ 2. [16] 8. Explain why the rate of transformation of austenite to pearlite goes through a maximum (the nose of the TTT as the reaction temperature is lowered below A1) (Supply TTT diagram in the examination). [16]
  • 4. www.studentyogi.com www.studentyogi.com Code No: RR220805 Set No. 4 II B.Tech II Semester Supplimentary Examinations, Apr/May 2008 MATERIAL SCIENCE FOR CHEMICAL ENGINEERING (Chemical Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks 1. (a) A sodium chloride crystal is used to measure the wave length of some X rays. The di raction angle is 5 20 for d111 spacing of chloride ions. What is the wavelength? (The lattice constant is 5.63 0) d111. (b) Write tin is bct with equivalent points at 0,0,0 and 1 2 , 1 , 12 2 and lattice constants of a 5.820 A and c =3.175 A. The unit cell however has four atoms (at 0,0,0; 1 2 , 12, 1 2; 0, 1 4, 14 and 0, 1 2, 3 4 ) (c) What is the linear density of equivalent points in i. (111) and ii. (201)directions? [5+5+6] 2. Give detailed explanation for powder method. [16] 3. Explain the di erence between edge and screw dislo cation. [16] 4. Explain clearly the role of dislocations in crystal growth? [16] 5. (a) What is the di erence between slip in single crystals and slip in polycrystalline metals? (b) Explain with neat sketches the mechanism for dislocation in plastic deforma- tion. [6+10] 6. Cite ve engineering applications where metal is cold-worked to increase the tensile strength? [16] 7. What is fracture? State the causes of fracture in a material? [16] 8. (a) What is meant by eutectoid, hypo eutectoid, hypereutectoid steels? (b) What is the relationship between them? [12+4]