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BELLWORK Balance the following redox reaction using the “half-reaction” method HNO 2  + I -      NO  + I 2 2e -  + 2H +  +   2 HNO 2      2 NO  + 2H 2 O 2 I -     I 2  + 2e - 2H +  +  2HNO 2  + 2I -     2NO + 2H 2 O + I 2
Electrochemical cells produce an electric current from redox reactions CAN ALSO BE CALLED A Voltaic cell  Galvanic cell  Battery
A simple battery separates the reduction reaction from the oxidation reaction so that the electrons must travel through a wire ,[object Object],[object Object]
Redox reaction Zn(s) + Cu 2+ (aq)    Zn 2+ (aq) + Cu(s) ,[object Object],[object Object],[object Object]
How to make a battery or an electrochemical cell ,[object Object],e -  e -  e -  e -  e -  e -  e -  e -  e -  e -  e -  e -  e -  e -  e -  e -   e -   e -   e -   e -   e -   Oxidation  Reduction half cell  half cell
To make the Zinc half cell  Add a strip of Zinc metal to a solution containing Zn 2+ 1M ZnSO 4 Zn(s) Zinc metal
To make the copper half cell  Add a strip of copper metal to a solution containing Cu 2+ 1M CuSO 4 Cu(s) Copper metal
The metal strips are electrodes The solutions are electrolytes ,[object Object],[object Object],[object Object],[object Object],[object Object]
 
When a wire connects the half cells an electrical current is created. This can’t occur for long because positive charge will build up at the anode and negative charge will build up at the cathode A salt bridge is used to keep the two cell compartments neutral
The salt bridge contains a salt (positive and negative ions) that flows into each beaker as needed to keep the charge neutral ,[object Object],SALT BRIDGE Gotta have it!!!
How do you determine the voltage of a battery? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],The element at the top of the table will be reduced.  The lower one will be oxidized. ADD THESE FOR VOLTAGE
Describe the voltaic cell represented as: Al (s)  |  Al 2 (SO 4 ) 3 (aq) ||  NiSO 4 (aq) |  Ni (s)

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Lecture 21- Electrochemical cells

  • 1. BELLWORK Balance the following redox reaction using the “half-reaction” method HNO 2 + I -  NO + I 2 2e - + 2H + + 2 HNO 2  2 NO + 2H 2 O 2 I -  I 2 + 2e - 2H + + 2HNO 2 + 2I -  2NO + 2H 2 O + I 2
  • 2. Electrochemical cells produce an electric current from redox reactions CAN ALSO BE CALLED A Voltaic cell Galvanic cell Battery
  • 3.
  • 4.
  • 5.
  • 6. To make the Zinc half cell Add a strip of Zinc metal to a solution containing Zn 2+ 1M ZnSO 4 Zn(s) Zinc metal
  • 7. To make the copper half cell Add a strip of copper metal to a solution containing Cu 2+ 1M CuSO 4 Cu(s) Copper metal
  • 8.
  • 9.  
  • 10. When a wire connects the half cells an electrical current is created. This can’t occur for long because positive charge will build up at the anode and negative charge will build up at the cathode A salt bridge is used to keep the two cell compartments neutral
  • 11.
  • 12.
  • 13.
  • 14. Describe the voltaic cell represented as: Al (s) | Al 2 (SO 4 ) 3 (aq) || NiSO 4 (aq) | Ni (s)