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Modern Model of The Atom


•   Rutherford’s Model: Pro’s and
    Con’s

    •   Improved on (Thomson’s)
        Plum Pudding Model

    •   Protons inside, Electrons
        outside

    •   Couldn’t explain how
        electrons stayed outside
Niels Bohr and The Planetary Model of
              The Atom


• Inspired by                  Niels
                               Bohr
  the work of
  Bunsen and
  Kirchoff
• Emission
  spectra of
                Spectrometer
  elements                     Bunsen and Kirchoff
Bohr: Electrons are ‘quantized’


•   Emission spectra
                                                  Emission Spectra

•   Electrons in                                      of a Few
                                                     Elements
    Energy Levels

•   Electrons

    •   Ground State           Ground State
        vs. Excited           and Excited State
        State
Bohr Model=Planetary Model



•   Bohr’s Model Pro’s and
    Con’s

    •   Explained small atoms
        well

    •   Failed to explain where
        electrons were in larger
        atoms                      Nitrogen Atom
Quantum Mechanic Model of The Atom


•   Erwin Schrodinger and
    Werner Heisenberg              Schrodinger


•   1925-30

•   Refined Bohr’s Model

•   Wave or Cloud Model of
    Electrons

•   Electrons in orbitals of
                                   Heisenberg

    differing energy
Quantum Mechanic Rules


•   Energy level (n=energy level)

•   Type of orbital (s,p,d,f)        s-orbital


•   Shape of orbital                 p-orbital


    •   sphere, dumbbell, rosette,   d-orbital
        complex
                                     f-orbital
•   Number of Electrons in orbital
                                                   Shapes
    •   s=2; p=6; d=10; f=14                     of Orbitals
Quantum Mechanic Rules Continued...

•   Aufbau Principle

    •   electrons occupy orbitals of lower energy first

    •   (s<p<d<f)

•   Hund’s Rule

    •   electrons occupy adjacent orbitals before pairing

•   Pauli Exclusion Principle

    •   electrons occupying the same orbital must have
        opposite spin
The Periodic Table:
Where Are The S, P, D, and F Orbitals?
   s-orbitals   d-orbitals   p-orbitals




                                          f-orbitals
Orbital Diagrams and
         Electron Configurations

• orbital diagrams
  show us where
  bonding occurs
• We’ll do elements
  1-10
• You will do
  elements 11-18,
  tonight
                          Aufbau Diagram

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Modern Model of the Atom

  • 1. Modern Model of The Atom • Rutherford’s Model: Pro’s and Con’s • Improved on (Thomson’s) Plum Pudding Model • Protons inside, Electrons outside • Couldn’t explain how electrons stayed outside
  • 2. Niels Bohr and The Planetary Model of The Atom • Inspired by Niels Bohr the work of Bunsen and Kirchoff • Emission spectra of Spectrometer elements Bunsen and Kirchoff
  • 3. Bohr: Electrons are ‘quantized’ • Emission spectra Emission Spectra • Electrons in of a Few Elements Energy Levels • Electrons • Ground State Ground State vs. Excited and Excited State State
  • 4. Bohr Model=Planetary Model • Bohr’s Model Pro’s and Con’s • Explained small atoms well • Failed to explain where electrons were in larger atoms Nitrogen Atom
  • 5. Quantum Mechanic Model of The Atom • Erwin Schrodinger and Werner Heisenberg Schrodinger • 1925-30 • Refined Bohr’s Model • Wave or Cloud Model of Electrons • Electrons in orbitals of Heisenberg differing energy
  • 6. Quantum Mechanic Rules • Energy level (n=energy level) • Type of orbital (s,p,d,f) s-orbital • Shape of orbital p-orbital • sphere, dumbbell, rosette, d-orbital complex f-orbital • Number of Electrons in orbital Shapes • s=2; p=6; d=10; f=14 of Orbitals
  • 7. Quantum Mechanic Rules Continued... • Aufbau Principle • electrons occupy orbitals of lower energy first • (s<p<d<f) • Hund’s Rule • electrons occupy adjacent orbitals before pairing • Pauli Exclusion Principle • electrons occupying the same orbital must have opposite spin
  • 8. The Periodic Table: Where Are The S, P, D, and F Orbitals? s-orbitals d-orbitals p-orbitals f-orbitals
  • 9. Orbital Diagrams and Electron Configurations • orbital diagrams show us where bonding occurs • We’ll do elements 1-10 • You will do elements 11-18, tonight Aufbau Diagram

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