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NANOTECHNOLOGY
INTRODUCTION

• A basic definition of nanotechnology is
  the study manipulation manufacture of
  extremely minute machines or devices.
  These devices are so small to the point
  of manipulating the atoms themselves
  to form materials.

• Nanotechnology is an enabling
  technology that allows us to develop
  materials with improved or totally new
  properties
Contd.,

      • Nanotechnology is the use of very
        small particles of material. A
        nanometer is a billionth of a meter.

      • Nanotechnology is not a new
        science and it is not a new
        technology. It is rather an
        extension of the sciences and
        technologies .
Advantages
• Nanotechnology will make most exiting
  products quite a bit more powerful and
  flexible.

• The nanotechnology promises a rapid
  improvement of technology at low cost
  and high convenience.

• Computers will compute
  faster, materials will become stronger
  and medicine will cure more diseases
Disadvantages
• The nanotechnology has potential of
  developing and fabricating dangerous
  weapons, drugs in large quantity.

• At this moment the main limitation is the
  high costs of nanotechnology. Also
  concerns with the environmental effects.
Introduction To Nano Materials
• Nano particle: It is defined as a
  particle with at least one dimension
  less than 200nm.

• Nano composite : It is produced by
  adding Nano particle to a bulk
                                         Fig.Nanotube on
  material in order to improve the       a small cement
  bulk material’s properties.            grain
Contd.,

                Carbon Nano Tubes(CNT)
• They are cylindrical with nanometer diameter.
• They have 5 times the Young’s modulus and 8 times
  (theoretically 100 times) the strength of steel.
Contd.,

                     Titanium oxide(TiO2)
     • Titanium dioxide is a widely used white pigment.

     •    When incorporated into outdoor building
          materials can substantially reduce concentrations
          of airborne pollutants.

     • Additionally, as TiO2 is exposed to UV light, it
       becomes increasingly hydrophilic ,thus it can be
       used for selfcleaning windows.
Nanotechnology In Construction

•   Concrete is stronger, more durable and more
    easily placed.
•
• Steel is made tougher .
•
• Glass is self-cleaning.
•
• Paints are made more insulating and water
  repelling.
Nanotechnology in concrete
• As we know, Concrete is a mixture of
  cement, sand(fine aggregate), coarse
  aggregate and water.

• As concrete is most usable material in
  construction industry it’s been require to Fig.Engineered
                                             Cementitious
  improve its quality.                       Composites
                                               (ECC) used to
                                               repair a bridge
• Concrete is, after all, a macro-material     deck

  strongly influenced by its nano-properties.
Contd.,

         Nano-silica in concrete
• Particle packing in concrete can be improved
  by using nano-silica which leads to a
  densifying of the micro and nanostructure
  resulting in improved mechanical properties.
•
                                                    Fig.ECC
• Related to improved particle packing as a         suppresses
  result, the compressive strength of the refined   cracking and
  material is also 3 to 6 times Increased then      becomes
  the ordinary portland cement.                     flexible
Contd.,

              Nano-cement in concrete
•    Average size of Portland cement particle is
     about 50 microns.

• Nano-cement is having particle size about 5
  microns so it is used in thinner final products
  and for faster setting time.

• Hydration tests indicated that the Nano-
  cement had a more rapid hydration rate than
  Portland cement.
Contd.,
               TiO2 in concrete
• It can be used as an excellent reflective
  coating.

• As when rain water is attracted to the surface
  and forms sheets which then collect the
  pollutants and dirt particles ,TiO2 then washes
  them off.

• The resulting concrete, already used in
  projects around the world, has a white color
  that retains its whiteness very effectively.      Fig.A building
                                                    coated with TiO2
Contd.,

               CNTs in concrete
• The addition of small amounts (1% wt) of
  CNT’s can improve the mechanical properties
  of samples consisting of the main Portland
  cement phase and water.

• Oxidized multi-walled Nano tubes (MWNT’s)
  show the best improvements both in
  compressive strength (+ 25 N/mm2) and
  flexural strength (+ 8 N/mm2) compared to the
  samples without the reinforcement.
Nanotechnology and steel

• Fatigue is a significant issue that can lead to
  the structural failure of steel subject to cyclic
  loading, such as in bridges or towers.

• Stress risers are responsible for initiating
  cracks from which fatigue failure results and
  research has shown that the addition of copper
  Nanoparticle reduces the surface unevenness
  of steel which then limits the number of stress
  risers and hence fatigue cracking.
Contd.,
     • Two products in international market
       Sandvik Nanoflex
        MMFX2 steel
        produced by Sandvik Materials
       Technology(Sweden),having desirable qualities of a
       high Young’s Modulus and high strength and
       resistant to corrosion is due to the presence of very
       hard nanometer-sized particles.

     • MMFX steel also launched by MMFX steel
       corporation (America) has the mechanical
       properties of conventional steel.
Contd.,

      • As the use of the stainless steel in the
        construction is limited for the sake of economy.
      • The MMFX Steel is an alternative to
        conventional stainless steel, but at a lower
        cost.
      • High rise structures require high strength joints
        and this in turn leads to the need for high
        strength bolts.
      • Vanadium and Molybdenum Nanoparticle has
        shown that they improve the delayed fracture
        and hence improving the steel micro-structure.
Nanotechnology and glass

• To block light& heat coming through
  windows, self cleaning glass using TiO2 is
  used in Nanoparticle form to coat glazing since
  it has sterilizing and anti-fouling properties.
• Fire-protective glass is another application of
  nanotechnology.
• This is achieved by using a clear intumescent
  layer sandwiched between glass panels (an
  inter-layer) formed of fumed silica (SiO2)
  Nanoparticle which turns into a rigid and
  opaque fire shield when heated.
Contd.,


      • As an active solution, thermo chromic
        technologies are being studied which react to
        temperature and provide insulation to give
        protection from heating while maintaining
        adequate lighting.

      • A third strategy, that produces a similar
        outcome by a different process, involves photo
        chromic technologies which react to changes
        in light intensity.
Nanotechnology and paints

• Nanotechnology is being applied to paints and
  insulating properties, produced by the addition
  of nano-sized cells, pores and particles, giving
  very limited paths for thermal conduction, are
  currently available.

• This type of paint is used, for corrosion
  protection under insulation since it is
  hydrophobic and repels water from the metal
  pipe and can also protect metal from salt water
  attack.
Contd.,


      • These can also be used for Elimination of toxic
        gases.

      • The absorption of carbon monoxide is done by
        using cuprous salt and adsorption of
        hydrocarbons is done by using a complex
        nanomaterial. i.e., Carbon Monolithic Aero
        gels.
Shape memory alloys(SMAs)

• These have found increasing application in
  civil structures .

• Due to super-elastics properties, the elastic
  deformation of SMAs is followed by a large
  increase of strain under an almost constant
  stress. After unloading, only elastic strain
  recovers and the residual stain can be
  removed through heating.
Case Studies




Fig(a) Tendon buckles        Fig(b)Tendon
during loading               recovers after heating
Fig(a) Concrete cracks   Fig(b) Crack is closed
upon loading             up after heating
• The barely visible blue-green area at
the top of this X-ray shows that very few
chloride ions (in green) penetrate into the
concrete. Infiltrating chloride and
sulphate ions cause internal structural
damage over time that leads to cracks
and weakens the concrete.
• This can be removed rather than
change the size and density of the
pores in concrete, it would be better to
change the viscosity of the solution in
the concrete at the microscale to reduce
the speed at which chlorides and
sulphates enter the concrete.            Fig. 7mm thick concrete
                                         wall
Refrences

• www.ieee.org
• www.nanowerk.com/news/newsid=905
• http://hello-engineers.blogspot.com/
• www.futuretechnologies.com
• Nanotechnology: A gentle introduction to the
  next big idea by Mark A Ratner, Daniel Ratner
  technology-2002.
• http://www.slideshare.net
Questions And Quarries
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Nanotechnology

  • 2. INTRODUCTION • A basic definition of nanotechnology is the study manipulation manufacture of extremely minute machines or devices. These devices are so small to the point of manipulating the atoms themselves to form materials. • Nanotechnology is an enabling technology that allows us to develop materials with improved or totally new properties
  • 3. Contd., • Nanotechnology is the use of very small particles of material. A nanometer is a billionth of a meter. • Nanotechnology is not a new science and it is not a new technology. It is rather an extension of the sciences and technologies .
  • 4. Advantages • Nanotechnology will make most exiting products quite a bit more powerful and flexible. • The nanotechnology promises a rapid improvement of technology at low cost and high convenience. • Computers will compute faster, materials will become stronger and medicine will cure more diseases
  • 5. Disadvantages • The nanotechnology has potential of developing and fabricating dangerous weapons, drugs in large quantity. • At this moment the main limitation is the high costs of nanotechnology. Also concerns with the environmental effects.
  • 6. Introduction To Nano Materials • Nano particle: It is defined as a particle with at least one dimension less than 200nm. • Nano composite : It is produced by adding Nano particle to a bulk Fig.Nanotube on material in order to improve the a small cement bulk material’s properties. grain
  • 7. Contd., Carbon Nano Tubes(CNT) • They are cylindrical with nanometer diameter. • They have 5 times the Young’s modulus and 8 times (theoretically 100 times) the strength of steel.
  • 8. Contd., Titanium oxide(TiO2) • Titanium dioxide is a widely used white pigment. • When incorporated into outdoor building materials can substantially reduce concentrations of airborne pollutants. • Additionally, as TiO2 is exposed to UV light, it becomes increasingly hydrophilic ,thus it can be used for selfcleaning windows.
  • 9. Nanotechnology In Construction • Concrete is stronger, more durable and more easily placed. • • Steel is made tougher . • • Glass is self-cleaning. • • Paints are made more insulating and water repelling.
  • 10. Nanotechnology in concrete • As we know, Concrete is a mixture of cement, sand(fine aggregate), coarse aggregate and water. • As concrete is most usable material in construction industry it’s been require to Fig.Engineered Cementitious improve its quality. Composites (ECC) used to repair a bridge • Concrete is, after all, a macro-material deck strongly influenced by its nano-properties.
  • 11. Contd., Nano-silica in concrete • Particle packing in concrete can be improved by using nano-silica which leads to a densifying of the micro and nanostructure resulting in improved mechanical properties. • Fig.ECC • Related to improved particle packing as a suppresses result, the compressive strength of the refined cracking and material is also 3 to 6 times Increased then becomes the ordinary portland cement. flexible
  • 12. Contd., Nano-cement in concrete • Average size of Portland cement particle is about 50 microns. • Nano-cement is having particle size about 5 microns so it is used in thinner final products and for faster setting time. • Hydration tests indicated that the Nano- cement had a more rapid hydration rate than Portland cement.
  • 13. Contd., TiO2 in concrete • It can be used as an excellent reflective coating. • As when rain water is attracted to the surface and forms sheets which then collect the pollutants and dirt particles ,TiO2 then washes them off. • The resulting concrete, already used in projects around the world, has a white color that retains its whiteness very effectively. Fig.A building coated with TiO2
  • 14. Contd., CNTs in concrete • The addition of small amounts (1% wt) of CNT’s can improve the mechanical properties of samples consisting of the main Portland cement phase and water. • Oxidized multi-walled Nano tubes (MWNT’s) show the best improvements both in compressive strength (+ 25 N/mm2) and flexural strength (+ 8 N/mm2) compared to the samples without the reinforcement.
  • 15.
  • 16. Nanotechnology and steel • Fatigue is a significant issue that can lead to the structural failure of steel subject to cyclic loading, such as in bridges or towers. • Stress risers are responsible for initiating cracks from which fatigue failure results and research has shown that the addition of copper Nanoparticle reduces the surface unevenness of steel which then limits the number of stress risers and hence fatigue cracking.
  • 17. Contd., • Two products in international market Sandvik Nanoflex MMFX2 steel produced by Sandvik Materials Technology(Sweden),having desirable qualities of a high Young’s Modulus and high strength and resistant to corrosion is due to the presence of very hard nanometer-sized particles. • MMFX steel also launched by MMFX steel corporation (America) has the mechanical properties of conventional steel.
  • 18. Contd., • As the use of the stainless steel in the construction is limited for the sake of economy. • The MMFX Steel is an alternative to conventional stainless steel, but at a lower cost. • High rise structures require high strength joints and this in turn leads to the need for high strength bolts. • Vanadium and Molybdenum Nanoparticle has shown that they improve the delayed fracture and hence improving the steel micro-structure.
  • 19. Nanotechnology and glass • To block light& heat coming through windows, self cleaning glass using TiO2 is used in Nanoparticle form to coat glazing since it has sterilizing and anti-fouling properties. • Fire-protective glass is another application of nanotechnology. • This is achieved by using a clear intumescent layer sandwiched between glass panels (an inter-layer) formed of fumed silica (SiO2) Nanoparticle which turns into a rigid and opaque fire shield when heated.
  • 20. Contd., • As an active solution, thermo chromic technologies are being studied which react to temperature and provide insulation to give protection from heating while maintaining adequate lighting. • A third strategy, that produces a similar outcome by a different process, involves photo chromic technologies which react to changes in light intensity.
  • 21. Nanotechnology and paints • Nanotechnology is being applied to paints and insulating properties, produced by the addition of nano-sized cells, pores and particles, giving very limited paths for thermal conduction, are currently available. • This type of paint is used, for corrosion protection under insulation since it is hydrophobic and repels water from the metal pipe and can also protect metal from salt water attack.
  • 22. Contd., • These can also be used for Elimination of toxic gases. • The absorption of carbon monoxide is done by using cuprous salt and adsorption of hydrocarbons is done by using a complex nanomaterial. i.e., Carbon Monolithic Aero gels.
  • 23. Shape memory alloys(SMAs) • These have found increasing application in civil structures . • Due to super-elastics properties, the elastic deformation of SMAs is followed by a large increase of strain under an almost constant stress. After unloading, only elastic strain recovers and the residual stain can be removed through heating.
  • 24. Case Studies Fig(a) Tendon buckles Fig(b)Tendon during loading recovers after heating
  • 25. Fig(a) Concrete cracks Fig(b) Crack is closed upon loading up after heating
  • 26. • The barely visible blue-green area at the top of this X-ray shows that very few chloride ions (in green) penetrate into the concrete. Infiltrating chloride and sulphate ions cause internal structural damage over time that leads to cracks and weakens the concrete. • This can be removed rather than change the size and density of the pores in concrete, it would be better to change the viscosity of the solution in the concrete at the microscale to reduce the speed at which chlorides and sulphates enter the concrete. Fig. 7mm thick concrete wall
  • 27. Refrences • www.ieee.org • www.nanowerk.com/news/newsid=905 • http://hello-engineers.blogspot.com/ • www.futuretechnologies.com • Nanotechnology: A gentle introduction to the next big idea by Mark A Ratner, Daniel Ratner technology-2002. • http://www.slideshare.net