Solid-state Battery

From Technologies to Market
Solid-state
Battery
Sample
June 2018

2
Biography & contact
ABOUTTHE AUTHOR
Dr Milan ROSINA
Dr. Milan Rosina is Senior Analyst,Power Electronics & Batteries, atYole Développement (Yole), within the Power & Wireless division.
Milan has 20 years of scientific, industrial and managerial experience involving equipment and process development, due diligence, technology, and
market surveys in the fields of renewable energies, EV/HEV, energy storage, batteries, power electronics, thermal management, and innovative materials
and devices.
He received his Ph.D. degree from National Polytechnical Institute (Grenoble, France). He previously worked for the Institute of Electrical Engineering
in Slovakia, Centrotherm in Germany,Fraunhofer IWS in Germany, CEA LETI in France, and utility company ENGIE in France.
E-mail: rosina@yole.fr
Solid State Battery | Sample | www.yole.fr | ©2018

3
o Report objectives 6
o Companies cited in this report 7
o List of abbreviations 8
o Executive summary 9
o Noteworthy news 35
o Introduction 38
• Three main axes of innovation in batteries
• Two ways for battery cell development to meet market expectations
o Solid-state battery 42
• Solid-state battery, in a nutshell
• Solid-state battery - principle and structure
• Comparison of conventional and solid-state Li-ion battery cell structures
• Solid-state microbattery vs. bulk solid-state battery
• Solid-state microbattery vs. bulk solid-state battery: comparative table
o Why solid-state battery? 48
• Solid-state battery as a the next-generation of Li-ion batteries
• Solid-state battery - main drivers
o What does solid-state battery compete with? - conventional Li-ion battery 51
• Current Li-ion battery cell structure
• Li-ion technologies and applications
• Variety of cell technologies still required
• Different LI-ion battery cells - comparative table
• Comparative graph of energy density for different Li-ion battery cells
• Where are Li-ion battery’s limitations/weak points?
• Safety issues related to Li-ion batteries - thermal runaway
• LIB incidents can result in severe human and financial consequences
• Solid-state battery’s “sweet spot”?
• How can advanced batteries compete with lithium-ion technologies?
• Solid-state battery - advantages
• Solid-state battery - challenges
• Solid-state battery - desired features
• Solid-state battery - electrolyte
• Separator used in conventional Li-ion batteries - overview
• Solid-state battery - a way to avoid a separator
• Solid-state battery - main advantages and drawbacks
• Applications and market forecast for solid-state batteries 73
• Applications
• Early adopters of solid-state batteries
• Solid-state battery attributes vs. application requirements
• Solid-state battery value gap analysis for each application
• Battery capacity per application
• EV/HEV - drivers for vehicle electrification
• EV/HEV - CO2 reduction regulations as the main driver
• EV/HEV - different electrification levels and their associated CO2 reduction
• EV/HEV - battery requirements
• EV/HEV – battery products + major suppliers and customers
• How EV/HEV drives technology innovations
• EV/HEV - added-value differentiation needed!
• EV/HEV -added-value differentiation via a new battery technology
• Space applications - main market drivers
• Space applications - battery usage and applications
• Space applications - battery specifications and requirements
• Space applications - battery products and main suppliers
TABLE OF CONTENTS (1/6)

4
• Aerospace applications - main drivers
• Aerospace - why more electric airplanes?
• Aerospace applications - battery specifications and requirements
• Aerospace applications - battery products + major suppliers and customers
• Consumer electronics
• Consumer electronics - battery requirements
• Market forecast
• Yole’s solid-state battery application roadmap
• 2018 - 2025 solid-state battery forecast
• Solid-state battery demand in 2025, split per application
• Yole’s “aggressive” forecast scenario - hypothesis
• How to make solid-state battery market-ready?
• Why is solid-state battery development accelerating?
• Commercialization approaches for solid-state battery in the EV/HEV
market
o Main solid-state battery challenges 114
• Remaining solid-state battery challenges
• Solid-state battery technology challenges - overview
• Solid-state electrolyte challenges
• Li-ion battery as a strong competitor
• Absence of a “killer application”
• Too many technology options
• Time-to-market factors for new technologies
• Lengthy, multiple-stage development process
• Lengthy development process - case studies
• Lengthy, costly automotive qualification
• Optimization on battery pack level is required
• Untapped potential for current Li-ion batteries’ safety enhancement
• Safety improvement must beeconomically compelling
• Better safety is not enough
• A single-supplier issue
• Solid-state battery electrolyte materials 131
• Solid-state electrolyte
• Solid-state battery - electrolyte types
• Comparing ionic conductivity of different electrolytes
• Criteria for solid-state electrolyte selection
• Comparative table of different solid-state electrolyte categories
• Inorganic crystalline solid-state electrolytes
• Sulfide-based solid-state electrolytes
• Polymer electrolyte
• Electrode/electrolyte interface
• Solid-state electrolyte - material enhancement
• Manufacturing techniques 142
• Battery manufacturing process flow - conventional Li-ion battery cells
• Battery manufacturing process flow - conventional Li-ion battery packs
• Is the manufacturing method for SSB different from that of conventional LIBs?
• What is an ideal approach for solid-state battery manufacturing?
• Solid-state battery manufacturing approach - being different can be advantageous
• Solid-state battery - bulk battery vs. microbattery
• Solid-state battery manufacturing approaches
• Solid-state battery manufacturing approaches - Hitachi Zosen
• Solid-state battery manufacturing approaches - Blue Solutions
• Solid-state battery manufacturing approaches - Solid Power
• Solid-state battery - development 155
• Solid-state battery - research synergies with other R&D topics
• Fuel cells vs. solid-state battery
• Toyota EV/HEV battery development roadmap - solid-state battery

5
• Solid-state battery research at Toyota
• TITECH & Toyota’s solid-state battery focus
• BMW - battery material development and cell roadmap
• Conventional li-ion cell technology roadmap - CATL
o Solid-state battery - supply chain, partnerships, and business approaches 163
• Main R&D players - geographic overview
• Main industrial players - geographic overview
• Solid-state battery companies - split by player type
• Solid-state battery companies - split by geographic region
• Solid-state battery companies - split by business type
• Solid-state battery - ranking of main patent assignees
• Solid-state battery IP dynamics - graph of patent assignees per year
• Solid-state battery - supply chain dynamics
• Solid-state battery - recent investments
• Solid-state battery -mergers & acquisitions, exits
• Strongly growing battery demand - impact on the solid-state battery supply chain
• Why are players from across the battery supply chain interested in solid-state battery?
• Li-ion cell manufacturers and solid-state battery
• Will automotiveTier1s appear as big SSB players?
• Solid-state battery business case analysis - Bosch
• Solid-state battery business case analysis – Bolloré Group
• Bolloré Group - LMP battery comparison with Li-ion battery
• Solid-state battery companies - split by player type
• Solid-state battery companies - split by geographic region
• Solid-state battery companies - split by business type
• Solid-state battery - ranking of main patent assignees
• Solid-state battery IP dynamics - graph of patent assignees per year
• Solid-state battery - supply chain dynamics
• Solid-state battery - recent investments
• Solid-state battery -mergers & acquisitions, exits
• Strongly growing battery demand - impact on the solid-state battery supply chain
• Why are players from across the battery supply chain interested in solid-state battery?
• Li-ion cell manufacturers and solid-state battery
• Will automotiveTier1s appear as big SSB players?
• Solid-state battery business case analysis - Bosch
• Solid-state battery business case analysis – Bolloré Group
• Bolloré Group - LMP battery comparison with Li-ion battery
• Toyota SSB development and electric vehicle strategy
• Partnerships
• Combining efforts
• Vertical integration in the solid-state battery business
• Solid-state battery - industrial partnerships and alliances
• Next-generation battery R&D partnership, led by University of Oxford
• European industry alliance to develop next-generation battery technology
• Lithium Ion Battery Technology and Evaluation Center (Libtec)
• Libtec members
• Conclusion 192
• Appendix - company profiles (20 companies and R&D institutions) 194

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A123 Systems,Asahi Kasei,Blue Solutions,BMW,Bolloré,Bosch,BrightVolt,CATL,CEA,China Dynamics,Continental,Delf University of
Technology,DongshiKingpower ScienceandTechnologyLtd,Forge Nano,Fraunhofer ISC,GSYuasa,Hitachi Zosen,Hydro Québec,Idemitsu
Kosan,Ilika,IMEC,Ionic Materials,JohnsonBatteryTechnologies,JapanAerospace ExplorationAgency (JAXA),Kalptree,Kuraray,LGChem,
Manz,NEI Corporation,Nissan,Panasonic,Pathion,PSA Peugot Citroën,Quantumscape,Renault,Saft,Samsung SDI, Sakti3,Siemens,
Solid Energy,Solid Power,Solvay,Tokyo Institute ofTechnology, Toray,Toshiba,Toyota,Umicore,University of Bath,University of Münster,
University of Oxford,Volkswagen,and more.
LIST OF COMPANIES MENTIONED IN THIS REPORT

7
SOLID-STATE BATTERY IN A NUTSHELL
The definition
of solid-state
battery in this
report.
Solid-state battery
• Solid electrolyte
• Solid electrodes (the same as for
conventional Li-ion batteries or
advanced-ones)
Conventional Li-ion batteries
• Liquid/polymer electrolyte
• Solid electrodes
The focus of this report is on Li-ion
chemistries ,but other solid-state battery
chemistries are also under development by
some R&D players
“Solid-state” characterizes the parts of battery cell
“Bulk” battery “Microbattery”
• Capacity per cell:> 1Ah/cell • Capacity per cell:typically less than 1mAh
• Production method not compatible with
large capacity cell
“Room” temperature
operation
Solid-state batteries which have to be heated to temperature >50°C
are not considered in this report as “true” solid-state batteries
Li-ion solid-
state battery
SSB
+ -

8
TWO WAYS OF BATTERY CELL DEVELOPMENTTO MEET MARKET EXPECTATIONS
Progressive and revolutionary battery cell development approaches
Yole Développement
 Higher performance (Wh/kg,
W/kg…)
 Higher safety
 Lower cost
 Less dependence on scarce /
expensive materials
…slow but steady progress
…Talkin’‘bouta Revolution
Solid-state
battery

9
SOLID-STATE BATTERY AS A NEXT-GENERATION OF LI-ION BATTERIES
• Today, Li-ion technologies are driving
battery applications.
• Li-ion battery is rather mature technology
but still with potential for further
performance improvement and cost
reduction.
• However, the further improvement is
increasingly challenging without
compromising safety or increasing
manufacturing costs.
• So, next generation battery technologies
are sought, especially by EV/HEV players
which need high technology differentiation
on battery level.
• Solid-state battery is the technology
approach, which has potential for greater
safety, higher energy density and cost
reduction.
Conventional
Li-ion
Introduction
Solid-state
batteryPerformance/cost
Safety
Solid-state battery is expected to reach higher energy density than
conventional Li-ion cell, with additional added value for greater safety

10
HOW CAN ADVANCED BATTERIES COMPETE WITH LITHIUM-IONTECHNOLOGIES?
There are
differentplayers
to rise the
interest of
investors,cell
manufacturers
and customers in
new advanced
battery
technologies,
such as solid-
state batteries.
How can advanced batteries compete with lithium-ion technologies?
Higher energy
density
Lower cost Higher safety
Lower
dependence on
scarce material
Lower
environmental
impact
Others
• Wh/kg
• Wh/L
• Use of cheaper
materials and
processes
• xxxxxx
• Lower cost
($/Wh) due to
higher energy
density
• Tolerance to
overcharging
• Tolerance to
deep
discharge
• xxxxx
• Wide
temperature
operational
range
• Substitution for
lithium,cobalt…
• Less geopolitical
dependence
• xxxxxx
• No toxic
materials
• No dangerous
chemicals
• No heavy
metals
• Environmentally
-friendly
production
• Materials easy
to
dispose/recycle
• Cycle life
• xxxxxx
• Deep discharge
capability
• Fast charge /
discharge
capability
Technology maturity
Solid-state battery main focus

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SOLID-STATE BATTERY ADVANTAGES
General
features are
presented
here.
The real
picture differs
for different
solid-state
battery
approaches.
Simple structure
Non-flammable solid electrolyte
• Solid electrolytes light play a role as a separator
preventing contact of the anode and cathode
Higher energy density
Safety
• Can be used at higher operating temperature
• Electrolyte is flame-retardant
• No liquid electrolyte leak risk
• Possibility of cell stacking in one package
• Less or simpler safety measures needed on the pack
level
High voltage
• The decomposition voltage of solid electrolytes is
high
Larger operating
temperature range
No cost for separator
Simpler cell structure and simpler
manufacturing process*
Lower costs
*mass production method not yet established

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SOUGHT FEATURES OF SOLID-STATE BATTERY
The main
featuresneeded
are high ionic
conductivity,
good interface
contact,
mechanical
stability,low cost
and mass-
production
compatible
process.
High ionic conductivity
“Must have” “Nice to have”
Large-area and stable contact
 xMechanical stability by charging/discharging
Low cost Process compatible with mass production
Compatible with existing battery
manufacturing equipment and
processes for Li-ion cells
No need for application of
mechanical pressure
No risk of toxic H2S formation
2D3D

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SOLID-STATE BATTERY ATTRIBUTESVS.APPLICATION REQUIREMENTS
Consumer EV/HEV Aerospace Space
Wh/kg 3 4 4 x
Wh/L x 5 x x
Temperature range x 3 4 x
Calendar lifetime 1 x x 5
Cycle life 1 4 3 x
Safety 2 x x x
Demand (MWh/y) 1 x 1 1
Overall attractiveness x x x x
Qualification requirements Weak High Very high
Very high: must withstand
very high levels of shock and
random vibration
1 – Not very important or differentiating
2 – Important
3 – Very important
4 – Critical
5 – Strong differentiator Negative Average Positive

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SPACE APPLICATIONS – BATTERY PRODUCTS AND MAIN SUPPLIERS
Major battery suppliers for
space applications:
28V Space Grade Battery System
SAFT
GEN II LSE lithium ion prismatic cells
for space applications
GS Yuasa Lithium Power
ABSL space batteries
Enersys
Battery pack for space applications
Mitsubishi Electric
Major customers for space
batteries:
Hitachi Zosen works with
JAXA on solid-state battery
applications for space
applications

15
SOLID-STATE BATTERY COMMERCIALIZATION
Why is solid-state battery development accelerating?
Common efforts
of players from
different
technology areas
The increasing number of R&D partnerships and large consortiums brings a strong additional momentum to the development of solid-state batteries.
Yole Développement
Strong additional momentum?
Situation in the past Today’s situation
or
Big partnerships
A single player
Few acquisitions

16
COMMERCIALIZATIONAPPROACHES FOR SOLID-STATE BATTERYATTHE EV/HEV MARKET
As an optional battery for an EV/HEV
If commercially
launched as a
optional battery
for a car model,
SSB can benefit
from several
advantages.
• Advantages of
launching SSB as an
optional battery:
• Xxxxx
• Xxxxx
• xxxxx
Li-ion proposed in option for
Toyota Prius Plug-in
Larger Li-ion battery
proposed in option for
“premium” Hyundai Kyona
Electric cars
SSB proposed in option
Proposing different battery (different battery type/size) for a “premium” car model has been already
used in the past. A similar approach might be used for commercial introduction of solid-state batteries.
Yole Développement
39.2kWh
64 kWh
StandardPremium

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SSB battery pack
production ramp-up
Pack testing and EV/HEV qualification
TECHNOLOGY AND MARKET CHALLENGES
Lengthy,multiple-stage development process
To bring
solid-state
battery to
the market is
not just
about
developing of
a suitable
solid-state
electrolyte
Electrolyte
Electrolyte
/ electrode
interfaces
Cell
design
Battery pack
design and
components
Mass
production
process
Cell testing
xxxxx
xxxxxxx
xxxxx
Cell and pack manufacturing equipment development
xxxxxxx
There are multiple R&D steps to be done before bringing SSB to commercial products. Those steps mustn’t be over skipped nor underestimated
Yole Développement
Securing material supply and sales

18
TECHNOLOGY AND MARKET CHALLENGES
Lengthy,development process – case studies
Despite years
of development,
many players
have not
succeeded to
bring solid-state
battery to the
market.
Examples of how long can be solid-state battery development
Yole Développement
• 2006 – acceleration of solid-state battery electrolyte development aiming applications in EV/HEV
• 2010 – announced to developing solid-state electrolyte with xxxxxxxx.The company showed xxxxxxxxxxxx.
• The company announced plans for xxxxxxxxxxx
• 2018 – xxxxxxxxxxxx
Xxxxxxx
Xxxxxx
xxxxxx
• 2014 -Toyota announced in 2014 its solid-state battery development efforts.
• Toyota planned the commercialization of solid-state batteries by early 2020.
• xxx
• 2018 – xxx
• 2014 - Sakti3 announced a solid state electrolyte lithium-ion battery
• 2015 - Dyson made the acquisition of Sakti3 for $90M
• 2017 – Dyson revealeda £2.5bn investment plan to produce an electric vehicle by 2020
• 2018 – Dyson plans xxxxxxx

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SOLID-STATE BATTERY ELECTROLYTETYPES
Solid-state
electrolyte is the
key component
of a solid-state
battery.
There are three
main types of
solid-state
electrolyte
materials
Solid-state electrolytes
Inorganic
Inorganic
crystalline
materials
xx
xx
Inorganic
amorphous
materials
xxx
xx
Solid polymers
Poly (ethylene)
oxide (PEO)
xxx
xxx
Inorganic / polymer
(composite)
Main types of solid-state electrolytes (non-exhaustive list).
Inorganic and polymer materials can be combined to use advantages of both types of materials.
Yole Développement
Considered as the
most promising
material (“take best of
two worlds”)

20
SULFIDE-BASED SOLID-STATE ELECTROLYTES
Some sulfide-
based
electrolytes
have ionic
conductivity
even higher
than liquid
electrolytes
• At room temperature the ionic electrolytes is typically
several orders of magnitude lower than that of liquid
electrolyte. This is one of the main hurdles for the
commercialization of solid-state batteries.
• xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx
• Xxxxx  minimizing issues with dendrite formation
along the grain boundaries in polycrystalline materials
• The conductivities of some sulfide materials are
comparable or even higher than that of liquid
electrolyte.
• xxxxxxxx
• The drawback of sulfide-based electrolytes is that they
can release toxic hydrogen sulfide when exposed to
moisture.
• Lithium metal electrode is one of the enablers of high
energy-density cells. However, sulfide-based electrolyte is
highly reactive with lithium metal and decomposition of
the solid electrolyte at the interfaces occurs. The
solution researched is to have
xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx.
Li7P3S11 and Li6PS5X (X = Cl, Br,I)
Li10GeP2S12 (LGPS)
• High ionic
conductivity
• Relatively
flexible
Li10SnP2S12 (LSPS)
High ionic conductivity at RT, but
germanium is costly
Li9.54Si1.74P1.44S11.7Cl0.3

21
SOLID-STATE-BATTERY MANUFACTURING APPROACHES
Hitachi Zosen (JP)
All solid-state
battery made by
a lamination
(machine
stamping or
press forming)
process resulting
in lower
electrolyte
resistanceand
no need for
application of
pressure on the
cell.
• Benefits of Hitachi Zosen
press technology approach:
• Battery can be
charged/discharged
without applying
mechanicalpressure
• Actually, the conventional
all-solid Li-ion
rechargeable batteries
need to be
charged/discharged while
being mechanically
pressured to keep the
ionic conductivity among
material particles of the
solid electrolyte.
Cross-section images of pellet-type and thin-layer solid-
state batteries
Hitachi Zosen
Prototype of a solid-state
Li-ion battery cell
Hitachi Zosen
Comparison of manufacturing of conventional Li-ion cells and Hitachi Zosen’s
approach for solid-state battery
Hitachi Zosen

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SOLID-STATE BATTERY PLAYERS
Split by business type
The main
interest in
SSB is on the
side of
material
development
and supply
and EV/HEV
makers.
Solid-state battery companies - split by business. Major players are shown (non-exhaustive list). R&D players are not shown here.
Yole Développement
xxxxxxxxxxxxxxxxxxxxx
xxxxxxx
xxxxxxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxxxxxxxxxxxx
xx
xx
xx
xxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxx
xxxxxx

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NEI CORPORATION (USA)
NEI Corporation
NEI Corporationdevelops,manufactures,and distributesnanoscale materials
xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx
Founded 1997 HQ Somerset, NJ,USA Website www.neicorporation.com
Company type Privately held Employees 50
Cell chemistry
Li-ion
Solid-state
battery
Cell format
Coin cell
Pouch cell
Product(s)
xxxxxxxxxxxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxx
Applications
and key
customers
• NEI offers a variety of cathode, anode, and electrolyte materials for use in lithium-ion and sodium-ion
batteries for various applications.
Highlights
• NEI offers also electrochemical testing services, including lithium-ioncoin cell and pouch cell fabrication (prototyping)
and testing.
• NEI offers its patent-pending, solid electrolyte material – lithium tin phosphorous sulfide (Li10SnP2S12)– along with
various custom produced oxide and non-oxide solid electrolyte material compositions (e.g., sulfide-based), as well as a
polymer-ceramic composite electrolyte and a PEO-based polymer solid electrolyte.

24
RELATED REPORTS

Conventional Li-ion battery technologies, based
on flammable liquid electrolytes, are continuously
improving. However, faster progress towards
greater safety, higher performance, and better
cost reduction is desired. A next-generation
battery technology like solid-state battery, which
uses solid electrodes and solid electrolytes, could
potentially satisfy these objectives.
The main drivers for solid-state battery
development are safety (especially in space,
aerospace, and automotive applications, as well
as some consumer applications), added-value
differentiation (especially for EV/HEV), and the
increasing difficulties faced by conventional Li-
ion cell technology in further increasing battery
energy density without compromising safety.
Solid-state battery’s commercialization and
market growth will depend on its added-value
differentiation gap compared to conventional Li-
ion batteries, which differs for each application
analyzed in this report: EV/HEV, space, aerospace,
and consumer electronics.
SOLID-STATE BATTERY
Market & Technology report - June 2018
SOLID-STATE BATTERY - DRIVERS AND APPLICATIONS
A feasible way towards safer, better-performing batteries?
KEY FEATURES
• 2018 - 2025 market forecast in
MWh for solid-state lithium-ion
batteries, along with applications
roadmap
• Overview of solid-state battery’s
main applications, Li-ion battery’s
current positioning, and solid-state
battery’s value proposition
• Analysis of solid-state battery’s
main advantages, as well as the
remaining key challenges for solid-
state battery commercialization
• Proposal of different approaches
for solid-state battery’s’
commercial introduction
• Solid-state battery supply chain
analysis
(Yole Développement, June 2018)
-
Now
(2018)
Soon
RD
EV/HEV
Aerospace
Space
Consumer
electronics
Space
EV/HEV
Commercialization start
Mid-term Long-term
Pre-commercialization
WHY IS SOLID-STATE BATTERY DEVELOPMENT ACCELERATING?
Solid-state battery is not a new technology - in
fact, the first research activities date to the
late 1950s. Solid-state battery technology has
found applications in the form of microbatteries
as a micro-power source for sensors, etc. (not
analyzed in this report). Unfortunately, the
materials and manufacturing methods used for
microbattery’s fabrication are extremely difficult
to translate into bulk-size battery manufacture on
a cost-effective basis.
Today, there is no commercially-available bulk
solid-state battery (not including the polymer-
based solid-state batteries from Bolloré Group,
which must be heated to 60 - 80°C). Over the
last several years, numerous different players have
made announcements regarding the readiness of
prototype cells and expected commercialization
starts, only to see these ultimately be cancelled or
postponed. And despite decades of development,
many technology challenges remain unsolved, as
shown in this report. So why do we see such a
strong, growing interest in solid-state battery
development and commercialization? What are
the key drivers here?
According to Yole Développement’s analysis,
the main cause of this momentum is the strong
application-pull of game-changing battery
industry players: the EV/HEV makers. Established
automotive players (Toyota, Volkswagen BMW,
etc.) and newcomers (i.e. Dyson, Fisker) plan to
commercialize EV/HEV with a battery that will be
safer, lighter, and longer-running than conventional
Li-ion battery. A growing number of players involved
in solid-state battery development is another reason
for increased momentum, as are a variety of newly-
established solid-state battery consortiums.
Numerous industry players (23 companies in
the Japanese Libtec consortium alone!) and RD
players from different areas are combining their
efforts, each bringing a piece of technology know-
how. Indeed, sharing know-how from four main
technology areas is crucial for bringing solid-state
battery to commercialization. Also, large coverage
Solid-state battery applications roadmap

SOLID-STATE BATTERY
WHO MAKESWHAT IN SOLID-STATE BATTERY TECHNOLOGY DEVELOPMENT?
Regarding solid-state battery technology development,
there are many technology bricks involved, including
electrolyte material screening, ionic conductivity
enhancement, electrolyte/electrode interface stability,
lithium metal anode, separator coating, cell and pack
manufacturing methods, battery management system
(BMS), and battery pack design.
According to Yole Développement’s analysis, there are
more than 100 companies and RD players involved
in solid-state battery development. For an emerging
technology, it might be surprising to see that only
14 of 68 industrial companies identified are start-
up companies (Ionic Materials, NEI Corporation,
QuantumScape, etc.). These start-ups are positioned
mainly in electrolyte material screening and
development. RD activities are rapidly developing
within big companies, 54 of which have been identified
by Yole Développement. The main big companies
are car makers: Toyota, BMW, Volkswagen, Renault-
Nissan-Mitsubishi Alliance, and Hyundai. Toyota, with
a strong solid-state development history and 200+
engineers working on solid-state battery technology,
is considered a leader here.
Strong participation from EV/HEV makers is extremely
important for solid-state battery commercialization.
Besides huge market potential, they bring to solid-
state battery development know-how regarding EV/
HEV battery requirements, battery pack assembly,
testing, and qualification. And in fact, the simplification
of battery pack design and its components will improve
solid-state battery’s cost-competitiveness compared
to conventional Li-ion batteries.
Other players include conventional Li-ion battery
cell manufacturers (i.e. Samsung SDI, LG Chem,
of multiple topics by different players is important for
solid-state battery, enabling accelerated evaluation of
different technology approaches and concentration
on the most promising ones.
Four different player types - joined forces and shared knowledge to
overcome the challenges of solid-state battery commercialization
3-
RD
1.Technology
provider
2. Equipment
supplier
3. Cell
manufacturer
4.Automotive
OEM
• Cell design
• High-volume
manufacturing
• Process control
• High yield
• SSB IP freedom to
operate
• Pack design and
manufacturing
• Pack components choice
• Direct customer for SSB
operate
• Equipment adapted
for SSB
• Manufacturing line
integration
• SSB IP freedom
to operate
• Electrolyte material
choice
operate
SSB
IP: Intellectual property
Solid-state battery players* - split by type
Start-up:
14
RD:
40
108
Big company:
54
*Non-exhaustive list (including RD players)

MARKET TECHNOLOGY REPORT
COMPANIES CITED IN THE REPORT (non exhaustive list)
A123 Systems, Asahi Kasei, Blue Solutions, BMW, Bolloré, Bosch, BrightVolt, CATL, CEA, China
Dynamics, Continental, Delf University of Technology, Dongshi Kingpower Science and Technology
Ltd, Forge Nano, Fraunhofer ISC, GS Yuasa, Hitachi Zosen, Hydro Québec, Idemitsu Kosan, Ilika,
IMEC, Ionic Materials, Johnson Battery Technologies, Japan Aerospace Exploration Agency (JAXA),
Kalptree, Kuraray, LG Chem, Manz, NEI Corporation, Nissan, Panasonic, Pathion, PSA Peugot Citroën,
Quantumscape, Renault, Saft, Samsung SDI, Sakti3, Siemens, Solid Energy, Solid Power, Solvay, Tokyo
Institute of Technology, Toray, Toshiba, Toyota, Umicore, University of Bath, University of Münster,
University of Oxford, Volkswagen, and more.

Report objectives 6
Companies cited in this report 7
List of abbreviations 8
Executive summary 9
Noteworthy news 35
Introduction 38
Three main axes of innovation in batteries
Two ways for battery cell development to meet
market expectations
Solid-state battery 42
Solid-state battery, in a nutshell
Solid-state microbattery vs. bulk solid-state
battery
Why solid-state battery? 48
Solid-state battery as a the next-generation of
Li-ion batteries
Solid-state battery - main drivers
What does solid-state battery compete
with? - conventional Li-ion battery 51
Li-ion technologies and applications
Different LI-ion battery cells - comparative table
Comparative graph of energy density for
different Li-ion battery cells
Where are Li-ion battery’s limitations/weak
points?
Safety issues related to Li-ion batteries -
thermal runaway
How can advanced batteries compete with
lithium-ion technologies?
Solid-state battery - main advantages and
drawbacks
Applications and market forecast
for solid-state batteries 73
Applications
- Early adopters of solid-state batteries
- Solid-state battery attributes vs. application
requirements
EV/HEV
Space applications
Aerospace applications - main drivers
Consumer electronics
Yole’s solid-state battery application roadmap
2018 - 2025 solid-state battery forecast
Solid-state battery demand in 2025, split per
application
Yole’s forecast - hypothesis
How to make solid-state battery market-ready?
Why is solid-state battery development
accelerating?
Commercialization approaches for solid-state
battery in the EV/HEV market
Main solid-state battery challenges 114
Solid-state battery electrolyte materials 131
Manufacturing techniques 142
Solid-state battery - development 155
Solid-state battery - supply chain,
partnerships, and business approaches 163
Main RD players
Main industrial players
Solid-state battery - ranking of main patent
assignees
Solid-state battery IP dynamics - graph of patent
assignees per year
Solid-state battery - supply chain dynamics
Solid-state battery - recent investments
Solid-state battery - mergers acquisitions, exits
Why are players from across the battery supply
chain interested in solid-state battery?
Partnerships
Conclusion 192
Appendix - company profiles (20 companies
and RD institutions) 194
TABLE OF CONTENTS (complete content on i-Micronews.com)
OBJECTIVES OF THE REPORT
• Offer deep insight into the key drivers and value proposition of solid-state battery technologies,
compared to conventional Li-ion batteries
• Provide an analysis of the remaining challenges to bringing solid-state battery to commercialization
• Present the main applications and different approaches for solid-state battery commercialization
• Furnish a market forecast for solid-state battery
• Deliver an overview of different solid-state electrolyte materials and manufacturing methods for
solid-state battery cells
• Identify the solid-state battery supply chain’s main trends. Provide a detailed analysis of the supply
chain, including main RD and industrial players, partnerships, and business approaches.
AUTHOR
Dr. Milan Rosina is Senior Analyst,
Power Electronics Batteries, within
the Power Wireless division at Yole
Développement (Yole).
Milan has 20 years of scientific, industrial,
and managerial experience involving
equipment and process development, due
diligence, technology, and market surveys
in the fields of renewable energies, EV/
HEV, energy storage, batteries, power
electronics, thermal management, and
innovative materials and devices.
Milan received his PhD from National
Polytechnical Institute (Grenoble, France).
Prior to joining Yole, Dr. Rosina worked
for the Institute of Electrical Engineering
in Slovakia; Centrotherm in Germany;
Fraunhofer IWS in Germany; CEA LETI
in France; and utility company ENGIE in
France.
Find more
details about
this report here:
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A123 Systems), battery separator technology
solutions suppliers (Asahi Kasei), and materials
suppliers (Solvay, Umicore, etc.). According to
Yole Développement’s market forecast, mass
production of solid-state batteries will begin by
2022 and represent less than 1% of Li-ion battery
demand by 2025. This might explain the relative
low interest from equipment suppliers, which might
change later on when the building of large solid-
state battery manufacturing capacities commences.

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2©2018 | www.yole.fr | About Yole Développement
YOLE DEVELOPPEMENT – 4 DIVISIONS
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Healthcare
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o Compound Semiconductors Emerging Materials
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o Batteries Energy Management
Semiconductor
Software
o Package Assembly Substrates
o SemiconductorManufacturing
o Memory
o Software Computing
Photonics,
Sensing Display
o Solid-State Lighting Display
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o Imaging
o Photonics Optoelectronics
Semiconductor
Software
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Photonics,
Sensing
Display
Life
Sciences
Healthcare

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Cost simulation tools
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www.knowmade.fr
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www.piseo.fr
Yole Group of Companies

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electronics
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Medical
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Energy
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o Yole Développement, System Plus Consulting, KnowMade and PISEO, all part of Yole Group of Companies, keep on increasing their collaboration to offer, in 2018, a
collection of 150+ reports. Combining respective expertise and methodologies from the 4 companies, the reports aim to provide market technology analysis, patent
investigation and patent infringement risk analysis, teardowns reverse costing analysis.They cover:
o You are looking for:
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The combined team of 60+ experts (PhDs, MBAs, industry veterans…) from Yole Développement, System Plus Consulting, KnowMade and PISEO, collect information,
identify the trends, the challenges, the emerging markets, the competitive environments and turn it into results to give you a complete picture of your industry
landscape.
In the past 20 years, we worked on more than 1 700 projects, interacting with technology professionals and high level opinion makers from the main players of the
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REPORTS COLLECTION
www.i-Micronews.com
• MEMS Sensors
• RF devices technologies
• Imaging
• Medical technologies (MedTech)
• Photonics
• Advanced packaging
• Manufacturing
• Advanced substrates
• Power electronics
• Batteries and energy management
• Compound semiconductors
• Solid state lighting
• Displays
• Software
• Memory

OUR 2018 REPORTS COLLECTION (1/4)
MEMS SENSORS
o MARKET AND TECHNOLOGY REPORT – by Yole Développement
− Status of the MEMS Industry 2018 – Update
− Silicon Photonics 2018 – Update
− Consumer Biometrics: Hardware Software 2018 – Update
− Inkjet Functional and Additive Manufacturing for Electronics 2018
− Fingerprint Sensor Applications and Technologies – Consumer Market Focus 2017
− Sensors and Sensing Modules for Smart Homes and Buildings 2017
− Acoustic MEMS and Audio Solutions 2017
− MEMS Sensors for Automotive Market Technology Trends 2017
− High End Inertial Sensors 2017
− Magnetic Sensor 2017
o REVERSE COSTING® – STRUCTURE, PROCESS COST REPORT
– by System Plus Consulting
− Piezo MEMS 2018 *
o PATENT ANALYSES – by KnowMade
− MEMS Microphone – Patent Landscape Analysis
− Knowles MEMS Microphones in Apple iPhone 7 Plus – Patent-to-Product
Mapping 2017
o LINKED REPORTS – by Yole Développement, System Plus Consulting and KnowMade
− MEMS Pressure Sensor 2018 – Market Technology Report
− MEMS Pressure Sensor Comparison 2018 – Structure, Process Cost Report
− Gas Particles 2018 – Market Technology Report
− Gas Particles Comparison 2018 – Structure, Process Cost Report
− LiDARs for Automotive and Industrial Applications 2018 – Market
Technology Report
− LiDAR for Automotive 2018 – Patent Landscape Analysis
− MEMS Packaging 2017 – Market Technology Report
− MEMS Packaging Comparison 2017 – Structure, Process Cost Report
RF DEVICES ANDTECHNOLOGIES
− Wireless technologies (Radar, V2X) for Automotive 2018
− RF Standards and Technologies for Connected Objects 2018
− RF Photonic Components Technologies for 5G Infrastructure2018
o REVERSE COSTING® – STRUCTURE, PROCESS COST REPORT– by System
Plus Consulting
− Automotive Radar Comparison 2018
− RF Acoustic Wave Filters 2017 – Patent Landscape Analysis
o LINKED REPORTS – by Yole Développement, System Plus Consulting andKnowMade
− 5G impact on RF Front End Modules and Connectivity for Cellphones 2018 – Market
Technology Report – Update
− RF Front-End Module Comparison 2018 – Structure, Process Cost Report
− RF Front End Modules for Cellphones 2018 – Patent Landscape Analysis
− Advanced RF System-in-Package for Cellphones 2018 – Market Technology
Report – Update*
− Advanced RF SiPs for Cell Phones Comparison 2017 – Structure, Process
Cost Report
− RF GaN Market: Applications, Players, Technology, and Substrates 2018-2023
Market Technology Report – Update
− RF GaN Comparison 2018* – Structure, Process Cost Report
− RF GaN 2018 – Patent Landscape Analysis
SOFTWARE
− Consumer Biometrics: Sensors Software 2018 – Update
− Processing Hardware and Software for AI 2018 - Vol. 1 2
− From Image Processing to Deep Learning, Introduction to Hardware and Software
Update : 2017 version still available / *To be confirmed

IMAGING OPTOELECTRONICS
− Status of the Compact Camera Module and Wafer Level Optics
− Industry 2018 – Update
− 3D Imaging and Sensing 2018 – Update
− Sensors for Robotic Vehicles 2018
− Machine Vision for Industry and Automation 2018
− Imagers and Detectors for Security and Smart Buildings 2018
− Uncooled Infrared Imagers 2017
− iPhone X Dot Projector – Patent-to-Product Mapping
− Status of the CMOS Image Sensor Industry 2018 – Market Technology Report -
Update
− CMOS Image Sensor Comparison 2018 – Structure, Process Cost Report
− CMOS Image Sensors Monitor 2018* – Quaterly Update**
− Camera Module 2017 – Market Technology Report
− Compact Camera Module Comparison 2018 – Structure, Process Cost Report
− LiDARs for Automotive and Industrial Applications 2018 – Market Technology
Report
− LiDAR for Automotive 2018 – Patent Landscape Analysis
ADVANCED PACKAGING
− Status of Advanced Packaging Industry 2018 – Update
− Status of Advanced Substrates 2018: Embedded Die andInterconnects,
Substrate Like PCB Trends
− 3D TSV and Monolithic Business Update 2018 – Update
− Power Modules Packaging 2018 – Update
− Discrete Power Packaging 2018 – Update*
− Status of Panel Level Packaging 2018
− Trends in Automotive Packaging 2018
− Hardware and Software for AI 2018 - Vol. 1 2
− Integrated Passive Devices (IPD) 2018
− Thin-Film Integrated Passive Devices 2018
− Memory Packaging Market and Technology Report 2018 – Update*
− Hybrid Bonding for 3D Stack – Patent Landscape Analysis
o LINKED REPORTS– by Yole Développement and System Plus Consulting
− Advanced RF System-in-Package for Cellphones 2018 – Market Technology Report -
Update*
− Advanced RF SiPs for Cell Phones Comparison 2017 – Structure, Process
Cost Report
− Fan-Out Packaging 2018 – Market Technology Report – Update*
− Fan-Out Packaging Comparison 2018* – Structure, Process Cost Report
MANUFACTURING
− Wafer Starts for More Than Moore Applications 2018
− Equipment for More than Moore: Technology Market Trends
for Lithography Bonding/Debonding 2018
− Polymeric Materials for wafer-level Advanced Packaging 2018
− Laser Technologies for Semiconductor Manufacturing 2017
− Glass Substrate Manufacturing in the Semiconductor Field 2017
− Equipment and Materials for Fan-Out Packaging 2017
− Equipment and Materials for 3D TSV Applications 2017
o LINKED REPORTS – by Yole Développement and System Plus Consulting
− Equipment for More than Moore: Technology Market Trends for
Lithography Bonding/Debonding 2018 – Market Technology Report
− Wafer Bonding Comparison2018 – Structure, Process Cost Report

MEMORY
− Emerging Non Volatile Memory 2018 – Update
− Memory Packaging Market and Technology Report 2018 – Update*
o QUARTERLY UPDATE – by Yole Développement**
− Memory Market Monitor 2018 (NAND DRAM)
o MONTHLY UPDATE – by Yole Développement**
− Memory Pricing Monitor 2018 (NAND DRAM)
o REVERSE ENGINEERING COSTING REVIEW – by System Plus Consulting
− DRAM Technology Cost Review 2018
− NAND Memory Technology Cost Review 2018
− 3D Non-Volatile Memories – Patent Landscape
COMPOUND SEMICONDUCTORS
− Status of Compound Semiconductor Industry 2018*
− GaAs Materials, Devices and Applications 2018
− InP Materials, Devices and Applications 2018
− Bulk GaN Substrate Market 2017
− Power SiC 2018: Materials, Devices, and Applications – Market Technology
Report – Update
− SiC Transistor Comparison 2018 – Structure, Process Cost Report
− Power SiC 2018 – Patent Landscape Analysis
− Power GaN 2018: Materials, Devices, and Applications – Market Technology Report
– Update
− GaN-on-Silicon Transistor Comparison 2018 – Structure, Process Cost Report
− Status of the GaN IP – Patent Watch 2018 Patent Activity 2017
− RF GaN Market: Applications, Players, Technology, and Substrates 2018-2023
– Market Technology Report – Update
− RF GaN – Patent Landscape Analysis
POWER ELECTRONICS
− Status of Power Electronics Industry 2018 – Update
− Discrete Power Packaging 2018 – Update*
− Power Electronics for Electric Vehicles 2018 – Update
− Integrated Passive Devices (IPD) 2018
− Wireless Charging Market Expectations and Technology Trends 2018
− Thermal Management Technology and Market Perspectives in Power
− Electronics and LEDs 2017
− Gate Driver 2017
− Power MOSFET 2017
− IGBT 2017
− Market Opportunities for Thermal Management Components in
Smartphones 2017
o LINKED REPORTS – by Yole Développement, System Plus Consulting
and KnowMade
− Power Modules Packaging 2018 – Market Technology Report – Update
− Automotive Power Module Packaging Comparison2018 – Structure,
Process Cost Report
− Power ICs Market Monitor 2018 – Quaterly Update**
− Power ICs Market Comparison 2018* – Structure, Process Cost Report
BATTERY AND ENERGY MANAGEMENT
− Li-ion Battery Packs for Automotive and Stationary Storage Applications 2018 –
Update
− Status of the Battery Patents – Patent Watch 2018 Patent Activity 2017
o LINKED REPORTS – by Yole Développement and KnowMade
− Solid State Electrolyte Battery 2018 – Market Technology Report
− Solid-State Batteries 2018 – Patent Landscape Analysis
Update : 2017 version still available / *To be confirmed / ** Can not be selected within an Annual Subscription offer

SOLID STATE LIGHTING
− IR LEDs and Lasers 2018: Technology, Industry and Market Trends – Update
− Automotive Lighting 2018: Technology, Industry and Market Trends – Update
− UV LEDs 2018: Technology, Industry and Market Trends – Update
− LiFi: Technology, Industry and Market Trends
− LED Lighting Module Technology, Industry and Market Trends 2017
− CSP LED Lighting Modules
− Phosphors Quantum Dots 2017 - LED Downconverters for Lighting Displays
− Horticultural Lighting 2017
o LINKED REPORTS – by Yole Développement and System Plus Consulting
− VCSELs 2018: Technology, Industry and Market Trends – Market Technology
Report
− VCSELs Comparison 2018 – Structure, Process Cost Report
DISPLAYS
− Quantum Dots and Wide Color Gamut Display Technologies 2018 – Update
− Displays and Optical Vision Systems for VR/AR/MR 2018
− MicroLED Displays 2018 – Market Technology Report – Update
− MicroLED Display – Patent Landscape Analysis
MEDTECH
− BioMEMS Non Invasive Emerging Biosensors: Microsystems for Medical
− Applications 2018 – Update
− Point-of-Need Testing Application of Microfluidic Technologies 2018 – Update
− Neurotechnologies and Brain Computer Interface 2018
− CRISPR-Cas9 Technology: From Lab to Industries 2018
− Ultrasound technologies for Medical, Industrial and Consumer 2018
− Inkjet Functional and Additive Manufacturing for Electronics 2018
− Liquid Biopsy: from Isolation to Downstream Applications 2018
− Chinese Microfluidics Industry 2018
− Scientific Cameras for the Life Sciences Analytical Instrumentation
Laboratory Markets 2018*
− Artificial Organ Technology and Market 2017
− Connected Medical Devices Market and Business Models 2017
− Status of the Microfluidics Industry 2017
− Organs-On-Chips 2017
− Solid-State Medical Imaging 2017
− Medical Robotics Market Technology Analysis 2017
− Microfluidic IC Cooling – Patent Landscape
− Circulating Tumor Cell Isolation – Patent Landscape
− OCT Medical Imaging – Patent Landscape
− Pumps for Microfluidic Devices – Patent Landscape 2017
− Microfluidic Technologies for Diagnostic Applications– Patent Landscape 2017
− FLUIDIGM – Patent Portfolio Analysis 2017
− Consumer Physics SCiO Molecular Sensor – Patent-to-Product Mapping 2017
− Organs-On-Chips 2017 – Market Technology Report
− Organ-on-a-Chip– Patent Landscape Analysis

OUR 2017 PUBLISHED REPORTS LIST (3/3)
OUR PARTNERS’ REPORTS
PATENT ANALYSES – by KnowMade
− Wireless Charging Patent LandscapeAnalysis
− RF Acoustic Wave Filters Patent LandscapeAnalysis
− NMC Lithium-Ion Batteries Patent LandscapeAnalysis
− Pumps for Microfluidic Devices Patent Landscape
− III-N PatentWatch
− FLUIDIGM Patent Portfolio Analysis
− Knowles MEMS Microphones in Apple iPhone 7 Plus Patent-to-Product Mapping 2017
− Consumer Physics SCiO Molecular Sensor Patent-to-Product Mapping
− Patent Licensing Companies in the Semiconductor Market - Patent Litigation Risk and Potential Targets
− Microfluidic Technologies for Diagnostic Applications Patent Landscape
TEARDOWN REVERSE COSTING – by System Plus Consulting
More than 60 teardowns and reverse costing analysis and cost simulation tools published in 2017
MORE INFORMATION
o All the published reports from theYole Group of Companies are available on our website www.i-Micronews.com.
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• Japan Rest ofAsia:
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Email: onozawa@yole.fr - +81 34405-9204
• Miho Othake, Account Manager (Japan)
Email: ohtake@yole.fr - +81 3 4405 9204
• Itsuyo Oshiba, Account Manager (Japan)
Email: oshiba@yole.fr - +81-80-3577-3042
• Greater China: MavisWang, Director of Greater China Business
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Email: wang@yole.fr - +886 979 336 809
• Europe: Lizzie Levenez,EMEA Business Development Manager
Email: levenez@yole.fr - +49 15 123 544 182
• RoW: Jean-Christophe Eloy,CEO President,Yole Développement
Email eloy@yole.fr - +33 4 72 83 01 80
o FINANCIAL SERVICES (in partnershipwithWoodside
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• Jean-Christophe Eloy,CEO President
Email: eloy@yole.fr - +33 4 72 83 01 80
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Email: ivan.donaldson@yole.fr - +1 208 850 3914
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