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BUILDING MANUFACTURING PROCESSES
          & PRODUCTS DROP BY DROP
                                                    Dr Alan Hudd
                                           Xennia Technology Ltd
           Presented at the 1st Digital Manufacturing Conference
                                          Florida, USA, June 2011
Section 1
INTRODUCTION TO XENNIA
Background to Xennia

  Xennia is the world’s leading industrial inkjet solutions provider
  15 year history, over 300 customer development programmes
  World class reputation underpinned by a strong IP portfolio
  Unique expertise in inkjet chemistry with strong engineering capability
  Headquartered in UK, sales offices in US and China
  Awarded Queen’s Award for Enterprise in 2010


  Offering reliable inkjet process solutions:
      Inkjet modules and inks for OEM partners with market access
      Printing systems and inks for end users through our distributors
Xennia helps customers lower
   operating costs, increase productivity
 and simplify mass customised production
by revolutionising manufacturing processes
FROM INKJET IDEAS ...
TO PRODUCTION REALITY




Feasibility studies   Process development   System design   Production solutions
Technology push to market pull
    Inkjet technology & market evolution curve: The next wave has started

          Technology      Market       Technology     Market    Technology                Market
          Innovation    Development    Innovation   Development Innovation              Development
Market
 size                                                                                            Ceramics
                                                                                Packaging        Electronics
                                                                                Food             Biomedical
                                                                Photo           Textiles
                                                                Labels
                                                                                      Screen print

                                                                          Cut vinyl

                                                    SOHO

                                        Graphics
                                 CAD                   E-stat

                Date Coding             Pen plotters
                Direct Mail



         1970    1975     1980    1985      1990       1995        2000     2005       2010      2015 2020
Manufacturing processes

 Key examples of inkjet in manufacturing processes & products
 Textiles
    Decoration and digital finishing
 Industrial decoration
    Ceramics, furniture laminates
 Printed electronics
    Solar energy, displays
 Biomedical
    Sensor manufacture
Inkjet for manufacture

 Use inkjet to:
     Coat
     Create manufacturing processes
     Manufacture products
 Inkjet printing difficult materials
     Pigments (including inorganic), phosphors, metals
     Polymers
     Functional materials
 Key inkjet ink technologies
     Pigment and polymer dispersion
     Solvent based and UV cure chemistries
Section 2
DIGITAL FINISHING
Digital finishing

  Major benefits of inkjet digital finishing
      Multi functionality
          Single sided application possible
          Two sides can have different functions
      Patterning – place function where you want it
      Functionality applied efficiently to textile surface only
      Highly consistent coat weight
      Environmental and energy savings


  Not influenced by underlying substrate variations
  Not influenced by bath concentration or dosing variations
Inkjet textile finishing

  Inkjet digital textile finishing process
  System can be
         Standalone; or
         Integrated in existing finishing lines




 Dust cleaning unit




                        Textile Finisher
                                                  UV   IR   Conventional Dryer   Conventional Dryer



                          Printing blanket
Functional materials
 Hydrophobic
     Comfort of cotton material on skin side
     Water and dirt repellent function on outside
 Dirt repellant/self-cleaning
     More efficient coating when applied with inkjet
     Single-sided application important
 Antimicrobial/anti-fungal/anti-insect
     Selective deposition, efficient usage
     Slow release technology
     Materials used cannot be in skin contact
     Single-sided application vital
Functional materials II
  Flame retardant
      Highly coherent coating very important
      Single side coating allows lighter weight
  UV blocking (anti-sunburn)
      Coating needs to be away from skin
  IR blocking
      Insulating fabrics – tents, clothing
  Electrically conductive
      Antennae incorporated into clothing, tents
      Communication with electronic devices
  Solar energy harvesting
      Tents, awnings, etc
      Low cost manufacturing essential
Functional textiles in action
Digital functionality
Textile value chain
 Current textile production technology is labour intensive
 Process automation will reduce labour content in costs
 Variable costs currently high for inkjet
     Inkjet machines will consume tons of ink
     Economy of scale dictates lower ink prices
     No fundamental reason for prices being higher
 Low cost location becomes less important
 Logistics will be the key component to control
Outlook
from

                       Inkjet will
                   revolutionise an
                 outdated industry to
                  deliver production
                      reliability &
                    productivity at
                      lower costs



to
Section 3
SOLAR PANEL MANUFACTURE
Renewable energy

 Concerns about
    Sustainability
    Global warming
    Pollution
 Lead to increasing trend for clean, renewable energy
    Solar photovoltaic
    Solar thermal
    Wind
    Tidal
    Geothermal
 Solar photovoltaic and wind have greatest potential
    Renewable energy proportion still very low (0.8% in 2002)
Solar energy generation

 Huge potential for energy generation
    840 W/m2 reaches Earth’s surface during daylight
    e.g. 1600 TW strikes continental USA
    All electricity needs met with 10% efficient devices covering 2% of area
    (Interstate highways currently cover 1.5% of area)


 Solar energy harvesting
    Thermal – heat from sun heats water
        Used for hot water and swimming pools


    Photovoltaic – energy from sun used to generate electricity
        Can be used for any purpose
Solar photovoltaics
 Types of photovoltaic (PV) (solar cells) available
 Conventional (inorganic)
     1st generation – crystalline Si
     2nd gen – poly-Si, a-Si, CdTe or CIGS
     Input energy creates electron-hole pairs
         Separated by internal field
     Generates photocurrent
 Organic (small molecule or polymer)
     Heterojunction design incorporates:
         Electron transport layer (ETL) and hole transport layer (HTL)
     Input energy creates excitons
         ETL/HTL interface drives dissociation into electrons and holes
     ‘Standard’ materials P3HT and C60 derivatives
OPV schematic




    P3HT bandgap 1.9 eV
    PCBM LUMO-P3HT HOMO separation ~ 1eV
    Carrier mobilities 10-4 cm2/Vs
                                                       Device efficiencies >4%
Christoph Brabec and James Durrant, Solution-
Processed Organic Solar Cells, MRS Bulletin, 33, 670
(2008)
Solar photovoltaics
 Key figures of merit for PV
 Efficiency
     Percentage of incident energy converted into electrical energy
     Includes collection efficiency as well as conversion efficiency
 Cost
     Measured in $ (or €)/Wp
     Current typical cost 2-8$/Wp
     Need to reduce significantly
 Lifetime
     Minimum 3-5 years
     Desirable 20-25 years
Key cost drivers

 Key to reducing cost of PV


    Lower cost materials


    Lower cost manufacturing
        Continuous
        Additive (no waste)
        Flexible
Manufacturing techniques

 Traditional semiconductor techniques
     Thermal/electron beam evaporation
     CVD/MOCVD etc
 Other coating techniques
     Spin coating
     Spray coating
 Printing
     Flexo/gravure printing
     Screen printing
     Inkjet printing
Traditional techniques
 Thermal/electron beam evaporation
    Material is heated and evaporates
    Deposits onto substrate and layer grows
 CVD/MOCVD
    Material made into volatile compound
    Compound decomposes to deposit material
 Spin coating
    Material in solution spun on flat surface
    Uniform coating with evaporation of solvent
 Spray coating
    Solution sprayed on surface
    Solvent evaporates
Technology comparison

Technology        Applicability   Scalability   Productivity   Materials   Film      Process       Multiple
                                                               Wastage     quality   type          layers?
Thermal           Inorganic/      Low           Low (batch)    Moderate    High      Subtractive   Yes but
evaporation       small                                                                            slow
(vacuum)          molecule
CVD (low          Inorganic/      Low           Low (batch)    Moderate    High      Subtractive   Yes but
pressure)         small                                                                            slow
                  molecule
Spin-coating      Polymer/small   Low           Low (batch)    Poor        Medium    Subtractive   Yes but
                  molecule                                                                         slow

Spray-coating     Polymer/small   High          High           Poor        Low       Subtractive   Yes
or doctor         molecule
blade
Screen or         Inorganic/      Medium        Very high      Moderate    Medium    Additive      Yes but
gravure           polymer/small                                                                    damage?
printing          molecule
Inkjet printing   Inorganic/      High          High           Good        Medium    Additive      Yes
                  polymer/small
                  molecule

         Gas phase versus solution phase deposition
Inkjet versus other techniques

 Strengths                                    Weaknesses

 Non-vacuum                                   Film quality not as good as TE/EB/CVD
 Highly scalable
 Compatible with continuous/reel-to-reel
 process on flexible substrates
 Compatible with multi-layer printing
 Additive process
 Opportunities                                Threats

 Creation of a low-cost organic PV solution
Inkjet deposition of coatings

  Production inkjet coating deposition requires


     High throughput
     High reliability  high productivity
     Excellent ink chemistry
         Functional performance
         Reliable printing
     Costs must make sense for application
Low cost manufacturing

 Inkjet has the potential to allow low cost manufacturing of PV
 Can create a new market dynamic for solar energy production


 Need to deposit
        PV materials
        Contacts
Applications for low cost PV

 Low cost, flexible PV allows
    Lower cost of ‘conventional’ power generation PV
    Easier installation
    Return on investment reasonable for mass market


 Enable new applications not currently possible/significant
    Power generation for mobile devices
    Power generation for signage
    Power generation in clothing
Applications example

 Sestar Technologies LLC
 SolarTurf™
    PV incorporated into synthetic grass
    Light absorbing layer can be coloured
    Absorbing grass is green!
    Make compatible with existing consumer products




 Allows power generation from existing areas
    Lower cost of lighting public and private areas
Applications example II
 Sestar Technologies LLC
 SolarFabrics™
    PV incorporated into clothing
    Military and civilian
    Absorbing materials in all colours
 Allows power generation from clothing
    Powering phones, radios, iPods, GPS
    Powering active camouflage
Applications example III

 Sestar Technologies LLC
 SolarFabrics™
    PV incorporated into tents, awnings, etc
    Multiple colours
 Allows power generation to campsites, homes and buildings
    Powering portable devices
    Lower cost of lighting public and private areas
Market size

 Photovoltaic market growing significantly
    20-25% per annum
    $30Bn industry generating 32GW
    Faster introduction impeded by costs
 Impact from
    Subsidies
    Regulations (e.g. specified renewables percentage)
    Emissions taxes


 Low cost solutions have massive potential
Future

 Potential
    Solar power generation everywhere!
    Based on low cost production



 Challenges
    Increase efficiency
        OPV ~1/3 efficiency of conventional
    Increase stability
        OPV relatively unstable
Outlook

  Inkjet deposition ready to replace conventional techniques
  2008: First organic solar cell fabricated with inkjet
  Commercialised inkjet PV production in 2009
      Report 1.5m wide, 40m/min


  Inkjet printed electronics expected to grow
      €62M in 2008
      €3,079 in 2013




  Source: Plus Plastic Electronics, Pira International
Conclusions
 Inkjet technology has the potential to transform industrial manufacture
    Higher productivity/lower cost
    Higher flexibility
    Economical shorter runs
    (Mass) customisation
    Faster product design introductions
    Higher quality
    New functionality
    Environmental benefits


 Digital finishing enables process automation
    Will strengthen competitive power of Western textile industry


 Inkjet promises low cost solar panel manufacture
    Solar power generation everywhere
Building Manufacturing Processes Drop By Drop

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Building Manufacturing Processes Drop By Drop

  • 1. BUILDING MANUFACTURING PROCESSES & PRODUCTS DROP BY DROP Dr Alan Hudd Xennia Technology Ltd Presented at the 1st Digital Manufacturing Conference Florida, USA, June 2011
  • 3. Background to Xennia Xennia is the world’s leading industrial inkjet solutions provider 15 year history, over 300 customer development programmes World class reputation underpinned by a strong IP portfolio Unique expertise in inkjet chemistry with strong engineering capability Headquartered in UK, sales offices in US and China Awarded Queen’s Award for Enterprise in 2010 Offering reliable inkjet process solutions: Inkjet modules and inks for OEM partners with market access Printing systems and inks for end users through our distributors
  • 4. Xennia helps customers lower operating costs, increase productivity and simplify mass customised production by revolutionising manufacturing processes
  • 5. FROM INKJET IDEAS ... TO PRODUCTION REALITY Feasibility studies Process development System design Production solutions
  • 6. Technology push to market pull Inkjet technology & market evolution curve: The next wave has started Technology Market Technology Market Technology Market Innovation Development Innovation Development Innovation Development Market size Ceramics Packaging Electronics Food Biomedical Photo Textiles Labels Screen print Cut vinyl SOHO Graphics CAD E-stat Date Coding Pen plotters Direct Mail 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020
  • 7. Manufacturing processes Key examples of inkjet in manufacturing processes & products Textiles Decoration and digital finishing Industrial decoration Ceramics, furniture laminates Printed electronics Solar energy, displays Biomedical Sensor manufacture
  • 8. Inkjet for manufacture Use inkjet to: Coat Create manufacturing processes Manufacture products Inkjet printing difficult materials Pigments (including inorganic), phosphors, metals Polymers Functional materials Key inkjet ink technologies Pigment and polymer dispersion Solvent based and UV cure chemistries
  • 10. Digital finishing Major benefits of inkjet digital finishing Multi functionality Single sided application possible Two sides can have different functions Patterning – place function where you want it Functionality applied efficiently to textile surface only Highly consistent coat weight Environmental and energy savings Not influenced by underlying substrate variations Not influenced by bath concentration or dosing variations
  • 11. Inkjet textile finishing Inkjet digital textile finishing process System can be Standalone; or Integrated in existing finishing lines Dust cleaning unit Textile Finisher UV IR Conventional Dryer Conventional Dryer Printing blanket
  • 12. Functional materials Hydrophobic Comfort of cotton material on skin side Water and dirt repellent function on outside Dirt repellant/self-cleaning More efficient coating when applied with inkjet Single-sided application important Antimicrobial/anti-fungal/anti-insect Selective deposition, efficient usage Slow release technology Materials used cannot be in skin contact Single-sided application vital
  • 13. Functional materials II Flame retardant Highly coherent coating very important Single side coating allows lighter weight UV blocking (anti-sunburn) Coating needs to be away from skin IR blocking Insulating fabrics – tents, clothing Electrically conductive Antennae incorporated into clothing, tents Communication with electronic devices Solar energy harvesting Tents, awnings, etc Low cost manufacturing essential
  • 16. Textile value chain Current textile production technology is labour intensive Process automation will reduce labour content in costs Variable costs currently high for inkjet Inkjet machines will consume tons of ink Economy of scale dictates lower ink prices No fundamental reason for prices being higher Low cost location becomes less important Logistics will be the key component to control
  • 17. Outlook from Inkjet will revolutionise an outdated industry to deliver production reliability & productivity at lower costs to
  • 18. Section 3 SOLAR PANEL MANUFACTURE
  • 19. Renewable energy Concerns about Sustainability Global warming Pollution Lead to increasing trend for clean, renewable energy Solar photovoltaic Solar thermal Wind Tidal Geothermal Solar photovoltaic and wind have greatest potential Renewable energy proportion still very low (0.8% in 2002)
  • 20. Solar energy generation Huge potential for energy generation 840 W/m2 reaches Earth’s surface during daylight e.g. 1600 TW strikes continental USA All electricity needs met with 10% efficient devices covering 2% of area (Interstate highways currently cover 1.5% of area) Solar energy harvesting Thermal – heat from sun heats water Used for hot water and swimming pools Photovoltaic – energy from sun used to generate electricity Can be used for any purpose
  • 21. Solar photovoltaics Types of photovoltaic (PV) (solar cells) available Conventional (inorganic) 1st generation – crystalline Si 2nd gen – poly-Si, a-Si, CdTe or CIGS Input energy creates electron-hole pairs Separated by internal field Generates photocurrent Organic (small molecule or polymer) Heterojunction design incorporates: Electron transport layer (ETL) and hole transport layer (HTL) Input energy creates excitons ETL/HTL interface drives dissociation into electrons and holes ‘Standard’ materials P3HT and C60 derivatives
  • 22. OPV schematic P3HT bandgap 1.9 eV PCBM LUMO-P3HT HOMO separation ~ 1eV Carrier mobilities 10-4 cm2/Vs Device efficiencies >4% Christoph Brabec and James Durrant, Solution- Processed Organic Solar Cells, MRS Bulletin, 33, 670 (2008)
  • 23. Solar photovoltaics Key figures of merit for PV Efficiency Percentage of incident energy converted into electrical energy Includes collection efficiency as well as conversion efficiency Cost Measured in $ (or €)/Wp Current typical cost 2-8$/Wp Need to reduce significantly Lifetime Minimum 3-5 years Desirable 20-25 years
  • 24. Key cost drivers Key to reducing cost of PV Lower cost materials Lower cost manufacturing Continuous Additive (no waste) Flexible
  • 25. Manufacturing techniques Traditional semiconductor techniques Thermal/electron beam evaporation CVD/MOCVD etc Other coating techniques Spin coating Spray coating Printing Flexo/gravure printing Screen printing Inkjet printing
  • 26. Traditional techniques Thermal/electron beam evaporation Material is heated and evaporates Deposits onto substrate and layer grows CVD/MOCVD Material made into volatile compound Compound decomposes to deposit material Spin coating Material in solution spun on flat surface Uniform coating with evaporation of solvent Spray coating Solution sprayed on surface Solvent evaporates
  • 27. Technology comparison Technology Applicability Scalability Productivity Materials Film Process Multiple Wastage quality type layers? Thermal Inorganic/ Low Low (batch) Moderate High Subtractive Yes but evaporation small slow (vacuum) molecule CVD (low Inorganic/ Low Low (batch) Moderate High Subtractive Yes but pressure) small slow molecule Spin-coating Polymer/small Low Low (batch) Poor Medium Subtractive Yes but molecule slow Spray-coating Polymer/small High High Poor Low Subtractive Yes or doctor molecule blade Screen or Inorganic/ Medium Very high Moderate Medium Additive Yes but gravure polymer/small damage? printing molecule Inkjet printing Inorganic/ High High Good Medium Additive Yes polymer/small molecule Gas phase versus solution phase deposition
  • 28. Inkjet versus other techniques Strengths Weaknesses Non-vacuum Film quality not as good as TE/EB/CVD Highly scalable Compatible with continuous/reel-to-reel process on flexible substrates Compatible with multi-layer printing Additive process Opportunities Threats Creation of a low-cost organic PV solution
  • 29. Inkjet deposition of coatings Production inkjet coating deposition requires High throughput High reliability  high productivity Excellent ink chemistry Functional performance Reliable printing Costs must make sense for application
  • 30. Low cost manufacturing Inkjet has the potential to allow low cost manufacturing of PV Can create a new market dynamic for solar energy production Need to deposit PV materials Contacts
  • 31. Applications for low cost PV Low cost, flexible PV allows Lower cost of ‘conventional’ power generation PV Easier installation Return on investment reasonable for mass market Enable new applications not currently possible/significant Power generation for mobile devices Power generation for signage Power generation in clothing
  • 32. Applications example Sestar Technologies LLC SolarTurf™ PV incorporated into synthetic grass Light absorbing layer can be coloured Absorbing grass is green! Make compatible with existing consumer products Allows power generation from existing areas Lower cost of lighting public and private areas
  • 33. Applications example II Sestar Technologies LLC SolarFabrics™ PV incorporated into clothing Military and civilian Absorbing materials in all colours Allows power generation from clothing Powering phones, radios, iPods, GPS Powering active camouflage
  • 34. Applications example III Sestar Technologies LLC SolarFabrics™ PV incorporated into tents, awnings, etc Multiple colours Allows power generation to campsites, homes and buildings Powering portable devices Lower cost of lighting public and private areas
  • 35. Market size Photovoltaic market growing significantly 20-25% per annum $30Bn industry generating 32GW Faster introduction impeded by costs Impact from Subsidies Regulations (e.g. specified renewables percentage) Emissions taxes Low cost solutions have massive potential
  • 36. Future Potential Solar power generation everywhere! Based on low cost production Challenges Increase efficiency OPV ~1/3 efficiency of conventional Increase stability OPV relatively unstable
  • 37. Outlook Inkjet deposition ready to replace conventional techniques 2008: First organic solar cell fabricated with inkjet Commercialised inkjet PV production in 2009 Report 1.5m wide, 40m/min Inkjet printed electronics expected to grow €62M in 2008 €3,079 in 2013 Source: Plus Plastic Electronics, Pira International
  • 38. Conclusions Inkjet technology has the potential to transform industrial manufacture Higher productivity/lower cost Higher flexibility Economical shorter runs (Mass) customisation Faster product design introductions Higher quality New functionality Environmental benefits Digital finishing enables process automation Will strengthen competitive power of Western textile industry Inkjet promises low cost solar panel manufacture Solar power generation everywhere