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OFET’s in rollable displays
                                                     Fred Touwslager
                                                     Technology R&D manager


confidential




     Outline

          ƒ   Introduction:
                  ƒ Organic Field Effect Transistor
                  ƒ Active matrix display
                  ƒ Why rollable displays?


          ƒ   Main technology choices

          ƒ   Summary




Themadag Organic and Printed Electronics November 10th 2011              2
Field Effect Transistor (a.k.a. TFT)

                   A 3-terminal device in which the current between 2 of the
                   terminals is determined by the voltage on the third.




Themadag Organic and Printed Electronics November 10th 2011                 3




     Field effect transistor: basic physics

                            Transfer characteristics

                                     Drain voltage = -1V
                             *
      - Drain current (A)




                            Accumulation                                  Variable



                                      Subthreshold

                                                 Vt Depletion
                                                              *
                                                                  Vt = onset of accumulation

                                 Gate voltage (V)

Themadag Organic and Printed Electronics November 10th 2011                 4
Field effect transistors: layouts
                                      bottom contact                         top contact




  bottom gate




      top gate




Themadag Organic and Printed Electronics November 10th 2011                                5




     Organic Field Effect Transistor

                                                                                                 Rollable display

                                                                      TFTs on ultra-thin
                                                                           plastic



                                              Room temperature
                                                 deposition
         Organic materials
                                                                                               Integrated in a rollable
                                                                                                       display

                                                                        Resulting in an
                                                                      extremely thin and
                                                                      flexible backplane
                                               Enable simple, room
                                             temperature processing

          Organics are highly
               flexible




Themadag Organic and Printed Electronics November 10th 2011                                6
(Rollable) Active Matrix display


        Active matrix display is a grid of pixels, with a switch connected
        to each pixel:


                                     Switch = TFT
                                                              CEink
                                        S
                         Data line




                                                 D

                                         G                       pixel


                                                   Gate line



Themadag Organic and Printed Electronics November 10th 2011                   7




     (Rollable) Active Matrix display




                                                                         data line




                                                                             pixel




Themadag Organic and Printed Electronics November 10th 2011                   8
(Rollable) Active Matrix display



                               Data




  Selection
   pulse




Themadag Organic and Printed Electronics November 10th 2011                               9




     Why displays on flexible carriers


      Proposition                                             Target market

      Rollable/Foldable                                       Mobile phones, E-readers, UMPCs, …




       Flexible                                               Smartcards, advertisement, point of
                                                              sale, wearable, …




      Robust and lightweight                                  E-readers, point of sale,
                                                              advertisement, …



Themadag Organic and Printed Electronics November 10th 2011                               10
Mobile market: More powerful smaller devices



                                                       Device Size decreasing




                                                              Storage increasing




                                                   Content volume increasing
                                                  1G             More data         3G+

                                                              Mobile display size
               Av. Display                                                                     Av. Display
               Size 1.65”
                                                     No relative improvement                    Size 2”

                                   Limited by glass based display technology
Themadag Organic and Printed Electronics November 10th 2011                              11




            The need for rollable displays
            Device size no longer coupled to display size




                                                                                              Display larger
                                                                                                 than the
                                                                                              device itself.




                        Ease of
                        mobility                                                               Display size
                                                                                                  ratio:
                                                                                               Smart phone:
                                                                                                          <0.3
                                                                                               iPhone:    0.56
                                                                                               Rollable:  >1


                                                                    Display size

Themadag Organic and Printed Electronics November 10th 2011                              12
Main technology choices
                                                                Typical dimensions:

                                                                ƒ   Pixel: 150μm x 150μm

                                                                ƒ   Smallest dimensions: 5μm

                                                                ƒ   Overlay accuracy: < 5 μm

                                                                ƒ   Layer thicknesses: < 2μm



                                                                ƒ   Total display thickness for a
                                                                    rollable display: <100μm


Themadag Organic and Printed Electronics November 10th 2011                            13




     Main technology choices


      Technology                   Technologies currently under development
      block


      Substrate                       Plastic                 Steel


      Substrate                       Bond-debond             Free standing Transfer
      handling

      Matrix stack                    Organic                 a-Si           Poly-Si        oxides


      Patterning                      Lithography             Printing      Other
      methods


      Frontplane                      Electrophoretic         OLED          Ch-LC           LCD


Themadag Organic and Printed Electronics November 10th 2011                            14
Substrate

       • Chemical stability
       • Thermal stability
       • Surface quality
       • Stiffness

                                                              For PEN:
                                                              E = 6 GPa
                                                              t = 25 μm         D = 0.11 Nm
                                                              Q =0.33
                       Et 3
         D
                     12(1 Q )                                For steel:
                                                              E = 190 GPa
                                                              Q = 0.27 – 0.30   t = 8μm
                                                              D = 0.11 Nm


Themadag Organic and Printed Electronics November 10th 2011                      15




     Substrate




Themadag Organic and Printed Electronics November 10th 2011                      16
Substrate




Themadag Organic and Printed Electronics November 10th 2011        17




     Substrate handling



         ƒ   Free standing (roll to roll or sheet to sheet). Keep in mind the desired
             substrate thickness.


         ƒ   Transfer

         ƒ   Bond-debond




Themadag Organic and Printed Electronics November 10th 2011        18
Matrix stack
           Semi-conductor:

           ƒ   poly-Si: vacuum deposition at T  600°C

           ƒ   amorphous Si: vacuum deposition / PECVD at T  100°C

           ƒ   organic: vacuum deposition or spin coating, low temperature

           ƒ   (mixed) oxides: low T vacuum deposition (ZnO, Ga2O3, ZnMgO, …)


           Dielectrics:

           ƒ   inorganic: vacuum deposition

           ƒ   organic: spin coating
Themadag Organic and Printed Electronics November 10th 2011      19




     Patterning: printing




                         the vision of kilometers display produced per minute
                           using roll-to-roll printing methods
Themadag Organic and Printed Electronics November 10th 2011      20
Benchmarking different printing technologies




      Printing                       Feature                  Layer thickness   Registration   Throughput
      Technique                      size (μm)                (μm)              (μm)           (m²/s)
      Inkjet                               20-50                    0.5           5 - 20        0.01 – 0.5

      Flexography                             80                  0.8 - 2.5         200           3 - 30

      Gravure                                 75                  0.1 – 8.0         20            3 - 60

      Screen                            20 - 200                 0.015 - 100        25            2-3

      Offset                             10 - 50                  0.5 – 2.0         10            5 - 30

      Pad                                     20                    1 -2            10             0.1


Themadag Organic and Printed Electronics November 10th 2011                               21




     Patterning

          Chosen for lithographic patterning:

          -   Subtractive technique

          -   Sacrificial layer

          +   Proven manufacturing technology

          +   Huge installed base

          +   Compatible with standard AMLCD manufacturing



Themadag Organic and Printed Electronics November 10th 2011                               22
Frontplane
    Electrophoretic display (EPD) effect:

    Black and white particles with opposite charge in a clear liquid.




Themadag Organic and Printed Electronics November 10th 2011                            23




        Polymer Vision technology


         Technology                  Technologies currently under development
         block


         Substrate                      Plastic               Steel


         Substrate                      Bond-debond           Free standing Transfer
         handling

         Matrix stack                    Organic              a-Si          Poly-Si         oxides


         Patterning                     Lithography           Printing      Other
         methods


         Frontplane                     Electrophoretic       OLED          C-LC            LCD

Themadag Organic and Printed Electronics November 10th 2011                            24
AM backplane layout




                          Pixel electrode

                                                                                               Field insulator
                                                    Semiconductor
                          Column                                             Pixel electrode
                                                       Row                                           Insulator

                      Plastic substrate



                                                                  Rigid support
Themadag Organic and Printed Electronics November 10th 2011                                    25
                                                                  carrier




        Display construction
        Display construction
        Laminate electrophoretic frontplane laminate
        Laminate electrophoretic frontplane laminate




                                                                                               Field insulator
                                                    Semiconductor                              Field insulator
                                                    Semiconductor
                          Column                                             Pixel electrode
                          Column                                             Pixel electrode
                                                       Row                                           Insulator
                                                       Row                                           Insulator
                      Plastic substrate
                      Plastic substrate


                                                                  Rigid support
                                                                  Rigid support
                                                                  carrier
Themadag Organic and Printed Electronics November   10th   2011                                26
                                                                  carrier
Thinnest, most flexible display in the World




                                                                   Plastic substrate
                                                                   30Pm




                                                                   E Ink display effect
                                                                   40Pm
                                                    0.1mm



                                                                   Organic electronics
                                                                   backplane
                                                                   5Pm

                                                                   Plastic substrate
                                                                   25Pm



     • Ultra-thin is rollable: roll radius § 50 x thickness

Themadag Organic and Printed Electronics November 10th 2011   27




     Unbreakable display




Themadag Organic and Printed Electronics November 10th 2011   28
Brief history – Philips Research highlights




                                   1995 First logic gates
                             1998 All-polymer ICs, first transponders (Si diode)
                              2000 150mm wafer process, scaleable and industrial
                                   2000 World’s 1st OE glass-based display
                                             2003 shift registers (~ 2000 TFTs)
                                           2004 Ferroelectric memory transistors
            Time (s)
                                                2006 13.56MHz RFID tag
              2000                        2001              2002              2003       2004
              rigid                     Grey scale        flexible         Size QVGA    rollable




Themadag Organic and Printed Electronics November 10th 2011                        29




     About Polymer Vision


                 20xx       “A rollable display in every mobile device!”
                 :
                 :
                 2010       MA local AMLCD facility
                 2009       Assets acquired by
                 2008       Qualified rollable display and device
                 2007       Production line transfer  yield

                 2006       Spin-out of Polymer Vision Ltd.
                 2005       Concept device development
                 :
                 2000       Development of rollable display
                 :
                 1991       Research on organic electronics




Themadag Organic and Printed Electronics November 10th 2011                        30
Summary
                                        Polymer Vision offers a robust, flexible and
                                        even rollable display solution.

                                        Polymer Vision uses proven manufacturing
                                        technologies to introduce a new display
                                        technology.


                                        The technology and process have successfully
                                        been introduced into a G2.5 AM-LCD line.



                                        The technology has further matured by the
                                        introduction of a full VGA display and touch.


Themadag Organic and Printed Electronics November 10th 2011               31




      Food for thought

  ƒ    Can cost be the driving force for introduction of disruptive
       alternative technologies (e.g. LCD versus CRT)?

  ƒ    Why is batch processing so popular in LCD and IC manufacturing?

  ƒ    Why is printing of e.g. value paper still done sheet to sheet?




Themadag Organic and Printed Electronics November 10th 2011               32

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Fred Touwslager - Polymer Vision

  • 1. OFET’s in rollable displays Fred Touwslager Technology R&D manager confidential Outline ƒ Introduction: ƒ Organic Field Effect Transistor ƒ Active matrix display ƒ Why rollable displays? ƒ Main technology choices ƒ Summary Themadag Organic and Printed Electronics November 10th 2011 2
  • 2. Field Effect Transistor (a.k.a. TFT) A 3-terminal device in which the current between 2 of the terminals is determined by the voltage on the third. Themadag Organic and Printed Electronics November 10th 2011 3 Field effect transistor: basic physics Transfer characteristics Drain voltage = -1V * - Drain current (A) Accumulation Variable Subthreshold Vt Depletion * Vt = onset of accumulation Gate voltage (V) Themadag Organic and Printed Electronics November 10th 2011 4
  • 3. Field effect transistors: layouts bottom contact top contact bottom gate top gate Themadag Organic and Printed Electronics November 10th 2011 5 Organic Field Effect Transistor Rollable display TFTs on ultra-thin plastic Room temperature deposition Organic materials Integrated in a rollable display Resulting in an extremely thin and flexible backplane Enable simple, room temperature processing Organics are highly flexible Themadag Organic and Printed Electronics November 10th 2011 6
  • 4. (Rollable) Active Matrix display Active matrix display is a grid of pixels, with a switch connected to each pixel: Switch = TFT CEink S Data line D G pixel Gate line Themadag Organic and Printed Electronics November 10th 2011 7 (Rollable) Active Matrix display data line pixel Themadag Organic and Printed Electronics November 10th 2011 8
  • 5. (Rollable) Active Matrix display Data Selection pulse Themadag Organic and Printed Electronics November 10th 2011 9 Why displays on flexible carriers Proposition Target market Rollable/Foldable Mobile phones, E-readers, UMPCs, … Flexible Smartcards, advertisement, point of sale, wearable, … Robust and lightweight E-readers, point of sale, advertisement, … Themadag Organic and Printed Electronics November 10th 2011 10
  • 6. Mobile market: More powerful smaller devices Device Size decreasing Storage increasing Content volume increasing 1G More data 3G+ Mobile display size Av. Display Av. Display Size 1.65” No relative improvement Size 2” Limited by glass based display technology Themadag Organic and Printed Electronics November 10th 2011 11 The need for rollable displays Device size no longer coupled to display size Display larger than the device itself. Ease of mobility Display size ratio: Smart phone: <0.3 iPhone: 0.56 Rollable: >1 Display size Themadag Organic and Printed Electronics November 10th 2011 12
  • 7. Main technology choices Typical dimensions: ƒ Pixel: 150μm x 150μm ƒ Smallest dimensions: 5μm ƒ Overlay accuracy: < 5 μm ƒ Layer thicknesses: < 2μm ƒ Total display thickness for a rollable display: <100μm Themadag Organic and Printed Electronics November 10th 2011 13 Main technology choices Technology Technologies currently under development block Substrate Plastic Steel Substrate Bond-debond Free standing Transfer handling Matrix stack Organic a-Si Poly-Si oxides Patterning Lithography Printing Other methods Frontplane Electrophoretic OLED Ch-LC LCD Themadag Organic and Printed Electronics November 10th 2011 14
  • 8. Substrate • Chemical stability • Thermal stability • Surface quality • Stiffness For PEN: E = 6 GPa t = 25 μm D = 0.11 Nm Q =0.33 Et 3 D 12(1 Q ) For steel: E = 190 GPa Q = 0.27 – 0.30 t = 8μm D = 0.11 Nm Themadag Organic and Printed Electronics November 10th 2011 15 Substrate Themadag Organic and Printed Electronics November 10th 2011 16
  • 9. Substrate Themadag Organic and Printed Electronics November 10th 2011 17 Substrate handling ƒ Free standing (roll to roll or sheet to sheet). Keep in mind the desired substrate thickness. ƒ Transfer ƒ Bond-debond Themadag Organic and Printed Electronics November 10th 2011 18
  • 10. Matrix stack Semi-conductor: ƒ poly-Si: vacuum deposition at T 600°C ƒ amorphous Si: vacuum deposition / PECVD at T 100°C ƒ organic: vacuum deposition or spin coating, low temperature ƒ (mixed) oxides: low T vacuum deposition (ZnO, Ga2O3, ZnMgO, …) Dielectrics: ƒ inorganic: vacuum deposition ƒ organic: spin coating Themadag Organic and Printed Electronics November 10th 2011 19 Patterning: printing the vision of kilometers display produced per minute using roll-to-roll printing methods Themadag Organic and Printed Electronics November 10th 2011 20
  • 11. Benchmarking different printing technologies Printing Feature Layer thickness Registration Throughput Technique size (μm) (μm) (μm) (m²/s) Inkjet 20-50 0.5 5 - 20 0.01 – 0.5 Flexography 80 0.8 - 2.5 200 3 - 30 Gravure 75 0.1 – 8.0 20 3 - 60 Screen 20 - 200 0.015 - 100 25 2-3 Offset 10 - 50 0.5 – 2.0 10 5 - 30 Pad 20 1 -2 10 0.1 Themadag Organic and Printed Electronics November 10th 2011 21 Patterning Chosen for lithographic patterning: - Subtractive technique - Sacrificial layer + Proven manufacturing technology + Huge installed base + Compatible with standard AMLCD manufacturing Themadag Organic and Printed Electronics November 10th 2011 22
  • 12. Frontplane Electrophoretic display (EPD) effect: Black and white particles with opposite charge in a clear liquid. Themadag Organic and Printed Electronics November 10th 2011 23 Polymer Vision technology Technology Technologies currently under development block Substrate Plastic Steel Substrate Bond-debond Free standing Transfer handling Matrix stack Organic a-Si Poly-Si oxides Patterning Lithography Printing Other methods Frontplane Electrophoretic OLED C-LC LCD Themadag Organic and Printed Electronics November 10th 2011 24
  • 13. AM backplane layout Pixel electrode Field insulator Semiconductor Column Pixel electrode Row Insulator Plastic substrate Rigid support Themadag Organic and Printed Electronics November 10th 2011 25 carrier Display construction Display construction Laminate electrophoretic frontplane laminate Laminate electrophoretic frontplane laminate Field insulator Semiconductor Field insulator Semiconductor Column Pixel electrode Column Pixel electrode Row Insulator Row Insulator Plastic substrate Plastic substrate Rigid support Rigid support carrier Themadag Organic and Printed Electronics November 10th 2011 26 carrier
  • 14. Thinnest, most flexible display in the World Plastic substrate 30Pm E Ink display effect 40Pm 0.1mm Organic electronics backplane 5Pm Plastic substrate 25Pm • Ultra-thin is rollable: roll radius § 50 x thickness Themadag Organic and Printed Electronics November 10th 2011 27 Unbreakable display Themadag Organic and Printed Electronics November 10th 2011 28
  • 15. Brief history – Philips Research highlights 1995 First logic gates 1998 All-polymer ICs, first transponders (Si diode) 2000 150mm wafer process, scaleable and industrial 2000 World’s 1st OE glass-based display 2003 shift registers (~ 2000 TFTs) 2004 Ferroelectric memory transistors Time (s) 2006 13.56MHz RFID tag 2000 2001 2002 2003 2004 rigid Grey scale flexible Size QVGA rollable Themadag Organic and Printed Electronics November 10th 2011 29 About Polymer Vision 20xx “A rollable display in every mobile device!” : : 2010 MA local AMLCD facility 2009 Assets acquired by 2008 Qualified rollable display and device 2007 Production line transfer yield 2006 Spin-out of Polymer Vision Ltd. 2005 Concept device development : 2000 Development of rollable display : 1991 Research on organic electronics Themadag Organic and Printed Electronics November 10th 2011 30
  • 16. Summary Polymer Vision offers a robust, flexible and even rollable display solution. Polymer Vision uses proven manufacturing technologies to introduce a new display technology. The technology and process have successfully been introduced into a G2.5 AM-LCD line. The technology has further matured by the introduction of a full VGA display and touch. Themadag Organic and Printed Electronics November 10th 2011 31 Food for thought ƒ Can cost be the driving force for introduction of disruptive alternative technologies (e.g. LCD versus CRT)? ƒ Why is batch processing so popular in LCD and IC manufacturing? ƒ Why is printing of e.g. value paper still done sheet to sheet? Themadag Organic and Printed Electronics November 10th 2011 32