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CARBON & IT’S
COMPOUNDS
Occurrence of carbon
Free State Combined State
• Graphite
• Diamond
• C combines with other
elements to form
compounds.
• CO2
• C6 H12 O6
• C12 H22 O11
• C8 H18
• CaCO3 , MgCO3
Carbon ( C )
• Atomic Number – 6
• Electronic Configuration – (2 , 4)
K , L ( Valence Shell )
• Valency of Carbon - 4
• C + 4e- = C4- (Anion)
- Gain 4 electrons
- Difficult for nucleus with 6 p+ to hold 10 e-
• C = C4+ + 4e- (Cation)
- Lose 4 electrons
- Require large amount of energy to remove 4e-
- Imbalance between 6 p+ with just 2e-
TYPES OF BOND
Ionic Covalent
• Give and take of e-
• Example :
• H+ with Cl- gives
HCl
• Sharing of e-
• Example :
• H2 , Cl2
Ionic Covalent
Formed By
Transfer of electrons that
are positively and
negatively charged.
Sharing the electrons.
Bonding
Involves a metal and
nonmetal
Between nonmetals.
Solubility in water More Less
Shape Definite No shape
Conductor of Heat Good Bad
Conductor of Electricity Good Bad
Ionic Covalent
Melting Point High Low
Boiling Point High Low
State at room
Temperature
Solid Solid, Liquid, Gaseous
How elements form Covalent Bonds ?
Hydrogen Atomic Number – 1
• 1 electron in K Shell
• Requires 1 electron to fill K Shell
• 1 electron contributed by each Hydrogen atom
• 1 pair of shared electrons – Constitutes Single Bond
H - H
Chlorine Atomic Number – 17
Oxygen Atomic Number – 8
• Outermost Shell - L Shell – 6 electrons
• Requires 2 electrons to complete its octet.
• 2 electrons contributed by each Oxygen atom
• 2 pairs of shared electrons – Constitutes Double Bond
Water – H2O
Nitrogen Atomic Number – 7
• Outermost Shell - L Shell – 5 electrons
• Requires 3 electrons to complete its octet.
• 3 electrons contributed by each Nitrogen atom
• 3 pairs of shared electrons – Constitutes Triple Bond
Ammonia – NH3
• How is carbon different from other elements ?
• 4 covalent bonds – tetravalent
• C is tetravalent in nature.
• Self combination ( Catenation )
C8 H18 - Petrol
• Carbon has a unique ability to combine with other
carbon atoms to form long carbon chains, this ability
of carbon is known as catenation. ( Can form infinite
compounds)
• Cause of Catenation
• Due to small size of C atom, the covalent bond
between the carbon atoms become very strong, as the
nuclei of two carbon atoms hold the shared electrons
very tightly.
• Versatile Nature of Carbon
- TETRAVALENCY
- Capable of bonding with other 4 atoms of Carbon
- Or atoms of other mono – valent elements
- Combines with oxygen, hydrogen, nitrogen, sulphur, chlorine
and many other elements.
- Gives rise to specific properties of compounds, which
depends on the elements other than Carbon.
- Small size – Strong Bond
• Versatile Nature of Carbon
- CATENATION
- Compounds may have long or branched chains of carbon
- Carbon atoms arranged in rings.
- Linked by single, double or triple bonds.
- Silicon have chains upto seven or eight atoms, but are very
reactive.
- Carbon – Carbon bond is very strong & hence stable.
- Gives large number of compounds with many carbons linked
to each other.
Saturated and Unsaturated Compounds
1. Ethane
CH3CH3
C2H6
• Valencies of all the atoms is satisfied by single bonds
• Such carbon compounds are called Saturated
compounds
• Normally not very reactive
2. Ethene
CH2CH2
C2H4
• If only two Hydrogen atoms attached with each Carbon
• One valency per carbon remains unsatisfied
• It can be satisfied only if there is a Double bond
between two carbon atoms
• If only one Hydrogen atom attached with each Carbon
• Two valencies per carbon remains unsatisfied
• It can be satisfied only if there is a Triple bond between
two carbon atoms
3. Ethyne
CHCH
C2H2
• Compounds of Carbon having Single bond
between the carbon atoms are known as
Saturated Carbon Compounds.
• Compounds of Carbon having Double and Triple
bonds between the carbon atoms are known as
Unsaturated Carbon Compounds.
• Unsaturated Carbon compounds are more reactive
than Saturated Carbon compounds.
• Formulae and Structures of Saturated Compounds of
Carbon and Hydrogen
( Straight Chain Carbon Compounds )
Structural Isomers ( Branched Chain Carbon Compounds )
Butane C4H10
Inner C attached with
other two carbon atoms
Inner C attached with
other three carbon atoms
• Identical Molecular Formula
• Different Structures
Cyclic Carbon Compounds
Cyclo Hexane Benzene
C6H12 C6H6

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Carbon part 1

  • 2.
  • 3. Occurrence of carbon Free State Combined State • Graphite • Diamond • C combines with other elements to form compounds. • CO2 • C6 H12 O6 • C12 H22 O11 • C8 H18 • CaCO3 , MgCO3
  • 4. Carbon ( C ) • Atomic Number – 6 • Electronic Configuration – (2 , 4) K , L ( Valence Shell ) • Valency of Carbon - 4
  • 5. • C + 4e- = C4- (Anion) - Gain 4 electrons - Difficult for nucleus with 6 p+ to hold 10 e- • C = C4+ + 4e- (Cation) - Lose 4 electrons - Require large amount of energy to remove 4e- - Imbalance between 6 p+ with just 2e-
  • 6. TYPES OF BOND Ionic Covalent • Give and take of e- • Example : • H+ with Cl- gives HCl • Sharing of e- • Example : • H2 , Cl2
  • 7. Ionic Covalent Formed By Transfer of electrons that are positively and negatively charged. Sharing the electrons. Bonding Involves a metal and nonmetal Between nonmetals. Solubility in water More Less Shape Definite No shape Conductor of Heat Good Bad Conductor of Electricity Good Bad
  • 8. Ionic Covalent Melting Point High Low Boiling Point High Low State at room Temperature Solid Solid, Liquid, Gaseous
  • 9. How elements form Covalent Bonds ? Hydrogen Atomic Number – 1 • 1 electron in K Shell • Requires 1 electron to fill K Shell • 1 electron contributed by each Hydrogen atom • 1 pair of shared electrons – Constitutes Single Bond H - H
  • 11. Oxygen Atomic Number – 8 • Outermost Shell - L Shell – 6 electrons • Requires 2 electrons to complete its octet. • 2 electrons contributed by each Oxygen atom • 2 pairs of shared electrons – Constitutes Double Bond
  • 13. Nitrogen Atomic Number – 7 • Outermost Shell - L Shell – 5 electrons • Requires 3 electrons to complete its octet. • 3 electrons contributed by each Nitrogen atom • 3 pairs of shared electrons – Constitutes Triple Bond
  • 15. • How is carbon different from other elements ? • 4 covalent bonds – tetravalent • C is tetravalent in nature.
  • 16. • Self combination ( Catenation ) C8 H18 - Petrol • Carbon has a unique ability to combine with other carbon atoms to form long carbon chains, this ability of carbon is known as catenation. ( Can form infinite compounds)
  • 17. • Cause of Catenation • Due to small size of C atom, the covalent bond between the carbon atoms become very strong, as the nuclei of two carbon atoms hold the shared electrons very tightly.
  • 18. • Versatile Nature of Carbon - TETRAVALENCY - Capable of bonding with other 4 atoms of Carbon - Or atoms of other mono – valent elements - Combines with oxygen, hydrogen, nitrogen, sulphur, chlorine and many other elements. - Gives rise to specific properties of compounds, which depends on the elements other than Carbon. - Small size – Strong Bond
  • 19. • Versatile Nature of Carbon - CATENATION - Compounds may have long or branched chains of carbon - Carbon atoms arranged in rings. - Linked by single, double or triple bonds. - Silicon have chains upto seven or eight atoms, but are very reactive. - Carbon – Carbon bond is very strong & hence stable. - Gives large number of compounds with many carbons linked to each other.
  • 20. Saturated and Unsaturated Compounds 1. Ethane CH3CH3 C2H6 • Valencies of all the atoms is satisfied by single bonds • Such carbon compounds are called Saturated compounds • Normally not very reactive
  • 21. 2. Ethene CH2CH2 C2H4 • If only two Hydrogen atoms attached with each Carbon • One valency per carbon remains unsatisfied • It can be satisfied only if there is a Double bond between two carbon atoms
  • 22. • If only one Hydrogen atom attached with each Carbon • Two valencies per carbon remains unsatisfied • It can be satisfied only if there is a Triple bond between two carbon atoms 3. Ethyne CHCH C2H2
  • 23.
  • 24. • Compounds of Carbon having Single bond between the carbon atoms are known as Saturated Carbon Compounds. • Compounds of Carbon having Double and Triple bonds between the carbon atoms are known as Unsaturated Carbon Compounds. • Unsaturated Carbon compounds are more reactive than Saturated Carbon compounds.
  • 25.
  • 26. • Formulae and Structures of Saturated Compounds of Carbon and Hydrogen ( Straight Chain Carbon Compounds )
  • 27. Structural Isomers ( Branched Chain Carbon Compounds ) Butane C4H10 Inner C attached with other two carbon atoms Inner C attached with other three carbon atoms • Identical Molecular Formula • Different Structures
  • 28. Cyclic Carbon Compounds Cyclo Hexane Benzene C6H12 C6H6