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Scale-up of low-carbon footprint material
recovery techniques in existing wastewater
treatment plants – General overview of the
H2020 project (2016 – 2020)
PHA production
Biogas
Cellulose
Sludge treatment
Nutrients removal
Struvite
Anaerobic digestion
Biomaterial
Ion Exchange
Low-carbon footprint
Bioprocess
Physical and chemical process
Daniel Dias • João Ribeiro
Nitrification Denitrification
Filtration
GHG
Membrane
2
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
7+2 pilot systems optimised for more than 2 years in real environment in 5 municipal water
treatment plants, including also 2 post-processing facilities;
Aim of optimising wastewater treatment, resource recovery, energy-efficiency and reduction of
greenhouse emissions;
Recover biopolymers, cellulose, fertilisers and intermediates and processed up to the final end-
products;
26 partners.
Instituto de Biologia Experimental e Tecnológica (iBET)  Application and validation of the
simulation environment for SMART processes integration.
OBJECTIVE:
SMART-Plant will scale-up in real environment eco-innovative and energy-efficient solutions to
renovate existing wastewater treatment plants and close the circular value chain by applying low-
carbon techniques to recover materials that are otherwise lost.
.
What is SMART-Plant?
3
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
Cellulose
Struvite
Calcium-P
P-Biofertilizer
Bio-
polymers
Biogas
and
Biomass
Fuel
Energy
and
Carbon
Efficiency
Water re-use and
fertigation
Scale-up of low-carbon
footprint MAterial
Recovery Techniques in
existing wastewater
treatment PLANTs
Consumer/IndustrialProducts
4
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
Who is SMART-Plant?
• Member of the ICT4WATER cluster;
• Member of the European Sustainable
Phosphorus Platform
5
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
Impact so far...
• SMART-PLANT (HORIZON 2020 PROGRAMME)” won
the best Research Project Award at the IWATER
Awards 2018 in Barcelona (SOCAMEX).
• EYDAP won a golden award at the 2018
Environmental Awards for the SMART-Plant Project
• Aquatech Innovation Award 2017 - Overall winner
and category: wastewater treatment - by Cellvation
cellulose recovery, CirTec, for the SMART-Plant
project
6
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
WWTP/WRRF
6
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
WWTP/WRRF
SMARTech1 - Geestmerambacht WWTP (NL)
SMARTech2b and Downstream
SMARTech B - Manresa WWTP (Spain)
SMARTech2a –
Karmiel WWTP (IL)
SMARTech3 – WWTP at Cranfield University (UK)
SMARTech 4b - Psyttalia WWTP (Greece)
SMARTech 4a and SMARTech 5
Carbonera WWTP (Italy)
7
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
SMART-Plant
AchievementsSMARTech
n.
Integrated
municipal WWTP
Key enabling process(es) SMART-product(s)
1 Geestmerambacht
(Netherlands)
Upstream dynamic fine-
screen and post-processing of
cellulosic sludge
Cellulosic sludge,
refined clean
cellulose
2a Karmiel (Israel) Mainstream polyurethane-
based anaerobic biofilter
Biogas, Energy-
efficient water reuse
2b Manresa (Spain) Mainstream SCEPPHAR Struvite, PHA
3 Cranfield (UK) Mainstream tertiary hybrid
ion exchange
Nutrients
4a Carbonera (Italy) Sidestream SCENA P-rich sludge, VFA
4b Psyttalia (Greece) Sidestream Thermal
hydrolysis – SCENA
P-rich sludge
5 Carbonera (Italy) Sidestream SCEPPHAR PHA, struvite, VFA
MainstreamSidestream
Demos commissioned:
June 2017 – Long-term
validation: May 2019
Environmental Technology
Verification (ETV):
tool to help innovative
environmental technologies
reach the market.
8
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
SMART-Plant
Approach
Influent
Effluent
Biogas
Dehydrated
sludge Water line
Sludge line
Conventional Primary
Sedimentation replaced by
Primary Upstream SMARTech1
Conventional Activated Sludge
replaced by Secondary Mainstream
SMARTechs 2a and/or 2b
Conventional or Enhanced
Anaerobic Digestion
integrated by Sidestream
SMARTechs 4a,4b or 5
Conventional Secondary
Effluent refined by Tertiary
Mainstream SMARTech3
SMARTech 1 – Upstream dynamic fine-screen and post-processing of cellulosic sludge
Wastewater treatment plant (WWTP) – Geestmerambacht, Netherlands
Aim
Cellulose recovery from
wastewater for cellulosic sludge
and refined clean cellulose
(e.g building material additive,
asphalt material for cycle
lanes)
Wastewater to cellulosic solid.
Aim
Reduced loads of COD and
TSS on the biological
treatment system  Energy-
efficient water reuse;
Biogas production.
Polyfoam filling
SMARTech 2a – Mainstream polyurethane-based anaerobic biofilter with biogas
recovery WWTP – Karmiel, Israel
SMARTech 2b – Secondary mainstream S.C.E.P.P.H.A.R. WWTP – Manresa, Spain
Aim
Phosphorus recovery (struvite) and PHA
sludge production from wastewater.
SCEPPHAR pilot plant in Manresa WWTP.
SMARTech 3 scheme.
SMARTech 3 – Mainstream tertiary nutrient recovery by mesolite and nano ion exchange
WWTP – Cranfield, England
a) b)
HAIX LanXess
Formed
commercialised
Mesolite
Aim
Nutrients adsorption
and recovery for
agriculture fertilisers
SMARTech 4a – Sidestream SCENA WWTP – Carbonera, Italy
DYNAMIC THICKENER
FERMENTATION
SCREW-PRESS
S/L SEPARATION
VFAs STORAGE
SUPERNATANTS STORAGE
VIA-NITRITE scSBR FERMENTER
scSBR
Aim
P-rich sludge and VFA
recovery/production
Aim
Via nitrite, treat
anaerobic supernatant
rich in ammonium
SMARTech 4b pilot plant.
SMARTech 4b –Sidestream Thermal hydrolysis – S.C.E.N.A WWTP – Psyttalia, Greece
Psyttalia island.
Aim
Via nitrite, treat anaerobic
supernatant rich in ammonium 
P-rich sludge recovery/production
SMARTech 4b scheme.
SMARTech 5 – Sidestream SCEPPHAR WWTP – Carbonera, Italy
Aim
Phosphorus recovery as struvite;
PHA production via feast and
famine regime; VFAs production.
Nitritation
Selection
Accumulation
Crystalliser for
struvite recovery
Biomass during PHA
accumulation
Selected PHA
biomass
Recovered Struvite
(purity and agronomic
properties under assessment
16
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
Current Achievements of the Project: Energy and Carbon-Efficient Valuable
Materials Recovery in SMART-Plant demos
350 – 400 kg Cellulose a week;
1.0 –1.2 kg PHA per day;
> 0.25 – 0.30 kg Struvite per day;
2-3 m3 of biogas per day;
60% of P recovered as CaPO4 from the
tertiary treatment;
15-20 kg of P-rich sludge, 60-65
gP/kgTS
> 10 kg BioFertilizers per day;
1: PHA rich biomass, 2: commercial HDPE
pellets, 3: commercial
PHA powder, 4: commercial PHA pellets.
• 10-30% Energy Efficiency;
• 10-50% Carbon
Efficiency.
1 2
3 4
Downstream A – Post-processing of recovered cellulose and PHA for bio-composites
production – London, England.
Semi-pilot extruder
Water cooling
Aim
Incorporate and valorise
the recovered cellulose
and PHA for post-
processing application
(biocomposites  Sludge
Plastic Composite-SPC) –
Formulation of recovered
cellulosic and PHA
materials + extrusion.
Downstream B – Post-processing of cellulosic and P-rich sludges – Manresa WWTP, Spain
Biodrying
Technology
Valorization of high-content cellulosic
sludge (SMARTech 1)
Production of biomass fuel and possible
phosphorous recovery from ashes.
Composting
Technology
Valorization of P-rich sludge (SMARTech 4a)
and nutrient rich mesolites (SMARTech 3)
Production of high quality fertilizers.
1. Composting reactor
(100 L).
2. Biodrying reactor
(100 L).
3. Scale.
4. Air compressor.
5. Monitoring and
control system.
6. Energy meter.
7. Pilot Plant Mobile
structure.
8. Mixer.
1
2
3
4
5
6
7
8
Aim
Valorisation of sludge
and other sub-products
generated in mainstream
wastewater plants of the
project, developing
optimised technologies
for composting and
biodrying of low porosity
materials.
Biodrying
Technology
Composting
Technology
Mixture of P-rich
sludge & Bulking Agent
19
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
ONGOING STEPS: closed value chain with validated techs and marketable
industrial/consumer products
Industrial production of lignocellulosic
PHA biocomposites
Post-processing of recovered
cellulose in mortars and concrete
Pilot-scale production of biocomposites
from raw PHA-rich biomass
Production and testing of phosphorus
bio-fertilizers and biomass fuels
20
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
ONGOING STEPS: Real-Time FootPrinting and DSS
21
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
SMART-Plant benefits
Category Main Benefits
Technical
 Validate and demonstrate that technologies are working well at real
conditions and at demo scale in long-term;
 Technology Verification;
 Solving real operating problems;
Environmental
 Low carbon footprint through online recording of energy and GHG
emissions;
Social
 Social acceptance of derived materials;
 Improved water utility reputation through the use of advance
technologies and ‘green and circular feedstock’;
Financial
 Cost-efficiency;
 Impact on water tariff;
 Circular inter-sectorial value chain with chemical, agricultural and
construction sectors.
22
This project has received funding from the European Union’s Horizon 2020 research and innovation
programme under grant agreement No 690323
Market
ready?
So far in Italy: > 4 WWTPs
are installing SMARTechs in
2018-2019.
Scale-up of low-carbon footprint MAterial
Recovery Techniques in existing wastewater
treatment PLANTs
PHA production
Biogas
Cellulose
Sludge treatment
Nutrients removal
Struvite
Anaerobic digestion
Biomaterial
Ion Exchange
Low-carbon footprint
Bioprocess
Physical and chemical process
Nitrification Denitrification
Filtration
GHG
Membrane
http://www.smart-plant.eu
https://www.facebook.com/smartplant2020/
https://twitter.com/smart_plant_eu
https://www.youtube.com/channel/UCPU0n-w_izmYWX854jULQ7A -
Channel name: Horizon2020 Innovation Action SMART-Plant

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SMART Plant Project - EUBCE2019

  • 1. Scale-up of low-carbon footprint material recovery techniques in existing wastewater treatment plants – General overview of the H2020 project (2016 – 2020) PHA production Biogas Cellulose Sludge treatment Nutrients removal Struvite Anaerobic digestion Biomaterial Ion Exchange Low-carbon footprint Bioprocess Physical and chemical process Daniel Dias • João Ribeiro Nitrification Denitrification Filtration GHG Membrane
  • 2. 2 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 7+2 pilot systems optimised for more than 2 years in real environment in 5 municipal water treatment plants, including also 2 post-processing facilities; Aim of optimising wastewater treatment, resource recovery, energy-efficiency and reduction of greenhouse emissions; Recover biopolymers, cellulose, fertilisers and intermediates and processed up to the final end- products; 26 partners. Instituto de Biologia Experimental e Tecnológica (iBET)  Application and validation of the simulation environment for SMART processes integration. OBJECTIVE: SMART-Plant will scale-up in real environment eco-innovative and energy-efficient solutions to renovate existing wastewater treatment plants and close the circular value chain by applying low- carbon techniques to recover materials that are otherwise lost. . What is SMART-Plant?
  • 3. 3 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 Cellulose Struvite Calcium-P P-Biofertilizer Bio- polymers Biogas and Biomass Fuel Energy and Carbon Efficiency Water re-use and fertigation Scale-up of low-carbon footprint MAterial Recovery Techniques in existing wastewater treatment PLANTs Consumer/IndustrialProducts
  • 4. 4 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 Who is SMART-Plant? • Member of the ICT4WATER cluster; • Member of the European Sustainable Phosphorus Platform
  • 5. 5 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 Impact so far... • SMART-PLANT (HORIZON 2020 PROGRAMME)” won the best Research Project Award at the IWATER Awards 2018 in Barcelona (SOCAMEX). • EYDAP won a golden award at the 2018 Environmental Awards for the SMART-Plant Project • Aquatech Innovation Award 2017 - Overall winner and category: wastewater treatment - by Cellvation cellulose recovery, CirTec, for the SMART-Plant project
  • 6. 6 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 WWTP/WRRF
  • 7. 6 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 WWTP/WRRF SMARTech1 - Geestmerambacht WWTP (NL) SMARTech2b and Downstream SMARTech B - Manresa WWTP (Spain) SMARTech2a – Karmiel WWTP (IL) SMARTech3 – WWTP at Cranfield University (UK) SMARTech 4b - Psyttalia WWTP (Greece) SMARTech 4a and SMARTech 5 Carbonera WWTP (Italy)
  • 8. 7 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 SMART-Plant AchievementsSMARTech n. Integrated municipal WWTP Key enabling process(es) SMART-product(s) 1 Geestmerambacht (Netherlands) Upstream dynamic fine- screen and post-processing of cellulosic sludge Cellulosic sludge, refined clean cellulose 2a Karmiel (Israel) Mainstream polyurethane- based anaerobic biofilter Biogas, Energy- efficient water reuse 2b Manresa (Spain) Mainstream SCEPPHAR Struvite, PHA 3 Cranfield (UK) Mainstream tertiary hybrid ion exchange Nutrients 4a Carbonera (Italy) Sidestream SCENA P-rich sludge, VFA 4b Psyttalia (Greece) Sidestream Thermal hydrolysis – SCENA P-rich sludge 5 Carbonera (Italy) Sidestream SCEPPHAR PHA, struvite, VFA MainstreamSidestream Demos commissioned: June 2017 – Long-term validation: May 2019 Environmental Technology Verification (ETV): tool to help innovative environmental technologies reach the market.
  • 9. 8 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 SMART-Plant Approach Influent Effluent Biogas Dehydrated sludge Water line Sludge line Conventional Primary Sedimentation replaced by Primary Upstream SMARTech1 Conventional Activated Sludge replaced by Secondary Mainstream SMARTechs 2a and/or 2b Conventional or Enhanced Anaerobic Digestion integrated by Sidestream SMARTechs 4a,4b or 5 Conventional Secondary Effluent refined by Tertiary Mainstream SMARTech3
  • 10. SMARTech 1 – Upstream dynamic fine-screen and post-processing of cellulosic sludge Wastewater treatment plant (WWTP) – Geestmerambacht, Netherlands Aim Cellulose recovery from wastewater for cellulosic sludge and refined clean cellulose (e.g building material additive, asphalt material for cycle lanes) Wastewater to cellulosic solid.
  • 11. Aim Reduced loads of COD and TSS on the biological treatment system  Energy- efficient water reuse; Biogas production. Polyfoam filling SMARTech 2a – Mainstream polyurethane-based anaerobic biofilter with biogas recovery WWTP – Karmiel, Israel
  • 12. SMARTech 2b – Secondary mainstream S.C.E.P.P.H.A.R. WWTP – Manresa, Spain Aim Phosphorus recovery (struvite) and PHA sludge production from wastewater. SCEPPHAR pilot plant in Manresa WWTP. SMARTech 3 scheme.
  • 13. SMARTech 3 – Mainstream tertiary nutrient recovery by mesolite and nano ion exchange WWTP – Cranfield, England a) b) HAIX LanXess Formed commercialised Mesolite Aim Nutrients adsorption and recovery for agriculture fertilisers
  • 14. SMARTech 4a – Sidestream SCENA WWTP – Carbonera, Italy DYNAMIC THICKENER FERMENTATION SCREW-PRESS S/L SEPARATION VFAs STORAGE SUPERNATANTS STORAGE VIA-NITRITE scSBR FERMENTER scSBR Aim P-rich sludge and VFA recovery/production Aim Via nitrite, treat anaerobic supernatant rich in ammonium
  • 15. SMARTech 4b pilot plant. SMARTech 4b –Sidestream Thermal hydrolysis – S.C.E.N.A WWTP – Psyttalia, Greece Psyttalia island. Aim Via nitrite, treat anaerobic supernatant rich in ammonium  P-rich sludge recovery/production SMARTech 4b scheme.
  • 16. SMARTech 5 – Sidestream SCEPPHAR WWTP – Carbonera, Italy Aim Phosphorus recovery as struvite; PHA production via feast and famine regime; VFAs production. Nitritation Selection Accumulation Crystalliser for struvite recovery Biomass during PHA accumulation Selected PHA biomass Recovered Struvite (purity and agronomic properties under assessment
  • 17. 16 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 Current Achievements of the Project: Energy and Carbon-Efficient Valuable Materials Recovery in SMART-Plant demos 350 – 400 kg Cellulose a week; 1.0 –1.2 kg PHA per day; > 0.25 – 0.30 kg Struvite per day; 2-3 m3 of biogas per day; 60% of P recovered as CaPO4 from the tertiary treatment; 15-20 kg of P-rich sludge, 60-65 gP/kgTS > 10 kg BioFertilizers per day; 1: PHA rich biomass, 2: commercial HDPE pellets, 3: commercial PHA powder, 4: commercial PHA pellets. • 10-30% Energy Efficiency; • 10-50% Carbon Efficiency. 1 2 3 4
  • 18. Downstream A – Post-processing of recovered cellulose and PHA for bio-composites production – London, England. Semi-pilot extruder Water cooling Aim Incorporate and valorise the recovered cellulose and PHA for post- processing application (biocomposites  Sludge Plastic Composite-SPC) – Formulation of recovered cellulosic and PHA materials + extrusion.
  • 19. Downstream B – Post-processing of cellulosic and P-rich sludges – Manresa WWTP, Spain Biodrying Technology Valorization of high-content cellulosic sludge (SMARTech 1) Production of biomass fuel and possible phosphorous recovery from ashes. Composting Technology Valorization of P-rich sludge (SMARTech 4a) and nutrient rich mesolites (SMARTech 3) Production of high quality fertilizers. 1. Composting reactor (100 L). 2. Biodrying reactor (100 L). 3. Scale. 4. Air compressor. 5. Monitoring and control system. 6. Energy meter. 7. Pilot Plant Mobile structure. 8. Mixer. 1 2 3 4 5 6 7 8 Aim Valorisation of sludge and other sub-products generated in mainstream wastewater plants of the project, developing optimised technologies for composting and biodrying of low porosity materials. Biodrying Technology Composting Technology Mixture of P-rich sludge & Bulking Agent
  • 20. 19 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 ONGOING STEPS: closed value chain with validated techs and marketable industrial/consumer products Industrial production of lignocellulosic PHA biocomposites Post-processing of recovered cellulose in mortars and concrete Pilot-scale production of biocomposites from raw PHA-rich biomass Production and testing of phosphorus bio-fertilizers and biomass fuels
  • 21. 20 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 ONGOING STEPS: Real-Time FootPrinting and DSS
  • 22. 21 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 SMART-Plant benefits Category Main Benefits Technical  Validate and demonstrate that technologies are working well at real conditions and at demo scale in long-term;  Technology Verification;  Solving real operating problems; Environmental  Low carbon footprint through online recording of energy and GHG emissions; Social  Social acceptance of derived materials;  Improved water utility reputation through the use of advance technologies and ‘green and circular feedstock’; Financial  Cost-efficiency;  Impact on water tariff;  Circular inter-sectorial value chain with chemical, agricultural and construction sectors.
  • 23. 22 This project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 690323 Market ready? So far in Italy: > 4 WWTPs are installing SMARTechs in 2018-2019.
  • 24. Scale-up of low-carbon footprint MAterial Recovery Techniques in existing wastewater treatment PLANTs PHA production Biogas Cellulose Sludge treatment Nutrients removal Struvite Anaerobic digestion Biomaterial Ion Exchange Low-carbon footprint Bioprocess Physical and chemical process Nitrification Denitrification Filtration GHG Membrane http://www.smart-plant.eu https://www.facebook.com/smartplant2020/ https://twitter.com/smart_plant_eu https://www.youtube.com/channel/UCPU0n-w_izmYWX854jULQ7A - Channel name: Horizon2020 Innovation Action SMART-Plant