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PRESENTED BY
BAGWAN NADIM M.
F.Y. M.TECH. AUTOMOBILE
UNDER GUIDANCE OF
PROF. S. T. SATPUTE
DEPARTMENT
OF
AUTOMOBILE
ENGINEERING
 Introduction
 Literature review
 Norms for NOx emissions
 NOx control technologies
 Case study
 Conclusion
 References
 Emission elements
 NOx emissions
 Why to control NOx emissions
 Environmental effects
 Human health and NOx emissions
AUTHOR TITLE OF PAPER/
DESCRIPTION
REMARK
Berit Fostas et al.
[3]
Effect of NOx in the
flue gas degradation
1. analyzed the
results through the
Aminox Test Rig
2. Ammonia and
organic acids
(formic, acetic and
oxalic) are the
main degradation
products observed
3. overall degradation
rate of MEA was
accelerated when
NOx impurities
were present in
the gas
AUTHOR TITLE/ DESCRIPTION REMARK
Deshai Notheju
et al.
The use of amine
reclaimer wastes as
a NOx reduction
agent
1. conducted experiments to
use amine reclaimer waste as
NOx reduction agent.
2. carried out in a laboratory
pilot scale test facility,
investigated the possibility of
using ARW.
3. A wide range of
temperatures and
stoichiometric ratios were
tested.
4. monoethanolamine (MEA) as
the absorbent.
AUTHOR TITLE/
DESCRIPTION
REMARK
Bambang Wahono
et al.
Diesel engine
optimization
control methods
for reduction of
exhaust emissions
and fuel
consumption.
1. conducted experiments
on single cylinder diesel
engine for emission
reductions and fuel
consumption
2. fuel efficiency and
emission reductions are
the two consistent
drivers for diesel engine
development.
3. Optimization techniques
are required to utilize
these methods in finding
optimal engine operating
conditions
AUTHOR TITLE/ DESCRIPTION REMARK
D. Kartikeyan
and C. G.
Saravanam
Experimental
analysis of Flyash
based ion exchanged
Fe, Cu and V-X
Zeolite catalysts for
SI engine exhaust
emission control.
1. conventional three-way
catalytic converter used in
gasoline engines, controls
effectively the levels of CO
and HC, but it displays poor
conversion in harmful NOx
emission.
2. fly ash which is relatively
abundant and inexpensive
has been used as a
replacement for expensive
materials.
 Various norms for each country like US
Standards, Euro standards, BS norms
 Euro Norms
 BS norms
 Reducing peak temperature (like FGR, LNB,
LEA, Air staging)
 Reducing residence time at peak
temperature (Inject air or fuel or steam)
 Chemical reduction of Nox (like FR, SCR and
SNCR)
 Oxidation of NOx with subsequent
absorption(NTPR, inject oxidents)
 Removal of nitrogen Using a sorbent (ultra
low nitrogen fuel, supply oxygen instead of
air)
 Engine optimization method
 Engine optimization method
 Catalyst converter using Flyash based
catalyst
 Engine specifications:
Bore * stroke: 78 mm * 80 mm
Top clearance: 0.98 mm
Compr. Ratio: 21.4
Cylinder capacity: 0.382 L
 Particle swarm optimization (PSO) technique
 Basic PSO algorithm
 Introduction
 Catalyst preperation
 Engine used for experiment:
Maruti omni engine (4 stroke SI engine)
no. of cylinders: 3
Displacement vol.- 796 cc
Rated speed: 2500 rpm
Compound Percentage (mass)
SiO2 52.54
Al2 O3 26.74
Fe2 O3 11.12
CaO 1.28
Na2 O 0.47
K2 O 0.82
TiO2 1.57
MgO 0.87
 The optimal control input parameters
obtained by PSO were tested and analyzed.
The result proved that the PSO is an
effective method for engine optimization
problem.
 It shows that the predictive accuracy by
stepwise method considering
multicollinearity is high.
 The In-house made metal zeolite catalysts
performs better than that of commercial 13-
X zeolite catalysts.
 The Cu-Zeolite catalyst showed the best low
temperature NOx reduction performance,
while the Fezeolite catalyst provided the
best high temperature NOx conversion.
 Saroj Kumar Sahu, Gufran Beig and Neha Parkhi, “Emerging
pattern of anthropogenic NOx emissions over Indian subcontinent
during 1990’s and 2000’s”, Atmospheric Pollution Research, p.p.
262-269, 2012.
 David C. Carslaw and Glyn Rhys-Tyler, “New insights from
comprehensive on road measurement of NOx, NO2 and NH3 from
vehicle emission remote sensing in London, UK”, Elsevier
Publication, p.p. 339-347, 2013.
 Berit Fostas, Audun Gangstad, Bjarne Nenster, Steinar Pedersen,
Merethe Sjvoll and Anne Lise Sorensen, “ Effect of NOx in the
flue gas degradation of MEA”, Elsevier Publication, p.p. 1566-
1573, 2011.
 Deshai Notheju, Peter Glarborg and Lars-Andre Tokheim, “The
use of amine reclaimer wastes as a NOx reduction agent”, Elsevier
Publication, p.p. 691-700, 2013.
 M. De las Obras-Loscertales, A. Rufas, L. F. De Diego and A.
Abad, “ Effects of temperature and flue gas recycle on the SO2
and NOx emissions in an oxy-fuel fluidized bed combustor”,
Elsevier Publication, p.p. 1275-1282.
 Xuebin Wang, Zhongfa Hu, Shuanghui Deng and Xiong
Houzhang Tan, “ Effect of biomass/coal firing and air staging on
NOx emissions and combustion efficiency in a drop tubefurnace”,
Elsevier Publication, p.p. 2331-2334, 2014.
 Lifang Guo, Youju Shu and Jummin Gao, “ Present and future
development of flue gas control technology of DeNOx in the
world”, Elsevier Publication, p.p. 397-403, 2013.
 A. D. Srinivasan and K. Chandrashekara, “ NOx Emission control
in bio diesel”, IEEE publication, 2013.
 Isabelle Liemans, Bruno Alban, Jean-Pierre Tranier and
Diane Thomas, “ SOx and NOx absorption based removal
into acidic conditions for the flue gas treatment in oxy-fuel
combustion”, Elsevier Publication, p.p. 2847-2854, 2011.
 Mette Bugge, Oyvind Skreiberg and Morten Seljeskog, “
Predictiong NOx emissions from wood stoves using detailed
chemistry and CFD”, Elsevier Publication, p.p. 1740-1745,
2015.
 Bambang Wahono, Harutoshi Ogai, Jin Kusaka and
Yasumasa Suzuki, “ Diesel engine optimization control
methods for reduction of exhaust emissions and fuel
consumption”, IEEE Publication, p.p. 722-727, 2012.
 D. Kartikeyan and C. G. Saravanam, “Experimental analysis
of Flyash based ion exchanged Fe, Cu and V-X Zeolite
catalysts for SI engine exhaust emission control”, IEEE
Publication, p.p. 657-660, 2013.
SEMINAR

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SEMINAR

  • 1. PRESENTED BY BAGWAN NADIM M. F.Y. M.TECH. AUTOMOBILE UNDER GUIDANCE OF PROF. S. T. SATPUTE DEPARTMENT OF AUTOMOBILE ENGINEERING
  • 2.  Introduction  Literature review  Norms for NOx emissions  NOx control technologies  Case study  Conclusion  References
  • 3.  Emission elements  NOx emissions  Why to control NOx emissions  Environmental effects  Human health and NOx emissions
  • 4.
  • 5.
  • 6. AUTHOR TITLE OF PAPER/ DESCRIPTION REMARK Berit Fostas et al. [3] Effect of NOx in the flue gas degradation 1. analyzed the results through the Aminox Test Rig 2. Ammonia and organic acids (formic, acetic and oxalic) are the main degradation products observed 3. overall degradation rate of MEA was accelerated when NOx impurities were present in the gas
  • 7. AUTHOR TITLE/ DESCRIPTION REMARK Deshai Notheju et al. The use of amine reclaimer wastes as a NOx reduction agent 1. conducted experiments to use amine reclaimer waste as NOx reduction agent. 2. carried out in a laboratory pilot scale test facility, investigated the possibility of using ARW. 3. A wide range of temperatures and stoichiometric ratios were tested. 4. monoethanolamine (MEA) as the absorbent.
  • 8. AUTHOR TITLE/ DESCRIPTION REMARK Bambang Wahono et al. Diesel engine optimization control methods for reduction of exhaust emissions and fuel consumption. 1. conducted experiments on single cylinder diesel engine for emission reductions and fuel consumption 2. fuel efficiency and emission reductions are the two consistent drivers for diesel engine development. 3. Optimization techniques are required to utilize these methods in finding optimal engine operating conditions
  • 9. AUTHOR TITLE/ DESCRIPTION REMARK D. Kartikeyan and C. G. Saravanam Experimental analysis of Flyash based ion exchanged Fe, Cu and V-X Zeolite catalysts for SI engine exhaust emission control. 1. conventional three-way catalytic converter used in gasoline engines, controls effectively the levels of CO and HC, but it displays poor conversion in harmful NOx emission. 2. fly ash which is relatively abundant and inexpensive has been used as a replacement for expensive materials.
  • 10.  Various norms for each country like US Standards, Euro standards, BS norms  Euro Norms  BS norms
  • 11.
  • 12.
  • 13.
  • 14.
  • 15.
  • 16.  Reducing peak temperature (like FGR, LNB, LEA, Air staging)  Reducing residence time at peak temperature (Inject air or fuel or steam)  Chemical reduction of Nox (like FR, SCR and SNCR)  Oxidation of NOx with subsequent absorption(NTPR, inject oxidents)  Removal of nitrogen Using a sorbent (ultra low nitrogen fuel, supply oxygen instead of air)  Engine optimization method
  • 17.  Engine optimization method  Catalyst converter using Flyash based catalyst
  • 18.  Engine specifications: Bore * stroke: 78 mm * 80 mm Top clearance: 0.98 mm Compr. Ratio: 21.4 Cylinder capacity: 0.382 L  Particle swarm optimization (PSO) technique  Basic PSO algorithm
  • 19.
  • 20.
  • 21.
  • 22.
  • 23.  Introduction  Catalyst preperation  Engine used for experiment: Maruti omni engine (4 stroke SI engine) no. of cylinders: 3 Displacement vol.- 796 cc Rated speed: 2500 rpm
  • 24. Compound Percentage (mass) SiO2 52.54 Al2 O3 26.74 Fe2 O3 11.12 CaO 1.28 Na2 O 0.47 K2 O 0.82 TiO2 1.57 MgO 0.87
  • 25.
  • 26.
  • 27.  The optimal control input parameters obtained by PSO were tested and analyzed. The result proved that the PSO is an effective method for engine optimization problem.  It shows that the predictive accuracy by stepwise method considering multicollinearity is high.
  • 28.  The In-house made metal zeolite catalysts performs better than that of commercial 13- X zeolite catalysts.  The Cu-Zeolite catalyst showed the best low temperature NOx reduction performance, while the Fezeolite catalyst provided the best high temperature NOx conversion.
  • 29.  Saroj Kumar Sahu, Gufran Beig and Neha Parkhi, “Emerging pattern of anthropogenic NOx emissions over Indian subcontinent during 1990’s and 2000’s”, Atmospheric Pollution Research, p.p. 262-269, 2012.  David C. Carslaw and Glyn Rhys-Tyler, “New insights from comprehensive on road measurement of NOx, NO2 and NH3 from vehicle emission remote sensing in London, UK”, Elsevier Publication, p.p. 339-347, 2013.  Berit Fostas, Audun Gangstad, Bjarne Nenster, Steinar Pedersen, Merethe Sjvoll and Anne Lise Sorensen, “ Effect of NOx in the flue gas degradation of MEA”, Elsevier Publication, p.p. 1566- 1573, 2011.  Deshai Notheju, Peter Glarborg and Lars-Andre Tokheim, “The use of amine reclaimer wastes as a NOx reduction agent”, Elsevier Publication, p.p. 691-700, 2013.
  • 30.  M. De las Obras-Loscertales, A. Rufas, L. F. De Diego and A. Abad, “ Effects of temperature and flue gas recycle on the SO2 and NOx emissions in an oxy-fuel fluidized bed combustor”, Elsevier Publication, p.p. 1275-1282.  Xuebin Wang, Zhongfa Hu, Shuanghui Deng and Xiong Houzhang Tan, “ Effect of biomass/coal firing and air staging on NOx emissions and combustion efficiency in a drop tubefurnace”, Elsevier Publication, p.p. 2331-2334, 2014.  Lifang Guo, Youju Shu and Jummin Gao, “ Present and future development of flue gas control technology of DeNOx in the world”, Elsevier Publication, p.p. 397-403, 2013.  A. D. Srinivasan and K. Chandrashekara, “ NOx Emission control in bio diesel”, IEEE publication, 2013.
  • 31.  Isabelle Liemans, Bruno Alban, Jean-Pierre Tranier and Diane Thomas, “ SOx and NOx absorption based removal into acidic conditions for the flue gas treatment in oxy-fuel combustion”, Elsevier Publication, p.p. 2847-2854, 2011.  Mette Bugge, Oyvind Skreiberg and Morten Seljeskog, “ Predictiong NOx emissions from wood stoves using detailed chemistry and CFD”, Elsevier Publication, p.p. 1740-1745, 2015.  Bambang Wahono, Harutoshi Ogai, Jin Kusaka and Yasumasa Suzuki, “ Diesel engine optimization control methods for reduction of exhaust emissions and fuel consumption”, IEEE Publication, p.p. 722-727, 2012.  D. Kartikeyan and C. G. Saravanam, “Experimental analysis of Flyash based ion exchanged Fe, Cu and V-X Zeolite catalysts for SI engine exhaust emission control”, IEEE Publication, p.p. 657-660, 2013.