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largest group of elements ,[object Object]
Mostly found as ORES combined with non-metal elements.  Metal + non-metal =  IONIC COMPOUNDS
IONIC COMPOUND ,[object Object],Stable? No Gain e- Give e- Share e- Metallic Lattice Metal
Useful properties that are not found in any other materials.
Metals are used where  strength  of a material is an important factor.
 
Why are metals lustrous?  Why do we see a perfect (but laterally inverted) image in a plane mirror (silvered glass)?
metals covalent molecular covalent network covalent layer IONIC BONDING (microscopic) STRUCTURE & names (Symbolic)  PROPERTIES (macroscopic)
METALS ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
Metal elements have: 1, 2 or 3 valence electrons. E.g. Magnesium 12: 2,8,2 To be stable they lose this last electron and become positively charged according to how many they lose 12p + Mg  2+
Since metal atoms have low electronegativities and they want to be more stable, the outer shell/ valence electron jumps out. These delocalised e-s form the pool/sea of delocalised e-s.  (note: the language of pool/sea).
Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+
YOU DRAW
Mg 2+ METAL LATTICE Electrostatic attraction between  CATIONS  &  Delocalised e- (sea of e-) (e-s free to move) Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+
[object Object],Metallic bonding  = electrostatic attraction  between… …  positive  cations  and  delocalised electrons
 
PROPERTIES
PROPERTIES EXPLAINED BY THE STRUCTURE
E- can absorb quantum of energy and become excited When they fall back they release it as light Metal lattice contains ‘ Free’ e- = almost all differences of energy levels can be  absorbed  and  re-emitted = almost all visible light reflected. =  Lustrous   (shiny) 1
Every  electron  can absorb a specific  quantum  or packet of radiation to become  excited  . "Free" electrons often absorb quanta of visible light.  In metals the outer electrons are essentially "free" electrons and their energy depends on their distance from a nucleus; as there are countless "free" electrons of almost every possible extranuclear distance and energy they can absorb  all the visible light  that falls on the metal surface. However an excited electron re-emits the same absorbed quantum of radiation as it becomes de-excited and most of the radiation that is incident on a metal surface is expelled from the surface thus:  metals are highly reflective  or  lustrous . 1
WHAT IS HAPPENING? (discuss) Good conductor of heat 2
Good conductor of heat ,[object Object],[object Object],2
Note: flow of current is the flow of positive charge, i.e. opposite direction of electron flow WHAT IS HAPPENING? (discuss) 3
Note: flow of current is the flow of positive charge, i.e. opposite direction of electron flow Current = flow of charge Sea of electrons = free to move 3
WHAT IS HAPPENING? (discuss) 4
[object Object],4 Metallic Lattice Electrostatic attraction b/w cations and sea of electrons still present after deformation. Ionic Lattice Electrostatic attraction b/w cations and anions broken
High melting and boiling point To break the lattice the bonds must be broken. The electrostatic force between the sea of electrons and the cations is very strong. Thus it requires lots of energy, therefore it has high melting point and it is hard. (note: the more delocalised electrons the stronger these properties)  The cations and electrons are closely packed together b/c strong… High density 5
Limitations of structure/properties Examples of some exceptions ,[object Object],[object Object],Chronium (brittle)
Properties  (GENERALLY) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Ball bearing model ,[object Object],[object Object]
 
Grain : areas of perfect close-packing of cations ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MODIFYING METALS ,[object Object],[object Object],[object Object]
Work hardening ,[object Object],[object Object],[object Object],[object Object],Bend a wire. What happens?
Heat  treatment Consistent small crystals Smaller crystals Larger crystals Retains hardness, reduce brittleness.  Quenched, warmed again to a lower temperature, cool slowly. Tempered Harder but more brittle (e.g. horseshoes) Heated to red hot, Cooled  quickly  (in cold water) Quenched Softer (restores ductility) Heated to red hot, cooled  slowly Annealed
Alloying ,[object Object],[object Object],[object Object]
Ni-Cu alloy Magnetic alloys are at the heart of a wide range of technological applications from the oldest of structural materials to the next generation of data storage and retrieval devices.
Two types of alloys:  ,[object Object],[object Object]

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Metals Structure Properties

  • 1.
  • 2. Mostly found as ORES combined with non-metal elements. Metal + non-metal = IONIC COMPOUNDS
  • 3.
  • 4. Useful properties that are not found in any other materials.
  • 5. Metals are used where strength of a material is an important factor.
  • 6.  
  • 7. Why are metals lustrous? Why do we see a perfect (but laterally inverted) image in a plane mirror (silvered glass)?
  • 8. metals covalent molecular covalent network covalent layer IONIC BONDING (microscopic) STRUCTURE & names (Symbolic) PROPERTIES (macroscopic)
  • 9.
  • 10.
  • 11. Metal elements have: 1, 2 or 3 valence electrons. E.g. Magnesium 12: 2,8,2 To be stable they lose this last electron and become positively charged according to how many they lose 12p + Mg 2+
  • 12. Since metal atoms have low electronegativities and they want to be more stable, the outer shell/ valence electron jumps out. These delocalised e-s form the pool/sea of delocalised e-s. (note: the language of pool/sea).
  • 13. Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+
  • 15. Mg 2+ METAL LATTICE Electrostatic attraction between CATIONS & Delocalised e- (sea of e-) (e-s free to move) Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+ Mg 2+
  • 16.
  • 17.  
  • 19. PROPERTIES EXPLAINED BY THE STRUCTURE
  • 20. E- can absorb quantum of energy and become excited When they fall back they release it as light Metal lattice contains ‘ Free’ e- = almost all differences of energy levels can be absorbed and re-emitted = almost all visible light reflected. = Lustrous (shiny) 1
  • 21. Every electron can absorb a specific quantum or packet of radiation to become excited . "Free" electrons often absorb quanta of visible light. In metals the outer electrons are essentially "free" electrons and their energy depends on their distance from a nucleus; as there are countless "free" electrons of almost every possible extranuclear distance and energy they can absorb all the visible light that falls on the metal surface. However an excited electron re-emits the same absorbed quantum of radiation as it becomes de-excited and most of the radiation that is incident on a metal surface is expelled from the surface thus: metals are highly reflective or lustrous . 1
  • 22. WHAT IS HAPPENING? (discuss) Good conductor of heat 2
  • 23.
  • 24. Note: flow of current is the flow of positive charge, i.e. opposite direction of electron flow WHAT IS HAPPENING? (discuss) 3
  • 25. Note: flow of current is the flow of positive charge, i.e. opposite direction of electron flow Current = flow of charge Sea of electrons = free to move 3
  • 26. WHAT IS HAPPENING? (discuss) 4
  • 27.
  • 28. High melting and boiling point To break the lattice the bonds must be broken. The electrostatic force between the sea of electrons and the cations is very strong. Thus it requires lots of energy, therefore it has high melting point and it is hard. (note: the more delocalised electrons the stronger these properties) The cations and electrons are closely packed together b/c strong… High density 5
  • 29.
  • 30.
  • 31.
  • 32.  
  • 33.
  • 34.
  • 35.
  • 36. Heat treatment Consistent small crystals Smaller crystals Larger crystals Retains hardness, reduce brittleness. Quenched, warmed again to a lower temperature, cool slowly. Tempered Harder but more brittle (e.g. horseshoes) Heated to red hot, Cooled quickly (in cold water) Quenched Softer (restores ductility) Heated to red hot, cooled slowly Annealed
  • 37.
  • 38. Ni-Cu alloy Magnetic alloys are at the heart of a wide range of technological applications from the oldest of structural materials to the next generation of data storage and retrieval devices.
  • 39.