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Water Treatment
http://www.ecologixsystems.com/images/chemical-jar-tests.jpg
Screening Primary Secondary Disinfection
treatment treatment
(Grit removal) (Settling) (Biological
treatment)
General layout of wastewater treatment plant
Typical Unit Operations of a Wastewater
treatment plant
Solutions: Primary and Secondary
Sewage Treatment
Screen
• First unit operation
• Objective
• Removal of coarse and fine objects, which may get entangled
in mechanical equipment e.g., grit chambers, sedimentation
tanks, etc.
• protection of pump impellers.
• Coarse screenings
• Rocks, twigs, leaves, paper, plastic rags and other materials
Oil & Grease Removal
• Objectives :
• Protect tank walls of subsequent sewage treatment plant
facilities from grease deposits.
• Protect the biological processes, especially air diffusers from
grease deposits.
• They adversely affect bacteria and protozoa life which is
essential in bio-treatment.
• They are difficult to digest, hence the cost of digestion is
increased.
• Oil and grease remover is absolutely necessary, if there is no
primary settling in sewage treatment plant.
Primary clarification/sedimentation
• Sedimentation
• Retention time
• Surface loading rate
• Sludge removal – circular clarifier
• Scraper or plower
Activated sludge processes (ASPs)
• ASP is an aerobic, continuous flow, treatment system that uses sludge with active
populations of microorganisms to breakdown organic matter in wastewater
• Activated sludge is a flocculated mass of microbes
• The organic load (generally coming from primary treatment operations such as
settling, screening or flotation) enters the reactor where the active microbial
population (activated sludge) is present.
• The reactor is continuously aerated.
• The mixture then passes to a secondary settling tank where the cells are settled.
• The cells are recycled in order to maintain sufficient biomass to degrade the
organic load as quickly as possible
Objective
• To reduce the water and organic content of sludge -> easy to handle
• To make it suitable for final disposal or reuse
Sources
• Water Treatment
• Alum waste - gelatinous waste;
- difficult to dewater
• Iron sludge - Inorganic in nature
• sand / silt
• suspended solids
• Activated Carbon
• Non biological decomposition
• Filter backwash ( solid: 0.01-0.1%)
• Softening units (soda/lime)
General aspects of sludge treatment
Fundamentals of Biological Treatment
• Objectives
• To coagulate and remove non-settlable colloidal solids
• To stabilize organic matter/substances
• To remove trace toxic organics
• To remove nutrients
• To reduce inorganic concentration
• All these carried out by microbes
• Based on form of carbon required
Autotrophs (photo-auto/chemo-auto) &
Heterotrophs (photohetero/chemohetero)
• Based on energy source
Phototrophs & Chemotrophs (chemo-organo/chemo-auto)
• Most of the enzymatic reactions involve redox reactions i.e.,
addition/removal of oxygen/hydrogen
• The electron acceptor is based on surrounding medium and cellular
characteristics
• In anaerobic reactions – an oxidized compound is electron
acceptor
• In aerobic reactions – oxygen is acceptor
• Environmental factors that influence microbial growth
• Temperature
 Psychrophilic – (-10 to 30 deg.C) opt. 12–18 0C
 Mesophilic – (20 to 50 deg.C) opt. 25-40 0C
 Thermophilic – (35 to 75 deg.C) opt. 55-65 0C
 facultatives
Fundamentals of biological treatment
Trickling filters
• A trickling filter (TF) is a aerobic attached growth type wastewater
treatment system that biodegrades organic matter and can also be
used to achieve nitrification.
• The wastewater trickles through a circular bed of coarse stones or
plastic material. A rotating distributor (a rotating pipe with several
holes across it) evenly distributes the wastewater from above the
bed.
• The microorganisms in the wastewater attach themselves to the
bed (also known as the filter media), which is covered with
bacteria.
• The bacteria break down the organic waste and remove pollutants
from the wastewater.
Trickling filters
Anaerobic fluidized bed process
• A combination of suspended growth and attached growth process
• Anaerobic microbes grow on the surface of the medium, expanding
the apparent volume of the medium; hence this reactor is also
designated an "expanded bed reactor"
Disinfection
• Any process to destroy or prevent the growth of microbes
• Intended to inactivate the microbes by physical, chemical or
biological processes
• Inactivation is achieved by altering or destroying essential
structures or functions within the microbe
• Inactivation processes include denaturation of:
– proteins (structural proteins, transport proteins, enzymes)
– nucleic acids (genomic DNA or RNA, mRNA, tRNA, etc)
– lipids (lipid bilayer membranes, other lipids)
Disinfection
• Partial destruction of disease causing (pathogenic) organisms
• Characteristics of an ideal disinfectant
• Availability
• Deodourizing ability
• Homogeneity
• Extraneous material interaction
• Non-corrosive and non-staining
• Toxic to microbes but non-toxic to higher organisms
• Penetration
• Solubility and stability
Properties of an Ideal Disinfectant
• Broad spectrum: active against all microbes
• Fast acting: produces rapid inactivation
• Effective in the presence of organic matter, suspended
solids and other matrix or sample constituents
• Nontoxic; soluble; non-flammable; non-explosive
• Compatible with various materials/surfaces
• Stable or persistent for the intended exposure period
• Provides a residual (sometimes this is undesirable)
• Easy to generate and apply
• Economical
Disinfectant Action
• Damage to cell wall and disturbance in cell permeability –
phenolics and detergents
• Damage to protoplasm and cell molecules – Radiation
• Molecular alterations and Inhibition of enzyme activity – Chlorine
and other halogens
• Factors that influence action
• Contact time
• Concentration (chemical)
• Intensity/nature (physical)
• Temperature
• Organisms
• Nature of w/w
Disinfection methods
Chemical Physical Mechanical Radiation
Halogens (Cl)
Ozone
Phenolics
Alcohols
Metals
Detergents,
etc.
Heating
Solar
insolation
Chemical
precipitators
and biofilters
Gamma rad.&
Cobalt-60 rad.
Properties of Water Disinfectants
• Free chlorine: HOCl (hypochlorous) acid and OCl- (hypochlorite ion)
– HOCl at low pH and OCl- at high pH; HOCl more potent germicide than OCl-
– strong oxidant; relatively stable in water (provides a disinfectant residual)
• Chloramines: mostly NH2Cl: weak oxidant; provides a stable residual
• Chlorine dioxide, ClO2,: strong oxidant; unstable (dissolved gas)
Concerns due to health risks of chemical disinfectants and their by-products
(DBPs), especially free chlorine and its DBPs
• Ozone, O3: strong oxidant; provides no residual (too volatile, reactive)
• UV radiation
– low pressure mercury lamp: low intensity; monochromatic at 254
nm
– medium pressure mercury lamp: higher intensity; polychromatic 220-280
nm)
– reacts primarily with nucleic acids: pyrimidine dimers and other alterations
• Boiling: efficient kill; no residual protection; issues ->
fuel/environmental costs
Reverse Osmosis Method for
Cleaning Water
http://lpt.lanxess.com/uploads/tx_lxsmatrix/01_lewabrane_manual_ro_theory.pdf
Contents:
 What is membrane
 What is osmosis
 Design of RO method
 RO method in plant
 Future technological challenges
What is membrane?
A membrane is a selective barrier; it allows some things
to pass through but stops others. Such things may be
molecules, ions, or other small particles.
ORIGIN
MATERIAL
MORPHOLOGY/
STRUCTURE
MEMBRANE
Synthetic Biological
Solid
Liquid
Organic Inorganic
Non-porous Porous
Different types of membranes
A membrane is a selective barrier that permits the
separation of certain species in a fluid by
combination of sieving and diffusion mechanisms.
Membranes can separate particles and
molecules and over a wide particle size range and
molecular weights.
Membrane Processes
Types of Membrane
Based on our applications, there are four
common types of membranes:
Reverse Osmosis
Nanofiltration
Ultrafiltration
Microfiltration
Cont…
Cont…
Osmosis
• Osmosis is the movement of pure solvent (most of the
time it is water) across a semi-permeable membrane
• At first the concentration of solute is very high on the left.
• But over time, the water moves across the semi-
permeable membrane and dilutes the particles.
Osmosis
Diffusion of water across a selectively permeable membrane (a barrier that allows
some substances to pass but not others). The cell membrane is such a barrier.
Small molecules pass through – ex: water
Large molecules can’t pass through – ex: proteins and complex
carbohydrated
Reverse Osmosis
In Reverse Osmosis a pump is used to raise the pressure and the feed
is distributed among a number, n, of modules. The reject is collected
and taken for further treatment, disposal or sale. The permeate is
recovered and constitute the clean stream.
Feed
Reject
Permeate
Reverse Osmosis Performance
Reverse Osmosis can be used in a legion of applications. Some of them
are: seawater desalting, treatment of cheese whey, metal finishing
solutions, bleach and dye plant effluent and waste water from sewage
treatment works.
If clean water and water with some concentration of solute are
separated by a semi-permeable membrane (permeable to only
water) water will be transported across the membrane until
increases hydrostatic pressure on the solute side will force the
process to stop.
Pressure requirements are based on osmotic pressure for R.O
Features of Reverse Osmosis
 It requires energy. Therefore, where the energy Is available but
drinking water is not available
 For water treatment, R.O. application mostly use for
desalination.
 Permeate: almost pure water containing low concentration of ions
 Concentration: having high concentration of small particles and
dissolved ions
Technology Involved for Large Scale RO Plant
 Design of membrane
 Design of integrated system
 Automation
Design integrated system
The purpose of the integrated design is to optimize the design of
the plant (in this case by minimizing the size of the tanks) taking
into account the control strategy. The main purpose of the control
is to be able to supply a water demand over a given timeframe
taking into account a series of restrictions
Future Challenges
Designing of membrane. It has not fully developed yet. Important
development is needed to achieve high water flux
Economy: It is not economically viable since it requires enormous
amount of energy; only rich countries can afford it
Integration: Integration with a suitable post-treatment
Sources of water: Water from multiple sources are difficult to
handle
These need to be addressed based on a total
system approach

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Water Treatment-Water Lecture-3 copy.pptx

  • 2. Screening Primary Secondary Disinfection treatment treatment (Grit removal) (Settling) (Biological treatment) General layout of wastewater treatment plant
  • 3. Typical Unit Operations of a Wastewater treatment plant
  • 4. Solutions: Primary and Secondary Sewage Treatment
  • 5. Screen • First unit operation • Objective • Removal of coarse and fine objects, which may get entangled in mechanical equipment e.g., grit chambers, sedimentation tanks, etc. • protection of pump impellers. • Coarse screenings • Rocks, twigs, leaves, paper, plastic rags and other materials
  • 6. Oil & Grease Removal • Objectives : • Protect tank walls of subsequent sewage treatment plant facilities from grease deposits. • Protect the biological processes, especially air diffusers from grease deposits. • They adversely affect bacteria and protozoa life which is essential in bio-treatment. • They are difficult to digest, hence the cost of digestion is increased. • Oil and grease remover is absolutely necessary, if there is no primary settling in sewage treatment plant.
  • 7. Primary clarification/sedimentation • Sedimentation • Retention time • Surface loading rate
  • 8. • Sludge removal – circular clarifier • Scraper or plower
  • 9. Activated sludge processes (ASPs) • ASP is an aerobic, continuous flow, treatment system that uses sludge with active populations of microorganisms to breakdown organic matter in wastewater • Activated sludge is a flocculated mass of microbes • The organic load (generally coming from primary treatment operations such as settling, screening or flotation) enters the reactor where the active microbial population (activated sludge) is present. • The reactor is continuously aerated. • The mixture then passes to a secondary settling tank where the cells are settled. • The cells are recycled in order to maintain sufficient biomass to degrade the organic load as quickly as possible
  • 10. Objective • To reduce the water and organic content of sludge -> easy to handle • To make it suitable for final disposal or reuse Sources • Water Treatment • Alum waste - gelatinous waste; - difficult to dewater • Iron sludge - Inorganic in nature • sand / silt • suspended solids • Activated Carbon • Non biological decomposition • Filter backwash ( solid: 0.01-0.1%) • Softening units (soda/lime) General aspects of sludge treatment
  • 11. Fundamentals of Biological Treatment • Objectives • To coagulate and remove non-settlable colloidal solids • To stabilize organic matter/substances • To remove trace toxic organics • To remove nutrients • To reduce inorganic concentration • All these carried out by microbes • Based on form of carbon required Autotrophs (photo-auto/chemo-auto) & Heterotrophs (photohetero/chemohetero) • Based on energy source Phototrophs & Chemotrophs (chemo-organo/chemo-auto)
  • 12. • Most of the enzymatic reactions involve redox reactions i.e., addition/removal of oxygen/hydrogen • The electron acceptor is based on surrounding medium and cellular characteristics • In anaerobic reactions – an oxidized compound is electron acceptor • In aerobic reactions – oxygen is acceptor • Environmental factors that influence microbial growth • Temperature  Psychrophilic – (-10 to 30 deg.C) opt. 12–18 0C  Mesophilic – (20 to 50 deg.C) opt. 25-40 0C  Thermophilic – (35 to 75 deg.C) opt. 55-65 0C  facultatives Fundamentals of biological treatment
  • 13. Trickling filters • A trickling filter (TF) is a aerobic attached growth type wastewater treatment system that biodegrades organic matter and can also be used to achieve nitrification. • The wastewater trickles through a circular bed of coarse stones or plastic material. A rotating distributor (a rotating pipe with several holes across it) evenly distributes the wastewater from above the bed. • The microorganisms in the wastewater attach themselves to the bed (also known as the filter media), which is covered with bacteria. • The bacteria break down the organic waste and remove pollutants from the wastewater.
  • 15. Anaerobic fluidized bed process • A combination of suspended growth and attached growth process • Anaerobic microbes grow on the surface of the medium, expanding the apparent volume of the medium; hence this reactor is also designated an "expanded bed reactor"
  • 16. Disinfection • Any process to destroy or prevent the growth of microbes • Intended to inactivate the microbes by physical, chemical or biological processes • Inactivation is achieved by altering or destroying essential structures or functions within the microbe • Inactivation processes include denaturation of: – proteins (structural proteins, transport proteins, enzymes) – nucleic acids (genomic DNA or RNA, mRNA, tRNA, etc) – lipids (lipid bilayer membranes, other lipids)
  • 17. Disinfection • Partial destruction of disease causing (pathogenic) organisms • Characteristics of an ideal disinfectant • Availability • Deodourizing ability • Homogeneity • Extraneous material interaction • Non-corrosive and non-staining • Toxic to microbes but non-toxic to higher organisms • Penetration • Solubility and stability
  • 18. Properties of an Ideal Disinfectant • Broad spectrum: active against all microbes • Fast acting: produces rapid inactivation • Effective in the presence of organic matter, suspended solids and other matrix or sample constituents • Nontoxic; soluble; non-flammable; non-explosive • Compatible with various materials/surfaces • Stable or persistent for the intended exposure period • Provides a residual (sometimes this is undesirable) • Easy to generate and apply • Economical
  • 19. Disinfectant Action • Damage to cell wall and disturbance in cell permeability – phenolics and detergents • Damage to protoplasm and cell molecules – Radiation • Molecular alterations and Inhibition of enzyme activity – Chlorine and other halogens • Factors that influence action • Contact time • Concentration (chemical) • Intensity/nature (physical) • Temperature • Organisms • Nature of w/w
  • 20. Disinfection methods Chemical Physical Mechanical Radiation Halogens (Cl) Ozone Phenolics Alcohols Metals Detergents, etc. Heating Solar insolation Chemical precipitators and biofilters Gamma rad.& Cobalt-60 rad.
  • 21. Properties of Water Disinfectants • Free chlorine: HOCl (hypochlorous) acid and OCl- (hypochlorite ion) – HOCl at low pH and OCl- at high pH; HOCl more potent germicide than OCl- – strong oxidant; relatively stable in water (provides a disinfectant residual) • Chloramines: mostly NH2Cl: weak oxidant; provides a stable residual • Chlorine dioxide, ClO2,: strong oxidant; unstable (dissolved gas) Concerns due to health risks of chemical disinfectants and their by-products (DBPs), especially free chlorine and its DBPs • Ozone, O3: strong oxidant; provides no residual (too volatile, reactive) • UV radiation – low pressure mercury lamp: low intensity; monochromatic at 254 nm – medium pressure mercury lamp: higher intensity; polychromatic 220-280 nm) – reacts primarily with nucleic acids: pyrimidine dimers and other alterations • Boiling: efficient kill; no residual protection; issues -> fuel/environmental costs
  • 22. Reverse Osmosis Method for Cleaning Water http://lpt.lanxess.com/uploads/tx_lxsmatrix/01_lewabrane_manual_ro_theory.pdf
  • 23. Contents:  What is membrane  What is osmosis  Design of RO method  RO method in plant  Future technological challenges
  • 24. What is membrane? A membrane is a selective barrier; it allows some things to pass through but stops others. Such things may be molecules, ions, or other small particles.
  • 26. A membrane is a selective barrier that permits the separation of certain species in a fluid by combination of sieving and diffusion mechanisms. Membranes can separate particles and molecules and over a wide particle size range and molecular weights. Membrane Processes
  • 27. Types of Membrane Based on our applications, there are four common types of membranes: Reverse Osmosis Nanofiltration Ultrafiltration Microfiltration
  • 30. Osmosis • Osmosis is the movement of pure solvent (most of the time it is water) across a semi-permeable membrane • At first the concentration of solute is very high on the left. • But over time, the water moves across the semi- permeable membrane and dilutes the particles.
  • 31. Osmosis Diffusion of water across a selectively permeable membrane (a barrier that allows some substances to pass but not others). The cell membrane is such a barrier. Small molecules pass through – ex: water Large molecules can’t pass through – ex: proteins and complex carbohydrated
  • 32. Reverse Osmosis In Reverse Osmosis a pump is used to raise the pressure and the feed is distributed among a number, n, of modules. The reject is collected and taken for further treatment, disposal or sale. The permeate is recovered and constitute the clean stream. Feed Reject Permeate Reverse Osmosis Performance Reverse Osmosis can be used in a legion of applications. Some of them are: seawater desalting, treatment of cheese whey, metal finishing solutions, bleach and dye plant effluent and waste water from sewage treatment works.
  • 33. If clean water and water with some concentration of solute are separated by a semi-permeable membrane (permeable to only water) water will be transported across the membrane until increases hydrostatic pressure on the solute side will force the process to stop. Pressure requirements are based on osmotic pressure for R.O
  • 34. Features of Reverse Osmosis  It requires energy. Therefore, where the energy Is available but drinking water is not available  For water treatment, R.O. application mostly use for desalination.  Permeate: almost pure water containing low concentration of ions  Concentration: having high concentration of small particles and dissolved ions
  • 35. Technology Involved for Large Scale RO Plant  Design of membrane  Design of integrated system  Automation
  • 36. Design integrated system The purpose of the integrated design is to optimize the design of the plant (in this case by minimizing the size of the tanks) taking into account the control strategy. The main purpose of the control is to be able to supply a water demand over a given timeframe taking into account a series of restrictions
  • 37. Future Challenges Designing of membrane. It has not fully developed yet. Important development is needed to achieve high water flux Economy: It is not economically viable since it requires enormous amount of energy; only rich countries can afford it Integration: Integration with a suitable post-treatment Sources of water: Water from multiple sources are difficult to handle These need to be addressed based on a total system approach