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MONITORING OF LEAD ACID BATTERIES
AN ELTEK WHITE PAPER
DIFFERENT METHODS OF PREDICTING PREMATURE
CAPACITY LOSS

Gunnar Hedlund - 2013-12-19

www.eltek.com
An Eltek White Paper

TABLE OF CONTENT
TABLE OF CONTENT ......................................................................................................... 2 
INTRODUCTION .................................................................................................................. 3 
DIFFERENT METHODS TO PREDICT PREMATURE BATTERY CAPACITY LOSS ...... 3 
Measurement of a significant deviation in the Impedance, conductance or
DC resistance of a battery cell.................................................................................. 4 
A partial discharge test with the battery connected to the load.................... 5 
Ongoing measurement and recording of cell temperature ............................... 6 
Measurement of cell voltage compared to midpoint voltage .......................... 6 
CONCLUSIONS .................................................................................................................... 7 
SUMMARY ........................................................................................................................... 7 
ELTEK`S APPROACH ......................................................................................................... 8 
Smartpack2 Battery Management Capabilities ................................................... 8 
FlexiMonitor .................................................................................................................... 9 
CONTROLLER BATTERY TEST (MONITORING) CAPABILITIES ............................... 9 
REFERENCES..................................................................................................................... 10 
 

Monitoring of Lead-Acid Batteries

2
An Eltek White Paper

INTRODUCTION
No foolproof indicators/tools for knowing and predicting the health and life of a leadacid battery have been evolved or devised. The only way to truly determine the health of
a standby lead-acid battery is to perform a 100 % capacity test, according to the battery
manufacturers discharge table. Such a capacity test means that the battery needs to be
disconnected from the load and another back-up battery connected when the capacity test
is performed. However, comprehensive controllers and instruments are now able to find
failing cells without this test and while the battery system is online.

DIFFERENT METHODS TO PREDICT PREMATURE BATTERY
CAPACITY LOSS
A large number of techniques have been explored and tried out in the field.
No single method or test instrument is capable of foolproof prediction about the
residual capacity without performing a 100% capacity test. On the other hand, by
combining some of them the state of health and expected residual life of the battery
can be predicted more precisely and reliably. This is especially true in the finding of
failing cells in a standby lead-acid battery.

Some of the techniques used for finding failing cells or predicting the state of a
battery’s health and expected residual capacity are:
A) Measurement of a significant deviation (>25%) in the Impedance,
conductance or DC resistance of the cell as compared to the one recorded at
the time of commissioning.
B) A partial discharge test with the battery connected to the load in which the
voltages of each cell in the string are recorded in a test that involves lowering
the rectifier float voltage below the open circuit voltage and discharging the
battery with the connected load current.
C) Measurement and recording of cell temperature periodically.
D) Measurement of cell voltage compared to midpoint voltage.

Monitoring of Lead-Acid Batteries

3
An Eltek White Paper

Measurement of a significant deviation in the impedance,
conductance or DC resistance of a battery cell
There are different methods used in the battery industry to describe internal ohmic
measurements:
– AC Impedance
– AC Conductance
– Resistance
– DC Resistance
All these methods try to find correlation between residual capacity and the given internal
ohmic value. Normally, change in impedance/conductance/resistance of more than 25%
could indicate a good or bad battery cell (see graph below).

The value of each cell shall be verified at the time of commissioning and shall be taken as
the reference value. Different cells from different manufacturers or different lots from the
same manufacturers will have different reference values.
Experimental data show that the internal resistance within a batch of cells (from the same
manufacturer) varies by about ±10% so that a residual capacity determination is afflicted
with at least the same uncertainty.
Conductivity, impedance or resistance measurements should therefore be used as
threshold value detectors (good – not good) instead of exact residual capacity detectors.
A capacity test is also recommended by the manufacturers of different test instruments
for conductivity, impedance or resistance measurement if the readings differ by more
than 20-30 % of the initial reference value.

Monitoring of Lead-Acid Batteries

4
An Eltek White Paper

A partial discharge test with the battery connected to the load
To evaluate the state of the battery bank, a partial discharge test could be performed by
reducing the rectifiers’ output voltage so that the batteries take over the full load current.

Partial battery discharge test

The batteries then become gradually discharged down to a specific end of discharge
value. Usually a Depth of Discharge (DOD) of 30-50% is recommended to give a good
indication of the residual capacity of the battery. However it is difficult to detect the
failure of a single cell when only measuring the overall string voltage as the failed cell
voltage will not manifest itself in the string voltage (see graphs below).

Individual cell discharge voltages

Maximum - individual cell voltages

The more cells that are connected in series, the more difficult to detect a failure of a
single cell. The possibility to detect a failure of a single cell becomes more essential in a
high voltage DC power plant with 50-120 cells in series (110-220 VDC)

Monitoring of Lead-Acid Batteries

5
An Eltek White Paper

Ongoing measurement and recording of cell temperature
The temperature at which the battery works is another important factor that seriously
affects the life of the battery. The chemical reaction in the cell depends mainly on two
factors: the charging voltage and battery temperature. The higher the temperature, the
faster the reaction in the cell. It is also true that the faster the reaction, the battery will
also have a higher level of active material shedding, gassing and grid corrosion. The
gassing may indicate the onset of a thermal runaway in a VRLA battery.
The rule of thumb is that for every 10°C rise in temperature, the operational life of the
battery is reduced by half.
Temperature

Percent life

20°C/ 68°F
25°C / 77°F
30°C / 86°F
40°C / 104°F

100%
71%
50%
25%

In addition to temperature trending, battery health conclusions can be derived from
comparing the intercell temperature of battery blocks or cell within the battery. It has
been recommended that a 3°C temperature difference between cells is a suitable threshold
for indicating the possibility of cell failure.
This is one approach employed during float charging for detecting thermal runaway in
VRLA batteries.

Measurement of cell voltage compared to midpoint voltage
Some battery monitors measure the midpoint voltage of each battery string to detect
voltage deviations within string. In this method, a monitor will create an alarm when
there is a sufficient imbalance in the two half string voltages.

This method can be used to detect faulty cells during float charge or during a partial
discharge test. However, it is difficult to detect the failure of a single cell when
measuring the midpoint voltage in a high-voltage DC system with many cells in series.

Monitoring of Lead-Acid Batteries

6
An Eltek White Paper

CONCLUSIONS
Ohmic resistance readings cannot replace a discharge test to determine percentage
capacity or ampere-hours capacity. Much work has been done and many papers have
been written on this subject, but there is no conclusive proof of the concept and it is
not an accepted industry technique for guaranteed capacity determination.
The correct way to use Ohmic readings is as a trending tool over time to detect
potentially weak or troublesome cells in a VRLA battery string in float in service.
The value of each cell shall be verified at the time of commissioning and shall be taken
as the reference value, and it is essential to follow each cell as the reference value varies
by about ±10% from the same manufacturer.
To evaluate the residual capacity in a lead acid battery, a partial discharge can be
performed to 30%-50 % DOD. Controllers with battery management capability utilizing
specific algorithms designed for various types of batteries are available.
With the possibility of measuring and detecting the failure of a single cell during a
partial discharge test, this method can find a faulty cell without any ohmic resistance
readings.
In addition to these methods, temperature readings of single cells could be a method to
find faulty cells, especially during float charging for detecting thermal runaway in
VRLA batteries.
Midpoint voltage readings of each battery string, to detect voltage deviations within a
string can be used. However it is difficult to detect the failure of a single cell when
measuring the midpoint voltage in a high voltage DC system with many cells in series.

SUMMARY
•

Ohmic measurements are not a substitute for capacity testing and should not
be used to predict absolute capacity values.

•

Ohmic measurements can be used as a trending tool over time in field service
to identify weak cells that may require further evaluation.

•

A partial discharge test with the possibility of detecting a failure of a single
cell can find a faulty cell without any ohmic resistance readings.

•

Temperature readings of single cells could be a method for detecting thermal
runaway in VRLA batteries.

Monitoring of Lead-Acid Batteries

7
An Eltek White Paper

ELTEK`S APPROACH
Eltek’s DC power system can be equipped with our state of the art Smartpack2
Monitoring and Control Unit. It provides a multitude of features that will improve today’s
operations and enable the operations of tomorrow. The Smartpack2 is easy and intuitive
to use through its high resolution display, touch-pad navigation, and icon-based menus
(depicted below in figure 1).

Figure 1 – Smartpack2 Monitoring and Control Unit

The controller provides comprehensive monitoring, reporting, and diagnostics, in a userfriendly format. In the event of an alarm condition, LEDs on the front of the controller
provide immediate visual indicators of major or minor alarms, and whether power is on.
The controller has the ability to automatically store up to 10,000 events or data entries in
its logs. This information can be an invaluable tool for understanding the sequence of
events that led to a failure condition. By connecting a laptop computer to the controller,
operations personnel can access this stored information and diagnostic messages from the
system, enabling them to more quickly determine the root cause of the alarm condition.
The Smartpack2 can also be accessed remotely via Ethernet using a web browser
interface. It supports SNMP protocol and enables the e-mailing of trapped alarms. It
also supports a Modbus and IEC 61850 interface to SCADA systems.

Smartpack2 Battery Management Capabilities
The Smartpack2 includes extensive battery management capability. For example, the
system provides automatic temperature-compensated battery charging, utilizing specific
algorithms designed for various types of batteries. It also supports several automatic and
manual boost charging methods.
Among the Smartpack2’s advanced features is the ability to implement the various
battery testing described earlier in this paper. There are several methods available for
remotely or automatically initiating controlled battery discharges, which provide valuable
information regarding the state of the batteries. The system will provide projections of
battery capacity as well as remaining lifetime.

Monitoring of Lead-Acid Batteries

8
An Eltek White Paper

FlexiMonitor
The Smartpack2 can measure individual cell voltage down to 2 V/cell. Our new CANnode FlexiMonitor also has the possibility to measure individual temperature readings of
single cell or battery block.

FlexiMonitor

Each CAN node can measure up to 16 individual cell voltage or temperature readings
with very high accuracy (10 mV, 1°C). It is possible to connect up to 14 CAN nodes to
each controller which then can be used in high-voltage DC systems up to 220 VDC.
The individual CAN nodes can be placed close to the battery for short voltage or
temperature connections from an individual cell or block.
During a partial discharge test, individual logging of a single cell will be available to
detect a faulty cell in the battery string. All readings of the individual cells will be stored
in the controller and presented in the graphical user interface (GUI) of the master
controller, or via the built-in web interface.

Controller battery test (monitoring) capabilities
•

Evaluation of the residual capacity in a lead acid battery thru a partial
discharge test with built-in algorithms designed for various types of batteries.

•

Midpoint voltage of each battery string, to detect voltage deviations within
string.

•

Readings of single cell or block for detection of faulty cell or block in a
battery string (with FlexiMonitor CAN node), up to 224 individual readings

•

Temperature readings of single cells or block for detection of faulty cell or
block in a battery string (with FlexiMonitor CAN node), up to 224 individual
readings

Monitoring of Lead-Acid Batteries

9
An Eltek White Paper

REFERENCES
1

Enersys Ohmic paper 8-05
Monitoring of VRLA batteries guidelines GL/BAT-04/02 MAR 2007
3
Standby VRLA battery behavioral predictions, University of Canterbury New Zeeland
4
Herbert Giess Product Compliance document PCI1.13 SL
5
Alber training and education, fundamentals of monitoring and ohmic measurements
2

Monitoring of Lead-Acid Batteries

10

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Monitoring of Lead Acid Batteries - an Eltek White Paper

  • 1. MONITORING OF LEAD ACID BATTERIES AN ELTEK WHITE PAPER DIFFERENT METHODS OF PREDICTING PREMATURE CAPACITY LOSS Gunnar Hedlund - 2013-12-19 www.eltek.com
  • 2. An Eltek White Paper TABLE OF CONTENT TABLE OF CONTENT ......................................................................................................... 2  INTRODUCTION .................................................................................................................. 3  DIFFERENT METHODS TO PREDICT PREMATURE BATTERY CAPACITY LOSS ...... 3  Measurement of a significant deviation in the Impedance, conductance or DC resistance of a battery cell.................................................................................. 4  A partial discharge test with the battery connected to the load.................... 5  Ongoing measurement and recording of cell temperature ............................... 6  Measurement of cell voltage compared to midpoint voltage .......................... 6  CONCLUSIONS .................................................................................................................... 7  SUMMARY ........................................................................................................................... 7  ELTEK`S APPROACH ......................................................................................................... 8  Smartpack2 Battery Management Capabilities ................................................... 8  FlexiMonitor .................................................................................................................... 9  CONTROLLER BATTERY TEST (MONITORING) CAPABILITIES ............................... 9  REFERENCES..................................................................................................................... 10    Monitoring of Lead-Acid Batteries 2
  • 3. An Eltek White Paper INTRODUCTION No foolproof indicators/tools for knowing and predicting the health and life of a leadacid battery have been evolved or devised. The only way to truly determine the health of a standby lead-acid battery is to perform a 100 % capacity test, according to the battery manufacturers discharge table. Such a capacity test means that the battery needs to be disconnected from the load and another back-up battery connected when the capacity test is performed. However, comprehensive controllers and instruments are now able to find failing cells without this test and while the battery system is online. DIFFERENT METHODS TO PREDICT PREMATURE BATTERY CAPACITY LOSS A large number of techniques have been explored and tried out in the field. No single method or test instrument is capable of foolproof prediction about the residual capacity without performing a 100% capacity test. On the other hand, by combining some of them the state of health and expected residual life of the battery can be predicted more precisely and reliably. This is especially true in the finding of failing cells in a standby lead-acid battery. Some of the techniques used for finding failing cells or predicting the state of a battery’s health and expected residual capacity are: A) Measurement of a significant deviation (>25%) in the Impedance, conductance or DC resistance of the cell as compared to the one recorded at the time of commissioning. B) A partial discharge test with the battery connected to the load in which the voltages of each cell in the string are recorded in a test that involves lowering the rectifier float voltage below the open circuit voltage and discharging the battery with the connected load current. C) Measurement and recording of cell temperature periodically. D) Measurement of cell voltage compared to midpoint voltage. Monitoring of Lead-Acid Batteries 3
  • 4. An Eltek White Paper Measurement of a significant deviation in the impedance, conductance or DC resistance of a battery cell There are different methods used in the battery industry to describe internal ohmic measurements: – AC Impedance – AC Conductance – Resistance – DC Resistance All these methods try to find correlation between residual capacity and the given internal ohmic value. Normally, change in impedance/conductance/resistance of more than 25% could indicate a good or bad battery cell (see graph below). The value of each cell shall be verified at the time of commissioning and shall be taken as the reference value. Different cells from different manufacturers or different lots from the same manufacturers will have different reference values. Experimental data show that the internal resistance within a batch of cells (from the same manufacturer) varies by about ±10% so that a residual capacity determination is afflicted with at least the same uncertainty. Conductivity, impedance or resistance measurements should therefore be used as threshold value detectors (good – not good) instead of exact residual capacity detectors. A capacity test is also recommended by the manufacturers of different test instruments for conductivity, impedance or resistance measurement if the readings differ by more than 20-30 % of the initial reference value. Monitoring of Lead-Acid Batteries 4
  • 5. An Eltek White Paper A partial discharge test with the battery connected to the load To evaluate the state of the battery bank, a partial discharge test could be performed by reducing the rectifiers’ output voltage so that the batteries take over the full load current. Partial battery discharge test The batteries then become gradually discharged down to a specific end of discharge value. Usually a Depth of Discharge (DOD) of 30-50% is recommended to give a good indication of the residual capacity of the battery. However it is difficult to detect the failure of a single cell when only measuring the overall string voltage as the failed cell voltage will not manifest itself in the string voltage (see graphs below). Individual cell discharge voltages Maximum - individual cell voltages The more cells that are connected in series, the more difficult to detect a failure of a single cell. The possibility to detect a failure of a single cell becomes more essential in a high voltage DC power plant with 50-120 cells in series (110-220 VDC) Monitoring of Lead-Acid Batteries 5
  • 6. An Eltek White Paper Ongoing measurement and recording of cell temperature The temperature at which the battery works is another important factor that seriously affects the life of the battery. The chemical reaction in the cell depends mainly on two factors: the charging voltage and battery temperature. The higher the temperature, the faster the reaction in the cell. It is also true that the faster the reaction, the battery will also have a higher level of active material shedding, gassing and grid corrosion. The gassing may indicate the onset of a thermal runaway in a VRLA battery. The rule of thumb is that for every 10°C rise in temperature, the operational life of the battery is reduced by half. Temperature Percent life 20°C/ 68°F 25°C / 77°F 30°C / 86°F 40°C / 104°F 100% 71% 50% 25% In addition to temperature trending, battery health conclusions can be derived from comparing the intercell temperature of battery blocks or cell within the battery. It has been recommended that a 3°C temperature difference between cells is a suitable threshold for indicating the possibility of cell failure. This is one approach employed during float charging for detecting thermal runaway in VRLA batteries. Measurement of cell voltage compared to midpoint voltage Some battery monitors measure the midpoint voltage of each battery string to detect voltage deviations within string. In this method, a monitor will create an alarm when there is a sufficient imbalance in the two half string voltages. This method can be used to detect faulty cells during float charge or during a partial discharge test. However, it is difficult to detect the failure of a single cell when measuring the midpoint voltage in a high-voltage DC system with many cells in series. Monitoring of Lead-Acid Batteries 6
  • 7. An Eltek White Paper CONCLUSIONS Ohmic resistance readings cannot replace a discharge test to determine percentage capacity or ampere-hours capacity. Much work has been done and many papers have been written on this subject, but there is no conclusive proof of the concept and it is not an accepted industry technique for guaranteed capacity determination. The correct way to use Ohmic readings is as a trending tool over time to detect potentially weak or troublesome cells in a VRLA battery string in float in service. The value of each cell shall be verified at the time of commissioning and shall be taken as the reference value, and it is essential to follow each cell as the reference value varies by about ±10% from the same manufacturer. To evaluate the residual capacity in a lead acid battery, a partial discharge can be performed to 30%-50 % DOD. Controllers with battery management capability utilizing specific algorithms designed for various types of batteries are available. With the possibility of measuring and detecting the failure of a single cell during a partial discharge test, this method can find a faulty cell without any ohmic resistance readings. In addition to these methods, temperature readings of single cells could be a method to find faulty cells, especially during float charging for detecting thermal runaway in VRLA batteries. Midpoint voltage readings of each battery string, to detect voltage deviations within a string can be used. However it is difficult to detect the failure of a single cell when measuring the midpoint voltage in a high voltage DC system with many cells in series. SUMMARY • Ohmic measurements are not a substitute for capacity testing and should not be used to predict absolute capacity values. • Ohmic measurements can be used as a trending tool over time in field service to identify weak cells that may require further evaluation. • A partial discharge test with the possibility of detecting a failure of a single cell can find a faulty cell without any ohmic resistance readings. • Temperature readings of single cells could be a method for detecting thermal runaway in VRLA batteries. Monitoring of Lead-Acid Batteries 7
  • 8. An Eltek White Paper ELTEK`S APPROACH Eltek’s DC power system can be equipped with our state of the art Smartpack2 Monitoring and Control Unit. It provides a multitude of features that will improve today’s operations and enable the operations of tomorrow. The Smartpack2 is easy and intuitive to use through its high resolution display, touch-pad navigation, and icon-based menus (depicted below in figure 1). Figure 1 – Smartpack2 Monitoring and Control Unit The controller provides comprehensive monitoring, reporting, and diagnostics, in a userfriendly format. In the event of an alarm condition, LEDs on the front of the controller provide immediate visual indicators of major or minor alarms, and whether power is on. The controller has the ability to automatically store up to 10,000 events or data entries in its logs. This information can be an invaluable tool for understanding the sequence of events that led to a failure condition. By connecting a laptop computer to the controller, operations personnel can access this stored information and diagnostic messages from the system, enabling them to more quickly determine the root cause of the alarm condition. The Smartpack2 can also be accessed remotely via Ethernet using a web browser interface. It supports SNMP protocol and enables the e-mailing of trapped alarms. It also supports a Modbus and IEC 61850 interface to SCADA systems. Smartpack2 Battery Management Capabilities The Smartpack2 includes extensive battery management capability. For example, the system provides automatic temperature-compensated battery charging, utilizing specific algorithms designed for various types of batteries. It also supports several automatic and manual boost charging methods. Among the Smartpack2’s advanced features is the ability to implement the various battery testing described earlier in this paper. There are several methods available for remotely or automatically initiating controlled battery discharges, which provide valuable information regarding the state of the batteries. The system will provide projections of battery capacity as well as remaining lifetime. Monitoring of Lead-Acid Batteries 8
  • 9. An Eltek White Paper FlexiMonitor The Smartpack2 can measure individual cell voltage down to 2 V/cell. Our new CANnode FlexiMonitor also has the possibility to measure individual temperature readings of single cell or battery block. FlexiMonitor Each CAN node can measure up to 16 individual cell voltage or temperature readings with very high accuracy (10 mV, 1°C). It is possible to connect up to 14 CAN nodes to each controller which then can be used in high-voltage DC systems up to 220 VDC. The individual CAN nodes can be placed close to the battery for short voltage or temperature connections from an individual cell or block. During a partial discharge test, individual logging of a single cell will be available to detect a faulty cell in the battery string. All readings of the individual cells will be stored in the controller and presented in the graphical user interface (GUI) of the master controller, or via the built-in web interface. Controller battery test (monitoring) capabilities • Evaluation of the residual capacity in a lead acid battery thru a partial discharge test with built-in algorithms designed for various types of batteries. • Midpoint voltage of each battery string, to detect voltage deviations within string. • Readings of single cell or block for detection of faulty cell or block in a battery string (with FlexiMonitor CAN node), up to 224 individual readings • Temperature readings of single cells or block for detection of faulty cell or block in a battery string (with FlexiMonitor CAN node), up to 224 individual readings Monitoring of Lead-Acid Batteries 9
  • 10. An Eltek White Paper REFERENCES 1 Enersys Ohmic paper 8-05 Monitoring of VRLA batteries guidelines GL/BAT-04/02 MAR 2007 3 Standby VRLA battery behavioral predictions, University of Canterbury New Zeeland 4 Herbert Giess Product Compliance document PCI1.13 SL 5 Alber training and education, fundamentals of monitoring and ohmic measurements 2 Monitoring of Lead-Acid Batteries 10