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Pulp And Paper 
Manufacturing 
2
How ? 
WHhoyw ? ? 
3
Cellulose Formation 
4
Chemical 
Composition 
5
6
Location Of Plant 
7
8 
Units in the East Godavari Region 
of Andhra Pradesh
9
10 
Rajahmundry
11 
Rajahmundry
12
13
14
De-Fibre Process 
Mechanical Mechanical Pulp 
(90-96%) 
Chemical 
Sulphate Process 
(Alkaline) 
43-52% 
Sulphite Process 
(Acid) 
15
Kraft Process 
 White liquor is a strong alkaline solution mainly of sodium hydroxide 
and Sodium Sulphide 
 White Liquor breaks the bonds between lignin and cellulose 
 Black liquor is the waste product Formed by combining 
lignin, hemicelluloses and other extractives from the wood 
to free the cellulose fibres. 
16
Bleaching 
• Modification of coloured 
substances in the pulp 
• Coloured substances loose the 
ability to fully absorb light 
• Residual lignin and other 
undesired substances are removed 
17
18
19
20
Characteristics Of Pulp and Paper Mill Wastes 
Item Small Mill Large Mill 
20 Tonnes Paper/Day 2000 Tonnes Paper/Day 
Waste Water Produced 330 푚3/Tonne 222 푚3/tonne 
Colour Hz 8000 7800 
pH 8.2-8.5 8.5-9.5 
Total Solids - 4410 
Suspended Solids mg/l 900-2000 3300 
COD mg/l 3400-5780 716 
BOD mg/l 680-1250 155 
COD/BOD 3.9-5 4.6 21
22
Effects of Waste Water 
• The fine fibres often clog the water intake screens in 
the down stream side 
• Toxic effect may also be induced upon the flora and 
fauna of the stream due to sulphites and phenols in the 
waste 
• * Lignin cellulosic material near the point of discharge of 
the waste in a stream undergo slow decomposition by 
the creation of anaerobic condition and destruction of the 
aquatic life 23
24
25
Treatment of Pulp and Paper Mill Wastes 
• 1. Recovery Process 
• 2. Chemical treatment for colour removal 
• 3.Physical treatment 
• 4.Biological treatment 
26
Recovery Process 
• The recovery of the process chemicals and the fibres 
reduces the pollution load to a great extent . 
• Where the economy permits the colour bearing “black 
liquor” is treated for the chemical recovery . 
• The fibres in the white water from the paper mills are 
recovered either by sedimentation or by floatation using 
forced air in the tank. 
• The recovery of lime from the lime mud , by the 
process of calcination, is not practiced in India, due to 
undesirable content of silica in it. 27
Biological Treatment By Stabilisation Ponds 
Anaerobic Ponds Aerobic Ponds 
Loading Rate 56 kg/hectare/day 670 to 1340 kg/hectare/day 
Detention Period 12-30 days 5 days 
Efficiency of Removal 85% 50-95% 
Nutrition Addition (BOD:N:P) Not Required 100:5:1 
28
29 
Screening Lime Treatment 
Equalization & 
Neutralization 
Primary 
Clarifier 
Anaerobic Ponds 
(Detention Period- 
3 Months) 
Aeration Tank Secondary 
Clarifier 
Stabilization 
Ponds 
(depth= 1.5m) 
Activated Carbon 
MLSS , X=4000mg/l
30mg/l 
Activated Sludge Process 
MLSS: 2000-4000mg/l 
30
Trickling Filter 
• Trickling filter has got a limited use in the treatment of the pulp and 
paper mill effluent , due to the greater chances of clogging of the media 
31
32
33

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Pulp and Paper Manufacturing and Treatment Of Waste Water

  • 1.
  • 2. Pulp And Paper Manufacturing 2
  • 3. How ? WHhoyw ? ? 3
  • 6. 6
  • 8. 8 Units in the East Godavari Region of Andhra Pradesh
  • 9. 9
  • 12. 12
  • 13. 13
  • 14. 14
  • 15. De-Fibre Process Mechanical Mechanical Pulp (90-96%) Chemical Sulphate Process (Alkaline) 43-52% Sulphite Process (Acid) 15
  • 16. Kraft Process  White liquor is a strong alkaline solution mainly of sodium hydroxide and Sodium Sulphide  White Liquor breaks the bonds between lignin and cellulose  Black liquor is the waste product Formed by combining lignin, hemicelluloses and other extractives from the wood to free the cellulose fibres. 16
  • 17. Bleaching • Modification of coloured substances in the pulp • Coloured substances loose the ability to fully absorb light • Residual lignin and other undesired substances are removed 17
  • 18. 18
  • 19. 19
  • 20. 20
  • 21. Characteristics Of Pulp and Paper Mill Wastes Item Small Mill Large Mill 20 Tonnes Paper/Day 2000 Tonnes Paper/Day Waste Water Produced 330 푚3/Tonne 222 푚3/tonne Colour Hz 8000 7800 pH 8.2-8.5 8.5-9.5 Total Solids - 4410 Suspended Solids mg/l 900-2000 3300 COD mg/l 3400-5780 716 BOD mg/l 680-1250 155 COD/BOD 3.9-5 4.6 21
  • 22. 22
  • 23. Effects of Waste Water • The fine fibres often clog the water intake screens in the down stream side • Toxic effect may also be induced upon the flora and fauna of the stream due to sulphites and phenols in the waste • * Lignin cellulosic material near the point of discharge of the waste in a stream undergo slow decomposition by the creation of anaerobic condition and destruction of the aquatic life 23
  • 24. 24
  • 25. 25
  • 26. Treatment of Pulp and Paper Mill Wastes • 1. Recovery Process • 2. Chemical treatment for colour removal • 3.Physical treatment • 4.Biological treatment 26
  • 27. Recovery Process • The recovery of the process chemicals and the fibres reduces the pollution load to a great extent . • Where the economy permits the colour bearing “black liquor” is treated for the chemical recovery . • The fibres in the white water from the paper mills are recovered either by sedimentation or by floatation using forced air in the tank. • The recovery of lime from the lime mud , by the process of calcination, is not practiced in India, due to undesirable content of silica in it. 27
  • 28. Biological Treatment By Stabilisation Ponds Anaerobic Ponds Aerobic Ponds Loading Rate 56 kg/hectare/day 670 to 1340 kg/hectare/day Detention Period 12-30 days 5 days Efficiency of Removal 85% 50-95% Nutrition Addition (BOD:N:P) Not Required 100:5:1 28
  • 29. 29 Screening Lime Treatment Equalization & Neutralization Primary Clarifier Anaerobic Ponds (Detention Period- 3 Months) Aeration Tank Secondary Clarifier Stabilization Ponds (depth= 1.5m) Activated Carbon MLSS , X=4000mg/l
  • 30. 30mg/l Activated Sludge Process MLSS: 2000-4000mg/l 30
  • 31. Trickling Filter • Trickling filter has got a limited use in the treatment of the pulp and paper mill effluent , due to the greater chances of clogging of the media 31
  • 32. 32
  • 33. 33

Notas do Editor

  1. APPM was Established as Carnatic Paper Mills in 1921 on the Banks Of River Godavari Unit Operates two mills Unit 1: Wood based capacity 1,80,000 TPA and Paper 1,11,000 TPA Unit 2 : Recycled paper 50,000 TPA and 6500 TPA
  2. Here is Glance of Complete Paper Production
  3. These Picture describes Bark portion removed bark Produce is not a waste but used for Generating Electricity in the industry and maintaining Temperatures in Digestors
  4. After De-barking Process The Wood Is cut in Chips and These Process Is know as Chipping
  5. After The Chipping Process , as I already said These Contains Three Components Lignin,Celloulose ,Hemi Celloulose Sodium sulfide is the chemical compound with the formula Na2S, Sodium sulfate is the sodium salt of sulfuric acid. When anhydrous, it is a white crystalline Na2SO4 Sodium sulfite (sodium sulphite) is a soluble sodium salt of sulfurous acid (sulfite) with the chemical formula Na2SO3.
  6. Sulphate Process is also known as Kraft Process most of the production is Based on these Method After Chipping the Wood is transferred to digester where white Liquor is transferred to the it High Temperature and Pressure is maintained ,White Liquor breaks the bonds between lignin and cellulose Pulp is separated from in the Separator and Cleaned with Water to produce Brown Stock Water or Wash water is transferred to EVA.TANK
  7. Bleaching is done to every pulp depending upon Quality of Paper Required . For Newspaper bleaching is lesser in Concentration Three Process Are involved there are Chlorine ,caustic ,Hypochlorite
  8. This is the one of the effect caused deu to improper treatment of waste water Wer the this pic . anaerobic condition and destruction of the aquatic life dicrbs