Corporate Presentation October 2012

1. TSX-V: CT
OTCQX: CTIIF
Growing Gold Projects in Canada
October 2012
Member of Forbes & Manhattan Group of Companies

2. Forward Looking Statements
The information presented contains “forward-looking statements”, within the meaning of the United States Private Securities Litigation Reform Act of 1995, and
“forward-looking information” under similar Canadian legislation, concerning the business, operations and financial performance and condition of the Company.
Forward-looking statements and forward-looking information include, but are not limited to, statements with respect to estimated production, the estimation of
mineral reserves and mineral resources; the realization of mineral reserve estimates; the timing and amount of estimated future production; costs of production;
capital expenditures; success of exploration activities; permitting time lines and permitting, mining or processing issues; government regulation of mining
operations; environmental risks; unanticipated reclamation expenses; title disputes or claims; litigation liabilities; and limitations on insurance coverage.
Generally, forward-looking statements and forward-looking information can be identified by the use of forward-looking terminology such as “plans”, “expects” or
“does not expect”, “is expected”, “budget”, “scheduled”, “estimates”, “forecasts”, “intends”, “anticipates” or “does not anticipate”, or believes”, or variations of
such words and phrases or state that certain actions, events or results “may”, “could”, “would”, “might” or “will be taken”, “occur” or “be achieved”. Forward-
looking statements and forward-looking information are based on the opinions and estimates of management as of the date such statements are made, and
they are subject to known and unknown risks, uncertainties and other factors that may cause the actual results, level of activity, performance or achievements
of the Company to be materially different from those expressed or implied by such forward-looking statements or forward-looking information. Although
management of the Company has attempted to identify important factors that could cause actual results to differ materially from those contained in forward-
looking statements or forward-looking information, there may be other factors that cause results not to be as anticipated, estimated or intended. There can be
no assurance that such statements will prove to be accurate, as actual results and future events could differ materially from those anticipated in such
statements. Accordingly, readers should not place undue reliance on forward-looking statements and forward-looking information. The Company does not
undertake to update any forward-looking statements or forward-looking information that are incorporated by reference herein, except in accordance with
applicable securities laws.
Dr. Bill Pearson, P.Geo. who is a Qualified Person as defined by National Instrument NI 43-101 and reviewed and approved the scientific and technical
information contained in this presentation.
Cautionary Note to U.S. Investors Concerning Estimates of Measured, Indicated or Inferred Resources.
The information presented uses the terms “measured”, “indicated” and “inferred” mineral resources. United States investors are advised that while such terms
are recognized and required by Canadian regulations, the United States Securities and Exchange Commission does not recognize these terms. “Inferred
mineral resources” have a great amount of uncertainty as to their existence, and as to their economic and legal feasibility. It cannot be assumed that all or any
part of an inferred mineral resource will ever be upgraded to a higher category. Under Canadian rules, estimates of inferred mineral resources may not form the
basis of feasibility or other economic studies. United States investors are cautioned not to assume that all or any part of measured or indicated mineral
resources will ever be converted into mineral reserves. United States investors are also cautioned not to assume that all or any part of an inferred mineral
resource exists, or is economically or legally mineable.
In connection with the recently announced private placement financing, this presentation shall not constitute an offer to sell or the solicitation of an offer to buy
nor shall there be any sale of the securities in any State in which such offer, solicitation or sale would be unlawful. The securities that are subject to the recently
announced private placement financing have not been registered under the United States Securities Act of 1933, as amended, and may not be offered or sold
in the United States absent registration or an applicable exemption from the registration requirements.
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3. Overview
Castillian Resources Corp.
TSX-V:CT, OTQX and CCTIIF
 Canadian mineral exploration company
whose focus is growing Gold projects in
Canada
 Castillian's Flag Ship property is the Hope
Brook Gold Project in southern
Newfoundland
 Updated NI 43-101 Mineral Resource
released for Hope Brook October 2012 only
8 months after initial estimate
 Canadian Creek property in central Yukon
is adjacent Kaminak’s Sugar Gold-in-Soil
Trend
 South American assets are being
monetized/joint ventured
 Strong Board, Management and Technical
Team
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4. 2011: Accomplishments
 Castillian has significantly advanced its flagship Hope Brook Gold Project in Newfoundland
• First NI 43 -101 mineral resource announced February 14, 2012 (filed April 5, 2012), meeting guidance
at 740,000 inferred ounces of gold and 290,000 indicated ounces of gold and in just 16 months of
exploration
• Discovery cost of approximately $10 per resource ounce
• Deposit is open along strike and at depth with a number of major target areas already defined
• Mineralization occurs over 8km+ structure that is very underexplored
• Positive tailing results have the potential to increase current mineral resource estimate
o Average grade of 58 tailings samples tested is 0.96 g Au/t and 0.10% Cu (see April 24, 2012 press
release).
 Substantially advanced Canadian Creek project in Yukon, outlining a 7.5 km long gold-in-
soil anomaly that is associated with a major structure (Press Release dated November 15,
2011)
 Working on completing the sale or joint venture of non-core South American assets
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5. Advancing Hope Brook
2010 2010 2011 2012
February December September June
Acquired Hope Intersected Intersected Successful initial 4,549
Brook Gold 2.41 g Au/t 4.09 g Au/t over metre drill program
Project over 26.5 metres 29.3 metres in Mine testing priority targets
in Pit Zone Zone Extension completed at Hope
Brook
2010 2011 2012 2012
September March February October
Started Drilling Intersected First NI 43 -101 Updated NI 43 -101
Program 4.56 g Au/t Mineral Resource Mineral Resource
over 8.9 metres Exploration Drilling Increasing indicated
in Hanging Wall Recommenced mineral resource
Zone at Hope Brook ounces by 102%
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6. 2012: Moving Castillian Forward
 Updated NI 43-1010 mineral resource announced October 1,
2012 with an increase in indicated resource to 590,000
ounces of gold and a modest reduction of inferred resource to
548,000 ounces of gold through successful conversion of
inferred to indicated
 Successful initial 4,549 metre drill program testing priority
targets completed at Hope Brook
• 5.47 g Au/t over 38.0m
• 3.78 g Au/t over 53.0m and 4.41 g Au/t over 5.0m
 Continue to test tailings
 Complete metallurgical testing
 Continue technical work for PEA
 Sell or joint venture non core assets
 Create a multi-million ounce resource company via drilling and
acquisitions
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7. AMC/M+I+I oz, US$/oz
$100
$125
$150
$175
$200
$25
$50
$75
$0
Torex Gold
Premier Gold
Trelawney
Romarco Minerals
TSX-V: CT OTCQX: CTIIF
Detour Gold
Maudore Minerals
Belo Sun Mining
Upside Potential
Prodigy Gold
Exploreco
Midway Gold
Rainy River…
Amarillo Gold
Rye Patch Gold
Castillian adjusted market capitalization (AMC)
Northern Gold
Magellan Minerals
Chesapeake Gold
CT Undervalued with Tremendous
AMC/oz, US$/oz
Guyana Goldfields
Gryphon Gold
Temex Resources
Forbes Manhattan Equity Research, JR. Golds – Explorers and Developers, AMC/oz Valuations, July 2012 Castillian Resources
Victoria Gold
Average adjusted market capitalization (AMC) for junior gold companies
Probe Mines
Carlisle Goldfields
PC Gold
Sandspring…
$10/oz
$33/oz
Mega Precious Metals
Aurvista Gold
Coral Gold
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Rio Novo

8. Hope Brook Gold: The Flagship Project
 Option to purchase 100%
interest in 993 claims covering
approximately 25,000 ha
 Historical production (1987 –
1997) of 752,163 ounces gold in
time of low gold prices
(<US$400/oz)
 No exploration drilling on property
since 1996 until Castillian started
diamond drilling in 2010
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9. Major Gold Mineralized Structure
more than 8 km in Length
Structure likely
continues under
granite sheet
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10. Large Scale Mineralized System
 Alteration zone Altered &
extends 8+ km along Mineralized
strike with a number of Shear Zone
gold occurrences Open Pit 500+m wide
Helicopter (behind hill)
 Mineralized zone open for scale
along strike in both
directions and at depth
 Major focus is
exploring for more
higher grade zones
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11. Hope Brook Gold Resource Model
548,000 inferred and 590,000 indicated ounces of gold are located within this model
Mine Zone
open
open
240 Zone
open
open
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TSX-V: CT OTCQX: CTIIF

12. Updated NI 43-101 Mineral Resource
NI 43-101 MINERAL RESOURCE ESTIMATE, HOPE BROOK GOLD PROJECT *
as at October 1, 2012
Within constraining shell Below constraining shell
Total
@ 0.50 g Au/t cutoff @ 2.0 g Au/t cutoff
Tonnes Gold Gold Tonnes Gold Gold Tonnes Gold Gold
Category
(millions) (g/t) (oz) (millions) (g/t) (oz) (millions) (g/t) (oz)
Indicated 10.6 1.24 422,000 1.7 2.99 168,000 12.3 1.48 590,000
Inferred 06.4 1.91 397,000 1.8 2.62 151,000 08.3 2.07 548,000
 Constraining shell incorporates essentially all of the remaining historic resources in the
former Hope Brook mine in addition to new areas of resource as defined by Castillian,
including the Pit Zone, Hanging Wall Zone and Mine Zone Extension.
 There is a possible copper credit that is not included in the mineral resource due to
missing copper assays in historical drill holes.
* Full Technical details and notes to the NI 43-101 Mineral Resource Estimate can be found in the Press Release dated October 1, 2012 . A NI 43-
101 Technical Report will be filed within 45 days of this press release.
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13. Growing the Resource
Change in NI 43-101 Indicated Mineral Resource
February 12, 2012  October 1, 2012
548,000oz
1,000,000 oz 740,000 oz
590,000 oz
500,000 oz Indicated Mineral
Resource
290,000 oz Inferred Mineral
Resource
February 2012 September 2012
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14. Major Exploration Upside at Hope Brook
 Deposit is open along strike
and at depth
 Twinned holes typically return
much higher gold and copper
grades compared to historical
holes
 Historic drill holes too short to
test depth extension
 Widespread higher grade
mineralization
 Silicified zones can be traced
using geophysics
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15. Major Targets and Planned Drilling Areas
at Hope Brook
Further drilling planned on priority targets
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16. Applying Technology: Titan 24 Survey at
Hope Brook
Former HB Mine
Extensive Resistivity Low Marks
Footwall Conductor (Blue)
Major
Target
Zone
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17. Hope Brook Gold’s Infrastructure Advantages
 Power from Provincial
Electrical Power Grid
 Wharf on Tide Water
Modern Winterized Camp
 Existing Tailings Ponds
Wharf
 1.2km Long Air Strip Air Strip
 Ramp to 350m below surface
Good Road Network
 Excellent Local Labour Force
Ramp Portal
 Highly rated mining jurisdiction
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18. Corporate Summary
Historical Price to September 30, 2012
CAPITALIZATION $0.14
$0.12
Symbol TSX-V: CT
$0.10
OTCQX: CTIIF
Frankfurt: CY4 $0.08
$0.06
52 Week Trading Range $0.03-0.24 $0.04
$0.02
Price (October 1, 2012) $0.04
$0.00
Average Volume (3 mth) 242,000
Market Cap $13.3 M
MAJOR SHAREHOLDERS
Shares Issued 332 M*
Management and Insiders
Fully Diluted 389 M Pyramis
Ned Goodman Investment Management
Cash at August 2012 $0.5 M
RBC Asset Management
* At the May 9th AGM, a proposed consolidation of Pinetree Capital
Castillian’s issued and outstanding common shares Aberdeen International
on the basis of one (1) post-consolidation common Howson Tattersall
share for every five (5) pre-consolidation common
shares issued and outstanding was passed. TD Asset Management
Source: Bloomberg
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19. Management
Bill Pearson, Ph.D., P.Geo., President & CEO, Director
– Over 37 years of exploration experience from grassroots through to advanced projects and mine
development; former VP Exploration for Desert Sun Mining.
Greg Duras, CGA, CPA, CFO
– Over 14 years of corporate and project finance experience in the resource sector.
Colinda Parent, CFA, Corporate Development
– Extensive capital markets experience having spent more than 15 years in institutional equity sales
and five years in investment banking.
Josh Van Deurzen, JD, MBA, Corporate Secretary
– Corporate and securities lawyer who works as a legal consultant to various public and private
companies in the resource-based sectors.
Kevin Brewer, P.Geo., Manager, Yukon
– Professional geoscientist with over 25 years of mining industry experience.
Chris Hale, Ph.D., P.Geo., Chief Geophysicist
– Exploration geophysicist with more than 35 years experience worldwide.
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20. Board of Directors
David Gower, P.Geo., Chairman
– Over 20 years’ experience with Falconbridge & Noranda (now Xstrata), most recently as GM of
Global Nickel & PGM Exploration.
Bill Pearson, Ph.D., P.Geo., President & CEO, Director
Mike Hoffman, P.Eng., Director
– Professional mining engineer with over 25 years of experience in mine operations, projects,
engineering and corporate development.
Brian Penney, P.Eng., Director
– Twenty years of experience in the mining sector also includes senior operating and environmental
positions in the gold industry, current COO of Alderon Iron Ore Corp.
David S. Warner, MBA, Independent Director
– Accounting professional with 30 year career spent at KPMG LLP, most recently as Partner.
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21. Contact Information
Bill Pearson
President & CEO
president@castillian.ca
+1 416 861 2968
www.castillian.ca
Rob Hopkins
Manager, Investor Relations
rhopkins@castillian.ca
+1 416 309 2895
www.castillian.ca
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TSX-V: CT OTCQX: CTIIF Member of Forbes & Manhattan Group of Companies