Presentation by Dr. Peter Sebaaly, UNR, at the joint L.A.-Orange County Technical Meeting of the California Asphalt Pavement Association (CalAPA) on Sept. 30, 2015 in Carlsbad, Calif.
1. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 1
WMA ADDITIVES
Western Regional Superpave Center
Dept. of Civil & Env. Engineering
University of Nevada
2. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 2
Warm Mix Asphalt
• Definition (FHWA): WMA is the general term used for
technologies that allow producers of asphalt pavement
material to lower the temperatures at which the material is
mixed and placed on the road.
– Reductions of 50 to 100°F have been documented.
3. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 3
Asphalt Mix Temperature Range
Ambient
Below water
vaporization 220°F-280°F 290°F – 345°F
After FHWA Report FHWA-PL-08-007
6. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 6
General WMA Technology Categories
WMA TechnologiesWMA TechnologiesWMA TechnologiesWMA Technologies
Chemical Additives orChemical Additives orChemical Additives orChemical Additives or
SurfactantsSurfactantsSurfactantsSurfactants
CecabaseRT
EvothermTM
HyperthermTM/
Qualitherm
RedisetTM WMX
Foaming ProcessesFoaming ProcessesFoaming ProcessesFoaming Processes
Accu-shear
Advera® WMA
AQUABlack WMA System
AquaFoam
Aspha-min®
Astec Green Systems
Eco-Foam II
LEA (Low Emission Asphalt)
Meeker Warm Mix
Terex® WMA System
Tri-Mix Warm Mix Injection
Ultrafoam GX2TM System
WAM Foam
NonNonNonNon----Foaming AdditivesFoaming AdditivesFoaming AdditivesFoaming Additives
BituTech PER
LEADCAP
Sasobit®
SonneWarmixTM
ThiopaveTM
7. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 7
WMA Technologies
Example: Surfactant
Evotherm 3G
• Chemistry package designed to enhance coating, adhesion, and
workability at reduced temperatures.
– Surfactant – reduces surface tension of asphalt films and allows easier
coating of aggregates
– Anti-strip additive – protects against moisture damage
– Temperature reduction ∼ 55 to 85°F
• Does not change the viscosity of the asphalt
• Asphalt binder can be PG graded
8. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 8
WMA Technologies
Example: Non-Foaming Additives
Sasobit®
• Product of Sasol Wax GmbH (Germany)
• Also known as WAX
– Not the wax that is naturally found in asphalt
– Melting point: 185 -239°F
– soluble in asphalt at temperature above 239°F
• Available in a solid form (prill or flake form)
Prilled Sasobit
Small Prilled Sasobit
Flaked Sasobit
9. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 9
WMA Technologies
Example: Foaming Process
Ultrafoam GX2 System
• Introduces water to cause the AC to foam
• The process of foaming aids in uniform distribution of the
AC around the aggregate surfaces to obtain
– maximum coating
– temporary lowering of the AC viscosity
– improved coating and workability of the mix at lower
temperatures
10. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 10
Economics of WMA (After FHWA)
• Start up costs:
– Foaming Systems… Range in price
From ~ $35,000 to $100,000+
– Additive Systems… most require the
addition of a pneumatic or volumetric
pumping system; Range in price from ~
$7,500 to $40,000
11. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 11
Economics of WMA (After FHWA)
• WMA Technology (Operating) Cost:
Fuel Savings
– Reducing production temperatures from 325ºF (HMA) to
around 265ºF (typical WMA) will save ½ to 1 gallon of fuel
per ton of mix
– Cost savings of approximately 45¢ to 90¢ per ton of mix
12. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 12
Economics of WMA (After FHWA)
• WMA Technology (Operating) Cost:
– Plant Foaming: water is basically free. If a liquid anti-strip
is needed, this adds ~ $1 to $2 / ton
– Additive: $1.75 to 2.50 /ton of mix
–Including fuel savings:
Net cost ~ Zero to $1.50 / ton
19. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 19
Permanent Deformation Model
• Model used to characterize the permanent deformation
behavior of the HMA mixtures:
32
1
aa
r
p
NTa=
ε
ε
20. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 20
Resistance to Fatigue Cracking
100
1,000
10,000
1,000 10,000 100,000 1,000,000
Cycles to Failure
Strain(microns)
Repeated haversine load on long-term oven
aged mixes
21. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 21
Fatigue Cracking Model
• Model used to characterize the fatigue behavior of the
HMA mixtures:
32
11
1
kk
t
f
E
kN
=
ε
25. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 25
Moisture Sensitivity
Condition one Subset: “Wet Set”
Vacuum Saturate (70-80%) with Water
Freeze Cycle at –18oC for 16 hours
Soak at 60oC for 24 hours
Leave other Subset Unconditioned: “Dry Set”
26. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 26
Bring Both Subsets to 25oC and Determine Tensile Strength Ratio
Moisture Sensitivity
TSR = x 100
Avg wet tensile strength
Avg dry tensile strength
29. www.wrsc.unr.edu ; www.arc.unr.edu Slide No. 29
Evaluation of Warm
Mix Asphalt Concrete
Pavement in South
Dakota Conditions
Sponsored by:
South Dakota DOT (Project SD2008-03)
30. Overall Research Objectives
Evaluate various types of WMA paving technologies for
applications in SD.
Assess the performance of WMA test sections during
construction and over time.
Conduct cost versus benefit analysis for WMA.
Research Phases:
Lab evaluation
Field Evaluation
Economic Analysis
31. Summary of Findings from Lab Study
Experimental Plan
3 aggregate sources; 1 binder source (PG64-28).
3 WMA technologies (Advera, Evotherm, Plant Foaming)
All mixes treated with 1% HL by DWA
Mix type
Aggregate source
Quartzite Limestone Natural Gravel
Conventional HMA X X X
WMA-Advera X X X
WMA-Evotherm X X X
WMA-Foaming X X X
HMA-2hrs STA X X --
HMA-Low temp (or WMA w/o Additives) X X X
Optimum Binder Content, % 6.0 4.9 5.5
Absorbed Asphalt Binder, % 0.45 0.21 0.91
36. Rutting Resistance, APA
All mixtures met the max APA rut
depth of 7.0 mm after 8,000 cycles.
Reducing the production
temperatures and short-term aging
increased the rut depth for the
Limestone mixtures.
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
0.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
Quartzite Limestone Natural Gravel
APARutDepthat147°°°°F(64°C),mm
Aggregate Source
WMA-Advera WMA-Evotherm
WMA-Foaming HMA
HMA-2 hrs STA WMA-w/o Additives
37. Rutting Resistance, FN
0
20
40
60
80
100
120
140
0
20
40
60
80
100
120
140
Quartzite Limestone Natural Gravel
FlowNumberat136°°°°F(58°°°°C)
Aggregate Source
WMA-Advera WMA-Evotherm
WMA-Foaming HMA
HMA-2 hrs STA WMA-w/o Additives
Reducing production temperatures & short-
term aging reduced FN values.
WMA may help improving the FN values
compared to WMA w/o additives.
Traffic Level,
Million ESALs
Min FN (HMA) Min FN (WMA)
< 3 NA NA
3 to 10 50 30
10 to < 30 190 105
≥≥≥≥ 30 740 415
38. Thermal Cracking Resistance
-36.0
-34.0
-32.0
-30.0
-28.0
-26.0
-24.0
-36.0
-34.0
-32.0
-30.0
-28.0
-26.0
-24.0
Quartzite Limestone Natural
Gravel
TSRSTFractureTemperature(°°°°C)
Aggregate Source
WMA-Advera WMA-Evotherm
WMA-Foaming HMA
WMA-w/o Additives
Reducing the production
temperatures and short-term aging
lowered the fracture temperature.
The impact of the WMA additives,
on thermal cracking depended on
the type of aggregate.
Quartzite Limestone N. Gravel
AC, % 6.0 4.9 5.5
%Abs AC 0.45 0.21 0.91
40. Summary of Fatigue Cracking Resistance
Reducing the short-term aging time did not have an impact on
the fatigue resistance of the mixtures due to overwhelming
impact of long-term aging
In most cases WMA improved the fatigue resistance of mixtures.
The impact of WMA additives on fatigue resistance depended on
the type of aggregate and the strain level.
41. WMA Field Sections in SD
Project Name Highway 73 Highway 20/79 Highway 18 Highway 262
Date of
Construction
April 2010 June 2010 October 2011 October 2012
Project Location
From Hwy 18 N
to Bennett-
Jackson Co line
From Prairie City
to 2.6 miles west
Bison
Southwest of SD
from Oglala to
Pine Ridge
Southeast of SD
from Alexandria to
Bridgewater
Project Length 12.3 miles 13.9 miles 15.5 miles 17.0 miles
WMA
Technologies
Evotherm Evotherm, Foam
Advera,
Evotherm, Foam
Advera, Evotherm,
Foam
HMA Section Yes Yes Yes Yes
Binder Grade PG64-28 PG64-28 PG64-34 SBS PG58-34
Aggregate Type Natural Gravel Limestone Limestone Quartzite
RAP No No No Yes (20%)
42. QC Measurements: Roughness
IRI Measurements:
Immediately after construction
1 ~ 3 years after construction
SDDOT Assigned Pay Factor
Based on IRI Measurements:
Incentive/Disincentive Pay Table
IRI (in/mile) Price Adjustment ($ per lot)
30.0 or less $600
30.1 to 35.0 $300
35.1 to 40.0 $200
40.1 to 45.0 $100
45.1 to 60.0 $0
60.1 to 65.0 ($100)
65.1 to 70.0 ($200)
70.1 to 80.0 ($300)
80.1 to 90.0 ($600)
90.1 or greater MUST GRIND
52. Resistance to Moisture Damage – E*
• Liquid anti-strip did not consistently improve the resistance to
moisture damage for all evaluated mixtures.
• The addition of 1% lime significantly improved the resistance to
moisture damage for all mixtures.
• The lime treatment was effective with modified binders for
Evotherm & Foaming.
• Both antistrip treatments were effective with modified binders for
Advera & Sasobit.
• Overall, lime treatment with modified WMA mixtures showed better
resistance to moisture damage.
62. Resistance to Fatigue Cracking
Overall Summary
• WMA mixtures with modified binders showed an increase in fatigue
life.
• The rubber-modified binder significantly improved the fatigue life of
the Advera & Sasobit mixtures compared to unmodified binder and
moderately improved the fatigue life of the Advera compared to
polymer-modified binder.
• The lime treatment with polymer-modified binder significantly
improved the fatigue life for Evotherm & Foaming mixtures.
• The liquid antistrip had no effect on the fatigue life of Evotherm &
Foaming mixtures, except rubber-modified liquid treated mixtures.