Spectrolytic has become the pioneer in the supply of cost effective, mid-infrared spectroscopy solutions, offering the lowest cost per measurement point. Spectrolytic’s product portfolio moves the powerful analytical technology of mid-infrared spectroscopy (FTIR) out of the laboratory into the field, providing real time analysis anywhere, anytime.
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Agenda
• Who we are
• Mid-IR Spectroscopy
• Product Portfolio (Current & Future)
• Applications and Examples
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Who is Spectrolytic
Spectrolytic was founded in 2012, to exploit the results of a PhD project
related to a mid-infrared oil sensor for gearboxes in wind turbines
Initially an IP only company with all operations located at Comline, it became
a fully operational commercial entity in 2015 to enable further growth with a
clear strategic focus on providing cost effective spectroscopic solutions.
All current spectroscopy products are still produced at Comline utilizing their
expertise in manufacturing electronic products for harsh environments
Spectrolytic also offers bespoke MEMs / process development service in its
cleanroom facilities. The process development activities are carried out by
world class trained MIT / Cambridge physicists and material experts.
A privately held and self-funded operation with continued positive growth year on year
and offices in Germany, US, UK and Spain.
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Location & Team
• Headquarters – Wackersdorf Germany
• R&D
• SW / HW Development
• Application development
• Manufacturing subcontracted to
Comline Elektronik Elektrotechnik GmbH
• Technology Research Center – Spain
• Advance process and technology research
• Sales, Marketing and Application Support
• UK
• USA – California
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What is mid-infrared spectroscopy
• A broad band emitter shines light through a samples
• The molecules in the sample will absorb certain wavelength of the light whist others pass through the
sample
• The wavelength of the light that is absorbed by the sample can be linked to certain molecular
structures that unequivocally identifies the molecules.
• Typically light in the wavelength range from 2.000nm to 12.000nm (mid infrared wavelength region)
provides the highest absorption signal whiles still providing a unique molecular identifier
• Monitoring the changes in the absorption spectrum of a sample over time provides information about
the concentration of relevant molecules in the sample.
Sample
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wavenumber (cm-1
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transmission(%)
Broad band emitter Absorption spectrum
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Transmission &ATR Spectrometer Principles
multi-element
IR-Emitter
ATR
LVF
Pyroelectric
linearray
oil
multi-element
IR-emitter
cuvette LVF pyroelectric line
sensor
-Light is emitted from broad band source
-Light penetrates cuvette with sample fluid/gas
-Certain wavelength get absorbed by sample
-Light is separated into its spectral components by
Linear Variable Filter (LVF)
-Signals (as function of wavelength) are detected with sensor
-Light is emitted from broad band source
-Light is coupled into an ATR crystal
-Sample fluid is placed on top of ATR crystal
-Light bounces in a controlled way through ATR crystal
and interacts with the sample on its surface
-Certain wavelength get absorbed by sample
-Light is separated into its spectral components by
Linear Variable Filter (LVF)
-Signals (as function of wavelength) are detected with sensor
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Product Portfolio
Static FTIR Spectrometer
Spectral range:
2.5um – 15.5um
7.0um – 15.5um
Voltage supply:
POE / 12V DC,10W
Communication interfaces:
Ethernet
Configurations
Transmission, ATR, Reflection, Gas cell
Features:
World‘s fastest FTIR spectrometer
No moving parts
Gas Spectrometer
Spectral range:
LVF1: 5.5-11µm (1808-909cm-1)
LVF2: 2.5-5µm (4000-2000cm-1)
Voltage supply:
5V / 3W
Communication interfaces:
Ethernet, Bluetooth, USB
Gascell:
Stainless steel, 12cm pathlength
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Product Portfolio
Lab in a Box
• Truly portable solution for instant
analysis.
• Simplified software user interface
to improve usability in the field
• Battery operated
• No need for additional wet
chemistry
• Dedicated solution for
• Biogas engine oil analysis
• Marine engine oil analysis
• FAME analysis
• Milk analysis
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Software - Sphinx Suite
Basic
Automation Chemometrics Prediction Standalone
Option A:
Modulations
Frequenz
Automation
Toolkit
• Definition of measurment
routine
• Continous execution of
measurement routine
• Automatic data capture
• Automatic Reconnect after
PC restart
• Trigger Modus
• Control of extention interface
Chemometrics
Toolkit
• ANN model builder
(Classification)
• PLS1 model builder
(Quantifikation)
• SIX model builder (Similarity
Index)
• Band pass filter model
builder (Industrial
Transmission device)
• Definition of control
parameters
• Saving of models
• Analysis of historic data
(Offline)
Prediction
Toolkit
• Integration in Automation
Toolkit
• Automatic evaluation of
measured IR-spectra
• Visualisation of control
values
• Saving of the analytical
results
• Generating pdf report
Stand allone
Toolkit
• Activation of OCOM
interface
• Transfer of the
automation sequences
onto the spectrometer
• Autonomous
measurement by
spectrometer without PC
Modulation
Toolkit
• Select modulation
freuqency between 5-20
Hz.
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Validated Market Segments
Marine
Wind Turbine
Agricultural
Medical
Fuel
Engine Oils,Grease and Lubricant
Transmission/Gearbox and Hydraulic Oil
Cholesterol, Pulmonary Disorders and Cancer
Dairy: Adulterant Analysis – Urea, Melamine, etc.
Content – Fat, Glucose, Protein etc.
Commodities: Spices, rape seed, etc.
Biofuels, Jetfuel, Diesel and Petrol,
Fuel Genuinity
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Soot measurement in marine engine oils
Samples:
25 unknown samples of engine oil
Explority interpretation of IR
spectra:
IR spectra of uncalibrated oils can be
interpreted as the soot content of
engine oil appears as a baseline shift
of the spectra
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Spektrenübersicht - LVF - marine engine
transmission(%)
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Spektrenübersicht - LVF - MSC- marine engine oil
transmission(%)
Mathematical correction the spectra
can quantify the of the soot content of
the engine oil
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Total Base Number (Biogas engine oil)
Öltyp:
Addinol GMO MG 40 Extra
PLUS
Quantitative Interpretation of
IR spectra:
Calibration files available from
oil analysis partners
Spectrolytic has established
relationships with a number of
reputable oil analysis labs
TBN can be measured very
accurately.
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spectra - LVF - biogas engine oil
transmission(%)
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measured y
predictedy
Spectrometer: LVF - parameter: TBN
samples
target line
regression line
RMSE0.2279
SE0.2375
R 0.9957
R-Square 0.9912
y = 1.0030x+ 0.0086
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Water contamination (Windturbine gear oil)
Absorptionsbands of water
v1: 3280 cm-1 (streck)
v2: 1644 cm-1 (beuge)
v3: 3490 cm-1 (streck)
Concentrations range of system:
250 – 5000 ppm
Plenty of scope to optimise
measurable water concentration if
required.
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Klüber Synth GEM4-320N - LVF spectra raw data
transmission(%)
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Analysis of raw milk (Agriculture)
• The analysis of the raw milk as
close as possible to the cow is
very important:
• Milk quality provides instant
information about health of cow
• Milk quality can be used to
optimise feeding of cows
• Provides the farmer with
information about the quality of
the milk
• Additional parameters that can be
measured are fat content, protein
content, milk contamination (urea,
melamine) and many more
Lactose concentration in raw milk
Water concentration in raw milk
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Differentiate cancerous from non-cancerous samples
• Infrared absorption spectra of all
samples are shown on the right.
• Offset shifts in y-direction are due to
variability in sample preparation.
• The Partial Least Square (PLS1)
method was used to analyse the data
using SphinxSuite
• Analysis of mid-infrared absorption
spectra allows to differentiate between
cancerous and non-cancerous
samples
• R2 = 0.9 with limit sample numbers
• 5 principle components
Cancerous
Non -Cancerous
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Spectrolytic‘s products can address all required
measurement needs
Spectrolytic current products address many of the relevant measurement problems
related to oil condition monitoring
Infrared absorption measurements of samples are a recognised and well established
technology
Spectrolytic products moved this technology out of the laboratory into the field /
processing plants
Next step is to bring this powerful technique to more mainstream application by
maintaining the accuracy of the measurements but bringing down the costs.
We believe the automotive & industrial market are very interesting market segments
and we currently identifying suitable partners with market insight and sales channels
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More stringent regulations by governments drive require
the cost per measurement to decrease
low
Number of measurements
Costpermeasurement
high
lowhigh
FTIR
Industrial fixed Spectrometer
Handheld Spectrometer
Application Specific Solutions
Spectrolytic
existing
business
Product Road Map
Industry 4.0 demand lower cost per measurement for the IoT of things
Government & regulators impose ever stricter environmental controls requiring novel
engine / software solution.
Non complying becomes increasingly difficult after VW scandal
Spectrolytic & partner(s) provide route for a cost effective sensor solution
to solve many challenging measurement problems
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Spectrolytic‘s cost effective sensor solution
Many applications use the same oil and therefore the absorption spectra from engine
to engine are very similar
Spectrolytic has developed a software that identifies key wavelength bands for each
relevant oil parameter for a specific oil type.
These parameters can then be translated into an application specific oil sensor
being able to measure any number of oil parameters.
These oil sensors can be very robust, accurate and cost effective
The same concept described above maps onto any other application
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Discrete filter solution performance matches FTIR
performance
Addinol GL 80 W
(Glysantineintrag)
Addinol GL 80 W
(Wassereintrag)
Addinol GMO MG 40
Extra Plus (gealtert)
Tectrol MethaFlexx ZS
Plus (gealtert)
Texaco Meropa 320
(gealtert)
Wasser 1.00 1.00 0.98 0.97 0.18
Ruß 1.00 0.97 0.99
Oxidation 0.99 0.99 0.90
Nitration 0.82 0.82
Sulfation 1.00 1.00 0.99
ZDDP 0.93 0.92 0.94
Glycol 1.00
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Zielgröße (ASTM E2412)
Zielgröße(Bandpassfilter)
Addinol GMO MG 40 Extra PLUS - Oxidation
Target
Regression Fit
Data
Simulation results based on infrared spectra
of used engine oils claculating the
parameter OXIDATION.
Bandpass filters were selected appropriately
and R² was calculated. Results are
referenced agains the ASTM E2412
standard
Table showing different oil parameters calculated from used engine oil samples measured with a FTIR and
simulated Bandpassfilters. R² was calculated against ASTM E2412.
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Spectrolytic‘s cost effective sensor platform for
industrial and automotive applications
Optical window or Lense
Coms: USB / UART
3x PZTSensor
1
2
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Stack system + Optical frontend
Reference design services for industrial and consumer applications based on modular
system design and application know-how.
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Summary
Spectrolytic has an exciting technology that addresses many problems that are
currently relevant in the automotive and industrial market segments
Applications we are already working on are oil condition monitoring,
gas detection, medical (cancer & COPD) and milk analysis
The technology is scalable, proven and can meet the cost targets required for
automotive and other high volume applications
Spectrolytic is currently evaluating additional partners with relevant market
knowledge and sales channels to enter high volume industrial & automotive
makets.