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Deformation of solids
Unit 2
Deformation of Solids
•
•
•
•
•
•
It is possible to change the shape or size (or both) of an object
through the application of external forces
It is described as strain.
As deformation occurs internal inter molecular forces arise
that oppose the applied force.
If the applied force is not too great these internal forces are
sufficient to completely resists the applied force and allow the
object to assume a new equilibrium state and to return to its
original state when the load is removed.
A larger applied force may lead to a permanent deformation of
the object or even to its structure failure.
Depending upon the type of material, size and geometry of the
object and the forces applied various deformation may result.
Elastic Deformation
•
•
•
•
It is reversible.
when the forces are removed, the object tends to
its original shape.
Elastomers and shape memory metals such as
nitinol exhibit large elastic deformation ranges as
does rubber. Elasticity is non linear. Metals and
ceramics show linear elasticity.
Linear elastic deformation is governed by Hooke’s
Law
σ = E ε
Where σ is applied stress, E is material constant
called young’s modulus or elastic modulus and ε
is the resulting strain.
•
•
•
The relationship indicates that the slope
of stress vs. strain curve can be used to
find the elastic or young modulus E.
The elastic range ends when the material
reaches its yield strength.
At this point plastic deformation begins.
Elastic Modulus
•
–
–
•
–
The elastic modulus is the constant of
proportionality between stress and strain
For sufficiently small stresses, the stress is directly
proportional to the strain
The constant of proportionality depends on the
material being deformed and the nature of the
deformation
The elastic modulus can be thought of as
the stiffness of the material
A material with a large elastic modulus is very
stiff and difficult to deform
Elastic Modulus
s t r e s s = E la s t ic m o d u lu s × s t r a in
Young’s Modulus
•
•
–
•
–
•
Tensile stress is the ratio of the external
force to the cross-sectional area
SI units of stress are Pascals, Pa
1 Pa = 1 N/m2
The tensile strain is the ratio of the change
in length to the original length
Strain is dimensionless
The elastic modulus is called Young’s
modulus
o
F L
Y
A L


Plastic Deformation
•
•
•
•
It is irreversible.
Object in plastic deformation range will first have
undergone elastic deformation which is reversible
so the object will partly return to its original shape.
Soft thermoplastic materials have rather large
plastic deformation range as do ductile metals
such as copper, silver and gold. An example of a
material with a large plastic deformation range is
a wet chewing gum which can be stretched
dozens of its times its original length.
Hard thermosetting plastics, rubber and ceramics
have minimal plastic deformation ranges.
•
1.
2.
3.
Under the tensile stress plastic deformation is
characterized as
Strain hardening region – material becomes
stronger through the movement of atomic
dislocations
Necking region – reduction in cross sectional
area of specimen. It begins after the ultimate
strength is reached. Material can no longer
withstand the maximum stress and strain in
the specimen rapidly increases
Fracture- indicates the end of the plastic
deformation
Breaking
•
–
•
–
–
If stress continues, it surpasses its ultimate
strength
The ultimate strength is the greatest stress the object
can withstand without breaking
The breaking point
For a brittle material, the breaking point is just beyond
its ultimate strength
For a ductile material, after passing the ultimate
strength the material thins and stretches at a lower
stress level before breaking
Shear Modulus
•
•
•
It defines the change in shape of an object
caused by pushing its top and bottom
surfaces in opposite directions.
Shear stress is the force per unit area
exerted on the top and bottom of solid.
Shear strain is the distance the top
surface has moved relative to the bottom
surface divided by the perpendicular
distance between them.
•
•
Shear Modulus is the ratio of shear stress to
shear strain and has a unit of N/m2.
S = Shear stress / Shear Strain
= F/A
∆x/h
Where
F is applied force: A is area, ∆x is the distance
the top surface has moved relative to bottom
surface, and h is perpendicular distance
between the top and bottom surfaces.
Shear Modulus, final
•
•
•
S is the shear modulus
A material having a
large shear modulus is
difficult to bend
F
s h e a r s t r e s s
A
x
s h e a r s t r a in
h
F x
S
A h





Bulk Modulus:
Volume Elasticity
•
–
•
•
Bulk modulus characterizes the response
of an object to uniform squeezing
Suppose the forces are perpendicular to, and
act on, all the surfaces
Example: when an object is immersed in a fluid
The object undergoes a change in volume
without a change in shape
Bulk Modulus, cont.
•
–
•
Volume stress, ∆P, is
the ratio of the force
to the surface area
This is also the
Pressure
The volume strain is
equal to the ratio of
the change in
volume to the
original volume
Heckel Equation
•
•
The variations in volume with applied
pressure are defined by way of numerous
equations among which Heckel theory is
most vital. Heckel measured that decline
in the voids follows the first order kinetics
connection with applied pressure. For
compression method heckel has
suggested following equation
ln(V/V- Vα) = KP + (Vo/ Vo- Vα)
•
•
•
•
•
Where V= volume at the applied pressure P
Vo= original volume of the powder including
the voids
Vα= volume of the powder excluding the voids
K = constant related to the yield pressure of
the powder
P = Applied pressure
as we know porosity E is the ratio of the total
volume of the void space to the bulk volume
of the powdered material
E= V- Vα / V
Replacing the value in previous equation it
becomes
ln(1/E) = KP + (Vo/ Vo- Vα)
Bulk Modulus, final
•
•
–
•
A material with a large bulk modulus is difficult
to compress
The negative sign is included since an increase
in pressure will produce a decrease in volume
B is always positive
The compressibility is the reciprocal of the bulk
modulus
V
P B
V

  

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Deformation of solids (Physical Pharmaceutics)

  • 2. Deformation of Solids • • • • • • It is possible to change the shape or size (or both) of an object through the application of external forces It is described as strain. As deformation occurs internal inter molecular forces arise that oppose the applied force. If the applied force is not too great these internal forces are sufficient to completely resists the applied force and allow the object to assume a new equilibrium state and to return to its original state when the load is removed. A larger applied force may lead to a permanent deformation of the object or even to its structure failure. Depending upon the type of material, size and geometry of the object and the forces applied various deformation may result.
  • 3. Elastic Deformation • • • • It is reversible. when the forces are removed, the object tends to its original shape. Elastomers and shape memory metals such as nitinol exhibit large elastic deformation ranges as does rubber. Elasticity is non linear. Metals and ceramics show linear elasticity. Linear elastic deformation is governed by Hooke’s Law σ = E ε Where σ is applied stress, E is material constant called young’s modulus or elastic modulus and ε is the resulting strain.
  • 4. • • • The relationship indicates that the slope of stress vs. strain curve can be used to find the elastic or young modulus E. The elastic range ends when the material reaches its yield strength. At this point plastic deformation begins.
  • 5.
  • 6. Elastic Modulus • – – • – The elastic modulus is the constant of proportionality between stress and strain For sufficiently small stresses, the stress is directly proportional to the strain The constant of proportionality depends on the material being deformed and the nature of the deformation The elastic modulus can be thought of as the stiffness of the material A material with a large elastic modulus is very stiff and difficult to deform
  • 7. Elastic Modulus s t r e s s = E la s t ic m o d u lu s × s t r a in
  • 8. Young’s Modulus • • – • – • Tensile stress is the ratio of the external force to the cross-sectional area SI units of stress are Pascals, Pa 1 Pa = 1 N/m2 The tensile strain is the ratio of the change in length to the original length Strain is dimensionless The elastic modulus is called Young’s modulus o F L Y A L  
  • 9. Plastic Deformation • • • • It is irreversible. Object in plastic deformation range will first have undergone elastic deformation which is reversible so the object will partly return to its original shape. Soft thermoplastic materials have rather large plastic deformation range as do ductile metals such as copper, silver and gold. An example of a material with a large plastic deformation range is a wet chewing gum which can be stretched dozens of its times its original length. Hard thermosetting plastics, rubber and ceramics have minimal plastic deformation ranges.
  • 10. • 1. 2. 3. Under the tensile stress plastic deformation is characterized as Strain hardening region – material becomes stronger through the movement of atomic dislocations Necking region – reduction in cross sectional area of specimen. It begins after the ultimate strength is reached. Material can no longer withstand the maximum stress and strain in the specimen rapidly increases Fracture- indicates the end of the plastic deformation
  • 11. Breaking • – • – – If stress continues, it surpasses its ultimate strength The ultimate strength is the greatest stress the object can withstand without breaking The breaking point For a brittle material, the breaking point is just beyond its ultimate strength For a ductile material, after passing the ultimate strength the material thins and stretches at a lower stress level before breaking
  • 12. Shear Modulus • • • It defines the change in shape of an object caused by pushing its top and bottom surfaces in opposite directions. Shear stress is the force per unit area exerted on the top and bottom of solid. Shear strain is the distance the top surface has moved relative to the bottom surface divided by the perpendicular distance between them.
  • 13. • • Shear Modulus is the ratio of shear stress to shear strain and has a unit of N/m2. S = Shear stress / Shear Strain = F/A ∆x/h Where F is applied force: A is area, ∆x is the distance the top surface has moved relative to bottom surface, and h is perpendicular distance between the top and bottom surfaces.
  • 14. Shear Modulus, final • • • S is the shear modulus A material having a large shear modulus is difficult to bend F s h e a r s t r e s s A x s h e a r s t r a in h F x S A h     
  • 15. Bulk Modulus: Volume Elasticity • – • • Bulk modulus characterizes the response of an object to uniform squeezing Suppose the forces are perpendicular to, and act on, all the surfaces Example: when an object is immersed in a fluid The object undergoes a change in volume without a change in shape
  • 16. Bulk Modulus, cont. • – • Volume stress, ∆P, is the ratio of the force to the surface area This is also the Pressure The volume strain is equal to the ratio of the change in volume to the original volume
  • 17. Heckel Equation • • The variations in volume with applied pressure are defined by way of numerous equations among which Heckel theory is most vital. Heckel measured that decline in the voids follows the first order kinetics connection with applied pressure. For compression method heckel has suggested following equation ln(V/V- Vα) = KP + (Vo/ Vo- Vα)
  • 18. • • • • • Where V= volume at the applied pressure P Vo= original volume of the powder including the voids Vα= volume of the powder excluding the voids K = constant related to the yield pressure of the powder P = Applied pressure as we know porosity E is the ratio of the total volume of the void space to the bulk volume of the powdered material E= V- Vα / V Replacing the value in previous equation it becomes ln(1/E) = KP + (Vo/ Vo- Vα)
  • 19. Bulk Modulus, final • • – • A material with a large bulk modulus is difficult to compress The negative sign is included since an increase in pressure will produce a decrease in volume B is always positive The compressibility is the reciprocal of the bulk modulus V P B V    