This document summarizes a study of the technogenic water body that has formed in closed oil shale mines in Estonia. Key findings include:
1) A large interconnected technogenic water body has formed across multiple closed and flooded underground oil shale mines in central Estonia. The water levels and quality within this body are analyzed.
2) Water quality testing of samples from four mines show average sulfate and iron levels exceeding drinking water standards, though decreasing over time. Variation is influenced by mine location and time since closure.
3) Modeling of the water table shows the mines forming a relatively stable interconnected water body. Water quality is improving over time, with sulfate and iron levels predicted to meet drinking water
2. E. Reinsalu, I. Valgma, H. Lind, K. Sokman
16
Table 1. Closed and flooded underground oil shale mines
Mine
Closed –
(pumps
were
stopped)
Mined
area,
km2 *
Water table
a.s.l.,
m
Outflow regulating
the water table
Approximate
water volume,
106 m3
Central part of the deposit:
Kukruse
1967
13
51–54
Mostly into Käva and
Jõhvi mines
3.5–6**
Käva and
Käva-2
1973
18
51–52
From an old adit into
Vahtsepa ditch
9–11**
Mine No. 2
(Jõhvi mine)
1974
13
51–56
Mostly into Tammiku
mine, during flood
to Jõhvi city
10–11**
Mine No. 4
1975
13
41–42
Mostly into neighbouring mines
3–8**
Tammiku
December
1999
40
44–48
Into the Kose River
and Viru mine
34
Sompa
February
2000
27
40–45
Into neighbouring
mines
23
Kohtla
June
2001
17
39–42
Into Aidu opencast
13
Ahtme
December
2001 –
December
2002
35
From drill holes and
springs into Sanniku
brook
36
From a ditch into the
Purtse River
Up to 29
From an adit into the
Toolse River
Not determined
47
≈
Separate mines in the western part of the deposit
Ubja
1960
2
Total
41
0.5
55
≈
29
≈
1989
±
Kiviõli &
Küttejõu
170
* [5]
** Depending on the water level [6]
As a rule, the mine workings and groundwater cone of depression formed
during mining fill with water after the cease of mine pumping. The degree of
filling depends on the mining depth and the height of outflow. The tunnels of
Ahtme, Sompa and Tammiku mines are completely, those of mines Nos. 2
and 4 almost completely water-filled. The rest of the mines (Kiviõli, Kukruse
and Käva) contain areas with dry floor. The museum founded in Kohtla mine
is dry because of to the draining effect of Aidu opencast and the water
barriers surrounding the exposition area. The water level changes depending
3. Technogenic Water in Closed Oil Shale Mines
17
50
Water level, m
45
40
35
30
25
20
15
10
2002
2003
Tarakuse well
2004
2005
Pagari well
Fig. 1. Increase in the water table in closed Ahtme mine
on the amount of precipitation and water exchange with neighbouring mines.
The rate and amplitude of the changes differ from mine to mine.
Several problems have arisen from the flooding of the closed mines.
First, the technogenic water body started to affect the amount of the water
pumped out of the working mines and its seasonal variation [2]. Clearly, the
water of the closed mines will influence also the new mines, planned to be
constructed in the Ojamaa and Uus-Kiviõli mine fields. Second, the environment is affected by the water that in several places has risen to the premining level (of the year 1945) and by the new springs formed. Several
projects have been undertaken to fight the flooding, and it has turned out that
no sufficient source data for mine planning are available. Third, the water of
the closed mines is an easily accessible water resource, thus it is important to
know and predict its quality [3]. Prediction of the mine water quality is
essential also because of the fact that groundwater elevation in the mine field
has started to affect the water supply of the region – the water richer in
sulphates runs into the outdated and leaky common wells. It has also been
prognosticated that if the groundwater table rises higher than 45–47 m, the
water in the Ahtme mine field will affect the water level and quality of the
Vasavere intake [4]. Fourth, the land above old mines has subsided and the
rocks are fractured, therefore the technogenic groundwater is weakly protected
and the contribution of precipitation to groundwater formation is very high.
Water level
The present study is based on the water level measurement data (incl.
archive data) provided by the Estonian Oil Shale Company, Geological
4. E. Reinsalu, I. Valgma, H. Lind, K. Sokman
Fig. 2. Map of the technogenic water body
18
5. Technogenic Water in Closed Oil Shale Mines
19
Survey of Estonia and Municipality of the town of Jõhvi. The water levels of
the Keila–Kukruse, Lasnamäe–Kunda and Nabala–Rakvere aquifers, closed
mines and main outlets were measured on an average period of 20 years.
New data were obtained in the years 2003 and 2004. Field works and
monitoring started in the spring of 2004 and are still going on.
An essential part of the research was the modelling of the level of the
Keila–Kukruse aquifer in the stationary regime. The modelling area included
the central part of the deposit – underground mines and Aidu opencast. Data
from about 50 observation wells were used. The water level of working mines
was described at the level of the oil shale bed floor. Closed mines were treated
as independent water sub-bodies, where the water level is constant at a certain
moment of time (Table 1). The MapInfo Professional software was used,
combined with the modelling package Vertical Mapper. The comparison and
calibration of the intermediate results obtained and discussions held showed
that the best interpolation method was triangulation with smoothing, because
in that case interpolation takes place only between data points or observation
wells, without modelling the situation outside the study area.
During the first stage of the research the state of the water body in August
2004 was assessed. According to the measurements and calculations performed,
precipitation accounts for up to 70% of the water pumped out of mines [2]. The
autumn–winter season of 2004 was rich in precipitation, with little snow and
relatively warm. Therefore it could be expected that Ahtme mine would fill with
water sooner than predicted [4]. To check that hypothesis, the model was
calibrated at the second stage of the research in December 2004. The contour
map of the modelled water table is shown in Fig. 2.
By continuous improvement of the existing and addition of new data
more than ten two- and three-dimensional map versions were completed.
The model enabled us to assess the water levels in different mines and their
border areas and to make assumptions and predictions about the water movement directions.
Water quality
In the years 2000–2004 the department of environmental services of the
Estonian Oil Shale Company had the waters of all closed mines analysed. The
samples were taken at six sites in four mines in different seasons. Analyses
were made at the central laboratory of the Estonian Oil Shale Company
(3 analyses), in Tartu Environmental Research Ltd. (2 analyses) and in the
Geological Survey of Estonia (12 analyses). Up to 16 quality parameters were
determined. The results of the analyses are presented in Table 2.
The quality parameters are arranged in Table 2 in the decreasing order of
the variation in measurement results. At first glance only the average contents
of iron, sulphates and phenols obtained for the observation period do not meet
the drinking water standards. This cannot be a final conclusion. The average
6. E. Reinsalu, I. Valgma, H. Lind, K. Sokman
20
Table 2. Water quality parameters in closed Ahtme, Kohtla,
Sompa and Tammiku mines
Quality
parameter
Unit
Leachates
Total
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mg/l
mge/l
mg/l
S/cm
mg/l
mg/l
µ
Total Fe
NO3NO2SO42Dry residue
Mg2+
K+
Ca2+
Na+
ClTotal hardness
Oil products
Conductivity
NH4+
Total phenols
pH
Number of
measurement
results
14
15
12
15
14
15
13
15
14
15
13
15
14
12
15
15
Numerical data for the entire period
(2000–2004)
Certain Arithmetical Standard Variation Max. levels
mean
deviation coefficient permitted in
numerical
values
drinking
water
10*
11*
7*
15
14
15
13
15
14
15
13
4*
14
2*
4**
15
0.69
11.7
0.015
342.4
845.5
51.6
12.9
174.5
10.4
16.4
13.72
0.15
1095
0.017
0.0017
7.1
1.16
18.55
0.0166
240.2
569.6
32.58
8.11
107.6
6.33
9.74
7.04
0.073
477.6
0.0064
0.00049
0.33
1.67
1.58
1.10
0.70
0.67
0.63
0.63
0.62
0.61
0.59
0.51
0.49
0.44
0.39
0.28
0.05
<0.2
<50
<0.5
<250
–
–
–
–
<200
<250
–
<0.05
<2500
<0.5
<0.0005
6.5–9.5
* due to the lack of a certain numerical value the result was smaller than the preciseness of the
laboratory tests, but not exceeding the limits permitted in drinking water
** due to the lack of a certain numerical value the result was smaller than the preciseness of
the laboratory tests, in two cases not exceeding the limits permitted in drinking water; rest of
the samples gave no unique result
Notes:
Quality parameters are ordered according to the variation coefficient.
The shaded lines contain the measurement results the average of which does not meet the
Estonian drinking water standard.
The content of benzo(a)pyrene was measured in 11 samples. The results are not included in
the table because no certain numerical values were obtained. In all samples the benzo(a)
pyrene content was lower than the permitted maximum value.
and standard deviations given in the table have been calculated for all closed
mines and for the entire observation period, thus they characterize only the
data set and not the quality of water or a particular mine. Variation in the
measurement results is caused by influential as well as random factors.
Influential factors are the sampling site (mine) and the time span that has passed
since the closure of the mine. Let us treat this assumption as a working
hypothesis. A random factor is the season when sampling was performed. For
example, in the years 2000 and 2001 samples were taken in summer, in 2002–
2004 in autumn. Surely the water quality parameters depend also on the
7. Technogenic Water in Closed Oil Shale Mines
21
location of the sampling site in the mine field. Some part of variations result
from the methodology of sampling and laboratory tests. The reliability of
iron content analyses carried out in different laboratories could be questioned.
The phenol content of mine water, measured repeatedly during mining, has
been 0.003 0.001 mg/l, except for Kiviõli mine, which has been strongly
affected by chemical industry. Here the phenol content of mine water was
0.38 mg/l [7].
For preliminary checking of the working hypothesis we conducted a twofactor (place and time) variation analysis of the sulphate and iron contents of
Tammiku and Sompa mine waters. The results of sulphate analysis are given
in Table 3. We can see that the hypothesis of the influence of place and time
on the sulphate content of water is relatively strong (probability of a counterhypothesis 18.0 and 18.8% respectively). The residual standard deviation
(187 mg/l), however, is too large for making definite conclusions. Obviously
the result is influenced by taking samples in different seasons. An analogous
result was obtained by the variation analysis of the iron content, whereas the
impact of time turned out to be small. Possibly this could result from the
treatment of samples in different laboratories.
In spite of great uncertainty of measurement, the sulphate and iron
contents decrease with time. This trend is depicted by graphs in Fig. 3. As
could be expected, the purification of water is best described by the
exponential function. The constants in the formulae (801 and 0.77 mg/l,
respectively) characterize the average concentrations at the initial moment of
the dilution process (at the closure of mines) and the time factors (–0.386
and –0.507, respectively) show the rate of water purification. The half-life of
the concentration calculated on the basis of time factors, i.e. the time period
during which the content of a component decrease twice, is about 1.8 years
for sulphates and 1.4 years for iron. From the half-life and graphs we may
presume that in about five years after the closure of a mine the content of
sulphates and iron decreases below the maximum permitted level in drinking
water. The highest permitted content of iron in first-class drinking water is
0.2 m/l and that of sulphates 250 m/l.
The data on all mines are included in the graphs of Fig. 3. The measurements revealed varying initial concentrations of sulphates for different
mines. The highest concentration was recorded in the first sample from
Ahtme mine, the lowest in Kohtla mine. Actually, this is not the initial level,
since the first samples were taken 4–11 months after the pumps had been
stopped. Approximating the results obtained from the samples of each mine
separately, we get theoretical dilution of the initial concentration level at the
zero moment, about 2200 mg/l for Ahtme and 300 mg/l for Sompa. These
values refer to a relation between the depth of the mine and the initial
concentration of sulphates. The hydrogeological background of this phenomenon is discussed by Erg [3].
±
8. E. Reinsalu, I. Valgma, H. Lind, K. Sokman
22
Table 3. Results of the variation analysis of the content of sulphates
Source of Variation
df
MS
F
P-value
Mines (Tammiku, Sompa)
Years (2002–2004)
Error
Residual Standard Deviation
Total
1
4
4
91681
92788
34924
187 mg/l
2.63
2.66
0.180
0.183
9
SO42- = 801 e-0.386 t , mg/l
SO42- - sulphate content, mg/l
R2 = 0.46
10000
1000
250 mg/l
100
10
0
1
2
3
4
5
6
7
t - closed, years
Fe = 0.77 e -0.509 t , mg/l
R2 = 0.39
Fe content, mg/l
10
1
0.2 mg/l
0.1
0.01
0
1
2
3
4
5
6
7
t - closed, years
Fig. 3. Decrease in the content of SO42- and Fe in closed
mines.
250 mg/l and 0.2 mg/l – maximum permitted levels in
drinking water.
The water quality parameters for which we had at least 14 reliable
measurement results (pH, electric conductivity, total hardness, Cl-, dry
9. Technogenic Water in Closed Oil Shale Mines
23
residue, Na+, Ca2+, Mg2+, K+ and SO42- ) were subjected to correlation
analysis. From the analysis we could conclude the following:
The content of sulphates can be considered a good indicator of mine
water quality, because it correlates well with most of the other water
quality parameters, except for K+.
Electric conductivity can be successfully used for rapid assessment of
water quality, because it correlates well with sulphates as well as with
other main parameters (except for K+).
pH is not informative enough, because it does not correlate with any
other water quality parameter.
•
•
•
Pilot model of water exchange
Continuous water exchange is going on between the closed mines. The
water penetrating into mines is derived mostly from precipitation, less from
groundwater. The part of the water not flowing out of the mine (Table 1)
infiltrates into the neighbouring mines or feeds aquifers. The water pumped
out of the working mines is formed of precipitation, groundwater and the
water coming from closed mines. Intensity of water exchange depends on
the length (L, km) and thickness (l, m) of the barrier left between the mines,
difference between the water levels of neighbouring mines (dh, m) and
permeability of the barrier and overburden (km, m2/d). The longer and thinner
is the barrier, the greater is the water level difference in neighbouring water
bodies, and the higher is the permeability of rocks in the areas separating the
mines, the more intensive is the exchange of water.
The water levels of the closed mines are precisely known. The measurements of barriers can be obtained from the plan of mining works, but the
length and thickness of the barriers are highly variable. Little data are
available on the permeability of pillars and bedrock. As seen in Table 4, the
permeability of the Keila–Kukruse aquifer differs up to 10 times within the
limits of the deposit.
Water permeability is largely affected by the geological disturbance of
the Earth crust (mostly karst zones), which makes the aquifer highly anisotropic [8, 9]. In the Estonia mine field twofold difference in the permeability
in the northeastern and southeastern directions has been recorded. According
to the data by Domanova, anisotropy is especially great in the area of
tectonic dislocations, where permeability in various directions may differ
several times. Water exchange between the mines is inhibited by extensive
karst zones running along the mine field boundaries between Sompa and
Viru, and Ahtme and Tammiku mines. At the same time, karst zones running
transversely to the mine boundary increase the water exchange between Sompa
and Kohtla mines. Additionally, the water exchange is affected by the properties
of the mined area, which depend on the roof handling methods used. In the area
10. E. Reinsalu, I. Valgma, H. Lind, K. Sokman
24
Table 4. Permeability of the Keila–Kukruse groundwater aquifer in the
mining district
Permeability,
m2/d
Estimated difference
in water tables,
m
Kohtla – Aidu,
northern part
1200
Kohtla – Aidu,
central part
780
District
Filtration module Publication
m/h
m/d
5
10
240
10
3.25
78
Kohtla
6–60
Viru
[8]
10–40
Aidu, generalized
393
10
1.6
39
Ahtme, generalized
335
10
1.4
[7]
34
Tammiku
4–20
Ahtme
[4]
1–15
Ahtme – Estonia
No. 2 – Tammiku
90
10
[7]
0.38
9
[4]
0.24
6
[10]
mined using roof caving the water-bearing horizon is thicker and of higher
permeability than in the area of room-and-pillar mining.
Because of high uncertainty the calculation of the water amounts moving
between the closed mines is complicated, not only due to the variability in L,
l, k, but also due to the lack of the relation uniquely describing all the
situations. Therefore the present study makes use of the balance method,
which unites the amounts of the water pumped out of the working mines,
and of precipitation and groundwater infiltrating into the mine. The relation
between these amounts is expressed by the approximate formula
qij = 365.25 × Lij × kij × (dhij/2) / (1000 × lij),
where
qij – the amount of the water migrating from one mine (i) to the other (j),
million m3/y,
Lij – length of the barrier between these mines, km,
lij – average thickness of the barrier, m,
dhji – difference between the water levels of two closed mines at the
moment of modelling, m,
kij – factor characterizing the permeability of the area between the mines
(barriers and overlying rock), which, with some reservation, can be
considered as generalized permeability, m2/d.
As model input we use the measurements of the barriers between the
mines, volume of the water pumped out of the working mines (especially
changes in it due to the closure of neighbouring mines), amount of precipitation and its relation to mine pumping [2]. The variable parameter of the
11. Technogenic Water in Closed Oil Shale Mines
25
model is generalized permeability, which is used to balance the model.
Permeability was fitted into the model taking into consideration the information available (Table 4), location of mines with respect to tectonic fault
zones and the orientation of the karst zones lying between the mines. The
balanced model can be used for calculating the migrating water amounts by
fluctuations in water level, for example during floods and heavy rains, but
also for planning water level regulations.
The model output is the matrix of water exchange (Table 5), where
“North” denotes the northern closed mines No. 2, Kukruse, and Käva
and its satellite mines
“West” denotes the western closed mines Kohtla, Sompa and No. 4
“Vasavere” is the area east of Ahtme and Estonia mines
The water amounts in the matrix of water exchange are given in
million m3/y, whereas (+) shows the amounts infiltrating into the mine (i)
from the mine (j) and (–) shows the amounts migrating from the mine (i)
to the other mine.
Explanations to the matrix of water exchange are given in Table 6. Water
movement inside the water body and the amounts of mine pumping are
shown in Fig. 1. The values presented characterize the state of the water body
in the year 2004, but as we have to do with a pilot model, these are all
approximate.
•
•
•
•
Table 5. Matrix of water exchange, year 2004, 106 m3/y
Elements
Jõhvi
of the water
Aidu Estonia Viru Ahtme Tammiku North West Vasavere
city
body
Sum
↓
→
Working mines:
Aidu
Estonia
0.00
0.00 0.00
0.00 0.00
0.00 –1.64
0.00
1.64
0.00
0.00
6.48
0.18
0.00
0.00
7.23
0.00 14.46
0.00 0.00
0.00 3.07
0.00
0.48
0.00
0.00 0.00
2.28 –1.69
0.00 –4.60
4.60 0.00
–1.07
–0.50
0.00
0.00
0.00
0.00
0.00
14.46
8.60
8.83
Technogenic water body; closed mines (sub-bodies):
Ahtme
Tammiku
North
West
0.00 –6.48 –0.18 0.00
0.00 0.00 –7.23 –0.07
0.00 0.00 0.00 0.00
– 0.00 –3.07 0.00
14.46
0.07
0.00
–2.28
1.69
0.00 –7.65
0.00 –7.22
–0.15 –7.03
0.00 –11.24
Geographical sites:
Vasavere
Town of
Jõhvi
0.00 –0.48
0.00 0.00
0.00
0.00
1.07
0.00
0.50
0.00
0.00
0.15
0.00
0.00
0.00
0.00
0.00
0.00
1.09
0.15
12. E. Reinsalu, I. Valgma, H. Lind, K. Sokman
26
Table 6. Water exchange between mines
Mines, technoWater
genic water
sub-bodies and exchange,
geographical 106 m3/y
sites
Comments
Working mines:
Aidu
Estonia
14.46
8.60
Inflow from closed Kohtla mine
Main inflow from closed Ahtme mine, less from the direction of
working Viru mine, partly also from the east
Viru
8.83
Inflow from closed Tammiku and Sompa mines, slight outflow
into Estonia mine
Technogenic water body; closed mines (sub-bodies):
Ahtme
–7.65
Tammiku
–7.22
Northern closed –7.03
mines Käva,
Kukruse and
No. 2
Western closed –11.24
mines Kohtla,
Sompa and
Mine No 4.
Geographical sites:
Vasavere
1.09
Town of Jõhvi
0.15
Outflow mainly into Estonia mine and into the catchment area
of the Pühajõgi River through springs and outflow wells
Intensive water exchange with other parts of the water body,
out flow into the catchment area of the Pühajõgi River through
a caving at Kose
Feeds other closed mines, outflow via Vahtsepa ditch into the
Kohtla River
Intensive water exchange with other parts of the water body,
feeds mostly Aidu opencast
Water inflow mostly from Ahtme mine, to some extent also
from closed Tammiku mine
Water infiltrates from closed mine No. 2
Conclusions and recommendations
No great changes in the water level of closed mines and its seasonal
variation are expected if no measures are taken. The situation should not
change after the closure of presently working mines either. In future the
water level of flooded Aidu opencast will be regulated by an outlet into the
Ojamaa River at 40–42 m level, which will be also the common water level
in Kohtla and Sompa mines. In the area of Viru and Estonia mines the
groundwater will rise to the pre-mining level, which will result in an increase
in groundwater flow into the Pühajõgi River at the eastern margin of
Tammiku and Ahtme mines.
It may turn necessary to regulate water level in the mining district. In
order to reduce the flow of groundwater from mine No. 2 to the lower, area
of the town of Jõhvi, the following options could be considered:
outlet of water at 51 m level at the northern boundary of the mine, near
the adit of unbuilt mine No. 1
•
13. Technogenic Water in Closed Oil Shale Mines
27
blasting of the barrier between mine No. 2 and Käva and Tammiku mines
to enable water outflow towards the Kohtla River (at a level of 51 m) or
into the Pühajõgi River (at 45–47 m level)
building of a pumping station regulating the water level and operating
seasonally, but this is evidently not efficient due to great expenses.
In order to reduce the water amounts penetrating into working mines and
towards Vasavere intake, it would be purposeful to lower the water level in
several closed mines:
to 45 m level in Tammiku mine, by dredging the present outlet
to 42–43 m level in Ahtme mine, by drilling artesian wells
The quality of the water of closed mines is improving. The content of
sulphates and iron in mine water decreases and in about five years after the
closure of the mine is below the maximum level permitted in drinking water.
Monitoring the water quality in closed mines should be aimed mostly at
protecting the water body from surface-derived pollution. The sampling
methods should be improved, with indicating justified times and places for
taking water samples. In some cases the number of parameters measured
could be reduced.
As no reliable data are available about the formation and distribution of
phenols in the water of closed mines, corresponding investigations are
needed before the use of the water. Although phenols are generally believed
to originate from the waste of shale oil plants or from burning spoil dumps,
the possibility of their formation during decomposition of kerogen in waterfilled mines cannot be excluded either. This hypothesis deserves further
special study.
•
•
•
•
Acknowledgements
This paper was written within the framework of Grant 5913 of the
Estonian Science Foundation “Usage of mined-out areas”, using the database
of research No. 416L “Forecast of hydrogeological changes resulting from
the activities of the Estonian Oil Shale Mining Company” carried out by
Tallinn University of Technology.
REFERENCES
1.
2.
3.
Reinsalu, E. Sillamäe uranium mine // Environment Technics. 2001. No. 2. P.
40–45 [in Estonian].
Reinsalu, E. Changes in mine dewatering after the closure of exhausted oil shale
mines // Oil Shale. 2005. Vol. 22, No. 3. P. 261–273.
Erg, K. Changes in groundwater sulphate content in Estonian oil shale mining
area // Oil Shale. 2005. Vol. 22, No. 3. P. 275–289.
14. 28
4.
E. Reinsalu, I. Valgma, H. Lind, K. Sokman
Savitski, L., Savva, V. Prognosis of hydrogeological changes in the mining
district of the Estonian oil shale deposit, stages 1–3, 2001 [in Estonian]
5. Reinsalu, E., Toomik, A., Valgma, I. Mined out land, Tallinn, 2002 [in
Estonian].
6. Butakova, A., Jürgenfeldt, G., Reinsalu, E. Assessment of the mine water
volume of water-filled oil shale mines // Gorjutšie slancy. 1980. No. 1. P. 6 [in
Russian].
7. Parahonski, E. Formation of mine water in oil shale mines and opencasts and
mine drainage. Tallinn, Valgus, 1983 [in Russian].
8. Domanova, N., Reinsalu, E. Analysis of hydrogeological conditions in Oktoobri
opencast, Topic 0107, Stage HD No. 1, Estonian Branch of A. Skotchinski
Institute of Mining Engineering, 1979 [in Russian].
9. Domanova, N. Formation and forecast of water flowing into the mine workings
driven into carbonate rocks with uneven infiltration properties. Candidate’s
thesis, A. Skotchinski Institute of Mining Engineering, 1986 [in Russian].
10. Domanova, N. Predicted increase in the water inflow into Viru mine due to the
flooding of Tammiku mine. Estonian Oil Shale Company, Jõhvi, 1999. Manuscript [in Russian].
Recieved June 20, 2005