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By Mr Jeremy Lee Redox Reaction
REDOX stands for REDuction & OXidation Both reduction and oxidation occur simultaneously. What is redox reaction? Substance that reduces  another substance is called reducing agent A Substance that oxidizes another substance is called oxidizing agent
Which substance is being oxidized and reduced?2Na  + Br2              2NaBr Sodium Bromine Bromine gas become bromide ions Chemical equation Br2  + 2e-                                2Br - The  2 electrons that sodium metal loses has been taken by bromine gas to become bromide ions Sodium metal become sodium ions Chemical equation 2Na (s)                  2Na +  +  2e- OR Na (s)                   Na +  +  e-   (Simplified) Sodium  metal has loses 2 electrons to become sodium ions
More example : Metal and acid reactionZn + 2H+                    Zn2+ + H2 Zinc metal Hydrogen Ion (from acid) Hydrogen ions becomes Hydrogen gas 2H+  + 2e-                H2 Hydrogen ions will receive the 2 electrons to become hydrogen gas. Zinc metal has become Zinc ions  ZnZn2+ + 2e- It becomes a Zinc ions after it happens
From the 2 examples, what are the conditions to consider a substance to become oxidized or reduced?
Oxidation number What are oxidation numbers? - Oxidation state or oxidation number is a + or - value given to an element to represent the charge of an atom or ion after Redox reaction. - Even for atoms inside a covalent compound, they contains oxidation number.
Overall charge of this compound is zero KMnO4 Examples Now you see it, now you don’t Potassium permanganate Potassium has a charge of +1 and permanganate ion has a charge of -1 Potassium permanganate (purple)  can be reduced to manganese ion  Mn2+(Colourless!) Decrease in oxidation state from +7  to become +2 REDUCTION! Oxygen carries a -2 charge each -2 X 4 = -8  +1 ?
Potassium dichromate Overall charge is Zero K2Cr2O7 Chromate ion has a charge of -2 Cr2O72- Each chromium has a charge of +6 Potassium dichromate (orange) can be reduced to chromate ion (green), Cr3+ Cr2O72−(aq) + 14H+ + 6e− -> 2Cr3+(aq) + 7H2O Decrease in oxidation state  Reduction!!!! Now  you see it, Now you don’t Potassium Dichromate -2 X 7 = -14 +1 X 2 = +2 ?
Iodide Ions Sodium Iodide Aqueous Sodium iodide (colourless), NaI, can be turned into brown solution. 	How? Solution contains iodide ions ( I- )  	Iodide ion can be turned into Iodine ( I2 ) 		2I-(aq)                                    I2 (aq) + 2e- Iodine is brown and has a oxidation state of zero Increase in oxidation state from -1 to O. oxidation has taken place

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Redox Reaction

  • 1. By Mr Jeremy Lee Redox Reaction
  • 2. REDOX stands for REDuction & OXidation Both reduction and oxidation occur simultaneously. What is redox reaction? Substance that reduces another substance is called reducing agent A Substance that oxidizes another substance is called oxidizing agent
  • 3. Which substance is being oxidized and reduced?2Na + Br2 2NaBr Sodium Bromine Bromine gas become bromide ions Chemical equation Br2 + 2e- 2Br - The 2 electrons that sodium metal loses has been taken by bromine gas to become bromide ions Sodium metal become sodium ions Chemical equation 2Na (s) 2Na + + 2e- OR Na (s) Na + + e- (Simplified) Sodium metal has loses 2 electrons to become sodium ions
  • 4. More example : Metal and acid reactionZn + 2H+ Zn2+ + H2 Zinc metal Hydrogen Ion (from acid) Hydrogen ions becomes Hydrogen gas 2H+ + 2e- H2 Hydrogen ions will receive the 2 electrons to become hydrogen gas. Zinc metal has become Zinc ions ZnZn2+ + 2e- It becomes a Zinc ions after it happens
  • 5. From the 2 examples, what are the conditions to consider a substance to become oxidized or reduced?
  • 6. Oxidation number What are oxidation numbers? - Oxidation state or oxidation number is a + or - value given to an element to represent the charge of an atom or ion after Redox reaction. - Even for atoms inside a covalent compound, they contains oxidation number.
  • 7. Overall charge of this compound is zero KMnO4 Examples Now you see it, now you don’t Potassium permanganate Potassium has a charge of +1 and permanganate ion has a charge of -1 Potassium permanganate (purple) can be reduced to manganese ion Mn2+(Colourless!) Decrease in oxidation state from +7 to become +2 REDUCTION! Oxygen carries a -2 charge each -2 X 4 = -8 +1 ?
  • 8. Potassium dichromate Overall charge is Zero K2Cr2O7 Chromate ion has a charge of -2 Cr2O72- Each chromium has a charge of +6 Potassium dichromate (orange) can be reduced to chromate ion (green), Cr3+ Cr2O72−(aq) + 14H+ + 6e− -> 2Cr3+(aq) + 7H2O Decrease in oxidation state Reduction!!!! Now you see it, Now you don’t Potassium Dichromate -2 X 7 = -14 +1 X 2 = +2 ?
  • 9. Iodide Ions Sodium Iodide Aqueous Sodium iodide (colourless), NaI, can be turned into brown solution. How? Solution contains iodide ions ( I- ) Iodide ion can be turned into Iodine ( I2 ) 2I-(aq) I2 (aq) + 2e- Iodine is brown and has a oxidation state of zero Increase in oxidation state from -1 to O. oxidation has taken place