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Manukaji John U. / International Journal of Engineering Research and Applications
                   (IJERA)           ISSN: 2248-9622         www.ijera.com
                        Vol. 3, Issue 2, March -April 2013, pp.006-009
       The Effects Of Sawdust Addition On The Insulating
   Characteristics Of Clays From The Federal Capital Territory
                             Of Abuja
                                           Manukaji John U.
           Department Of Mechanical Engineering The Federal Polytechnic,Bida Niger State Nigeria



ABSTRACT
         Insulating properties of clays from The         layer is mainly gibbsite but with some substitution
Federal Capital of Abuja like linear shrinkage,          of aluminum by magnesium.Manukaji (2004) A
solid density, apparent porosity and thermal             variety of metallic ions (other than k+) provide weak
conductivity were characterized with a view of           linkage between sheets. As a result of this weak
studying the effect of sawdust on them. The              linkage water molecules are easily admitted between
results showed that the linear shrinkage                 sheets, resulting in a high shrinkage swelling
improved from an average of 8.57% for the three          potential.Agha (1998)
samples for 0% sawdust to an average of 8.32%                     The degradation of micas (e.g. muscovite
with 40% addition of saw dust, bringing them             and sericite) under marine conditions results in a
closer to the lower range of the international           group of structurally similar minerals called illites.
standard of 7-10%. Solid density averaged                These, feature as predominant minerals in marine
3.18g/cm3 with 0% saw dust and 2.91g/cm 3 with           clays and shells, such as London clay and Oxford
40% saw dust, still bringing them closer to the          clay. Mahmoud et al (2003). Some illites are also
international range of 2.3-3.5g/cm3. Apparent            produced when in the weathering of orthoclase not
porosity averaged 13% with 0% saw dust and               all of the potassium ions are removed. The
17% with 40% addition of saw dust bringing               structures consist of three layer gibbsite sheets with
them closer to the acceptable range of 20-80%.           k+ ions providing a bond between adjacent silica
while thermal conductivity averaged 0.493W/mok           layers. The linkage is weaker than that in kaolinite,
with 0% saw dust and 0.134W/mok with 40%                 resulting in thinner and smaller particles. Li
saw dust thereby improving their insulating              Zaigeng et al (2001)
properties. This 40% sawdust addition was
discovered to be the maximum under which                 INSULATING REFRACTORIES
mechanical strength and other refractory                           These are high porosity refractories having
properties of clay will remain stable.                   low thermal conductivity and high thermal
                                                         insulation properties suitable for minimizing heat
INTRODUCTION                                             losses and maximizing heat conservation in
          Clay is a natural earthy fine grained          furnaces. They derive their low thermal conductivity
material, which is powdery when dry, plastic when        from their pores, while their heat capacity is
wet and stone-like when baked Mohammed et al             determined almost entirely by the solid component.
(2011). Most clays are crystalline, with a definite      The insulating effect is principally the result of
repeating arrangement of atoms in them. The              achieving a series of air spaces between an alternate
majority of them are made up of planes of oxygen         series of solid boundaries. Other things being equal,
atoms, with silicon and aluminum atoms holding the       the more pores present, and the less solid, the lower
oxygen together by ionic bonding .Brady et al            will be the conductivity. Such correlations between
(1999)                                                   porosity and conductivity are therefore to be
          Clay minerals have the ability to exchange     expected. These refractories are produced from
ions. This mineral property of clays that causes ion     fireclay, kieselguhr or asbestos, glass wool, slag
in solution to be fixed on the clay surface or within    wool. Vermiculite are also used as insulating
internal sites applies to all types of ions, including   materials at low temperatures. Ceramic fibres and
organic molecules. Hans(1994)                            wool are used for high temperature insulation. Foam
Depending on the source, there are four main groups      ceramic fibres and wool are used for high
of clays namely montmorillonite-smectite, illite, and    temperature insulation. Foam ceramic is a recent
chlorite.                                                addition to this class of refractories.Olusola (1998)
          Montmorillonite often results from the                   Insulation rarely adds to refractory life, and
further degradation of illite, but the weathering of     indeed may even reduce it. It does however save
plagioclase feldspar in volcanic ash deposits also       energy- the heat loss through many refractory
forms it. Essentially, the structure consists of three   structures can be halved by judicious use of external
layer arrangements in which the middle octahedral        insulation. Abifarin (1999) Insulating refractories


                                                                                                    6|Page
Manukaji John U. / International Journal of Engineering Research and Applications
                   (IJERA)           ISSN: 2248-9622         www.ijera.com
                        Vol. 3, Issue 2, March -April 2013, pp.006-009
owe their low conductivity to their pores, while their                                                         insulating characteristics. Apart from the natural
heat capacity depends on the weight per unit volume                                                            occurring fire clays which has been adjudged an
of solids, and of course its specific heat.Obi (1998)                                                          insulating refractories, other clays can have their
One of the most widely used materials is diatomite,                                                            insulating characteristics improved by the addition
also known as kieselguhr, which is made up of a                                                                of materials like saw dust, rice husks and other farm
mass of skeletons of minute aquatic plants-deposited                                                           wastes. Akinbode (1996)
thousands of years ago on the beds of seas and                                                                 For a refractory clay to have good insulating
lakes. Chemically this consists essentially of silica                                                          characteristics, it must have amongst others the
contaminated by clay and organic matter. Among                                                                 following characteristics
the larger deposits are those of Denmark, Germany,                                                             (1) It must be highly porous
Portugal etc.Theraja et al (1999)                                                                              (2) It must have low thermal conductivity
                                                                                                               (3) It must have low solid density
          Insulating refractories are a special class of                                                       (4) It must have a reasonably low linear shrinkage.
refractories produced to have a highly porous                                                                  In this experiment therefore, the effects of saw dust
structure with air entrapped therein. The presence of                                                          addition on the above properties of the clay
air in this pores reduces the conductive capacity of                                                           specimens were studied and the results are shown in
the refractories and therefore increasing their                                                                the graphs below




                                                                             EFFECT OF SAWDUST ADDITION ON LINEAR
                                                                                     SHRINKAGE AT 1200oC
                                                                   9.4
                                                                   9.2
                                      LINEAR SHRINKAGE AT 1200oC




                                                                    9
                                                                   8.8
                                                                   8.6
                                                                                                                                          spc A
                                                                   8.4
                                                                                                                                          spc B
                                                                   8.2
                                                                                                                                          spc C
                                                                    8
                                                                   7.8
                                                                   7.6
                                                                   7.4
                                                                   7.2
                                                                             1       2       3    4    5   6      7       8       9
                                                                                                 SAWDUST IN %


                                                                                                      FIGURE 1
                                                                     EFFECT OF SAWDUST ADDITION ON SOLID DENSITY


                                                      4

                                      3.5

                                                      3
                      SOLID DENSITY




                                      2.5
                                                                                                                                            Spc A
                                                      2                                                                                     Spc B
                                                                                                                                            Spc C
                                      1.5

                                                      1

                                      0.5

                                                      0
                                                                         1       2       3        4    5   6          7       8       9
                                                                                                 SAWDUST IN %


                                                                                                      FIGURE 2


                                                                                                                                                        7|Page
Manukaji John U. / International Journal of Engineering Research and Applications
                   (IJERA)           ISSN: 2248-9622         www.ijera.com
                        Vol. 3, Issue 2, March -April 2013, pp.006-009

                                                           EFFECT OF SAWDUST ADDITION ON % APPARENT
                                                                       POROSITY AT 1200oC


                                                 20
                   APPARENT POROSITY AT 1200oC   18
                                                 16
                                                 14
                                                 12                                                             Spc A
                                                 10                                                             Spc B
                                                  8                                                             Spc C
                                                  6
                                                  4
                                                  2
                                                  0
                                                       1      2    3   4     5    6     7     8     9
                                                                       SAWDUST IN %


                                                                            FIGURE 3


                                                            EFFECT OF SAWDUST ADDITION ON THERMAL
                                                                         CONDUCTIVITY


                                                 0.6
                  THERMAL CONDUCTIVITY




                                                 0.5

                                                 0.4
                                                                                                                Spc A
                                                 0.3                                                            Spc B
                                                                                                                Spc C
                                                 0.2

                                                 0.1

                                                  0
                                                       1      2    3    4    5    6     7     8     9
                                                                       SAWDUST IN %


                                                                            FIGURE 4

RESULTS AND DISCUSSION
The effects of saw dust addition on the above                                               international range of 20-80% Theraja et
properties of the clay specimens were studied and                                           al(1999), Oaikhinan (1988).
the results are shown and discussed as follows.                                        4.   The thermal conductivity of the samples
     1. The linear shrinkage showed a steady                                                decreased steadily from 0.491 – 0.134
          reduction in value from 8.57 -8.32% as the                                        W/mok as more sawdust was added making
          quantity of sawdust addition increased                                            the      samples      better   insulators
          thereby bringing the values closer to the                                         Manukaji(2004)
          lower values of the acceptable range of 7-
          10% IEE(1992).                                                          CONCLUSION                                    AND
     2. The solid density of the samples reduced                                  RECOMMENDATION
          steadily from 3.18 -2.91 g/cm3 as the                                   CONCLUSION
          sawdust addition increased moving them                                  (1) From the tests carried out on the addition of
          closer to the lower acceptable range of 2.3-                                saw dust to the clay samples, it could be
          3.5g/cm3 Ijagbemi (2002)                                                    concluded that properties like porosity, thermal
     3. The apparent porosity increased in value                                      conductivity, linear shrinkage and solid density
          from 13- 17% in most of the samples                                         of the clays from these locations improved
          thereby bringing them closer to the                                         significantly and can be varied to suit the
                                                                                      particular insulating property desired.



                                                                                                                          8|Page
Manukaji John U. / International Journal of Engineering Research and Applications
                   (IJERA)           ISSN: 2248-9622         www.ijera.com
                        Vol. 3, Issue 2, March -April 2013, pp.006-009
                                                               refractories. China’s refractories Volume
RECOMMENDATIONS FOR FURTHER                                    10 number 1
WORK                                                     9.    Mohammed A. D. and Agbajelola D. O.
         With the studies carried out, and the                 (2011) Characterization of some selected
analysis done of the accruing results, the following           clay deposits in Benue State. A paper
recommendations for further studies and analysis is            presented at the 2nd Biennial Engineering
hereby proposed.                                               Conference. School of Engineering and
    (1) Further studies on the insulating properties           Engineering        technology,       Federal
         of the clay samples could be carried out by           University of Technology, Minna
         analyzing the effects of the addition of rice   10.   Mahmoud S., Ayman H and Mousa A
         husks, ash and other farm wastes on the               (2003) Pretreatment effects on the catalytic
         clay samples.                                         activity of Jordanian bentonite . Journal of
    (2) An investigation should also be carried out            the clay mineral society Volume 51
         on the effects of the addition of bentonite           number 1
         on the clay samples.                            11.   Manukaji J.U.(2004) An investigation
    (3) A study should also be carried out on how              into the use of local clays as a high
         the addition of graphite, coal and asbestors          temperature insulator for electric cookers.
         would reduce the linear shrinkage                     PhD Thesis mech. eng. dept. Federal
         properties of the clay.                               University Of Technology, Minna
    (4) Efforts should also be made to reduce the        12.   Oaikhinan E.P (1988) Rheological
         ferrous and ferric content of the samples             properties of certain Nigerian clay.
         thereby      reducing       their    thermal          Proceedings of the international ceramic
         conductivity.                                         conference Australia.
    (5) Slag from iron extraction should be added        13.   Olusola E O (1998) Investigation of
         to the samples to improve their insulating            Zungeru clay as refractory material for high
         properties.                                           temperature applications M. Eng. Thesis,
    (6) Investigation should be made on the effects            Dept. of mech. engrg. F. U. T. Minna
         of the addition of foam-ceramic-fibres on       14.   Obi V S (1995) Experimental analysis of
         the insulating properties of the samples.             clay for refractory purpose , B.Eng. Thesis,
                                                               Dept. of mech. engrg. F. U. T Minna pp
REFERENCES                                                     34-48
  1.     Agha O A (1998) Testing of local                15.   Theraja B. L. and Theraja A. K , (1999)
         refractory clay for producing furnace lining          Electrical technology, S. Chand and co.
         bricks. M. Eng. Thesis: Mech. Eng. Dept.              Ltd, New Delhi
         F.U.T. Minna
  2.     Akinbode F O. (1996). An investigation
         on the properties of termite hill as
         refractory material for furnace lining:
         Indian Foundry Journal. Pp 11-13
  3.     Abifarin M. S. (1999) Investigation on
         local refractory materials for high
         temperature applications, PhD Thesis
         mech. eng. dept. Federal University Of
         Technology, Minna
  4.     Brady N.C. and Ray R.W. (1999). The
         Nature properties of soil, 20th Edition and
         Pub Prentice-Hall Inc. New Jersey
  5.     Hans T. (1994) Industrial Minerals and
         rocks, 6th Edition, Pergamon Press, Oxford.
  6.     IEE (1992) Wiring regulation requirement
         for electrical installation BS7671 , 15th
         Edition , A Mclay and co. Ltd Cardiff
  7.     Ijagbemi C.O.(2002) Development and
         performance evaluation of a biomass clay
         lined cookstove. Meng thesis , Department
         of mechanical Federal University of
         Technology Akure, Nigeria.
  8.     Li Zaigeng and Zhou Ningsheng (2001)
         Technological      advancement     in    the
         preparation and application of monolithic


                                                                                              9|Page

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The Effects of Sawdust on Insulating Properties of Clays

  • 1. Manukaji John U. / International Journal of Engineering Research and Applications (IJERA) ISSN: 2248-9622 www.ijera.com Vol. 3, Issue 2, March -April 2013, pp.006-009 The Effects Of Sawdust Addition On The Insulating Characteristics Of Clays From The Federal Capital Territory Of Abuja Manukaji John U. Department Of Mechanical Engineering The Federal Polytechnic,Bida Niger State Nigeria ABSTRACT Insulating properties of clays from The layer is mainly gibbsite but with some substitution Federal Capital of Abuja like linear shrinkage, of aluminum by magnesium.Manukaji (2004) A solid density, apparent porosity and thermal variety of metallic ions (other than k+) provide weak conductivity were characterized with a view of linkage between sheets. As a result of this weak studying the effect of sawdust on them. The linkage water molecules are easily admitted between results showed that the linear shrinkage sheets, resulting in a high shrinkage swelling improved from an average of 8.57% for the three potential.Agha (1998) samples for 0% sawdust to an average of 8.32% The degradation of micas (e.g. muscovite with 40% addition of saw dust, bringing them and sericite) under marine conditions results in a closer to the lower range of the international group of structurally similar minerals called illites. standard of 7-10%. Solid density averaged These, feature as predominant minerals in marine 3.18g/cm3 with 0% saw dust and 2.91g/cm 3 with clays and shells, such as London clay and Oxford 40% saw dust, still bringing them closer to the clay. Mahmoud et al (2003). Some illites are also international range of 2.3-3.5g/cm3. Apparent produced when in the weathering of orthoclase not porosity averaged 13% with 0% saw dust and all of the potassium ions are removed. The 17% with 40% addition of saw dust bringing structures consist of three layer gibbsite sheets with them closer to the acceptable range of 20-80%. k+ ions providing a bond between adjacent silica while thermal conductivity averaged 0.493W/mok layers. The linkage is weaker than that in kaolinite, with 0% saw dust and 0.134W/mok with 40% resulting in thinner and smaller particles. Li saw dust thereby improving their insulating Zaigeng et al (2001) properties. This 40% sawdust addition was discovered to be the maximum under which INSULATING REFRACTORIES mechanical strength and other refractory These are high porosity refractories having properties of clay will remain stable. low thermal conductivity and high thermal insulation properties suitable for minimizing heat INTRODUCTION losses and maximizing heat conservation in Clay is a natural earthy fine grained furnaces. They derive their low thermal conductivity material, which is powdery when dry, plastic when from their pores, while their heat capacity is wet and stone-like when baked Mohammed et al determined almost entirely by the solid component. (2011). Most clays are crystalline, with a definite The insulating effect is principally the result of repeating arrangement of atoms in them. The achieving a series of air spaces between an alternate majority of them are made up of planes of oxygen series of solid boundaries. Other things being equal, atoms, with silicon and aluminum atoms holding the the more pores present, and the less solid, the lower oxygen together by ionic bonding .Brady et al will be the conductivity. Such correlations between (1999) porosity and conductivity are therefore to be Clay minerals have the ability to exchange expected. These refractories are produced from ions. This mineral property of clays that causes ion fireclay, kieselguhr or asbestos, glass wool, slag in solution to be fixed on the clay surface or within wool. Vermiculite are also used as insulating internal sites applies to all types of ions, including materials at low temperatures. Ceramic fibres and organic molecules. Hans(1994) wool are used for high temperature insulation. Foam Depending on the source, there are four main groups ceramic fibres and wool are used for high of clays namely montmorillonite-smectite, illite, and temperature insulation. Foam ceramic is a recent chlorite. addition to this class of refractories.Olusola (1998) Montmorillonite often results from the Insulation rarely adds to refractory life, and further degradation of illite, but the weathering of indeed may even reduce it. It does however save plagioclase feldspar in volcanic ash deposits also energy- the heat loss through many refractory forms it. Essentially, the structure consists of three structures can be halved by judicious use of external layer arrangements in which the middle octahedral insulation. Abifarin (1999) Insulating refractories 6|Page
  • 2. Manukaji John U. / International Journal of Engineering Research and Applications (IJERA) ISSN: 2248-9622 www.ijera.com Vol. 3, Issue 2, March -April 2013, pp.006-009 owe their low conductivity to their pores, while their insulating characteristics. Apart from the natural heat capacity depends on the weight per unit volume occurring fire clays which has been adjudged an of solids, and of course its specific heat.Obi (1998) insulating refractories, other clays can have their One of the most widely used materials is diatomite, insulating characteristics improved by the addition also known as kieselguhr, which is made up of a of materials like saw dust, rice husks and other farm mass of skeletons of minute aquatic plants-deposited wastes. Akinbode (1996) thousands of years ago on the beds of seas and For a refractory clay to have good insulating lakes. Chemically this consists essentially of silica characteristics, it must have amongst others the contaminated by clay and organic matter. Among following characteristics the larger deposits are those of Denmark, Germany, (1) It must be highly porous Portugal etc.Theraja et al (1999) (2) It must have low thermal conductivity (3) It must have low solid density Insulating refractories are a special class of (4) It must have a reasonably low linear shrinkage. refractories produced to have a highly porous In this experiment therefore, the effects of saw dust structure with air entrapped therein. The presence of addition on the above properties of the clay air in this pores reduces the conductive capacity of specimens were studied and the results are shown in the refractories and therefore increasing their the graphs below EFFECT OF SAWDUST ADDITION ON LINEAR SHRINKAGE AT 1200oC 9.4 9.2 LINEAR SHRINKAGE AT 1200oC 9 8.8 8.6 spc A 8.4 spc B 8.2 spc C 8 7.8 7.6 7.4 7.2 1 2 3 4 5 6 7 8 9 SAWDUST IN % FIGURE 1 EFFECT OF SAWDUST ADDITION ON SOLID DENSITY 4 3.5 3 SOLID DENSITY 2.5 Spc A 2 Spc B Spc C 1.5 1 0.5 0 1 2 3 4 5 6 7 8 9 SAWDUST IN % FIGURE 2 7|Page
  • 3. Manukaji John U. / International Journal of Engineering Research and Applications (IJERA) ISSN: 2248-9622 www.ijera.com Vol. 3, Issue 2, March -April 2013, pp.006-009 EFFECT OF SAWDUST ADDITION ON % APPARENT POROSITY AT 1200oC 20 APPARENT POROSITY AT 1200oC 18 16 14 12 Spc A 10 Spc B 8 Spc C 6 4 2 0 1 2 3 4 5 6 7 8 9 SAWDUST IN % FIGURE 3 EFFECT OF SAWDUST ADDITION ON THERMAL CONDUCTIVITY 0.6 THERMAL CONDUCTIVITY 0.5 0.4 Spc A 0.3 Spc B Spc C 0.2 0.1 0 1 2 3 4 5 6 7 8 9 SAWDUST IN % FIGURE 4 RESULTS AND DISCUSSION The effects of saw dust addition on the above international range of 20-80% Theraja et properties of the clay specimens were studied and al(1999), Oaikhinan (1988). the results are shown and discussed as follows. 4. The thermal conductivity of the samples 1. The linear shrinkage showed a steady decreased steadily from 0.491 – 0.134 reduction in value from 8.57 -8.32% as the W/mok as more sawdust was added making quantity of sawdust addition increased the samples better insulators thereby bringing the values closer to the Manukaji(2004) lower values of the acceptable range of 7- 10% IEE(1992). CONCLUSION AND 2. The solid density of the samples reduced RECOMMENDATION steadily from 3.18 -2.91 g/cm3 as the CONCLUSION sawdust addition increased moving them (1) From the tests carried out on the addition of closer to the lower acceptable range of 2.3- saw dust to the clay samples, it could be 3.5g/cm3 Ijagbemi (2002) concluded that properties like porosity, thermal 3. The apparent porosity increased in value conductivity, linear shrinkage and solid density from 13- 17% in most of the samples of the clays from these locations improved thereby bringing them closer to the significantly and can be varied to suit the particular insulating property desired. 8|Page
  • 4. Manukaji John U. / International Journal of Engineering Research and Applications (IJERA) ISSN: 2248-9622 www.ijera.com Vol. 3, Issue 2, March -April 2013, pp.006-009 refractories. China’s refractories Volume RECOMMENDATIONS FOR FURTHER 10 number 1 WORK 9. Mohammed A. D. and Agbajelola D. O. With the studies carried out, and the (2011) Characterization of some selected analysis done of the accruing results, the following clay deposits in Benue State. A paper recommendations for further studies and analysis is presented at the 2nd Biennial Engineering hereby proposed. Conference. School of Engineering and (1) Further studies on the insulating properties Engineering technology, Federal of the clay samples could be carried out by University of Technology, Minna analyzing the effects of the addition of rice 10. Mahmoud S., Ayman H and Mousa A husks, ash and other farm wastes on the (2003) Pretreatment effects on the catalytic clay samples. activity of Jordanian bentonite . Journal of (2) An investigation should also be carried out the clay mineral society Volume 51 on the effects of the addition of bentonite number 1 on the clay samples. 11. Manukaji J.U.(2004) An investigation (3) A study should also be carried out on how into the use of local clays as a high the addition of graphite, coal and asbestors temperature insulator for electric cookers. would reduce the linear shrinkage PhD Thesis mech. eng. dept. Federal properties of the clay. University Of Technology, Minna (4) Efforts should also be made to reduce the 12. Oaikhinan E.P (1988) Rheological ferrous and ferric content of the samples properties of certain Nigerian clay. thereby reducing their thermal Proceedings of the international ceramic conductivity. conference Australia. (5) Slag from iron extraction should be added 13. Olusola E O (1998) Investigation of to the samples to improve their insulating Zungeru clay as refractory material for high properties. temperature applications M. Eng. Thesis, (6) Investigation should be made on the effects Dept. of mech. engrg. F. U. T. Minna of the addition of foam-ceramic-fibres on 14. Obi V S (1995) Experimental analysis of the insulating properties of the samples. clay for refractory purpose , B.Eng. Thesis, Dept. of mech. engrg. F. U. T Minna pp REFERENCES 34-48 1. Agha O A (1998) Testing of local 15. Theraja B. L. and Theraja A. K , (1999) refractory clay for producing furnace lining Electrical technology, S. Chand and co. bricks. M. Eng. Thesis: Mech. Eng. Dept. Ltd, New Delhi F.U.T. Minna 2. Akinbode F O. (1996). An investigation on the properties of termite hill as refractory material for furnace lining: Indian Foundry Journal. Pp 11-13 3. Abifarin M. S. (1999) Investigation on local refractory materials for high temperature applications, PhD Thesis mech. eng. dept. Federal University Of Technology, Minna 4. Brady N.C. and Ray R.W. (1999). The Nature properties of soil, 20th Edition and Pub Prentice-Hall Inc. New Jersey 5. Hans T. (1994) Industrial Minerals and rocks, 6th Edition, Pergamon Press, Oxford. 6. IEE (1992) Wiring regulation requirement for electrical installation BS7671 , 15th Edition , A Mclay and co. Ltd Cardiff 7. Ijagbemi C.O.(2002) Development and performance evaluation of a biomass clay lined cookstove. Meng thesis , Department of mechanical Federal University of Technology Akure, Nigeria. 8. Li Zaigeng and Zhou Ningsheng (2001) Technological advancement in the preparation and application of monolithic 9|Page