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CLEAN WORLD INNOVATIONS
      Tank Cleaning Services
WE OFFER:


•   Turnkey Operation

•   Global experience

•   On-site Support

•   Joint planning

•   Rapid Turnaround

•   Resource Recovery
COMPREHENSIVE TURNKEY PLAN

      Turn-key critique            Scope Development

  Job Execution/                               Quantitative Analysis
   Supervision

                                                  Environmental and
   Pre-                                          Safety Requirements
Inspection


    Develop                                     Material Assessment
 Procedures/
Design Program
                                            Costing
                          Scheduling
WHY CLEAN TANKS?


•   Repair leaks

•   Recover storage capacity

•   Eliminate crude unit upsets

•   Floating roof seal replacement

•   Floor coating

•   Inspection
BENEFITS


•   Reduces turnaround time

•   Reduces labor costs

•   Reduces air emissions

•   Reduces danger of explosive and toxic vapors - lowers H2S & TEL
    levels

•   Restores equipment efficiency/capacity
BENEFITS


•   Minimizes waste

•   Provides virtually oil-free
    surfaces and gas-free environment ready for entry

•   Water has no impact on wastewater treatment plant

•   Water has low BOD, COD, and TOC levels (dependent on sludge
    characteristics)
MECHANICAL SUPPLIER




•   Experience working with independent mechanical and turnaround
    contractors in various regions.

•   Experience in coordinating and running projects with customer
    specific maintenance contractors
MECHANICAL CONTRACTOR
                  REQUIREMENTS

•   Equipment specifically designed for chemical cleaning

•   Capability to perform several circulation loops within one unit

•   Self-contained equipment

•   Equipment meets all customer requirements

•   Closed-loop circulation

•   Ability to process sample during circulation
WASTE MINIMIZATION INCENTIVES



•   Landfarm restrictions mounting

•   RCRA legislation compliance issues

•   Reduce disposal costs

•   Valuable crude oil recovery
TRADITIONAL METHODS-SLUDGE
                 REMOVAL



•   Shovel or vacuum truck

•   Front end loader

•   Remote mechanical devices

•   Power spray nozzle
TRADITIONAL METHODS-
                 HYDROCARBON RECOVERY


•   Move to another crude tank

•   Mix with crude in vat

•   Belt press

•   Centrifuge

•   Separation tank
CWI CAPABILITIES


•   Storage Tank Cleaning

    •   Patented Warm Water Method

    •   Proven experience

•   Storage Tank Degassing

    •   Patented degassing chemistry

    •   Proven experience
TANK CLEANING-ONES APPROACH
       PATENTED WARM WATER METHOD
                EVALUATION

•   Obtain representative sample

•   Determine job requirements

•   Determine limitations

•   Tank cleaning beaker simulation

•   Customized cleaning program
CRITERIA FOR SUCCESS




•   Obtain a representative sample

•   Apply proper heat and chemistry

•   Develop processes to separate recovered hydrocarbon, water, and
    solids
LABORATORY TESTING FOR THE
HYDROCARBON RECOVERY AND WASTE
      MINIMIZATION PROCESS




        BEAKER WITH SLUDGE
LABORATORY TESTING FOR THE
HYDROCARBON RECOVERY AND WASTE
      MINIMIZATION PROCESS




          ADDITION OF SOLUTION
LABORATORY TESTING FOR THE
HYDROCARBON RECOVERY AND WASTE
      MINIMIZATION PROCESS




       ADDITION OF DILUENT, START TEST
LABORATORY TESTING FOR THE
HYDROCARBON RECOVERY AND WASTE
      MINIMIZATION PROCESS




       BEAKER SIMULATION IN PROGRESS
LABORATORY TESTING FOR THE
HYDROCARBON RECOVERY AND WASTE
      MINIMIZATION PROCESS




        END OF OF BEAKER SIMULATION
APPLICATION METHOD - CRUDE
                 STORAGE TANK

•   Pump crude from tank

•   Floating Roof - Lower roof to lowest level

•   Add equal volumes of water-chemical solution, and diluent

•   Floating Roof - Allow roof to float (2 ft)

•   Heat and circulate the cleaning solution

•   When complete, initiate customized recovery program
MONITORING


•   In Process Monitoring

    •   Emulsification Progress

    •   Temperatures

    •   Suspended Solids

    •   Free Oil

    •   Water-Wet Solids
CRUDE STORAGE TANK - FIXED OR
           FLOATING ROOF


IDENTIFY EXISTING
 PUMPS & HEATING                                  SLUDGE
    SOURCES




                    PUMP TANK TO LOWEST LEVEL
                     USING EXISTING DRAIN LINES
CRUDE STORAGE TANK - FIXED OR
        FLOATING ROOF

CLEANING
                                              DILUENT
SOLUTION


 SLUDGE




           ADD WATER, CHEMICAL, AND DILUENT
CRUDE STORAGE TANK - EXTERNAL
        CIRCULATION


                  DILUENT
             CLEANING SOLUTION
WATER CUTS
 CHANNEL
                  SLUDGE
EXTERNAL CIRCULATION
OF WATER USING CARGO HOSE
MANWAY WITH HARD PIPE
MANWAY CONNECTIONS FOR
   WATER CIRCULATION
MANIFOLD USED FOR
CIRCULATION PATTERN
SMALL EXCHANGERS AND PUMPS
       250,000 BBL TANK
CRUDE STORAGE TANK - CLEANING
       CONFIGURATION




 POSSIBLE TANK CIRCULATION AND HEATING ARRANGEMENTS
CRUDE STORAGE TANK - CLEANING IN
           PROGRESS


CUTTER OIL
                                                SLUDGE LIFTING
                                               FROM TANK FLOOR
PENETRATING
 CLEANING
 SOLUTION




              CHEMICAL PENETRATES THE SLUDGE
                 AND LIFTS IT OFF THE FLOOR
CRUDE STORAGE TANK - MONITORING
           PROGRESS
CRUDE STORAGE TANK - MONITORING
     THROUGH SAMPLE WELL
CRUDE STORAGE TANK - MONITORING
       THROUGH THE ROOF
MONITORING PROGRESS
CRUDE STORAGE TANK - END OF
              PROCESS


RECOVERED OIL
  READY FOR
 PROCESSING


  SOLIDS ARE    RECOVERED HYDROCARBON     INITIATE RECOVERY
HYDROCARBON           AND DILUENT               PROCESS
     FREE
                SPENT CLEANING SOLUTION
                        SOLIDS
CASE STUDY #1




      Tank Capacity - 500,000 bbl
        Tank Diameter - 273 ft
   Sludge Volume - 5.5 ft (60,000 bbl)
CRUDE STORAGE TANK SLUDGE SAMPLE


     Component              % by Volume
      Hydrocarbon                  73.3

        Water                      24.6

       Sediment                    2.1


           Recoverable Oil = 44,000 bbl
CRUDE STORAGE TANK CLEANING IN
          PROGRESS
CRUDE STORAGE TANK CLEANING
                  RESULTS



•   Tank cleaned in 21 days

•   43,500 bbl of oil recovered

•   98.9% oil recovery

•   Net = $70,000 after expenses
CRUDE STORAGE TANK 500-3 INTERNALS
CASE STUDY #2




     Tank Capacity - 400,000 bbl
        Tank Diameter - 224 ft
   Sludge Volume - 5 ft (35,900 bbl)
CASE STUDY #2 - CUSTOMER GOALS



•   Eliminate crude unit upsets

•   Restore storage tank capacity

•   Monitor crude deliveries

•   Three week window
CASE STUDY #2 - CUSTOM PROCEDURE



•   Sludge sample obtained

•   Sample tested using beaker simulation

•   Located existing pumps and exchangers

•   Light cycle oil used as diluent
CASE STUDY #2 -TANK BOTTOM SLUDGE
           COMPOSITION

     Component              % by Volume
      Hydrocarbon                   92

        Water                      6.7

       Sediment                    1.3


           Recoverable Oil = 33,000 bbl
CASE STUDY #2 - RESULTS


•   Back in service in 17 days

•   Average 1” solids on bottom (75 bbl)

•   Tank entry not required

•   33,000 bbl of oil recovered

•   99.9% recovery
CASE STUDY #2 - ECONOMIC RESULTS
                            Improved technique (Dollars)

Item/Basis
                                       495,000
Income
                                             0
                                             0
Recovered Hydrocarbon:                   3,000
                                        13,200
    33,000 bbl at 15$/bbl               74,800
                                         1,500

Expenses                                17,800


Sludge Disposal - None                       0
                                      $103,100
                                      $391,900
Tank Downtime - None


Manpower - Estimate
STORAGE TANK DEGASSING
TRADITIONAL METHODS FOR
        DEGASSING

                     OPEN MANWAYS
               •     Produces vapors
               •   Several weeks to degas
               • Environmentally unsound
APPLICATION METHOD - DEGASSING


•   Pump out the tank

•   Remove the access doors

•   Apply cleaning/degassing solution

    •   Use degassing solution EC9008A

    •   PORTA-FEED Jr. per 100,000 bbl tank capacity

•   Monitor the process
MONITORING


•   In Process Monitoring

    •   Emulsification Progress

    •   Temperatures

    •   Suspended Solids

    •   Free Oil

    •   Water-Wet Solids
APPLICATION METHOD - DEGASSING
          FIXED ROOF

                           DEGASSING PROCEDURE
                       •        Remove product
                       •     Vacuum last 6 - 8 inches
        FIXED ROOF     •      Educt water-chemical
                                    solution




                     DRAIN
APPLICATION METHOD -
DEGASSINGFIXED NOZZLE
                      DEGASSING PROCEDURE
                  •       Remove product
                  •    Vacuum last 6 - 8 inches
                  • Use Butterworth or Gammajet
                      to spray cleaning solution
    FIXED ROOF




                 DRAIN
APPLICATION METHOD -
DEGASSINGFLOATING ROOF
                        DEGASSING PROCEDURE
                    •       Remove product
                    •         Lower roof

   FLOATING ROOF    •     Educt water-chemical
                           degassing solution




                   DRAIN
EDUCTOR
DEGASSING CASE STUDY - PROBLEM



•   Large Gulf Coast Refiner needed to enter a 180,000 barrel crude
    storage tank.

•   Previously required taking the tank out of service to clean with
    conventional methods

•   Air ventilation was taking a significant amount of time
DEGASSING CASE STUDY - PROCESS


•   Site review from the local team resulted in applying the following
    process:

    •   Tank drained of HC and filled with several feet of water to float
        excess HC for removal.

    •   Flush water drained from tank

    •   Opening of many ways showed 3-4% of HC present in the tank
        atmosphere.
DEGASSING CASE STUDY - PROCESS



•   ONES implemented the use of a special feed system to apply a
    solution of the ONES degassing chemical.

•   Spray nozzle was used for the chemical application.

•   Walls, roof, internal support and structures were thoroughly rinsed
    from each of the manways
DEGASSING CASE STUDY - RESULTS


•   After 6 hours the solution was drained to the API separator

•   No additional cleaning was necessary

•   Atmosphere within the tank was completely free of Hydrocarbon
    vapors in less than ONE day. Therefore providing a SAFE environment

•   Refiner able to begin immediate maintenance

•   Reduced total cleaning costs

•   No waste water problems were encountered

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Tank Cleaning and Degassing Services

  • 1. CLEAN WORLD INNOVATIONS Tank Cleaning Services
  • 2. WE OFFER: • Turnkey Operation • Global experience • On-site Support • Joint planning • Rapid Turnaround • Resource Recovery
  • 3. COMPREHENSIVE TURNKEY PLAN Turn-key critique Scope Development Job Execution/ Quantitative Analysis Supervision Environmental and Pre- Safety Requirements Inspection Develop Material Assessment Procedures/ Design Program Costing Scheduling
  • 4. WHY CLEAN TANKS? • Repair leaks • Recover storage capacity • Eliminate crude unit upsets • Floating roof seal replacement • Floor coating • Inspection
  • 5. BENEFITS • Reduces turnaround time • Reduces labor costs • Reduces air emissions • Reduces danger of explosive and toxic vapors - lowers H2S & TEL levels • Restores equipment efficiency/capacity
  • 6. BENEFITS • Minimizes waste • Provides virtually oil-free surfaces and gas-free environment ready for entry • Water has no impact on wastewater treatment plant • Water has low BOD, COD, and TOC levels (dependent on sludge characteristics)
  • 7. MECHANICAL SUPPLIER • Experience working with independent mechanical and turnaround contractors in various regions. • Experience in coordinating and running projects with customer specific maintenance contractors
  • 8. MECHANICAL CONTRACTOR REQUIREMENTS • Equipment specifically designed for chemical cleaning • Capability to perform several circulation loops within one unit • Self-contained equipment • Equipment meets all customer requirements • Closed-loop circulation • Ability to process sample during circulation
  • 9. WASTE MINIMIZATION INCENTIVES • Landfarm restrictions mounting • RCRA legislation compliance issues • Reduce disposal costs • Valuable crude oil recovery
  • 10. TRADITIONAL METHODS-SLUDGE REMOVAL • Shovel or vacuum truck • Front end loader • Remote mechanical devices • Power spray nozzle
  • 11. TRADITIONAL METHODS- HYDROCARBON RECOVERY • Move to another crude tank • Mix with crude in vat • Belt press • Centrifuge • Separation tank
  • 12. CWI CAPABILITIES • Storage Tank Cleaning • Patented Warm Water Method • Proven experience • Storage Tank Degassing • Patented degassing chemistry • Proven experience
  • 13. TANK CLEANING-ONES APPROACH PATENTED WARM WATER METHOD EVALUATION • Obtain representative sample • Determine job requirements • Determine limitations • Tank cleaning beaker simulation • Customized cleaning program
  • 14. CRITERIA FOR SUCCESS • Obtain a representative sample • Apply proper heat and chemistry • Develop processes to separate recovered hydrocarbon, water, and solids
  • 15. LABORATORY TESTING FOR THE HYDROCARBON RECOVERY AND WASTE MINIMIZATION PROCESS BEAKER WITH SLUDGE
  • 16. LABORATORY TESTING FOR THE HYDROCARBON RECOVERY AND WASTE MINIMIZATION PROCESS ADDITION OF SOLUTION
  • 17. LABORATORY TESTING FOR THE HYDROCARBON RECOVERY AND WASTE MINIMIZATION PROCESS ADDITION OF DILUENT, START TEST
  • 18. LABORATORY TESTING FOR THE HYDROCARBON RECOVERY AND WASTE MINIMIZATION PROCESS BEAKER SIMULATION IN PROGRESS
  • 19. LABORATORY TESTING FOR THE HYDROCARBON RECOVERY AND WASTE MINIMIZATION PROCESS END OF OF BEAKER SIMULATION
  • 20. APPLICATION METHOD - CRUDE STORAGE TANK • Pump crude from tank • Floating Roof - Lower roof to lowest level • Add equal volumes of water-chemical solution, and diluent • Floating Roof - Allow roof to float (2 ft) • Heat and circulate the cleaning solution • When complete, initiate customized recovery program
  • 21. MONITORING • In Process Monitoring • Emulsification Progress • Temperatures • Suspended Solids • Free Oil • Water-Wet Solids
  • 22. CRUDE STORAGE TANK - FIXED OR FLOATING ROOF IDENTIFY EXISTING PUMPS & HEATING SLUDGE SOURCES PUMP TANK TO LOWEST LEVEL USING EXISTING DRAIN LINES
  • 23. CRUDE STORAGE TANK - FIXED OR FLOATING ROOF CLEANING DILUENT SOLUTION SLUDGE ADD WATER, CHEMICAL, AND DILUENT
  • 24. CRUDE STORAGE TANK - EXTERNAL CIRCULATION DILUENT CLEANING SOLUTION WATER CUTS CHANNEL SLUDGE
  • 25. EXTERNAL CIRCULATION OF WATER USING CARGO HOSE
  • 27. MANWAY CONNECTIONS FOR WATER CIRCULATION
  • 29. SMALL EXCHANGERS AND PUMPS 250,000 BBL TANK
  • 30. CRUDE STORAGE TANK - CLEANING CONFIGURATION POSSIBLE TANK CIRCULATION AND HEATING ARRANGEMENTS
  • 31. CRUDE STORAGE TANK - CLEANING IN PROGRESS CUTTER OIL SLUDGE LIFTING FROM TANK FLOOR PENETRATING CLEANING SOLUTION CHEMICAL PENETRATES THE SLUDGE AND LIFTS IT OFF THE FLOOR
  • 32. CRUDE STORAGE TANK - MONITORING PROGRESS
  • 33. CRUDE STORAGE TANK - MONITORING THROUGH SAMPLE WELL
  • 34. CRUDE STORAGE TANK - MONITORING THROUGH THE ROOF
  • 36. CRUDE STORAGE TANK - END OF PROCESS RECOVERED OIL READY FOR PROCESSING SOLIDS ARE RECOVERED HYDROCARBON INITIATE RECOVERY HYDROCARBON AND DILUENT PROCESS FREE SPENT CLEANING SOLUTION SOLIDS
  • 37. CASE STUDY #1  Tank Capacity - 500,000 bbl  Tank Diameter - 273 ft  Sludge Volume - 5.5 ft (60,000 bbl)
  • 38. CRUDE STORAGE TANK SLUDGE SAMPLE Component % by Volume Hydrocarbon 73.3 Water 24.6 Sediment 2.1 Recoverable Oil = 44,000 bbl
  • 39. CRUDE STORAGE TANK CLEANING IN PROGRESS
  • 40. CRUDE STORAGE TANK CLEANING RESULTS • Tank cleaned in 21 days • 43,500 bbl of oil recovered • 98.9% oil recovery • Net = $70,000 after expenses
  • 41. CRUDE STORAGE TANK 500-3 INTERNALS
  • 42. CASE STUDY #2  Tank Capacity - 400,000 bbl  Tank Diameter - 224 ft  Sludge Volume - 5 ft (35,900 bbl)
  • 43. CASE STUDY #2 - CUSTOMER GOALS • Eliminate crude unit upsets • Restore storage tank capacity • Monitor crude deliveries • Three week window
  • 44. CASE STUDY #2 - CUSTOM PROCEDURE • Sludge sample obtained • Sample tested using beaker simulation • Located existing pumps and exchangers • Light cycle oil used as diluent
  • 45. CASE STUDY #2 -TANK BOTTOM SLUDGE COMPOSITION Component % by Volume Hydrocarbon 92 Water 6.7 Sediment 1.3 Recoverable Oil = 33,000 bbl
  • 46. CASE STUDY #2 - RESULTS • Back in service in 17 days • Average 1” solids on bottom (75 bbl) • Tank entry not required • 33,000 bbl of oil recovered • 99.9% recovery
  • 47. CASE STUDY #2 - ECONOMIC RESULTS Improved technique (Dollars) Item/Basis 495,000 Income 0 0 Recovered Hydrocarbon: 3,000 13,200 33,000 bbl at 15$/bbl 74,800 1,500 Expenses 17,800 Sludge Disposal - None 0 $103,100 $391,900 Tank Downtime - None Manpower - Estimate
  • 49. TRADITIONAL METHODS FOR DEGASSING OPEN MANWAYS • Produces vapors • Several weeks to degas • Environmentally unsound
  • 50. APPLICATION METHOD - DEGASSING • Pump out the tank • Remove the access doors • Apply cleaning/degassing solution • Use degassing solution EC9008A • PORTA-FEED Jr. per 100,000 bbl tank capacity • Monitor the process
  • 51. MONITORING • In Process Monitoring • Emulsification Progress • Temperatures • Suspended Solids • Free Oil • Water-Wet Solids
  • 52. APPLICATION METHOD - DEGASSING FIXED ROOF DEGASSING PROCEDURE • Remove product • Vacuum last 6 - 8 inches FIXED ROOF • Educt water-chemical solution DRAIN
  • 53. APPLICATION METHOD - DEGASSINGFIXED NOZZLE DEGASSING PROCEDURE • Remove product • Vacuum last 6 - 8 inches • Use Butterworth or Gammajet to spray cleaning solution FIXED ROOF DRAIN
  • 54. APPLICATION METHOD - DEGASSINGFLOATING ROOF DEGASSING PROCEDURE • Remove product • Lower roof FLOATING ROOF • Educt water-chemical degassing solution DRAIN
  • 56. DEGASSING CASE STUDY - PROBLEM • Large Gulf Coast Refiner needed to enter a 180,000 barrel crude storage tank. • Previously required taking the tank out of service to clean with conventional methods • Air ventilation was taking a significant amount of time
  • 57. DEGASSING CASE STUDY - PROCESS • Site review from the local team resulted in applying the following process: • Tank drained of HC and filled with several feet of water to float excess HC for removal. • Flush water drained from tank • Opening of many ways showed 3-4% of HC present in the tank atmosphere.
  • 58. DEGASSING CASE STUDY - PROCESS • ONES implemented the use of a special feed system to apply a solution of the ONES degassing chemical. • Spray nozzle was used for the chemical application. • Walls, roof, internal support and structures were thoroughly rinsed from each of the manways
  • 59. DEGASSING CASE STUDY - RESULTS • After 6 hours the solution was drained to the API separator • No additional cleaning was necessary • Atmosphere within the tank was completely free of Hydrocarbon vapors in less than ONE day. Therefore providing a SAFE environment • Refiner able to begin immediate maintenance • Reduced total cleaning costs • No waste water problems were encountered