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Journal of Natural Sciences Research www.iiste.org
ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online)
Vol.3, No.9, 2013
166
Geochemistry and Petrographic Analysis of Sandstone Facies of
Eze-Aku Formation in Amasiri Area, Lower Benue through
Nigeria: Implications for Provenance and Tectonic Setting.
Igwe Ezekiel O.*
Igweaja Jude U., Obasi Arisi I. and Edene Emmanuel N.
Department of Geology and Exploration Geophysics, Ebonyi State University, P.M.B., 053, Abakaliki Nigeria.
*
ezekieloigwe@yahoo.com
Abstract
This study was undertaken to determine the provenance and tectonic setting for the sandstones of Eze-Aku
Formation in Amasiri area through evaluation and re-appraisal of the petrography and geochemistry of
sandstones. Local stratigraphy and field relationship show that the lithologic succession consists of thick
sequence of shale alternating with sandstone ridges trending NE-SW direction. Two units were delineated
namely: Unit I which is composed of calcareous/ siliceous sandstone and dark grey shale, and Unit II which
consists of friable and slightly consolidated pebbly sandstone belonging to Turonian sediments. Analysis and
interpretation of the sedimentary structures, mostly cross-beds and structures of quartz grains indicates that the
sandstones were derived primarily from granitic Basement complex rocks from the Oban Massif in a humid
paleoclimate. Petrographic analysis show that the sandstones essentially contain quartz, feldspar and few rock
fragment and are classified as subarkosic sandstone using calculated framework grains. The application of Q-F-
RF diagram, suggest plutonic igneous and metamorphic rocks, from the Craton interior, recycled Orogen and
transitional continental field as the provenance for the sandstones. The geochemistry of the major element oxides
(SiO2, Fe2O3, Na2O, Al2O3, K2O, MgO, MnO, TiO2 and SO3) suggests the Active Continental Margin as the
tectonic setting of the area.
Keywords: Amasiri area, Benue Trough, sandstones, geochemistry, petrography
1. Introduction
Amasiri area (Figure 1) lies in the Afikpo Synclinorium, lower Benue Trough which is a depression formed in
the eastern flank of southeastern edge of the trough as a result of Santonian tectonism and uplift of the Abakaliki
Anticlinorium. The area is made up of an alternating sequence of sandstone ridges trending NE-SW and the
shales both of Turonian Eze-Aku Formation. Reyment (1965) first described the Eze-Aku Formation as
comprising of dark grey to black shales, sandstone, subordinate limestone and siltstone deposited in a shallow
marine environment. Offodile (1976) established the existence of an unconformity between the Turonian Eze-
Aku Formation and the overlying Campanian-Maastrichtian Nkporo shale in the Afikpo Synclinorium of
southern Benue Trough. He explained the absence of the Awgu Formation in the Afikpo Syncline to result from
extensive erosion of older beds which accompanied the Santonian uplift. Hoque (1976, 1977) discussed
petrographic differentiation of tectonically controlled Cretaceous sedimentary cycle in southeastern Nigeria and
found out that the first sedimentary cycle was characterized by feldspar while that of the second cycle was
characterized by quartz-arenites. Murat (1972) believed that the Eze-Aku Formation was deposited under marine
conditions and sandstone coinciding with the regressive phases of epi-continental Sea Banerjee (1980) utilizes
the process-response methodology to sedimentary facies analysis and suggested that the Eze-Aku Formation was
deposited in a subtidal, tidal dominated environment. He however, preferred a barrier bar island origin for
sandstone unit at Ibii, near Akpoha. Amajor (1987) suggested that bioturbated sandstone and limestone clasts of
Eze-Aku Formation were probably derived from uplifted Asu River group shoreline sand bodies by the
Cenomanian uplift. They were probably scattered on the foot of the uplift as screes and talus provably brought
there by braided streams. Petters (1978) recognized three depositional cycles or sequences. He established the
facts that Eze-Aku Formation belongs to the second trangressive/regressive phase, (Turonian) and that they
represent the basal coastal shoreline and shallow sublittoral facies of a major marine onlap sequences. Reyment
(1965) suggested that the Turonian Eze-Aku Formation of the Benue Trough (Figure 2) is dominated by shales.
But on the southeastern part of the trough that is north of Afikpo Synclinorium, there are member of northeast-
southwest trending sand-bodies, which are parallel to the axis of the trough and are themselves linear and
parallel.
2. Methodology
The geological field mapping of the work involved description, measurements and sampling of the exposed
sections of the sandstones of Eze-Aku Formation. The sandstone outcropping in Ibii, Amasiri, Ozara- ukwu,
Crushed stone quarry and Amoha were studied. Thin sections were prepared from the representative sandstone
Journal of Natural Sciences Research www.iiste.org
ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online)
Vol.3, No.9, 2013
167
samples obtained in the field for thin section petrography which was studied under transmitted light petrographic
microscope. Petrographic classification was done using the framework elements of quartz (Q), feldspar (F) and
rock fragment (RF). The mineral maturity calculated using the mineralogical maturity index (IMM) of Nwajide
and Hoque(1985). Geochemical analyses (major elements) of eight samples were performed by x-ray difraction
technique (Minipal 4ED Version). The required filters for each element were selected accordingly and probed.
The initial results of concentration of the elements selected were shown in diffractions, which were then
converted to concentration in weight percentage of the major oxide of the elements in question.
3. Results and Discussion
3.1. Lithostratigraphy and field descriptions
Based on local lithostratigraphy and field descriptions, the sandstones of Eze-Aku Formation in Amasiri area are
grouped into two units: Ibii/Ozaraukwu Sandstone and Amasiri junction Sandstone.
Ibii/Ozaraukwu Sandstone unit consists dominantly of calcareous, araneceous and siliceous sandstones that
occur in ridges, which trend in a NE-SW direction alternating with thick sequence of shales. The contact
between the shale and the sandstone is very sharp and transitional in some places. There is gradation from shales
to interbedded siltstones and mudstone interlamination to sandstone near Amasiri Junction. The sedimentary
structures observed are mainly cross-stratificatios, burrows and mudstone laminations along Edda Road. In Ibii
junction, bioturbated fine-grained sandstone with rip-up clast is observed, and the sandstone opposite Amasiri
Community Primary School are micaceous and silty.. The shales have very high dips up to 320
to the SE at
Crushstone Quarry. Outcropping along Edda Road is consolidated whitish sandstone that is highly siliceous.
Generally, the sandstone beds dip to the southeast at angles ranging from 300
-500
and strike in the NE-SW
direction.
The Amasiri junction Sandston is friable to weakly consolidated, brownish to dark reddish in weathered parts
and whitish sandstone. The grain size ranges from medium to very coarse and occasionally pebbly. It contains
some clay siltstone bands. It shows coarsening upward sequence from coarse grain to pebbly at the base to the
fine and medium grained at the tops of the beds. The sandstone is moderately sorted. The minerals are
dominantly quartz and feldspars,. The sedimentary structures that characterize this unit are ripples and cross-
beds.
3.2 Detrital Framework Components and Classification
Based on the petrographic study, the sandstones composed of quartz, feldspars, rock fragment and mica (Figures
3 & 4). Quartz being the dominant framework grains has a percentage range of 68% to 74% of the framework
and dominantly subangular to subrounded (Figure 3) straight to strongly undulose extinction. The feldspars
which are mainly k-feldspar have 5 to 17% of the framework grains. Rock fragments constitute a minute
proportion of the framework grains with range of about 3-8%. The lithic fragments include igneous and
metamorphic rocks. Micas include biotite and muscovite with muscovites being most common. It has percentage
range of 1-7%. Matrix has a percentage range of 5-9% of the detrital fraction, and more common in fine to
medium sandstone samples. Cement in the detrital framework grains are calcite, silica and iron oxide in their
order of abundance. Cement however, constitute a significant percentage range of 4-8% in almost the entire
sample. From the high matrix content (>5%), the sub angular to sub rounded grains are moderately sorting. The
sandstones in the study area is texturally submature (Folk, 1951). From the recalculated framework composition
of quartz, feldspars and rock fragments, a ternary plot (QFR) for classification of the sandstone was constructed
after Folk (1974) (Figure 5 & Table 1).
3.3. Parent Rock Lithology
The abundance of quartz and feldspar minerals and their predominance over the lithic fragments in the Amasiri
sandstone suggests a primary rather than reworked source for the sandstone (Pettijohn et al; 1987). The absence
of volcanic rock fragments and quartz containing inclusion in the samples studied indicate a non-volcanic source
for the sandstone (Moorehouse, 1959). The presence of polycrystalline quartz that are not elongated or flattened
and of nearly equant grains (Figures 3) with sutured intercrystalline boundaries; non-undulose quartz extinction
favour a plutonic igneous granitoid source as the dominant source rock of a humid environment (Pettijohn et al,
1987; Folk, 1974; Blatt et al; 1980; Basu, 1985). In addition, the presence of monocrystalline quartz (Figures 3
& 4) with strong undulose extinction and metamorphic rock fragment suggest contributions from metamorphic
sources. To evaluate the importance of plutonic and metamorphic rocks as the Amasiri Sandstone sources, the
compositional framework grain data was gotten or deduced by plotting the point count data on Suttner et al
(1981) as shown in Figure. 6. This approach also points to both metamorphic and plutonic igneous source rocks
for the Amasiri Sandstone.
3.3. Tectonic Provenance
In the QFR ternary diagram of Dickson et al, (1985), the compositional framework grain data plot in the craton
interior, transitional continental and recycled Orogen fields as shown in Figure 7. As pointed out by Dickson et
Journal of Natural Sciences Research www.iiste.org
ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online)
Vol.3, No.9, 2013
168
al (1985), sandstones plotting in the craton interior field are mature sandstones derived from relatively low-lying
granitoid and gneissic sources, supplemented by recycled sands from associated platform or passive margin
basins. This low relief and short transport distance gave rise to typically quartzo-feldspathic sandstones of classic
subarkosic character.
3.3. Source Area Weathering and Climatic Index
Petrographic evidences of Amasiri sandstones such as the presence of quartz with sub angular to sub rounded
grains and weathered feldspar imply the significance of both mechanical and chemical weathering in the grains
of the sandstone. They therefore, suggest that the compositional submaturity of these sandstones may be due to
the short distance transport, relatively low source relief and relatively close provenance which may be related to
humid climatic condition. Also, using the Q-R-F ternary diagram of Suttner et al; (1981) to deduce the climatic
setting at the time of deposition, the sand bodies plot in the plutonic humid and metamorphic fields as shown in
Figure 6. This suggests that the parent rocks were situated in a humid climatic setting during Turonian time.
3.4. Geochemistry
From Table 2, the result shows a slight variation in element composition of all the samples analysed, reflecting
homogeneity of all the sediment suit and indicating constancy of provenance and sedimentary environment of
the rock. This variation reflects changes in the chemical and mineralogical composition of the sediment,
especially in the quartz-feldspar ratio and SiO2 abundance. Also, to characterize the tectonic setting of the
depositional basin, the major element geochemistries of Amasiri Sandstones are discussed in terms of
discrimination diagram of Kroonenberg (1994). The discrimination diagram shows that the Amasiri Sandstone
was deposited in an active continental margin as shown in Figure 8, analogous to conclusions from the
petrographic studies.
The Chemical Index of Alteration(CIA) defined by Nesbitt and Young (1982) as
CIA=100xAl2O3/(Al2O3+CaO+Na2O+K2O) which has a narrow range of 62-71, and Chemical Index of
weathering (CIW) defined by Harnois (1988) as: CIW=Al2O3/(Al2O3+CaO+Na2O)x100 with also a narrow range
of about 80-89 indicate the degree of weathering in sediment source areas, thus reflecting their tectonic setting
and prevailing paleoclimatic condition. The sandstones of Eze-Aku Formation shows a narrow range of both
CIA values (62-71) and CIW values (80-89), indicate intense of weathering of the sandstone as shown in Table
3. These values, in general, can be due to either intense recycling in humid or arid/semiarid climatic conditions
(Osae et al; 2006; Wanas and Andel-Maguid, 2006). Therefore, petrographic evidences, point count and
geochemical data as well as the CIA and CIW values are consistent with active recycling in a humid climatic
condition for the sandstones.
3.5. Paleocurrent
Paleocurrent indicators are oriented sedimentary structures interpreted to have been deposited by ancient flows.
Crossbeds, slip face, pebble imbrications, parting lineation, toolmarks, and groove casts, and ripple crest
orientation are all examples of possible paleocurrent indicators (Pettijohn, 1975). Some paleocurrent indicators
are unidirectional- that is, their shape provides unique information about the direction of the ancient paleoflow.
Unidirectional paleocurrent indicators include fore-sets, flute casts, and clast imbrication. Some paleocurrent
indicators are bi-directional-that is, their shape eliminates all but two possible directions (upcurrent or
downcurrent). Bi-directional paleocurrent indicators include oriented wood fragments or other elongate clasts,
tool marks or elongate sole marks and parting lineation. In the study area, the predominant paleocurrent indicator
is crossbeds. Some cross beds data were measured (Table 4), about 300metres from Amasiri junction along
Okigwe Road. The southwesterly, westerly and northwesterly directed paleocurrent modes (Figure 9), suggest
the Basement Complex of Oban Massif to the east as probably the major source (provenance) for the sandstones.
4. Conclusion
The sandstones of Eze-Aku Formation in Amasiri area are made up of calcareous and non-calcareous, medium
to coarse grain, poorly to moderately sorted, subarkosic Sandstones occur in fairly parallel, linear, Northeast-
Southwest trending ridges alternating with thick sequence of shales and characterized by a coarsening upward
textural sequence. Petrographic and paleocurrent study suggest the sandstones probabaly emanated from the
Basement Complex rocks of Oban massifs under humid climatic setting during Turonian time. The sandstones
are typically quartzo-feldspathic sandstones of classic subarkosic character. The geochemical and petrographic
plots show the tectonic setting of the Amasiri sandstone lies in active continental margin, and the provenance
signatures from the plots suggests the craton interior, transitional continental and recycled Orogen as the
provenance fields.
References
Amajor, L.C. (1987). The Eze-Aku sandstone ridges (Turonian) of southeastern Nigeria. A re- interpretation of
their Depositional origin. Nigerian Journal of mining and Geology, 23 (1&2), 19-26.
Journal of Natural Sciences Research www.iiste.org
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Vol.3, No.9, 2013
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Banerjee, K. (1980). A subtidal bar model for the Ezeaku sand bodies, Nigeria. Journal of sedimentary Geology,
25, 291-309.
Basu, A., (1985). Reading Provenance from detrital quartz, in:Zuffa, G.G.(ed.), Provenance of Arenites:
Dordrecht, NATO ASI series, C148, D. Reidel Publishing Company, 231-247.
Blatt, H., Middleton, G. and Murray, R., (1980). Origin of Sedimentary rocks, Prentice Hall NewJersey, 634p.
Dickinson, W.R. (1985).Interpreting provenance relation from detrial modes of sandstones, in Zuffa, G.G. (ed),
provenance of Arenites: NATO ASI series, C-148, D. Reidel publishing companu, Dickiuson, W.R. and Suczek,
C.A. 1979. Plate tectonics and sandstone compositions. American association of petroleum Geologist Bulletin,
63, 2164-2181.
Folk, R.L. (1974). Petrology of sedimentary rocks. Hemphili Publ. Co. texas, 182pp.
Harnois, L., (1988). The CIW index. A new chemical index of weathering. Sedimentary Geology. 55, 315-322
Hoque, M. (1976).Significance of textural and petrographic attributes of several cretaceous sandstones, southern
Nigeria. Bull. Geol. Soc. India, 17, 514-521.
Hoque,M.(1977).Petrographic differentiation of tectonically controlled cretaceous sedimentary cycles, South
Nigeria. Journal of Sedimentary Geology, V.17, 235-245.
Kroonenberg, S.B. (1994).Effects of Provenance, sorting and weathering on the geochemistry of fluvial sands
from different tectonic and climatic environment preceedings of the 29th
International Geological Congress, part
A, pp. 69-81.
Moorehouse, W.W.(1959). The study of rocks in Thin section. Horper and Row, New York, 160p.
Murat, R.C. (1972). Stratigraphy and paleogeography of cretaceous lower tertiary in southern Nig. African Geol.
T.F.J. Dessauvagie and M.d. Whiteman (Ed), university of Ibadan press 251-268.
Nesbitt, H. W., and Young, G. M., (1982). Early Proterozoic climates and plate motions inferred from major
element geochemistry of lutites. Nature, 299, 715-717.
Offodile, M.A. (1976).A review of the Geology of the cretaceous of the Benue Valley. In Kogbe, C.A., (ed),
Geology of Nigeria. Elizabethan publishing Co., Lagos, 319-330.
Petters, S.W. (1978).Stratigraphic evolution of the Beune Trough and its implication for the upper Cretaceous
paleogeography for West Africa Journal of Geology, 86, 311-322.
Reyment. R. A., (1965). Aspects of the Geology of Nigeria, Ibadan University Press, Ibadan 145pp.
Short,K.C.,and Stauble,A.J.(1967).Outline of geology of Niger Delta.Am.Assoc.Petroleum Geologist Bull. 51,
pp.761-779.
Simpson, A. (1955).The Nigeria Coalfield.The geology of parts of Onitsha,Owerri and Benue
Provinces.Geol.,v.103.pp.385-397.
Suttner, L.J., Basu, A. and Mach, G.H.(1981). Climate and the origin of Quartz arenites. Journal of sedimentary
petrology, 51, 1235-1246.
Wana, H. A., and Andel-Maguid, N. M., (2006). Petrography and geochemistry of Cambro Ordovician Wajid
sandstone, southwest Saudi Arabia; Implication for provenance and tectonic setting, Journal of Asian Earth
Sciences.27,416-429.
Weltje, G.J. (2012). Quantitative analysis of detrital modes: Statistically rigorous confidence regions in ternary
diagrams and their use in sedimentary petrology. Earth science Review; 57,211-253.
Whiteman,A.(1982).Nigeria:It petroleum Geology, Resources and potencials.v,1 and 2.Graham and Trotman
Ltd. London, UK.
Wright, J.B.(1976).Origin of the Benue Trough a critical review. In Kogbe, C.A.(ed),Geology of
Nigeria,Elizabethan Publishing Co,Lagos,309-317.
Journal of Natural Sciences Research www.iiste.org
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Vol.3, No.9, 2013
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Figure 1: Geographic map of Nigeria showing Amasiri and other major cities
Figure 2: Geology of the Cretaceous sediments of the Benue Trough (After Cratchley and Jones, 1965).
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
Sokoto
Katsina
Maiduguri
Kaduna
Yola
Jos
Abuja
Minna
Ilorin
Lagos
Ibadan
Benin
Asaba
Warri
Yenogoa
Port-Harcourt
AbakilikiEnugu
Amasiri
R.Niger
R. Benue
N
4°
6°
8° 8°
10° 10°
12° 12°
14° 14°
2° 4°
°
6° 8°
10°
10°
12°
12°
14°
14°
Rivers
Lakes
Study area&
Towns#
Key
300 0 300 600 Kilometers
Journal of Natural Sciences Research www.iiste.org
ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online)
Vol.3, No.9, 2013
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Figure 3 : Photomicrograph of sample IUO7 under XPL, showing feldspar (F) and
monocrystalline quartz (MQ).
Figure 4: a and b: photomicrograph of samples IU10A and IU17 respectively under XPL showing feldspar (F)
and polycrystalline quartz (PQ). a cylindrical muscovite (MT) and weathered feldspar (WF).
X10 X10a b
Journal of Natural Sciences Research www.iiste.org
ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online)
Vol.3, No.9, 2013
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Figure 5: QFR triangular classification plot for the sandstones in Amasiri using (Folk, 1974).
Table 1: Recalculated Modal Analysis Data For Framework Composition
Sample No. Quartz % Feldspar % RF % Total %
IU06 80 17 3 100
IU07 77 14 9 100
IU10A 87 6 7 100
IU10B 87 6 7 100
IU17 85 11 4 100
IU22 76 19 5 100
RF= Rock Fragment
Figure 6: The Effect of Source Rock on Composition of the Amasiri Sandstone using Suttner et al., (1981)
Diagram
Journal of Natural Sciences Research www.iiste.org
ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online)
Vol.3, No.9, 2013
173
Figure 7: QRF Diagram plot for the Sandstones at Amasiri, using Dickson et al., (1983).
Table 2: Major Element Composition in Percentage.
Major oxides IU06 IU07 IU08 IU10 IU17 IU22 IU23
SiO2 67.45 66.41 63.45 66.94 66.43 62.90 66.06
Al2O3 16.95 15.29 17.14 15.67 15.38 17.66 15.00
Fe2O3 0.79 0.87 1.88 0.77 1.52 1.86 1.84
CaO 0.42 0.49 0.60 0.43 0.50 0.64 0.63
MgO 0.24 0.31 0.49 0.28 0.50 0.51 0.60
K2O 5.89 5.67 5.94 5.65 4.31 5.39 4.44
Na2O 3.12 2.87 3.11 3.43 1.31 1.99 1.84
MnO 0.01 0.01 0.02 0.01 0.01 0.02 0.03
TiO2 0.12 0.11 0.18 0.13 0.09 0.25 0.15
SO3 0.18 0.11 0.17 0.19 0.06 0.03 0.09
Fe2O3+MgO 1.03 1.18 2.37 1.05 2.02 2.37 2.44
Al2O3+SiO2 0.25 0.23 0.27 0.23 0.23 0.28 0.23
K2O/Na2O 1.89 1.98 1.91 1.65 3.29 2.71 2.41
Al2O3/(CaO+Na2O) 4.79 4.55 4.62 4.06 8.50 6.71 6.07
Figure: 8: Plot of the Major Element Composition of the sandstones in the study area on the Tectonic Setting
Discrimination Diagram of Kroonenberg (1994). A: Oceanic Island; B: Continental Island Arc; C: Active
Continental Margin; D: Passive Margin
Journal of Natural Sciences Research www.iiste.org
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Vol.3, No.9, 2013
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Table 3: Chemical Index of Alteration (CIA) (Nesbitt and Young, 1982) and Chemical Index of Weathering
(CIW) (Harnois, 1988).
Sample No CIA= Al2O3/(Al2O3+CaO+Na2O+K2O)x100 CIW= Al2O3/(Al2O3+CaO+Na2O)x100
IU06 64.25 82.72
IU07 62.87 81.98
IU08 63.97 82.21
IU10 62.23 80.23
IU17 71.53 89.47
IU22 68.77 87.03
IU23 68.46 85.86
Table 4: Crossbeds analysis using front Azimuth and its back equivalence and class interval of 300
S/N Class interval Equivalent Frequency
1 0-30 181-210 0
2 31-60 211-240 0
3 61-90 241-270 9
4 91-120 271-300 8
5 121-150 301-330 3
6 151-180 331-360 0
∑f=20
Figure 9 : Plot of rose diagram for the cross-beds data along Amasiri-Okigwe Road. The paeocurrent direction
trends SE-NW direction
2700
3600
N
300
600
900
E
1200
1500
1800
S2100
2400
3000
3300
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Geochemistry and petrographic analysis of sandstone facies of eze aku formation in amasiri area, lower benue through nigeria-implications for provenance and tectonic setting.

  • 1. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 166 Geochemistry and Petrographic Analysis of Sandstone Facies of Eze-Aku Formation in Amasiri Area, Lower Benue through Nigeria: Implications for Provenance and Tectonic Setting. Igwe Ezekiel O.* Igweaja Jude U., Obasi Arisi I. and Edene Emmanuel N. Department of Geology and Exploration Geophysics, Ebonyi State University, P.M.B., 053, Abakaliki Nigeria. * ezekieloigwe@yahoo.com Abstract This study was undertaken to determine the provenance and tectonic setting for the sandstones of Eze-Aku Formation in Amasiri area through evaluation and re-appraisal of the petrography and geochemistry of sandstones. Local stratigraphy and field relationship show that the lithologic succession consists of thick sequence of shale alternating with sandstone ridges trending NE-SW direction. Two units were delineated namely: Unit I which is composed of calcareous/ siliceous sandstone and dark grey shale, and Unit II which consists of friable and slightly consolidated pebbly sandstone belonging to Turonian sediments. Analysis and interpretation of the sedimentary structures, mostly cross-beds and structures of quartz grains indicates that the sandstones were derived primarily from granitic Basement complex rocks from the Oban Massif in a humid paleoclimate. Petrographic analysis show that the sandstones essentially contain quartz, feldspar and few rock fragment and are classified as subarkosic sandstone using calculated framework grains. The application of Q-F- RF diagram, suggest plutonic igneous and metamorphic rocks, from the Craton interior, recycled Orogen and transitional continental field as the provenance for the sandstones. The geochemistry of the major element oxides (SiO2, Fe2O3, Na2O, Al2O3, K2O, MgO, MnO, TiO2 and SO3) suggests the Active Continental Margin as the tectonic setting of the area. Keywords: Amasiri area, Benue Trough, sandstones, geochemistry, petrography 1. Introduction Amasiri area (Figure 1) lies in the Afikpo Synclinorium, lower Benue Trough which is a depression formed in the eastern flank of southeastern edge of the trough as a result of Santonian tectonism and uplift of the Abakaliki Anticlinorium. The area is made up of an alternating sequence of sandstone ridges trending NE-SW and the shales both of Turonian Eze-Aku Formation. Reyment (1965) first described the Eze-Aku Formation as comprising of dark grey to black shales, sandstone, subordinate limestone and siltstone deposited in a shallow marine environment. Offodile (1976) established the existence of an unconformity between the Turonian Eze- Aku Formation and the overlying Campanian-Maastrichtian Nkporo shale in the Afikpo Synclinorium of southern Benue Trough. He explained the absence of the Awgu Formation in the Afikpo Syncline to result from extensive erosion of older beds which accompanied the Santonian uplift. Hoque (1976, 1977) discussed petrographic differentiation of tectonically controlled Cretaceous sedimentary cycle in southeastern Nigeria and found out that the first sedimentary cycle was characterized by feldspar while that of the second cycle was characterized by quartz-arenites. Murat (1972) believed that the Eze-Aku Formation was deposited under marine conditions and sandstone coinciding with the regressive phases of epi-continental Sea Banerjee (1980) utilizes the process-response methodology to sedimentary facies analysis and suggested that the Eze-Aku Formation was deposited in a subtidal, tidal dominated environment. He however, preferred a barrier bar island origin for sandstone unit at Ibii, near Akpoha. Amajor (1987) suggested that bioturbated sandstone and limestone clasts of Eze-Aku Formation were probably derived from uplifted Asu River group shoreline sand bodies by the Cenomanian uplift. They were probably scattered on the foot of the uplift as screes and talus provably brought there by braided streams. Petters (1978) recognized three depositional cycles or sequences. He established the facts that Eze-Aku Formation belongs to the second trangressive/regressive phase, (Turonian) and that they represent the basal coastal shoreline and shallow sublittoral facies of a major marine onlap sequences. Reyment (1965) suggested that the Turonian Eze-Aku Formation of the Benue Trough (Figure 2) is dominated by shales. But on the southeastern part of the trough that is north of Afikpo Synclinorium, there are member of northeast- southwest trending sand-bodies, which are parallel to the axis of the trough and are themselves linear and parallel. 2. Methodology The geological field mapping of the work involved description, measurements and sampling of the exposed sections of the sandstones of Eze-Aku Formation. The sandstone outcropping in Ibii, Amasiri, Ozara- ukwu, Crushed stone quarry and Amoha were studied. Thin sections were prepared from the representative sandstone
  • 2. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 167 samples obtained in the field for thin section petrography which was studied under transmitted light petrographic microscope. Petrographic classification was done using the framework elements of quartz (Q), feldspar (F) and rock fragment (RF). The mineral maturity calculated using the mineralogical maturity index (IMM) of Nwajide and Hoque(1985). Geochemical analyses (major elements) of eight samples were performed by x-ray difraction technique (Minipal 4ED Version). The required filters for each element were selected accordingly and probed. The initial results of concentration of the elements selected were shown in diffractions, which were then converted to concentration in weight percentage of the major oxide of the elements in question. 3. Results and Discussion 3.1. Lithostratigraphy and field descriptions Based on local lithostratigraphy and field descriptions, the sandstones of Eze-Aku Formation in Amasiri area are grouped into two units: Ibii/Ozaraukwu Sandstone and Amasiri junction Sandstone. Ibii/Ozaraukwu Sandstone unit consists dominantly of calcareous, araneceous and siliceous sandstones that occur in ridges, which trend in a NE-SW direction alternating with thick sequence of shales. The contact between the shale and the sandstone is very sharp and transitional in some places. There is gradation from shales to interbedded siltstones and mudstone interlamination to sandstone near Amasiri Junction. The sedimentary structures observed are mainly cross-stratificatios, burrows and mudstone laminations along Edda Road. In Ibii junction, bioturbated fine-grained sandstone with rip-up clast is observed, and the sandstone opposite Amasiri Community Primary School are micaceous and silty.. The shales have very high dips up to 320 to the SE at Crushstone Quarry. Outcropping along Edda Road is consolidated whitish sandstone that is highly siliceous. Generally, the sandstone beds dip to the southeast at angles ranging from 300 -500 and strike in the NE-SW direction. The Amasiri junction Sandston is friable to weakly consolidated, brownish to dark reddish in weathered parts and whitish sandstone. The grain size ranges from medium to very coarse and occasionally pebbly. It contains some clay siltstone bands. It shows coarsening upward sequence from coarse grain to pebbly at the base to the fine and medium grained at the tops of the beds. The sandstone is moderately sorted. The minerals are dominantly quartz and feldspars,. The sedimentary structures that characterize this unit are ripples and cross- beds. 3.2 Detrital Framework Components and Classification Based on the petrographic study, the sandstones composed of quartz, feldspars, rock fragment and mica (Figures 3 & 4). Quartz being the dominant framework grains has a percentage range of 68% to 74% of the framework and dominantly subangular to subrounded (Figure 3) straight to strongly undulose extinction. The feldspars which are mainly k-feldspar have 5 to 17% of the framework grains. Rock fragments constitute a minute proportion of the framework grains with range of about 3-8%. The lithic fragments include igneous and metamorphic rocks. Micas include biotite and muscovite with muscovites being most common. It has percentage range of 1-7%. Matrix has a percentage range of 5-9% of the detrital fraction, and more common in fine to medium sandstone samples. Cement in the detrital framework grains are calcite, silica and iron oxide in their order of abundance. Cement however, constitute a significant percentage range of 4-8% in almost the entire sample. From the high matrix content (>5%), the sub angular to sub rounded grains are moderately sorting. The sandstones in the study area is texturally submature (Folk, 1951). From the recalculated framework composition of quartz, feldspars and rock fragments, a ternary plot (QFR) for classification of the sandstone was constructed after Folk (1974) (Figure 5 & Table 1). 3.3. Parent Rock Lithology The abundance of quartz and feldspar minerals and their predominance over the lithic fragments in the Amasiri sandstone suggests a primary rather than reworked source for the sandstone (Pettijohn et al; 1987). The absence of volcanic rock fragments and quartz containing inclusion in the samples studied indicate a non-volcanic source for the sandstone (Moorehouse, 1959). The presence of polycrystalline quartz that are not elongated or flattened and of nearly equant grains (Figures 3) with sutured intercrystalline boundaries; non-undulose quartz extinction favour a plutonic igneous granitoid source as the dominant source rock of a humid environment (Pettijohn et al, 1987; Folk, 1974; Blatt et al; 1980; Basu, 1985). In addition, the presence of monocrystalline quartz (Figures 3 & 4) with strong undulose extinction and metamorphic rock fragment suggest contributions from metamorphic sources. To evaluate the importance of plutonic and metamorphic rocks as the Amasiri Sandstone sources, the compositional framework grain data was gotten or deduced by plotting the point count data on Suttner et al (1981) as shown in Figure. 6. This approach also points to both metamorphic and plutonic igneous source rocks for the Amasiri Sandstone. 3.3. Tectonic Provenance In the QFR ternary diagram of Dickson et al, (1985), the compositional framework grain data plot in the craton interior, transitional continental and recycled Orogen fields as shown in Figure 7. As pointed out by Dickson et
  • 3. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 168 al (1985), sandstones plotting in the craton interior field are mature sandstones derived from relatively low-lying granitoid and gneissic sources, supplemented by recycled sands from associated platform or passive margin basins. This low relief and short transport distance gave rise to typically quartzo-feldspathic sandstones of classic subarkosic character. 3.3. Source Area Weathering and Climatic Index Petrographic evidences of Amasiri sandstones such as the presence of quartz with sub angular to sub rounded grains and weathered feldspar imply the significance of both mechanical and chemical weathering in the grains of the sandstone. They therefore, suggest that the compositional submaturity of these sandstones may be due to the short distance transport, relatively low source relief and relatively close provenance which may be related to humid climatic condition. Also, using the Q-R-F ternary diagram of Suttner et al; (1981) to deduce the climatic setting at the time of deposition, the sand bodies plot in the plutonic humid and metamorphic fields as shown in Figure 6. This suggests that the parent rocks were situated in a humid climatic setting during Turonian time. 3.4. Geochemistry From Table 2, the result shows a slight variation in element composition of all the samples analysed, reflecting homogeneity of all the sediment suit and indicating constancy of provenance and sedimentary environment of the rock. This variation reflects changes in the chemical and mineralogical composition of the sediment, especially in the quartz-feldspar ratio and SiO2 abundance. Also, to characterize the tectonic setting of the depositional basin, the major element geochemistries of Amasiri Sandstones are discussed in terms of discrimination diagram of Kroonenberg (1994). The discrimination diagram shows that the Amasiri Sandstone was deposited in an active continental margin as shown in Figure 8, analogous to conclusions from the petrographic studies. The Chemical Index of Alteration(CIA) defined by Nesbitt and Young (1982) as CIA=100xAl2O3/(Al2O3+CaO+Na2O+K2O) which has a narrow range of 62-71, and Chemical Index of weathering (CIW) defined by Harnois (1988) as: CIW=Al2O3/(Al2O3+CaO+Na2O)x100 with also a narrow range of about 80-89 indicate the degree of weathering in sediment source areas, thus reflecting their tectonic setting and prevailing paleoclimatic condition. The sandstones of Eze-Aku Formation shows a narrow range of both CIA values (62-71) and CIW values (80-89), indicate intense of weathering of the sandstone as shown in Table 3. These values, in general, can be due to either intense recycling in humid or arid/semiarid climatic conditions (Osae et al; 2006; Wanas and Andel-Maguid, 2006). Therefore, petrographic evidences, point count and geochemical data as well as the CIA and CIW values are consistent with active recycling in a humid climatic condition for the sandstones. 3.5. Paleocurrent Paleocurrent indicators are oriented sedimentary structures interpreted to have been deposited by ancient flows. Crossbeds, slip face, pebble imbrications, parting lineation, toolmarks, and groove casts, and ripple crest orientation are all examples of possible paleocurrent indicators (Pettijohn, 1975). Some paleocurrent indicators are unidirectional- that is, their shape provides unique information about the direction of the ancient paleoflow. Unidirectional paleocurrent indicators include fore-sets, flute casts, and clast imbrication. Some paleocurrent indicators are bi-directional-that is, their shape eliminates all but two possible directions (upcurrent or downcurrent). Bi-directional paleocurrent indicators include oriented wood fragments or other elongate clasts, tool marks or elongate sole marks and parting lineation. In the study area, the predominant paleocurrent indicator is crossbeds. Some cross beds data were measured (Table 4), about 300metres from Amasiri junction along Okigwe Road. The southwesterly, westerly and northwesterly directed paleocurrent modes (Figure 9), suggest the Basement Complex of Oban Massif to the east as probably the major source (provenance) for the sandstones. 4. Conclusion The sandstones of Eze-Aku Formation in Amasiri area are made up of calcareous and non-calcareous, medium to coarse grain, poorly to moderately sorted, subarkosic Sandstones occur in fairly parallel, linear, Northeast- Southwest trending ridges alternating with thick sequence of shales and characterized by a coarsening upward textural sequence. Petrographic and paleocurrent study suggest the sandstones probabaly emanated from the Basement Complex rocks of Oban massifs under humid climatic setting during Turonian time. The sandstones are typically quartzo-feldspathic sandstones of classic subarkosic character. The geochemical and petrographic plots show the tectonic setting of the Amasiri sandstone lies in active continental margin, and the provenance signatures from the plots suggests the craton interior, transitional continental and recycled Orogen as the provenance fields. References Amajor, L.C. (1987). The Eze-Aku sandstone ridges (Turonian) of southeastern Nigeria. A re- interpretation of their Depositional origin. Nigerian Journal of mining and Geology, 23 (1&2), 19-26.
  • 4. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 169 Banerjee, K. (1980). A subtidal bar model for the Ezeaku sand bodies, Nigeria. Journal of sedimentary Geology, 25, 291-309. Basu, A., (1985). Reading Provenance from detrital quartz, in:Zuffa, G.G.(ed.), Provenance of Arenites: Dordrecht, NATO ASI series, C148, D. Reidel Publishing Company, 231-247. Blatt, H., Middleton, G. and Murray, R., (1980). Origin of Sedimentary rocks, Prentice Hall NewJersey, 634p. Dickinson, W.R. (1985).Interpreting provenance relation from detrial modes of sandstones, in Zuffa, G.G. (ed), provenance of Arenites: NATO ASI series, C-148, D. Reidel publishing companu, Dickiuson, W.R. and Suczek, C.A. 1979. Plate tectonics and sandstone compositions. American association of petroleum Geologist Bulletin, 63, 2164-2181. Folk, R.L. (1974). Petrology of sedimentary rocks. Hemphili Publ. Co. texas, 182pp. Harnois, L., (1988). The CIW index. A new chemical index of weathering. Sedimentary Geology. 55, 315-322 Hoque, M. (1976).Significance of textural and petrographic attributes of several cretaceous sandstones, southern Nigeria. Bull. Geol. Soc. India, 17, 514-521. Hoque,M.(1977).Petrographic differentiation of tectonically controlled cretaceous sedimentary cycles, South Nigeria. Journal of Sedimentary Geology, V.17, 235-245. Kroonenberg, S.B. (1994).Effects of Provenance, sorting and weathering on the geochemistry of fluvial sands from different tectonic and climatic environment preceedings of the 29th International Geological Congress, part A, pp. 69-81. Moorehouse, W.W.(1959). The study of rocks in Thin section. Horper and Row, New York, 160p. Murat, R.C. (1972). Stratigraphy and paleogeography of cretaceous lower tertiary in southern Nig. African Geol. T.F.J. Dessauvagie and M.d. Whiteman (Ed), university of Ibadan press 251-268. Nesbitt, H. W., and Young, G. M., (1982). Early Proterozoic climates and plate motions inferred from major element geochemistry of lutites. Nature, 299, 715-717. Offodile, M.A. (1976).A review of the Geology of the cretaceous of the Benue Valley. In Kogbe, C.A., (ed), Geology of Nigeria. Elizabethan publishing Co., Lagos, 319-330. Petters, S.W. (1978).Stratigraphic evolution of the Beune Trough and its implication for the upper Cretaceous paleogeography for West Africa Journal of Geology, 86, 311-322. Reyment. R. A., (1965). Aspects of the Geology of Nigeria, Ibadan University Press, Ibadan 145pp. Short,K.C.,and Stauble,A.J.(1967).Outline of geology of Niger Delta.Am.Assoc.Petroleum Geologist Bull. 51, pp.761-779. Simpson, A. (1955).The Nigeria Coalfield.The geology of parts of Onitsha,Owerri and Benue Provinces.Geol.,v.103.pp.385-397. Suttner, L.J., Basu, A. and Mach, G.H.(1981). Climate and the origin of Quartz arenites. Journal of sedimentary petrology, 51, 1235-1246. Wana, H. A., and Andel-Maguid, N. M., (2006). Petrography and geochemistry of Cambro Ordovician Wajid sandstone, southwest Saudi Arabia; Implication for provenance and tectonic setting, Journal of Asian Earth Sciences.27,416-429. Weltje, G.J. (2012). Quantitative analysis of detrital modes: Statistically rigorous confidence regions in ternary diagrams and their use in sedimentary petrology. Earth science Review; 57,211-253. Whiteman,A.(1982).Nigeria:It petroleum Geology, Resources and potencials.v,1 and 2.Graham and Trotman Ltd. London, UK. Wright, J.B.(1976).Origin of the Benue Trough a critical review. In Kogbe, C.A.(ed),Geology of Nigeria,Elizabethan Publishing Co,Lagos,309-317.
  • 5. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 170 Figure 1: Geographic map of Nigeria showing Amasiri and other major cities Figure 2: Geology of the Cretaceous sediments of the Benue Trough (After Cratchley and Jones, 1965). # # # # # # # # # # # # # # # # # Sokoto Katsina Maiduguri Kaduna Yola Jos Abuja Minna Ilorin Lagos Ibadan Benin Asaba Warri Yenogoa Port-Harcourt AbakilikiEnugu Amasiri R.Niger R. Benue N 4° 6° 8° 8° 10° 10° 12° 12° 14° 14° 2° 4° ° 6° 8° 10° 10° 12° 12° 14° 14° Rivers Lakes Study area& Towns# Key 300 0 300 600 Kilometers
  • 6. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 171 Figure 3 : Photomicrograph of sample IUO7 under XPL, showing feldspar (F) and monocrystalline quartz (MQ). Figure 4: a and b: photomicrograph of samples IU10A and IU17 respectively under XPL showing feldspar (F) and polycrystalline quartz (PQ). a cylindrical muscovite (MT) and weathered feldspar (WF). X10 X10a b
  • 7. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 172 Figure 5: QFR triangular classification plot for the sandstones in Amasiri using (Folk, 1974). Table 1: Recalculated Modal Analysis Data For Framework Composition Sample No. Quartz % Feldspar % RF % Total % IU06 80 17 3 100 IU07 77 14 9 100 IU10A 87 6 7 100 IU10B 87 6 7 100 IU17 85 11 4 100 IU22 76 19 5 100 RF= Rock Fragment Figure 6: The Effect of Source Rock on Composition of the Amasiri Sandstone using Suttner et al., (1981) Diagram
  • 8. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 173 Figure 7: QRF Diagram plot for the Sandstones at Amasiri, using Dickson et al., (1983). Table 2: Major Element Composition in Percentage. Major oxides IU06 IU07 IU08 IU10 IU17 IU22 IU23 SiO2 67.45 66.41 63.45 66.94 66.43 62.90 66.06 Al2O3 16.95 15.29 17.14 15.67 15.38 17.66 15.00 Fe2O3 0.79 0.87 1.88 0.77 1.52 1.86 1.84 CaO 0.42 0.49 0.60 0.43 0.50 0.64 0.63 MgO 0.24 0.31 0.49 0.28 0.50 0.51 0.60 K2O 5.89 5.67 5.94 5.65 4.31 5.39 4.44 Na2O 3.12 2.87 3.11 3.43 1.31 1.99 1.84 MnO 0.01 0.01 0.02 0.01 0.01 0.02 0.03 TiO2 0.12 0.11 0.18 0.13 0.09 0.25 0.15 SO3 0.18 0.11 0.17 0.19 0.06 0.03 0.09 Fe2O3+MgO 1.03 1.18 2.37 1.05 2.02 2.37 2.44 Al2O3+SiO2 0.25 0.23 0.27 0.23 0.23 0.28 0.23 K2O/Na2O 1.89 1.98 1.91 1.65 3.29 2.71 2.41 Al2O3/(CaO+Na2O) 4.79 4.55 4.62 4.06 8.50 6.71 6.07 Figure: 8: Plot of the Major Element Composition of the sandstones in the study area on the Tectonic Setting Discrimination Diagram of Kroonenberg (1994). A: Oceanic Island; B: Continental Island Arc; C: Active Continental Margin; D: Passive Margin
  • 9. Journal of Natural Sciences Research www.iiste.org ISSN 2224-3186 (Paper) ISSN 2225-0921 (Online) Vol.3, No.9, 2013 174 Table 3: Chemical Index of Alteration (CIA) (Nesbitt and Young, 1982) and Chemical Index of Weathering (CIW) (Harnois, 1988). Sample No CIA= Al2O3/(Al2O3+CaO+Na2O+K2O)x100 CIW= Al2O3/(Al2O3+CaO+Na2O)x100 IU06 64.25 82.72 IU07 62.87 81.98 IU08 63.97 82.21 IU10 62.23 80.23 IU17 71.53 89.47 IU22 68.77 87.03 IU23 68.46 85.86 Table 4: Crossbeds analysis using front Azimuth and its back equivalence and class interval of 300 S/N Class interval Equivalent Frequency 1 0-30 181-210 0 2 31-60 211-240 0 3 61-90 241-270 9 4 91-120 271-300 8 5 121-150 301-330 3 6 151-180 331-360 0 ∑f=20 Figure 9 : Plot of rose diagram for the cross-beds data along Amasiri-Okigwe Road. The paeocurrent direction trends SE-NW direction 2700 3600 N 300 600 900 E 1200 1500 1800 S2100 2400 3000 3300
  • 10. This academic article was published by The International Institute for Science, Technology and Education (IISTE). The IISTE is a pioneer in the Open Access Publishing service based in the U.S. and Europe. The aim of the institute is Accelerating Global Knowledge Sharing. More information about the publisher can be found in the IISTE’s homepage: http://www.iiste.org CALL FOR JOURNAL PAPERS The IISTE is currently hosting more than 30 peer-reviewed academic journals and collaborating with academic institutions around the world. There’s no deadline for submission. Prospective authors of IISTE journals can find the submission instruction on the following page: http://www.iiste.org/journals/ The IISTE editorial team promises to the review and publish all the qualified submissions in a fast manner. All the journals articles are available online to the readers all over the world without financial, legal, or technical barriers other than those inseparable from gaining access to the internet itself. Printed version of the journals is also available upon request of readers and authors. MORE RESOURCES Book publication information: http://www.iiste.org/book/ Recent conferences: http://www.iiste.org/conference/ IISTE Knowledge Sharing Partners EBSCO, Index Copernicus, Ulrich's Periodicals Directory, JournalTOCS, PKP Open Archives Harvester, Bielefeld Academic Search Engine, Elektronische Zeitschriftenbibliothek EZB, Open J-Gate, OCLC WorldCat, Universe Digtial Library , NewJour, Google Scholar