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By Triambak
 Sahai…..
CHEMICAL REACTIONS




 Reactants: Zn + I2   Product: Zn I2
Chemical Equations
Their Job: Depict the kind of
 reactants and products and their
 relative amounts in a reaction.
4 Al (s) + 3 O2 (g) ---> 2 Al2O3 (s)
The numbers in the front are called
stoichiometric ____________
The letters (s), (g), and (l) are the
 physical states of compounds.
Symbols We Use
+      Added to
→      Yields or Produces
(s)    Substance is a solid
(l)    Substance is a liquid
(g)    Substance is a gas
(aq)   Substance is aqueous
↔      Reaction can go both ways (Reversible)
Δ      Heat if above arrows
↑      Subs for (g) to show a gas is produced
↓      Subs for (s) to show a precipitate is formed
Introduction
Chemical reactions occur when bonds
 between the outermost parts of atoms
 are formed or broken
Chemical reactions involve changes in
 matter, the making of new materials with
 new properties, and energy changes.
Symbols represent elements, formulas
 describe compounds, chemical equations
 describe a chemical reaction
Parts of a Reaction Equation
Chemical equations show the conversion of reactants
 (the molecules shown on the left of the arrow) into
 products (the molecules shown on the right of the
 arrow).
 A + sign separates molecules on the same side
 The arrow is read as “yields”
 Example

  C + O2  CO2
 This reads “carbon plus oxygen react to yield
  carbon dioxide”
The charcoal used in a grill is basically carbon. The
 carbon reacts with oxygen to yield carbon dioxide.
 The chemical equation for this reaction, C + O2 
 CO2, contains the same information as the English
 sentence but has quantitative meaning as well.
Chemical Equations

Because of the principle of the
 conservation of matter,
an equation    must be
 balanced.
It must have the same
   number of atoms of the
   same kind on both sides.
                                  Lavoisier, 1788
Balancing Equations
When balancing a chemical reaction you
 may add coefficients in front of the
 compounds to balance the reaction, but

 you may   not    change the subscripts.
 Changing  the subscripts changes the
  compound. Subscripts are determined
  by the valence electrons (charges for
  ionic or sharing for covalent)
Chemical Equations
4 Al(s) + 3 O2(g)
           ---> 2 Al2O3(s)
This equation means
4 Al atoms + 3 O2 molecules
           ---produces--->
    2 molecules of Al2O3


      AND/OR



4 moles of Al + 3 moles of O2
           ---produces--->
Steps in Balancing An
   Equation
There are four basic steps to balancing a chemical
  equation.
   1.   Write the correct formula for the reactants and the
        products. DO NOT TRY TO BALANCE IT YET! You must
        write the correct formulas first. And most importantly,
        once you write them correctly DO NOT CHANGE THE
        FORMULAS!
   2.   Find the number of atoms for each element on the left side.
         Compare those against the number of the atoms of the
        same element on the right side.
   3.   Determine where to place coefficients in front of formulas
        so that the left side has the same number of atoms as the
        right side for EACH element in order to balance the
        equation.
   4.   Check your answer to see if:
           The numbers of atoms on both sides of the
            equation are now balanced.
Balancing Equations
     2                           2
    ___ H2(g) + ___ O2(g) ---> ___ H2O(l)
What Happened to the Other
Oxygen Atom?????
This equation is not balanced!
Two hydrogen atoms from a hydrogen
molecule (H2) combines with one of the
oxygen atoms from an oxygen molecule
(O2) to form H2O. Then, the remaining
oxygen atom combines with two more
hydrogen atoms (from another H2 molecule)
to make a second H2O molecule.
Types of chemical
equations
         COMBINATION
        DECOMPOSITION
         DISPLACEMENT
      DOUBLE-DISPLACEMENT
COMBINATION REACTION
• COMBINATION reactions occur when two substances
  (generally elements) combine and form a compound.
  (Sometimes these are called combination or addition
  reactions.)
      reactant + reactant  1 product
• Basically: A + B  AB
  • Example: 2H2 + O2  2H2O
  • Example: C + O2  CO2
EXAMPLE OF A COMBINATION
REACTION
• Here is another example of a synthesis reaction
DECOMPOSITION
REACTION
• Decomposition reactions occur when a compound
  breaks up into the elements or in a few to simpler
  compounds
• 1 Reactant  Product + Product
• In general: AB  A + B
• Example: 2 H2O  2H2 + O2
• Example: 2 HgO  2Hg + O2
EXAMPLE OF A DECOMPOSITION
REACTION
• Another view of a decomposition reaction:
DISPLACEMENT REACTION
• Single Replacement Reactions occur when one element
  replaces another in a compound.
• A metal can replace a metal (+) OR
   a nonmetal can replace a nonmetal (-).
• element + compound element + compound
  A + BC  AC + B (if A is a metal) OR
  A + BC  BA + C (if A is a nonmetal)
 (remember the cation always goes first!)

When H2O splits into ions, it splits into
H+ and OH- (not H+ and O-2 !!)
EXAMPLE OF A DISPLACEMENT
REACTION

• Another view:
DOUBLE-DISPLACEMENT
  REACTION

• Double Replacement Reactions occur when a metal
  replaces a metal in a compound and a nonmetal replaces
  a nonmetal in a compound
• Compound + compound  compound+ compound
• AB + CD  AD + CB
For Spending your precious
time

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Chemical equations and reactions

  • 2. CHEMICAL REACTIONS Reactants: Zn + I2 Product: Zn I2
  • 3. Chemical Equations Their Job: Depict the kind of reactants and products and their relative amounts in a reaction. 4 Al (s) + 3 O2 (g) ---> 2 Al2O3 (s) The numbers in the front are called stoichiometric ____________ The letters (s), (g), and (l) are the physical states of compounds.
  • 4. Symbols We Use + Added to → Yields or Produces (s) Substance is a solid (l) Substance is a liquid (g) Substance is a gas (aq) Substance is aqueous ↔ Reaction can go both ways (Reversible) Δ Heat if above arrows ↑ Subs for (g) to show a gas is produced ↓ Subs for (s) to show a precipitate is formed
  • 5. Introduction Chemical reactions occur when bonds between the outermost parts of atoms are formed or broken Chemical reactions involve changes in matter, the making of new materials with new properties, and energy changes. Symbols represent elements, formulas describe compounds, chemical equations describe a chemical reaction
  • 6. Parts of a Reaction Equation Chemical equations show the conversion of reactants (the molecules shown on the left of the arrow) into products (the molecules shown on the right of the arrow). A + sign separates molecules on the same side The arrow is read as “yields” Example C + O2  CO2 This reads “carbon plus oxygen react to yield carbon dioxide”
  • 7. The charcoal used in a grill is basically carbon. The carbon reacts with oxygen to yield carbon dioxide. The chemical equation for this reaction, C + O2  CO2, contains the same information as the English sentence but has quantitative meaning as well.
  • 8. Chemical Equations Because of the principle of the conservation of matter, an equation must be balanced. It must have the same number of atoms of the same kind on both sides. Lavoisier, 1788
  • 9. Balancing Equations When balancing a chemical reaction you may add coefficients in front of the compounds to balance the reaction, but you may not change the subscripts. Changing the subscripts changes the compound. Subscripts are determined by the valence electrons (charges for ionic or sharing for covalent)
  • 10. Chemical Equations 4 Al(s) + 3 O2(g) ---> 2 Al2O3(s) This equation means 4 Al atoms + 3 O2 molecules ---produces---> 2 molecules of Al2O3 AND/OR 4 moles of Al + 3 moles of O2 ---produces--->
  • 11. Steps in Balancing An Equation There are four basic steps to balancing a chemical equation. 1. Write the correct formula for the reactants and the products. DO NOT TRY TO BALANCE IT YET! You must write the correct formulas first. And most importantly, once you write them correctly DO NOT CHANGE THE FORMULAS! 2. Find the number of atoms for each element on the left side. Compare those against the number of the atoms of the same element on the right side. 3. Determine where to place coefficients in front of formulas so that the left side has the same number of atoms as the right side for EACH element in order to balance the equation. 4. Check your answer to see if:  The numbers of atoms on both sides of the equation are now balanced.
  • 12. Balancing Equations 2 2 ___ H2(g) + ___ O2(g) ---> ___ H2O(l) What Happened to the Other Oxygen Atom????? This equation is not balanced! Two hydrogen atoms from a hydrogen molecule (H2) combines with one of the oxygen atoms from an oxygen molecule (O2) to form H2O. Then, the remaining oxygen atom combines with two more hydrogen atoms (from another H2 molecule) to make a second H2O molecule.
  • 13. Types of chemical equations COMBINATION DECOMPOSITION DISPLACEMENT DOUBLE-DISPLACEMENT
  • 14. COMBINATION REACTION • COMBINATION reactions occur when two substances (generally elements) combine and form a compound. (Sometimes these are called combination or addition reactions.) reactant + reactant  1 product • Basically: A + B  AB • Example: 2H2 + O2  2H2O • Example: C + O2  CO2
  • 15. EXAMPLE OF A COMBINATION REACTION • Here is another example of a synthesis reaction
  • 16. DECOMPOSITION REACTION • Decomposition reactions occur when a compound breaks up into the elements or in a few to simpler compounds • 1 Reactant  Product + Product • In general: AB  A + B • Example: 2 H2O  2H2 + O2 • Example: 2 HgO  2Hg + O2
  • 17. EXAMPLE OF A DECOMPOSITION REACTION • Another view of a decomposition reaction:
  • 18. DISPLACEMENT REACTION • Single Replacement Reactions occur when one element replaces another in a compound. • A metal can replace a metal (+) OR a nonmetal can replace a nonmetal (-). • element + compound element + compound A + BC  AC + B (if A is a metal) OR A + BC  BA + C (if A is a nonmetal) (remember the cation always goes first!) When H2O splits into ions, it splits into H+ and OH- (not H+ and O-2 !!)
  • 19. EXAMPLE OF A DISPLACEMENT REACTION • Another view:
  • 20. DOUBLE-DISPLACEMENT REACTION • Double Replacement Reactions occur when a metal replaces a metal in a compound and a nonmetal replaces a nonmetal in a compound • Compound + compound  compound+ compound • AB + CD  AD + CB
  • 21. For Spending your precious time