Power engg.

S
Career Point Cares
FUEL CELL
MINOR-2 ASINGNMENT
Career Point Cares
content
 Introduction
 Fuel Cell Operation
 Hydrogen Fuel Cell Efficiency
 Parts of a Fuel Cell
 Working
 Advantages/Disadvantages of Fuel Cells
 Applications
Career Point Cares
Introduction
What is fuel cell?
A Fuel cell is a electrochemical device that converts chemical energy into
electrical energy.
 Every fuel cell has two electrodes, one positive and one negative,called
respectively, the cathode and anode. The reactions that produce electricity take
place at the electrodes.
In all types of fuel cell, hydrogen is used as fuel and can be obtained from any
source of hydrocarbon.
The fuel cell transform hydrogen and oxygen into electric power,emitting water
as their only waste product.
Career Point Cares
Every fuel cell also has an electrolyte, which carries electrically charged particles
from one electrode to the other, and a catalyst, which speeds the reactions at the
electrodes.
 A single fuel cell generates a tiny amount of direct current (DC) electricity.
A converter is used to produce AC current
In practice, many fuel cells are usually assembled into a stack. Cell or stack, the
principles are the same.
 In 1932, Francis Bacon developed the first successful FC. He used hydrogen,
oxygen, an alkaline electrolyte, and nickel electrodes.
Career Point Cares
Fuel Cell Operation
Pressurized hydrogen gas (H2) enters cell on anode side.
Gas is forced through catalyst by pressure.
When H2 molecule comes contacts platinum catalyst, it splits into two H+ ions
and two electrons (e-).
Electrons are conducted through the anode
Make their way through the external circuit (doing useful work such as
turning a motor) and return to the cathode side of the fuel cell.
On the cathode side, oxygen gas (O2) is forced through the catalyst
Forms two oxygen atoms, each with a strong negative charge.
Negative charge attracts the two H+ ions through the membrane,
Combine with an oxygen atom and two electrons from the external circuit to
form a water molecule (H2O).
Career Point Cares
Hydrogen Fuel Cell Efficiency
1. 40% efficiency converting methanol to hydrogen in reformer.
2. 80% of hydrogen energy content converted to electrical energy.
3. 80% efficiency for inverter/motor
4. Converts electrical to mechanical energy
5. Overall efficiency of 24-32%
Career Point Cares
Parts of a Fuel Cell
Anode
Negative post of the fuel cell.
Conducts the electrons that are freed from the hydrogen molecules so
that they can be used in an external circuit.
Etched channels disperse hydrogen gas over the surface of catalyst.
Cathode
Positive post of the fuel cell
Etched channels distribute oxygen to the surface of the catalyst.
Conducts electrons back from the external circuit to the catalyst
Recombine with the hydrogen ions and oxygen to form water.
Electrolyte
Proton exchange membrane.
Specially treated material, only conducts positively charged ions.
Membrane blocks electrons.
Catalyst
Special material that facilitates reaction of oxygen and hydrogen
Usually platinum powder very thinly coated onto carbon paper or cloth.
Rough & porous maximizes surface area exposed to hydrogen or oxygen
The platinum-coated side of the catalyst faces the PEM.
Career Point Cares
Working
The Fuel gas (hydrogen rich) is passed towards the anode where the following
oxidation reaction occurs:
H2 (g) = 2H+ + 2e-
The liberated electrons from hydrogen in anode side do not migrate through
electrolyte.
Therefore, they passes through the external circuit where work is performed,
then finally goes into the cathode.
On the other hand, the positive hydrogen ions (H+) migrate across the electrolyte
towards the cathode.
Career Point Cares
At the cathode side the hydrogen atom reacts with oxygen gas (from air)
and electrons to form water as byproduct according to:
The overall cell reaction is
fuel + oxidant  product + Heat
H2 + 1/2 O2 +2e- = H2O + Heat
Career Point CaresPH 0101 Unit-5 Lecture-6 10
Career Point Cares11
The liberated electrons from the hydrogen are responsible for the production of
electricity.
The water is produced by the combination of hydrogen, oxygen and liberated
electrons and is sent out from the cell.
The DC current produced by fuel cell is later converted into AC current using an
inverter for practical application.
The voltage developed in a single fuel cell various from 0.7 to 1.4 volt.More power
can be obtained by arranging the individual fuel cell as a stack. In this case, each
single cell is sandwiched with one another by a interconnect.
Therefore, electricity power ranging from 1 kW to 200 kW can be obtained for
domestic as well as industrial application.
Career Point Cares12
Hydrogen Oxygen
Electrical power production by fuel cell
Rotating shaft connected to generator for electricity production
Career Point Cares
Advantages/Disadvantages of Fuel Cells
• Zero Emissions: a fuel cell vehicle only emits water vapour. There fore, no air
pollution occurs.
• High efficiency: Fuel cells convert chemical energy directly into electricity
without the combustion process.As a result, Fuel cells can achieve high
efficiencies in energy conversion.
• High power density: A high power density allows fuel cells to be relatively
compact source of electric power, beneficial in application with space
constraints.
Career Point Cares
Applications
1. Portable applications
They used in portable appliances and power tools .
They can be used in small personal vehicles .
They are used Consumer electronics like laptops, cell phones can be operated.
They can be used in Backup power .
2. Transportation applications
They can be used for transport application in the following areas.
Industrial transportation.
Public transportation.
Commercial transportation (truck, tractors).
Marine and Military transportation.
Career Point Cares
Power distribution application
• Fuel cells can be used for the distribution of power in various
fields such as,
• Homes and small businesses
• Commercial and industrial sites
• Remote, off-grid locations (telecom towers, weather stations)
Power engg.
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Power engg.

  • 1. Career Point Cares FUEL CELL MINOR-2 ASINGNMENT
  • 2. Career Point Cares content  Introduction  Fuel Cell Operation  Hydrogen Fuel Cell Efficiency  Parts of a Fuel Cell  Working  Advantages/Disadvantages of Fuel Cells  Applications
  • 3. Career Point Cares Introduction What is fuel cell? A Fuel cell is a electrochemical device that converts chemical energy into electrical energy.  Every fuel cell has two electrodes, one positive and one negative,called respectively, the cathode and anode. The reactions that produce electricity take place at the electrodes. In all types of fuel cell, hydrogen is used as fuel and can be obtained from any source of hydrocarbon. The fuel cell transform hydrogen and oxygen into electric power,emitting water as their only waste product.
  • 4. Career Point Cares Every fuel cell also has an electrolyte, which carries electrically charged particles from one electrode to the other, and a catalyst, which speeds the reactions at the electrodes.  A single fuel cell generates a tiny amount of direct current (DC) electricity. A converter is used to produce AC current In practice, many fuel cells are usually assembled into a stack. Cell or stack, the principles are the same.  In 1932, Francis Bacon developed the first successful FC. He used hydrogen, oxygen, an alkaline electrolyte, and nickel electrodes.
  • 5. Career Point Cares Fuel Cell Operation Pressurized hydrogen gas (H2) enters cell on anode side. Gas is forced through catalyst by pressure. When H2 molecule comes contacts platinum catalyst, it splits into two H+ ions and two electrons (e-). Electrons are conducted through the anode Make their way through the external circuit (doing useful work such as turning a motor) and return to the cathode side of the fuel cell. On the cathode side, oxygen gas (O2) is forced through the catalyst Forms two oxygen atoms, each with a strong negative charge. Negative charge attracts the two H+ ions through the membrane, Combine with an oxygen atom and two electrons from the external circuit to form a water molecule (H2O).
  • 6. Career Point Cares Hydrogen Fuel Cell Efficiency 1. 40% efficiency converting methanol to hydrogen in reformer. 2. 80% of hydrogen energy content converted to electrical energy. 3. 80% efficiency for inverter/motor 4. Converts electrical to mechanical energy 5. Overall efficiency of 24-32%
  • 7. Career Point Cares Parts of a Fuel Cell Anode Negative post of the fuel cell. Conducts the electrons that are freed from the hydrogen molecules so that they can be used in an external circuit. Etched channels disperse hydrogen gas over the surface of catalyst. Cathode Positive post of the fuel cell Etched channels distribute oxygen to the surface of the catalyst. Conducts electrons back from the external circuit to the catalyst Recombine with the hydrogen ions and oxygen to form water. Electrolyte Proton exchange membrane. Specially treated material, only conducts positively charged ions. Membrane blocks electrons. Catalyst Special material that facilitates reaction of oxygen and hydrogen Usually platinum powder very thinly coated onto carbon paper or cloth. Rough & porous maximizes surface area exposed to hydrogen or oxygen The platinum-coated side of the catalyst faces the PEM.
  • 8. Career Point Cares Working The Fuel gas (hydrogen rich) is passed towards the anode where the following oxidation reaction occurs: H2 (g) = 2H+ + 2e- The liberated electrons from hydrogen in anode side do not migrate through electrolyte. Therefore, they passes through the external circuit where work is performed, then finally goes into the cathode. On the other hand, the positive hydrogen ions (H+) migrate across the electrolyte towards the cathode.
  • 9. Career Point Cares At the cathode side the hydrogen atom reacts with oxygen gas (from air) and electrons to form water as byproduct according to: The overall cell reaction is fuel + oxidant  product + Heat H2 + 1/2 O2 +2e- = H2O + Heat
  • 10. Career Point CaresPH 0101 Unit-5 Lecture-6 10
  • 11. Career Point Cares11 The liberated electrons from the hydrogen are responsible for the production of electricity. The water is produced by the combination of hydrogen, oxygen and liberated electrons and is sent out from the cell. The DC current produced by fuel cell is later converted into AC current using an inverter for practical application. The voltage developed in a single fuel cell various from 0.7 to 1.4 volt.More power can be obtained by arranging the individual fuel cell as a stack. In this case, each single cell is sandwiched with one another by a interconnect. Therefore, electricity power ranging from 1 kW to 200 kW can be obtained for domestic as well as industrial application.
  • 12. Career Point Cares12 Hydrogen Oxygen Electrical power production by fuel cell Rotating shaft connected to generator for electricity production
  • 13. Career Point Cares Advantages/Disadvantages of Fuel Cells • Zero Emissions: a fuel cell vehicle only emits water vapour. There fore, no air pollution occurs. • High efficiency: Fuel cells convert chemical energy directly into electricity without the combustion process.As a result, Fuel cells can achieve high efficiencies in energy conversion. • High power density: A high power density allows fuel cells to be relatively compact source of electric power, beneficial in application with space constraints.
  • 14. Career Point Cares Applications 1. Portable applications They used in portable appliances and power tools . They can be used in small personal vehicles . They are used Consumer electronics like laptops, cell phones can be operated. They can be used in Backup power . 2. Transportation applications They can be used for transport application in the following areas. Industrial transportation. Public transportation. Commercial transportation (truck, tractors). Marine and Military transportation.
  • 15. Career Point Cares Power distribution application • Fuel cells can be used for the distribution of power in various fields such as, • Homes and small businesses • Commercial and industrial sites • Remote, off-grid locations (telecom towers, weather stations)