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Chap 15 Acids and Bases Key components ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What are acids? What are bases? ,[object Object],[object Object]
Write the Equilibrium Equation for ionization of water. ,[object Object],[object Object],[object Object]
Water is excluded in the equilibrium expression for aqueous solutions. ,[object Object],[object Object],[object Object],[object Object],[object Object]
Thus: ,[object Object],[object Object],[object Object],[object Object]
The Proton in Water ,[object Object],[object Object],[object Object]
Practice Problems Chapter 15 Page 641-644 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Bronsted -Lowery Acids and Bases. ,[object Object],[object Object],[object Object],[object Object]
NH 3  + HCl    NH 4 +  + Cl - -Who is the acid, who is the base? ,[object Object],[object Object]
Conjugate Acid-Base Pairs ,[object Object],[object Object],[object Object]
[object Object],[object Object]
Conjugate Acid Base Strength ,[object Object],[object Object]
[object Object],[object Object],[object Object]
The pH Scale ,[object Object],[object Object],[object Object]
Logarithms ,[object Object],[object Object],[object Object],[object Object]
Antilogarithm ,[object Object],[object Object],[object Object],[object Object],[object Object]
pH ,[object Object],[object Object],[object Object],[object Object]
[H+] = 1.0 x 10 -3 : What is the pH? ,[object Object],[object Object],[object Object],[object Object]
How do you find the hydrogen ion concentration when given the pH? ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
pOH ,[object Object],[object Object],[object Object]
Strong Acids and Strong bases ,[object Object],[object Object],[object Object]
Strong Acids and Strong Bases ,[object Object],[object Object],[object Object]
What is the pH of a 0.011 M solution of Ca(OH) 2  ?
Weak Acids   partially ionized ,[object Object],[object Object],[object Object]
Equilibrium Expression  ,[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Niacin Overhead Question  page 7
pH calculations of Weak Acids ,[object Object]
[object Object]
[object Object]
[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
Polyprotic Acids ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
[object Object]
Weak Bases ,[object Object],[object Object],[object Object],[object Object]
Calculate the [OH - ] in a 0.15M solution of NH 3 ? K b = 1.8 x 10 -5 ,[object Object],[object Object],[object Object]
Which of the following compounds should have the highest pH as a 0.05 M solution? ,[object Object],[object Object],[object Object]
Types of Weak Bases ,[object Object],[object Object],[object Object]
Types of Weak Bases ,[object Object],[object Object],[object Object]
Example ,[object Object],[object Object],[object Object]
[object Object]
[object Object]
Relation Between K a  & K b ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Remember Reaction 1 + Reaction 2 = Reaction 3 (sum) ,[object Object],[object Object],[object Object],[object Object]
Don’t Get Freaked Out ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
5 points:  Acid Base  Properties of Salts ,[object Object],[object Object],[object Object]
5 Points: Acid Base Properties of Salts ,[object Object]
5 Points:  Acid Base Properties of Salts ,[object Object]
Predict whether the salt  Na 2 HPO 4  will form an acidic or basic solution when dissolved in water.  Overhead 22
[object Object]
What can you do? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
5 Points:  Acid Base Properties of Salts ,[object Object]
5 Points of Acid Base Properties of Salts ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Consider Aluminum ,[object Object]
pH of a solution of a salt ,[object Object]
This can only be done by considering a “Normal Salt”.One without ionizable proton. ,[object Object]
4 Rules for predicting pH of a salt. ,[object Object]
[object Object]
[object Object]
[object Object]
Use all 9 rules to solve for the following problems .(1-5)explains why (6-9) work . ,[object Object],[object Object],[object Object],[object Object],[object Object]
9 Rules ,[object Object],[object Object],[object Object],[object Object]
List the following solutions in order of increasing pH  ,[object Object],[object Object],[object Object],[object Object]
Of the following pairs of salts, which one form the more acidic 0.010 M solution ,[object Object],[object Object],[object Object],[object Object]
Stomach
Stomach
Which solution will be acidic? ,[object Object],[object Object],[object Object],[object Object],[object Object]
Acid Base behavior and Chemical Structure ,[object Object],[object Object],[object Object]
Hydrogen atoms can act as acids, bases or neither. ,[object Object],[object Object],[object Object]
The Strength of an acid depends on three factors.  ,[object Object],[object Object],[object Object]
Overhead # 30  ,[object Object],[object Object]
Overhead # 30 ,[object Object]
Oxyacids- When O-H bonds and additional O are bound to a central atom. ,[object Object]
General Rule 1 ,[object Object],[object Object],[object Object]
General Rule #2 ,[object Object]
Arrange the compound according to increasing acid strength. ,[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
Carboxyl Acids ,[object Object],[object Object],[object Object],[object Object]
[object Object]
Lewis Acids and Bases ,[object Object],[object Object],[object Object]
However, Lewis Acids and bases have an advantage. ,[object Object],[object Object],[object Object]
Other Examples ,[object Object],[object Object],[object Object]

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Key components of acids and bases

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  • 24. What is the pH of a 0.011 M solution of Ca(OH) 2 ?
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  • 53. Predict whether the salt Na 2 HPO 4 will form an acidic or basic solution when dissolved in water. Overhead 22
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