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TREATMENT OF
             WATER

GUIDED BY:-             SHUBHAM BAPHANA
Er. Ravi Parmar sir     CE (3RD YEAR)
Er. Sugandh singh sir   0862CE101115
The available raw water must be
treated and purified before they can
be supplied to the public for domestic
use or any industrial use. The extent of
treatment of water depends upon
following two-

1.Characteristics and quality of
  available water.
2.Quality requirements for the
  intended use.
Parameters           Desirable-Undesirable   If no alternative source
                                                  available, limit
                                                  extended upto
PHYSICAL
  Turbidity (NTU unit)             < 10                     25
Colour (Hazen scale)               < 10                     50
   Taste and Odour          Un-objectionable         Un-objectionable
CHEMICAL
           pH                    7.0-8.5                  6.5-9.2
 Total Dissolved Solids
                                500-1500                   3000
          mg/l
 Total Hardness mg/l
                                 200-300                    600
     (as CaCO3)
Chlorides mg/l (as Cl)           200-250                   1000
  Sulphates mg/l (as
                                 150-200                    400
        SO4)
 Fluorides mg/l (as F )          0.6-1.2                    1.5
Nitrates mg/l (as NO3)             45                       45
Unit treatment            Function (removal)
Aeration, chemicals use   Colour, Odour, Taste
Screening                 Floating matter
Chemical methods          Iron, Manganese, etc.
Softening                 Hardness
Sedimentation             Suspended matter
                          Suspended matter, a part of
Coagulation
                          colloidal matter and bacteria
                          Remaining colloidal dissolved
Filtration
                          matter, bacteria
                          Pathogenic bacteria, Organic
Disinfection
                          matter and Reducing substances
Source                        Treatment required
1. Ground water and spring water No treatment or Chlorination
fairly free from contamination
2. Ground water with chemicals, Aeration,         coagulation      (if
minerals and gases              necessary),         filtration   and
                                disinfection
3. Lakes, surface water reservoirs Disinfection
with less amount of pollution
4. Other surface waters such as Complete treatment
rivers, canals and impounded
reservoirs with a considerable
amount of pollution
AERATION:-

•Aeration removes odor due to volatile gases and due
to algae and related organisms.

•Removes CO2 and reduce corrosion and remove
methane and other inflammable gases.

•Increases dissolved oxygen content in water.


                                         Aeration
                                        Gravity aerators
                                       Fountain aerators
                                       Diffused aerators
                                      Mechanical aerators
FOUNTAIN AERATOR   MECHANICAL AERATOR




DIFFUSED AERATOR        GRAVITY AERATOR
Settling:-
In this Solid particle are separated out from the water.
• Clarified floating particle at the top of the sedimentation tank.
• Concentrated sludge leaving the bottom of the sedimentation
tank.

Purpose of settling:-
• To remove Coarse dispersed phase.
• To remove coagulated and flocculated impurities.
• To settle the Sludge.

Principle of settling:-
• Suspended solid present in water having specific gravity greater
than that of water tend to settle down by gravity.
• Basing in which the flow is retarded is called settling tank.
• Theoretical average time for which the water is detained in the
settling tank is called Detention Time.
Types of settling:-
1. Type 1 Discrete particle settling:-

• In discrete settling individual particles settle independently.
• It occurs when there is a relatively low solids concentration.


2. Type 2 Flocculent particle settling:-
• In flocculant settling, individual particles stick together into clumps
called flocs.
• This occurs when there is a greater solids concentration and
chemical or biological reactions alter particle surfaces to enhance
attachment.

3. Type 3 Compression:-
Compression settling occurs when particles settle by compressing
the mass below

4. Type 4 Zone settling:-
Type of settling tank:-

1. Intermittent or Quiescent Type tank:- Those which store water for a
   certain period and keep it in complete rest.
2. Continuous Flow type tank:- The flow velocity is reduced and the water
   is not bought to complete rest as is done in above one.

Long Rectangular Settling basin:-

• They are hydraulically more stable and flow control for large volume is
easier with this configuration.
• Length is 2 to 4 times of widht with bottom to be made slope.
This long rectangular settling basin is divided in four zones:-

Inlet zone: Region in which the flow is uniformly distributed over the cross
section.
Settling zone: Settling occurs.
Outlet zone: Clarified effluent is collected and discharge through outlet
weir.
Sludge zone: For collection of sludge below settling zone.
Circular Basin:-
• Circular settling basins have the same functional zones as the long
rectangular basin, but the flow regime is different. When the flow enters at
the centre and is baffled to flow radially towards the perimeter, the
horizontal velocity of the water is continuously decreasing as the distance
from the center increases.
• Sludge removal mechanisms in circular tanks are simpler and require
less maintenance.
Design Details:-
1. Detention period: for plain sedimentation: 3 to 4 h, and for
   coagulated sedimentation: 2 to 2.5 h.
2. Velocity of flow: Not greater than 30 cm/min (horizontal
   flow).
3. Tank dimensions: L:B = 3 to 5:1. Generally L= 30 m (common)
   maximum 100 m. Breadth= 6 m to 10 m. Circular: Diameter
   not greater than 60 m. generally 20 to 40 m.
4. Depth 2.5 to 5.0 m (3 m).
5. Surface Overflow Rate: For plain sedimentation 12000 to
   18000 L/d/m2 tank area; for thoroughly flocculated water
   24000 to 30000 L/d/m2 tank area.
6. Slopes: Rectangular 1% towards inlet and circular 8%.
Coagulation and flocculation:-

• Colloidal particles are difficult to separate from water because they do
not settle by gravity and are so small that they pass through the pores of
filtration media.
• To be removed, the individual colloids must aggregate and grow in size.
•The aggregation of colloidal particles can be considered as involving two
separate and distinct steps:
      a. Particle transport to effect interparticle collision.
      b. Particle destabilization to permit attachment when contact occurs.
Flocculation:-

It is a common practice to provide an initial rapid (or) flash mix for the
dispersal of the coagulant or other chemicals into the water. Slow mixing is
then done, during which the growth of the floc takes place.

Rapid or Flash mixing is the process by which a coagulant is rapidly and
uniformly dispersed through the mass of water. Generally, the detention
period is 30 to 60 seconds and the head loss is 20 to 60 cms of water. Here
colloids are destabilised and the nucleus for the floc is formed.

Slow mixing brings the contacts between the finely divided destabilised
matter formed during rapid mixing.
-:Filltration:-
To remove or to reduce the remaining impurities still further, the water
is filtered through the beds of fine granular material, such as
sand, etc. The process of passing the water through the beds of such
granular materials is known as Filtration.
                        -:Filter material:-
1. Sand:-Sand, either fine or coarse, is generally used as filter media
   The size of sand is measured and expressed by the term called
   effective size.
2. Gravel:- The layer of sand may be supported on gravel, which
   permits the filtered water to move freely to the under drains.
3. Other materials:- Instead of using sand, sometimes anthrafilt is
   used as filter media. Anthrafilt is made from anthracite. It is
   cheaper and has been able to give high rate of filtration.
TYPES OF FILTERS

1. Slow Sand filter:- They consist of fine sand, supported by gravel.
   They capture particles near the surface of the bed and are
   usually cleaned by scraping away the top layer of sand that
   contains the particles.

2. Rapid sand Filter:- They consist of larger sand grains supported
   by gravel and capture particles throughout the bed. They are
   cleaned by backwashing water through the bed to 'lift out' the
   particles.

3. Multemedia Filter:- They consist of two or more layers of different
    granular materials, with different densities. Usually, anthracite
    coal, sand, and gravel are used. Because of the differences in
    densities, the layers stay neatly separated, even after backwashing.
Difference Between SSF and RSF:-


                              Slow sand filter      Rapid sand filter
     Base Material       varies from 3 to 65 mm     varies from 3 to 40 mm
                         in size and 30 to 75 cm    in size and its depth is
                         in depth                   slightly more, i.e. about
                                                    60 to 90 cm.
       Filter sand       the effective size         In RSF the effective size
                         ranges between 0.2 to      ranges between 0.35 to
                         0.4 mm and uniformity      0.55 and uniformity
                         coefficient between        coefficient between
                         1.8 to 2.5 or 3.0.         1.2 to 1.8.
    Rate of filtration   it is small, such as 100 to it is large, such as 3000
                         200 L/h/sq.m. of filter     to 6000 L/h/sq.m. of
                         area                        filter area.
    Post treatment       Almost pure water is       water may be
                         obtained                   disinfected slightly to
                                                    make it completely
                                                    safe. Disinfection is a
                                                    must after RSF.
Slow sand filter      Rapid sand filter
Method of Cleaning   Scrapping and             To clean RSF, sand is
                     removing of the top 1.5   agitated and
                     to 3 cm thick layer is    backwashed with or
                     done to clean SSF.        without compressed air.
Disinfection
The filtered water may normally contain some harmful disease producing
bacteria in int. These bacteria must be killed in order to move the water safe
for drinking, and this process of killing bacteria is known as Disinfection or
sterilization

                       Menthod of disinfection
1. Boiling :- The bacteria present in water can be destroyed by boiling it for
   a long time.
2. Treatment with excess of lime:-Lime is used in water treatment plant for
   softening. But if excess lime is added to the water, it can in addition, kill
   the bacteria also.
3. Treatment with ozone:-Ozone readily breaks down into normal
   oxygen, and releases nascent oxygen. The nascent oxygen is a powerful
   oxidising agent and removes the organic matter as well as the bacteria
   from the water.
4. Chlorination:- The chlorine enters the cell walls of bacteria and kill the
   enzymes which are essential for the metabolic processes of living
   organisms.
Chlorine Chemistry
Chlorine is added to the water supply in two ways. It is most often added as
a gas, Cl2(g). However, it also can be added as a salt, such as sodium
hypochlorite (NaOCl) or bleach. Chlorine gas dissolves in water following
Henry's Law.
             Cl2(g) Cl2(aq) KH =6.2 x 10-2

Once dissolved, the following reaction occurs forming hypochlorous acid
(HOCl):
        Cl2(aq)+H2O HOCl + H+ + Cl-

Hypochlorous acid is a weak acid that dissociates to form hypochlorite ion
(OCl-).
          HOCl OCl- + H+ Ka = 3.2 x 10-8
All forms of chlorine are measured as mg/L of Cl2 (MW = 2 x 35.45 = 70.9
g/mol)
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Water Treatment-Domestic

  • 1. TREATMENT OF WATER GUIDED BY:- SHUBHAM BAPHANA Er. Ravi Parmar sir CE (3RD YEAR) Er. Sugandh singh sir 0862CE101115
  • 2.
  • 3. The available raw water must be treated and purified before they can be supplied to the public for domestic use or any industrial use. The extent of treatment of water depends upon following two- 1.Characteristics and quality of available water. 2.Quality requirements for the intended use.
  • 4.
  • 5. Parameters Desirable-Undesirable If no alternative source available, limit extended upto PHYSICAL Turbidity (NTU unit) < 10 25 Colour (Hazen scale) < 10 50 Taste and Odour Un-objectionable Un-objectionable CHEMICAL pH 7.0-8.5 6.5-9.2 Total Dissolved Solids 500-1500 3000 mg/l Total Hardness mg/l 200-300 600 (as CaCO3) Chlorides mg/l (as Cl) 200-250 1000 Sulphates mg/l (as 150-200 400 SO4) Fluorides mg/l (as F ) 0.6-1.2 1.5 Nitrates mg/l (as NO3) 45 45
  • 6. Unit treatment Function (removal) Aeration, chemicals use Colour, Odour, Taste Screening Floating matter Chemical methods Iron, Manganese, etc. Softening Hardness Sedimentation Suspended matter Suspended matter, a part of Coagulation colloidal matter and bacteria Remaining colloidal dissolved Filtration matter, bacteria Pathogenic bacteria, Organic Disinfection matter and Reducing substances
  • 7. Source Treatment required 1. Ground water and spring water No treatment or Chlorination fairly free from contamination 2. Ground water with chemicals, Aeration, coagulation (if minerals and gases necessary), filtration and disinfection 3. Lakes, surface water reservoirs Disinfection with less amount of pollution 4. Other surface waters such as Complete treatment rivers, canals and impounded reservoirs with a considerable amount of pollution
  • 8. AERATION:- •Aeration removes odor due to volatile gases and due to algae and related organisms. •Removes CO2 and reduce corrosion and remove methane and other inflammable gases. •Increases dissolved oxygen content in water. Aeration Gravity aerators Fountain aerators Diffused aerators Mechanical aerators
  • 9. FOUNTAIN AERATOR MECHANICAL AERATOR DIFFUSED AERATOR GRAVITY AERATOR
  • 10. Settling:- In this Solid particle are separated out from the water. • Clarified floating particle at the top of the sedimentation tank. • Concentrated sludge leaving the bottom of the sedimentation tank. Purpose of settling:- • To remove Coarse dispersed phase. • To remove coagulated and flocculated impurities. • To settle the Sludge. Principle of settling:- • Suspended solid present in water having specific gravity greater than that of water tend to settle down by gravity. • Basing in which the flow is retarded is called settling tank. • Theoretical average time for which the water is detained in the settling tank is called Detention Time.
  • 11. Types of settling:- 1. Type 1 Discrete particle settling:- • In discrete settling individual particles settle independently. • It occurs when there is a relatively low solids concentration. 2. Type 2 Flocculent particle settling:- • In flocculant settling, individual particles stick together into clumps called flocs. • This occurs when there is a greater solids concentration and chemical or biological reactions alter particle surfaces to enhance attachment. 3. Type 3 Compression:- Compression settling occurs when particles settle by compressing the mass below 4. Type 4 Zone settling:-
  • 12.
  • 13. Type of settling tank:- 1. Intermittent or Quiescent Type tank:- Those which store water for a certain period and keep it in complete rest. 2. Continuous Flow type tank:- The flow velocity is reduced and the water is not bought to complete rest as is done in above one. Long Rectangular Settling basin:- • They are hydraulically more stable and flow control for large volume is easier with this configuration. • Length is 2 to 4 times of widht with bottom to be made slope.
  • 14. This long rectangular settling basin is divided in four zones:- Inlet zone: Region in which the flow is uniformly distributed over the cross section. Settling zone: Settling occurs. Outlet zone: Clarified effluent is collected and discharge through outlet weir. Sludge zone: For collection of sludge below settling zone.
  • 15. Circular Basin:- • Circular settling basins have the same functional zones as the long rectangular basin, but the flow regime is different. When the flow enters at the centre and is baffled to flow radially towards the perimeter, the horizontal velocity of the water is continuously decreasing as the distance from the center increases. • Sludge removal mechanisms in circular tanks are simpler and require less maintenance.
  • 16. Design Details:- 1. Detention period: for plain sedimentation: 3 to 4 h, and for coagulated sedimentation: 2 to 2.5 h. 2. Velocity of flow: Not greater than 30 cm/min (horizontal flow). 3. Tank dimensions: L:B = 3 to 5:1. Generally L= 30 m (common) maximum 100 m. Breadth= 6 m to 10 m. Circular: Diameter not greater than 60 m. generally 20 to 40 m. 4. Depth 2.5 to 5.0 m (3 m). 5. Surface Overflow Rate: For plain sedimentation 12000 to 18000 L/d/m2 tank area; for thoroughly flocculated water 24000 to 30000 L/d/m2 tank area. 6. Slopes: Rectangular 1% towards inlet and circular 8%.
  • 17. Coagulation and flocculation:- • Colloidal particles are difficult to separate from water because they do not settle by gravity and are so small that they pass through the pores of filtration media. • To be removed, the individual colloids must aggregate and grow in size. •The aggregation of colloidal particles can be considered as involving two separate and distinct steps: a. Particle transport to effect interparticle collision. b. Particle destabilization to permit attachment when contact occurs. Flocculation:- It is a common practice to provide an initial rapid (or) flash mix for the dispersal of the coagulant or other chemicals into the water. Slow mixing is then done, during which the growth of the floc takes place. Rapid or Flash mixing is the process by which a coagulant is rapidly and uniformly dispersed through the mass of water. Generally, the detention period is 30 to 60 seconds and the head loss is 20 to 60 cms of water. Here colloids are destabilised and the nucleus for the floc is formed. Slow mixing brings the contacts between the finely divided destabilised matter formed during rapid mixing.
  • 18. -:Filltration:- To remove or to reduce the remaining impurities still further, the water is filtered through the beds of fine granular material, such as sand, etc. The process of passing the water through the beds of such granular materials is known as Filtration. -:Filter material:- 1. Sand:-Sand, either fine or coarse, is generally used as filter media The size of sand is measured and expressed by the term called effective size. 2. Gravel:- The layer of sand may be supported on gravel, which permits the filtered water to move freely to the under drains. 3. Other materials:- Instead of using sand, sometimes anthrafilt is used as filter media. Anthrafilt is made from anthracite. It is cheaper and has been able to give high rate of filtration.
  • 19. TYPES OF FILTERS 1. Slow Sand filter:- They consist of fine sand, supported by gravel. They capture particles near the surface of the bed and are usually cleaned by scraping away the top layer of sand that contains the particles. 2. Rapid sand Filter:- They consist of larger sand grains supported by gravel and capture particles throughout the bed. They are cleaned by backwashing water through the bed to 'lift out' the particles. 3. Multemedia Filter:- They consist of two or more layers of different granular materials, with different densities. Usually, anthracite coal, sand, and gravel are used. Because of the differences in densities, the layers stay neatly separated, even after backwashing.
  • 20. Difference Between SSF and RSF:- Slow sand filter Rapid sand filter Base Material varies from 3 to 65 mm varies from 3 to 40 mm in size and 30 to 75 cm in size and its depth is in depth slightly more, i.e. about 60 to 90 cm. Filter sand the effective size In RSF the effective size ranges between 0.2 to ranges between 0.35 to 0.4 mm and uniformity 0.55 and uniformity coefficient between coefficient between 1.8 to 2.5 or 3.0. 1.2 to 1.8. Rate of filtration it is small, such as 100 to it is large, such as 3000 200 L/h/sq.m. of filter to 6000 L/h/sq.m. of area filter area. Post treatment Almost pure water is water may be obtained disinfected slightly to make it completely safe. Disinfection is a must after RSF.
  • 21. Slow sand filter Rapid sand filter Method of Cleaning Scrapping and To clean RSF, sand is removing of the top 1.5 agitated and to 3 cm thick layer is backwashed with or done to clean SSF. without compressed air.
  • 22.
  • 23. Disinfection The filtered water may normally contain some harmful disease producing bacteria in int. These bacteria must be killed in order to move the water safe for drinking, and this process of killing bacteria is known as Disinfection or sterilization Menthod of disinfection 1. Boiling :- The bacteria present in water can be destroyed by boiling it for a long time. 2. Treatment with excess of lime:-Lime is used in water treatment plant for softening. But if excess lime is added to the water, it can in addition, kill the bacteria also. 3. Treatment with ozone:-Ozone readily breaks down into normal oxygen, and releases nascent oxygen. The nascent oxygen is a powerful oxidising agent and removes the organic matter as well as the bacteria from the water. 4. Chlorination:- The chlorine enters the cell walls of bacteria and kill the enzymes which are essential for the metabolic processes of living organisms.
  • 24. Chlorine Chemistry Chlorine is added to the water supply in two ways. It is most often added as a gas, Cl2(g). However, it also can be added as a salt, such as sodium hypochlorite (NaOCl) or bleach. Chlorine gas dissolves in water following Henry's Law. Cl2(g) Cl2(aq) KH =6.2 x 10-2 Once dissolved, the following reaction occurs forming hypochlorous acid (HOCl): Cl2(aq)+H2O HOCl + H+ + Cl- Hypochlorous acid is a weak acid that dissociates to form hypochlorite ion (OCl-). HOCl OCl- + H+ Ka = 3.2 x 10-8 All forms of chlorine are measured as mg/L of Cl2 (MW = 2 x 35.45 = 70.9 g/mol)

Editor's Notes

  1. Volatile gases- Hydrogen sulphideGravity Aerators (Cascades): In gravity aerators, water is allowed to fall by gravity such that a large area of water is exposed to atmosphere, sometimes aided by turbulence.Fountain Aerators : These are also known as spray aerators with special nozzles to produce a fine spray. Each nozzle is 2.5 to 4 cm diameter discharging about 18 to 36 l/h. Nozzle spacing should be such that each m3 of water has aerator area of 0.03 to 0.09 m2 for one hour.Injection or Diffused Aerators : It consists of a tank with perforated pipes, tubes or diffuser plates, fixed at the bottom to release fine air bubbles from compressor unit. The tank depth is kept as 3 to 4 m and tank width is within 1.5 times its depth. If depth is more, the diffusers must be placed at 3 to 4 m depth below water surface. Time of aeration is 10 to 30 min and 0.2 to 0.4 litres of air is required for 1 litre of water.