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Industry Update on Nitrogen Removal
Programs Across the United States:
What Does it Mean for New England?
March 3rd, 2011

Richard H. Cisterna, P.E.
Cisterna, P.E.

1
Outline
1

Water Industry Sustainability

2

National Perspective - Nitrogen and Hypoxia

3

Massachusetts Estuaries
Nitrogen Treatment Technology Overview

4
5

Conventional and Advanced
Case Studies

6
2

Summary and Conclusions
Water Industry Sustainability

3
Sustainability is in Vogue

4
Focus of Sustainability has been on Energy
● Energy Audits
● Energy Optimization
● Renewable Energy
Sources

5
Sustainability Balancing Act

Nitrogen

Water Supply /
Wastewater Effluent

Green Energy
Carbon Footprint
6
National Perspective on
Nitrogen and Hypoxia

7
Nitrogen is an Emerging National Concern

8
Nitrogen’s Impact on the Ecosystem

Source: evworld.com
9
Chesapeake Bay Oxygen Depletion

Source: evworld.com
10
Long Island Sound Nitrogen Control Program
● In 1998, CT, NY, and EPA agreed to reduce
human sources of N by 58.5% by 2014. A
TMDL was developed and approved by EPA
in 2001.

11
Long Island Sound

12
Source: CTDEP and Long Island Sound Study
The Mississippi River Carries A lot of Nitrogen

13
And the Gulf of Mexico Pays the Price…

Source: evworld.com
14
Historical Development of Nitrogen Limits

10
9

Chesapeake Bay

Long Island Sound, NYC

8 mg/l

8
7

TMDL
(mg/l)

6

Long Island Sound, CT

North Carolina

5 mg/l

5
4

3 mg/l

3
2

1.5 mg/l

1

Florida

0

1990
15

2000

2010

2020
Massachusetts Estuaries

16
Mass Estuaries also have nitrogen concerns

17
Mass Nitrogen Reduction Program Goals
» Reduce ‘N’ to estuaries
» Consider centralized and decentralized
approaches
» Highly treat wastewater to new
Massachusetts DEP Standards
» Strategically recharge reclaimed water

18
Western Cape Recharge Basins

Source: USGS
19
Mass. DEP: Groundwater Discharge Program
(314 CMR 5.00)
Requirements


Meet secondary treatment effluent limits:
» Nitrate as Nitrogen < 10 mg/L
» Total Nitrogen
< 10 mg/L
» Fecal Coliform
< 200 colonies per 100 mL

All Discharges


Discharges within
Zone II or IWPA

Effluent shall be filtered to meet:
» TSS
» Turbidity

» TOC


Discharges within
Zone II or IWPA
and 2 year Travel
Time

< 10 mg/L
< 5 NTU

< 3 mg/L

Effluent shall be oxidized, filtered, disinfected and coagulated
to meet:
» TSS
» Turbidity
» BOD

< 5 mg/L
< 2 NTU
< 10 mg/L

» TOC

< 1 mg/L

» Fecal Coliform

= avg. of zero colonies per 100 mL over a
continuous 7 day sampling period; no single
sample shall exceed 14 colonies per 100 mL
= 5 Log Inactivation and/or Removal

or

20

Direct Injection
(into saturated
zone)

» Virus


Disinfection shall not be waived.



Coagulation may be waived if meet turbidity requirement with
filtration alone.
Treatment Approaches?
● Decentralized Advanced Septic Systems
● Biological Treatment
● Centralized MF/RO, (AOP?) – Concentrate Issue
● MF, GAC, (AOP?)

21
Regulations for Indirect Potable Reuse
Florida

Mass.

10 ppm*

10 ppm*

5 ppm

10 ppm

1 ppm

TOC

3 ppm

3 ppm
1 ppm

0.5 ppm

---

1 ppm

Emerging
Contaminants

No/Yes

No?

Yes

No/Yes

Yes

Nitrogen

California Arizona

* Local requirements can be more stringent

22

Australia
Nitrogen Treatment

23
Nitrification / Denitrification Activated
Sludge Process - MLE
TKN = 30 mg/L
TP = 7 mg/L

Aeration Tanks

3Q
Pretreated
Wastewater

Primary
Clarifiers

NH3-N < 2 mg/L
NO3-N < 5 mg/L
TN = 8 mg/L
TP = 5 mg/L
Secondary
Clarifiers

Anoxic

Air Blowers

Secondary
Effluent

Aerobic

Return Sludge

Primary
Sludge

Waste Activated
Sludge

N&P Removal

● Solids in primary sludge (5 - 10 %)
● Biosynthesis in WAS (10 - 20 %)
● Denitrification (40 - 60 %)
24

TN ~ 8 to 10 mg/L
BNR Step Feed Configuration
TWO-STEP FEED PROCESS

Step Feed
Secondary
Clarifiers

Pretreated
Wastewater

Anoxic

Aerobic Anoxic

Secondary
Effluent

Aerobic

RAS

TN ~ 6 to 9 mg/L

Waste Activated
Sludge

FOUR - STEP FEED PROCESS
Secondary
Clarifiers

Pretreated
Wastewater

Secondary
Effluent

Anoxic Aerobic Anoxic Aerobic Anoxic Aerobic Anoxic Aerobic
RAS

25

TN ~ 4 to 6 mg/L

Waste Activated
Sludge
BNR Process Configurations – 5-stage
Typical 5-stage BNR Process – Lower TN limit
Carbon
Secondary
Clarifier
Wastewater
Anaerobic Primary
Anoxic

Aerobic Secondary
Anoxic

BNR
Aeration Tank

Secondary
Effluent

Reaeration

WAS

TN ~ 3 to 4 mg/L
26
3+ Stage with Denitrification Filters
TN < 3 mg/L
Acetate

Methanol

Secondary
Clarifier
Wastewater
Anaerobic Anoxic

Aerobic

BNR
Aeration Tank

WAS

27

Granular
Media
Filter

Secondary
Effluent
Denitrification Filters
● Nitrified secondary effluent sent to filtration
● Filter media used to grow an attached biomass that
will denitrify the secondary effluent
● Supplemental carbon addition
● Good solids removal + denite – 2 gpm/ft2

28
Membrane Bioreactor (MBR)
Typical MBR Process

29
Integrated Fixed Film Activated Sludge
(IFAS)
● Media held in Aeration Basins to provide
attached growth for Nitrifying biomass
● Typical Floating and Fixed IFAS Media
» Kaldnes (plastic)
» Linpor (sponge)
» Ringlace (cord)

30

30
IFAS in Nutrient Removal
ANA

ANOX AEROBIC

•Higher capacity in same
volume
•“Modular” phasing
•Improved wet weather
stability
31

ANOX
TZ Osborne WRF – Pilot Layout
RAS

To Final
Clarifier No. 7

Primary
Effluent

IFAS
Cell 1

~ 35% fill (AK-K3)
3 distinct zones
32

IFAS
Cell 2

IFAS
Cell 3

Screens for each cell
Isolation / throttle air
valve for each cell
IFAS Pilot Results / Lessons Learned
● Effective nitrification in
approximately half the
aerobic volume
● Dynamic microbial
population
● Higher air usage
● Screen headloss higher than
expected
● Foam handling a must
● Influent screening must be
sized correctly (i.e. opening
size)

33

Biomass on Media (gTSS/m2 of media surface)

30

25

20

15

10

5

0
04/01/08

06/13/08

08/25/08

11/06/08

01/18/09

04/01/09

Date
Cell D Biomass

Cell E Biomass

Cell F Biomass
BioMag

From CWT Website http://cambridgewatertech.com/technology/biomag
34
Typical Process Treatment Train for Ultra-Low
UltraNutrient Standards

35
Cost vs. Nitrogen Removal

Cost ($)

Nitrogen Removal (mg/L)
36
Nitrogen Removal Option Summary*

2-Stage
BNR

4/54/5-Stage
BNR
+ Carbon
Feed

4/54/5-Stage
BNR
+ Denite
Filters

4/5-Stage
4/5BNR
+ MBR w/
Carbon Feed

4/5-Stage
4/5BNR
+ UF + NF or
RO

TN effluent
Achievable

8 - 12 mg/L

3 - 6 mg/L

3 - 4 mg/L

2 - 3 mg/L

< 1.5 mg/L

Capital Cost
per GPD

$0.25 - $1.25

$0.50 - $2.00

$1.25 - $2.50

$2.50 - $3.00

$3.00 - $4.00

40 kW

50 kW

55 kW

100 kW

125 kW

$21k - $28k

$30k - $40k

$35k - $47k

Criteria

Energy
Usage per
MGD
Annual O&M
Cost per
MGD

$121k - $161k $261k - $348k

*Relative cost for additional treatment only. Total cost will depend on the available plant infrastructure.
37
Supplemental Carbon

38
Available Supplemental Carbon Sources
● Methanol
● Ethanol
● Acetic acid
● Corn syrup/sugar
● Glycerin
● MicroC™
● Primary fermentate
39
Methanol Considerations
● Benefits
» Low cost (relative to alternatives)
» Low yield (low solids production)
» Proven technology
● Drawbacks
» Requires specialist population
■ Slow growing
» Volatile price
» Slower kinetics
» Flammable
40

Recent Methanol Accident Site at
Bethune Point WWTP
41

www.methanex.com

Mar-09

Sep-08

Mar-08

Sep-07

Mar-07

Sep-06

Mar-06

Sep-05

Mar-05

Sep-04

Apr-04

Oct-03

Apr-03

Oct-02

Apr-02

Oct-01

Apr-01

Methanol Price ($/Gallon)

Methanol Costs – 2001 to 2009
(Expect Price Fluctuations)
$3.00

$2.50

$2.00

$1.50

$1.00

$0.50

$0.00
Glycerin
● Typically byproduct of
biodiesel production
● Benefits
» Faster kinetics

● Drawbacks
» Potential for product
inconsistencies with
waste products

» Viscous in cold weather
» Specialist population not
required
● Products
» Brenntag
» Unicarb-DN
» BioCarb DN (Denite-1)
» MicroC-Glycerin
» Waste products
42
Alternative Carbon Testing
Parameter

NRWWTP

HCWRF

Size (mgd)
Feed point
Basins fed
carbon
Control
(if
applicable)

75

75

One

All

Substrate
43

PWWTP

SDWRF

NDWRF

7.5
Second anoxic zone
All

20

20

One

4 out of 5

One parallel Full-scale
Full-scale One parallel One parallel
basin that
evaluation, evaluation,
basin that
basin that
was fed
therefore no therefore no was not fed was not fed
methanol
control
control
carbon
carbon
Glycerin
Sugar water
Glycerin
Glycerin
Glycerin
and glycerin
Parkway WWTP
CHLORINE
CONTACT
BASINS

INFLUENT PUMP
STATION
RAS
PUMP
STATION

SECONDARY
CLARIFIERS

BNR BASIN #2
(RB2)
GRIT
REMOVAL

PRIMARY
CLARIFIERS
BNR BASIN #1
(RB1)
SOLIDS HANDLING

44

MLR PUMP
STATION
Parkway Full-Scale Pilot Data
Full■ No Acclimation Period Required
Full Scale Pilot Data

1/26/2008

1/19/2008

1/12/2008

45
Effluent NOx

Effluent TN

Brenntag Glycerin

7 per. Mov. Avg. (Effluent NOx)

7 per. Mov. Avg. (Effluent TN)

Carbon dose, gal/day

0

1/5/2008

0

12/29/2007

20

12/22/2007

1

12/15/2007

40

12/8/2007

2

12/1/2007

60

11/24/2007

3

11/17/2007

80

11/10/2007

4

11/3/2007

100

10/27/2007

120

5

Concentration (mg/L)

6
Cell
1

Cell 2

Cell 3

3848-047

Primary
Anoxic/
Aerobic Zone

Cell 4

Cell 5

Secondary
Anoxic/
Aerobic Zone

Aerobic Zone

Cell 6

Cell 7

Cell 8

R
eAeration
Zone

Prim
ary
A
noxic/
Anaerobic Zone

Anaerobic
Zone

RA
S
Ferm
entation

Henrico VA

Cell 9

Cell 10

Cell 11

Cell 12

Cell 13

NRCY

RAS

M istributionC
LD
hannel

PED
istributionChannel

RA
SPipeline

BNR Tank 8

NRCY

RAS

BNR Tank 7

NRCY

RAS

BNR Tank 6

NRCY

RAS

To
Secondary
Clarifier
No. 8

BNR Tank 5

ML Distribution Channel
RAS/WAS
Pump Station

RAS

46

To
Secondary
Clarifier
No. 7
Henrico County WRF Plant Effluent Nitrogen
Profile vs. Substrate Feed Rate
● Sugar water and glycerin both effective.

47
North Carolina “Conventional”
Case Studies

48
Neuse River WWTP, Raleigh, NC
● 60 mgd Advanced WWTP
» Primary Clarifiers
» 4-stage BNR w/ methanol
addition
» Denitrification Filters w/
methanol addition
● Largest Plant in Eastern U.S.
Achieving LOT for TN Utilizing
Conventional Suspended Growth
BNR Process
● Upcoming Expansion to 75 mgd
» TN = 2.7 mg/L, TP = 1 mg/L
● Calibrated BioWin Model Used to
Evaluate/ Optimize Expansion
49
Neuse River –
4-stage w/ denitrification filters
Typical Operating Parameters

50
Neuse River - Operation and Performance
● Most TN Removal in BNR Basins
● Filters “Trimming” ± 1 mg/L (~ 5 mg/L Methanol Dose)
● Annual Average Effluent TN = 2.4 mg/L (2004 - 2008)
S E a n d F in a l E fflu e n t N itr o g e n C o n c e n tr a tio n s

6

● 2007 Annual Average Effluent TN = 1.96 mg/L

Concentration (mg/L)

5

4

3

2

1

EFF TN

SE TN

3 0 p e r. M o v . A v g . (E F F T N )

3 0 p e r. M o v . A v g . (S E T N )

Sep-07

Jul-07

May-07

Mar-07

Jan-07

Nov-06

Sep-06

Jul-06

May-06

Mar-06

Jan-06

Nov-05

Sep-05

Jul-05

May-05

Mar-05

Jan-05

Nov-04

Sep-04

Jul-04

May-04

Mar-04

51

Jan-04

0
High Point, NC – 26 mgd, 5-stage process
mgd, 5-

52
53
EFF TN

No alum or ferric
10/29/2008

7/31/2008

5/2/2008

2/2/2008

11/4/2007

8/6/2007

5/8/2007

2/7/2007

11/9/2006

8/11/2006

5/13/2006

2/12/2006

11/14/2005

20

8/16/2005

5/18/2005

2/17/2005

11/19/2004

8/21/2004

5/23/2004

2/23/2004

11/25/2003

8/27/2003

5/29/2003

2/28/2003

11/30/2002

9/1/2002

EFF Total Nitrogen (mg/L)

High Point Performance

22

Average Eff TN 1/07 to 12/08 = 3.3 mg/L

18

16

14

12

No supplemental
carbon

10

8

6

4

2

0

30 per. Mov. Avg. (EFF TN)

Avg TP = 0.18 mg/L Biologically
Major Recycle Impacts
● Solids handling recycle streams
» Filtrate, centrate, gravity thickener
overflow
● Frequency of return
Parameters

Plant Recycle Loads
(lbs/day)

Contribution From
Plant Recycles
(%)

BOD

43,600

2,830

6.5

TSS

39,300

6,590

17

TKN
54

Plant Influent Loads
(lbs/day)

5,700

1,620

29

TP

1,280

680

53
Florida “Advanced”
Case Studies

55
Florida vs. Mass Estuary Nitrogen Challenge
● FL - Existing Ocean Outfalls and Septic Tanks
● Cape – Mostly Septic Tanks
● Both – High Level Nitrogen Treatment / Recharge

56
Historically, South Florida’s sole source supply
(the Biscayne Aquifer), was fiercely protected
Effluent
Reuse

Class I
Deep Injection Wells
57

Two Key issues for FDEP:
● Alternate Water Supply
Resource
● Environmental
enhancement (Nitrogen)
Existing Supply Limited for Utilities

C.E.R.P
No New Water
for the Public
58
Recent Legislation – Ocean Outfall Ban
● Outfall shut down due to nitrogen – Coral Reefs
● Achieve significant TN & TP reductions by 2018
● “Reuse” 60% of outfall flow by 2025
● After 2025, outfall for wet weather back-up, w/
nutrient reductions

59
Legislated Water Reuse Requirements
Lake
Okeechobee

7.7 MGD
6.2 MGD
22.4 MGD
24.1 MGD
48.6 MGD
68.9 MGD

Total = 178 MGD

60

South Central Regional
Boca Raton
Broward Co. North

Hollywood
Miami-Dade North
Miami-Dade Central District
Recharging Groundwater is Essentially a Surface
Water Discharge – nitrogen concerns

County / Local Issues

61
Miami Dade County

62
Miami South District
Water Reclamation Plant
● 1st indirect potable reuse project in Florida
● Recharge drinking water aquifer with 23 mgd of
highly treated wastewater
● Addressing pharmaceuticals and pathogens with
regulators and public
● MF, RO, UV-AOP
● Ultra-pure drinking
water quality

63
Emerging Contaminants
Pharmaceuticals

Personal
Care Products

64

Endocrine
Disrupting Compounds
Advanced Oxidation Processes (AOPs)
High dosage UV w/ H2O2
UV ~ 500 mj/cm2
H2O2 ~ 1-3 ppm

UV – TiO2
Ozone
65
Hydroxyl Radical (OH°) is a very strong oxidant!

OXIDIZING SPECIES

RELATIVE OXIDATION
POTENTIAL (V)

Hydroxyl Radical

2.05

Ozone

1.52

Hydrogen Peroxide

1.31

Permanganate

1.24

Chlorine Dioxide

1.15

Chlorine

1.00

Data from Metcalf & Eddy, 2003

66

Increasing
ability to
degrade
pollutants
Miami Dade South District WRP

Miami-Dade County
Miami-

67
Example of the complexities
Moat

Drainage Canal

Regional Canal

Proposed
Biscayne Wells

68

Note: Locations are conceptual. Intended for discussion purposes only
Biscayne National Park is Environmentally
Sensitive

69
Groundwater Recharge Criteria

Miami Dade
County

Florida
State
Standard

TOC

--

3 mg/l

Total Suspended Solids (TSS)

--

5 mg/l

Total Nitrogen (TN)

--

10 mg/L

Ammonia

2.8 mg/l
0.5 mg/l

--

Total Phosphorus (TP)

.003 mg/l

--

Yes

No

Parameter

Emerging Contaminants
70
Precedent Setting Treatment Levels

71
Plantation, FL Pilot Study

72
WWTP Located Near Canal That Could
Recharge the Biscayne Aquifer

Plantation
WWTF

East Holloway
Canal

East
Wellfields
Central
Wellfields

73
Pilot Goals
● Demonstrate technology
can meet water quality
» TN
» TP
● Unregulated Parameters
» Microconstituents
» Toxicity
» Algal growth potential
» Hormonal impacts

74
Things to consider

75
Nutrient Control
● What is the
technology
necessary to meet
the stringent TN &
TP limits?
● Biological vs
Chemical nutrient
removal
● Are RO
membranes
necessary?
76
Aquatic Organism Impact
● Whole effluent
toxicity (WET)
tests
● Is the RO
permeate toxic?
● Will the effluent
cause any
hormonal
impacts?

77
Microconstituents
● Which
microconstituents are
in your wastewater?
● What technology will
most effectively
remove them?
● Are
microconstituents
really a concern at
these concentrations
(ng/L)?
78
Recharge Modeling
● Does your
point of
discharge “offset” your
withdrawal
impacts?
● Can you get a
1/1 credit?
● What happens
during the wet
season?
79
Sustainability
● Is this really
sustainable?
● Water Supply
vs Carbon
Footprint?

80
Public Outreach
● How do you
change the “Sewer
to Tap” mentality?
● How do you
involve the public
early in the
project?

81
Costs
● Capital cost
● Energy costs

82
Plantation Pilot

83
Broward County
Canal Recharge Effluent Limits
Parameter

Effluent Limit

TN

< 1.5 mg/L

TP

< 0.02 mg/L

Nitrate

< 10 mg/L

Ammonia
TSS

< 5.0 mg/L

CBOD5

< 10.0 mg/L

BOD

84

< 0.02 mg/L

< 5.0 mg/L
MBR Scheme

85
Conventional Treatment Scheme

86
MBR Scheme Data

87
Plantation AWT MBR Scheme
MBR Pilot

88

RO/UV
Pilot Trailer
Total nitrogen removal of
MBR and RO Pilot Units

89
Total phosphorus removal of
MBR and RO Pilot Units

90
Conventional Treatment Data

91
Plantation AWT Conventional
Treatment Scheme
Denitrification
Filter Pilot

92

UF/RO/UV
Pilot Trailer
Total nitrogen removal of
Deep Bed Filter and RO Pilot Units

93
Total phosphorus removal of
Deep Bed Filter and RO Pilot Units

94
Conclusions – Nutrient Removal

● Both pilots met stringent TN & TP limits
● RO membranes are necessary to meet TP limit
● Membranes alone (UF/RO) with no chemical
addition met TN & TP limits

95
Microconstituents

96
What are Microconstituents?
● Pharmaceutically Active Compounds (PhAC)
» Ethynyl Estradiol
» Sulfamethaxazole
● Personal Care Products (PCP)

Ethynyl Estradiol

» Triclosan
» Toiletries, cosmetics, fragrances
● Endocrine Disrupting Compounds (EDC)
» Bisphenol-a
» Atrazine
» DEET
97

DEET

Triclosan
Concentration (ng/l)

Microconstituents –
RO Influent Concentrations

98
Concentration (ng/l)

Microconstituents – Most were
removed by RO membranes

99
Aquatic Organism Toxicity Testing

100
Is the RO permeate toxic?
● RO permeate is too clean
» RO re-stabilization/re-mineralization
» Added salts and minerals
● How would this work full scale?
» Dilution
» Mixing zone

101
Does RO Pre-treatment
Preaffect toxicity?
● RO Pre-treatment
» Antiscalant
» Chloramines
● Pilot Results
Fatheaded Minnow

102

Water Flea
Summary
● The pilot demonstrated to meet stringent nutrient
limits at different test conditions.
● RO membranes are necessary for surface water
discharge due to stringent TP limits.
● Almost all microconstituents were removed by
RO system.
● RO permeate could be toxic re-stabilization/remineralization is necessary.
● The observed toxicity to aquatic organisms was
likely caused by chloramines. Other forms of RO
pretreatment should be evaluated.
103
University of Connecticut
Advanced Reuse Project

104
University of Connecticut Reuse Project

105
This is a Spotlight Project

106
Potential Uses of Reclaimed Wastewater
Reuse
Facility ►

▼ WWTP

◄ Power Plant

107

◄ Irrigation Sites ►
Process Flow Diagram

108
UCONN Reclaimed Water Facility
University of Connecticut
– Reclaimed Water Facility
Location

Storrs, CT

Capacity

1.0 mgd

Technology

Microfiltration +
UV Disinfection +
Chloramination

Application

• Cooling Tower
Make-Up Water
• Boiler Feed Water
(post RO treatment)

• Irrigation
Unique
Challenges

109

• Corrosion &
Scaling Control for
Cooling Towers
MF System Design Criteria
Parameter
Type

Pressurized

System Rated Capacity

1 mgd

No. of MF Units

3

No. of Membrane Modules per Unit

32

Membrane Type

0.1 micron PVDF

Specific Design Flux

39 gfd

Minimum Recovery Percent
110

Value

91%
UV System Design Criteria
Parameter
Type

LPHO

System Rated Capacity

1 mgd

No. of UV Systems

2+1

UV Design Dose

80 mJ/cm2

UV Transmittance

≥ 65% at 254 nm

Effluent Turbidity

≤ 0.2 NTU (95% of the time)

Effluent Total Coliform Max.

2.2/100 mL (7 day geometric mean)

Suspended Solids Max.
111

Value

5 mg/L
Sustainability Features
● Replaces as much as
40% of water supply at
times
● Reclaimed water
reservoir used as a
heating source
● Stormwater capture and
blending with wastewater
● Solar electricity

112
Constructed New Facility?

113
Summary and Conclusions

114
Summary and Conclusions
● Nitrogen control programs are growing
● Very low nitrogen requires significant energy and $
● Range of treatment options
● Good experiences and resources in other states to
draw upon

115

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DATA STRUCTURE AND ALGORITHM for beginners
 

Industry update on nitrogen removal programs across the United States: What does it mean for New England?

  • 1. Industry Update on Nitrogen Removal Programs Across the United States: What Does it Mean for New England? March 3rd, 2011 Richard H. Cisterna, P.E. Cisterna, P.E. 1
  • 2. Outline 1 Water Industry Sustainability 2 National Perspective - Nitrogen and Hypoxia 3 Massachusetts Estuaries Nitrogen Treatment Technology Overview 4 5 Conventional and Advanced Case Studies 6 2 Summary and Conclusions
  • 5. Focus of Sustainability has been on Energy ● Energy Audits ● Energy Optimization ● Renewable Energy Sources 5
  • 6. Sustainability Balancing Act Nitrogen Water Supply / Wastewater Effluent Green Energy Carbon Footprint 6
  • 8. Nitrogen is an Emerging National Concern 8
  • 9. Nitrogen’s Impact on the Ecosystem Source: evworld.com 9
  • 10. Chesapeake Bay Oxygen Depletion Source: evworld.com 10
  • 11. Long Island Sound Nitrogen Control Program ● In 1998, CT, NY, and EPA agreed to reduce human sources of N by 58.5% by 2014. A TMDL was developed and approved by EPA in 2001. 11
  • 12. Long Island Sound 12 Source: CTDEP and Long Island Sound Study
  • 13. The Mississippi River Carries A lot of Nitrogen 13
  • 14. And the Gulf of Mexico Pays the Price… Source: evworld.com 14
  • 15. Historical Development of Nitrogen Limits 10 9 Chesapeake Bay Long Island Sound, NYC 8 mg/l 8 7 TMDL (mg/l) 6 Long Island Sound, CT North Carolina 5 mg/l 5 4 3 mg/l 3 2 1.5 mg/l 1 Florida 0 1990 15 2000 2010 2020
  • 17. Mass Estuaries also have nitrogen concerns 17
  • 18. Mass Nitrogen Reduction Program Goals » Reduce ‘N’ to estuaries » Consider centralized and decentralized approaches » Highly treat wastewater to new Massachusetts DEP Standards » Strategically recharge reclaimed water 18
  • 19. Western Cape Recharge Basins Source: USGS 19
  • 20. Mass. DEP: Groundwater Discharge Program (314 CMR 5.00) Requirements  Meet secondary treatment effluent limits: » Nitrate as Nitrogen < 10 mg/L » Total Nitrogen < 10 mg/L » Fecal Coliform < 200 colonies per 100 mL All Discharges  Discharges within Zone II or IWPA Effluent shall be filtered to meet: » TSS » Turbidity » TOC  Discharges within Zone II or IWPA and 2 year Travel Time < 10 mg/L < 5 NTU < 3 mg/L Effluent shall be oxidized, filtered, disinfected and coagulated to meet: » TSS » Turbidity » BOD < 5 mg/L < 2 NTU < 10 mg/L » TOC < 1 mg/L » Fecal Coliform = avg. of zero colonies per 100 mL over a continuous 7 day sampling period; no single sample shall exceed 14 colonies per 100 mL = 5 Log Inactivation and/or Removal or 20 Direct Injection (into saturated zone) » Virus  Disinfection shall not be waived.  Coagulation may be waived if meet turbidity requirement with filtration alone.
  • 21. Treatment Approaches? ● Decentralized Advanced Septic Systems ● Biological Treatment ● Centralized MF/RO, (AOP?) – Concentrate Issue ● MF, GAC, (AOP?) 21
  • 22. Regulations for Indirect Potable Reuse Florida Mass. 10 ppm* 10 ppm* 5 ppm 10 ppm 1 ppm TOC 3 ppm 3 ppm 1 ppm 0.5 ppm --- 1 ppm Emerging Contaminants No/Yes No? Yes No/Yes Yes Nitrogen California Arizona * Local requirements can be more stringent 22 Australia
  • 24. Nitrification / Denitrification Activated Sludge Process - MLE TKN = 30 mg/L TP = 7 mg/L Aeration Tanks 3Q Pretreated Wastewater Primary Clarifiers NH3-N < 2 mg/L NO3-N < 5 mg/L TN = 8 mg/L TP = 5 mg/L Secondary Clarifiers Anoxic Air Blowers Secondary Effluent Aerobic Return Sludge Primary Sludge Waste Activated Sludge N&P Removal ● Solids in primary sludge (5 - 10 %) ● Biosynthesis in WAS (10 - 20 %) ● Denitrification (40 - 60 %) 24 TN ~ 8 to 10 mg/L
  • 25. BNR Step Feed Configuration TWO-STEP FEED PROCESS Step Feed Secondary Clarifiers Pretreated Wastewater Anoxic Aerobic Anoxic Secondary Effluent Aerobic RAS TN ~ 6 to 9 mg/L Waste Activated Sludge FOUR - STEP FEED PROCESS Secondary Clarifiers Pretreated Wastewater Secondary Effluent Anoxic Aerobic Anoxic Aerobic Anoxic Aerobic Anoxic Aerobic RAS 25 TN ~ 4 to 6 mg/L Waste Activated Sludge
  • 26. BNR Process Configurations – 5-stage Typical 5-stage BNR Process – Lower TN limit Carbon Secondary Clarifier Wastewater Anaerobic Primary Anoxic Aerobic Secondary Anoxic BNR Aeration Tank Secondary Effluent Reaeration WAS TN ~ 3 to 4 mg/L 26
  • 27. 3+ Stage with Denitrification Filters TN < 3 mg/L Acetate Methanol Secondary Clarifier Wastewater Anaerobic Anoxic Aerobic BNR Aeration Tank WAS 27 Granular Media Filter Secondary Effluent
  • 28. Denitrification Filters ● Nitrified secondary effluent sent to filtration ● Filter media used to grow an attached biomass that will denitrify the secondary effluent ● Supplemental carbon addition ● Good solids removal + denite – 2 gpm/ft2 28
  • 30. Integrated Fixed Film Activated Sludge (IFAS) ● Media held in Aeration Basins to provide attached growth for Nitrifying biomass ● Typical Floating and Fixed IFAS Media » Kaldnes (plastic) » Linpor (sponge) » Ringlace (cord) 30 30
  • 31. IFAS in Nutrient Removal ANA ANOX AEROBIC •Higher capacity in same volume •“Modular” phasing •Improved wet weather stability 31 ANOX
  • 32. TZ Osborne WRF – Pilot Layout RAS To Final Clarifier No. 7 Primary Effluent IFAS Cell 1 ~ 35% fill (AK-K3) 3 distinct zones 32 IFAS Cell 2 IFAS Cell 3 Screens for each cell Isolation / throttle air valve for each cell
  • 33. IFAS Pilot Results / Lessons Learned ● Effective nitrification in approximately half the aerobic volume ● Dynamic microbial population ● Higher air usage ● Screen headloss higher than expected ● Foam handling a must ● Influent screening must be sized correctly (i.e. opening size) 33 Biomass on Media (gTSS/m2 of media surface) 30 25 20 15 10 5 0 04/01/08 06/13/08 08/25/08 11/06/08 01/18/09 04/01/09 Date Cell D Biomass Cell E Biomass Cell F Biomass
  • 34. BioMag From CWT Website http://cambridgewatertech.com/technology/biomag 34
  • 35. Typical Process Treatment Train for Ultra-Low UltraNutrient Standards 35
  • 36. Cost vs. Nitrogen Removal Cost ($) Nitrogen Removal (mg/L) 36
  • 37. Nitrogen Removal Option Summary* 2-Stage BNR 4/54/5-Stage BNR + Carbon Feed 4/54/5-Stage BNR + Denite Filters 4/5-Stage 4/5BNR + MBR w/ Carbon Feed 4/5-Stage 4/5BNR + UF + NF or RO TN effluent Achievable 8 - 12 mg/L 3 - 6 mg/L 3 - 4 mg/L 2 - 3 mg/L < 1.5 mg/L Capital Cost per GPD $0.25 - $1.25 $0.50 - $2.00 $1.25 - $2.50 $2.50 - $3.00 $3.00 - $4.00 40 kW 50 kW 55 kW 100 kW 125 kW $21k - $28k $30k - $40k $35k - $47k Criteria Energy Usage per MGD Annual O&M Cost per MGD $121k - $161k $261k - $348k *Relative cost for additional treatment only. Total cost will depend on the available plant infrastructure. 37
  • 39. Available Supplemental Carbon Sources ● Methanol ● Ethanol ● Acetic acid ● Corn syrup/sugar ● Glycerin ● MicroC™ ● Primary fermentate 39
  • 40. Methanol Considerations ● Benefits » Low cost (relative to alternatives) » Low yield (low solids production) » Proven technology ● Drawbacks » Requires specialist population ■ Slow growing » Volatile price » Slower kinetics » Flammable 40 Recent Methanol Accident Site at Bethune Point WWTP
  • 42. Glycerin ● Typically byproduct of biodiesel production ● Benefits » Faster kinetics ● Drawbacks » Potential for product inconsistencies with waste products » Viscous in cold weather » Specialist population not required ● Products » Brenntag » Unicarb-DN » BioCarb DN (Denite-1) » MicroC-Glycerin » Waste products 42
  • 43. Alternative Carbon Testing Parameter NRWWTP HCWRF Size (mgd) Feed point Basins fed carbon Control (if applicable) 75 75 One All Substrate 43 PWWTP SDWRF NDWRF 7.5 Second anoxic zone All 20 20 One 4 out of 5 One parallel Full-scale Full-scale One parallel One parallel basin that evaluation, evaluation, basin that basin that was fed therefore no therefore no was not fed was not fed methanol control control carbon carbon Glycerin Sugar water Glycerin Glycerin Glycerin and glycerin
  • 44. Parkway WWTP CHLORINE CONTACT BASINS INFLUENT PUMP STATION RAS PUMP STATION SECONDARY CLARIFIERS BNR BASIN #2 (RB2) GRIT REMOVAL PRIMARY CLARIFIERS BNR BASIN #1 (RB1) SOLIDS HANDLING 44 MLR PUMP STATION
  • 45. Parkway Full-Scale Pilot Data Full■ No Acclimation Period Required Full Scale Pilot Data 1/26/2008 1/19/2008 1/12/2008 45 Effluent NOx Effluent TN Brenntag Glycerin 7 per. Mov. Avg. (Effluent NOx) 7 per. Mov. Avg. (Effluent TN) Carbon dose, gal/day 0 1/5/2008 0 12/29/2007 20 12/22/2007 1 12/15/2007 40 12/8/2007 2 12/1/2007 60 11/24/2007 3 11/17/2007 80 11/10/2007 4 11/3/2007 100 10/27/2007 120 5 Concentration (mg/L) 6
  • 46. Cell 1 Cell 2 Cell 3 3848-047 Primary Anoxic/ Aerobic Zone Cell 4 Cell 5 Secondary Anoxic/ Aerobic Zone Aerobic Zone Cell 6 Cell 7 Cell 8 R eAeration Zone Prim ary A noxic/ Anaerobic Zone Anaerobic Zone RA S Ferm entation Henrico VA Cell 9 Cell 10 Cell 11 Cell 12 Cell 13 NRCY RAS M istributionC LD hannel PED istributionChannel RA SPipeline BNR Tank 8 NRCY RAS BNR Tank 7 NRCY RAS BNR Tank 6 NRCY RAS To Secondary Clarifier No. 8 BNR Tank 5 ML Distribution Channel RAS/WAS Pump Station RAS 46 To Secondary Clarifier No. 7
  • 47. Henrico County WRF Plant Effluent Nitrogen Profile vs. Substrate Feed Rate ● Sugar water and glycerin both effective. 47
  • 49. Neuse River WWTP, Raleigh, NC ● 60 mgd Advanced WWTP » Primary Clarifiers » 4-stage BNR w/ methanol addition » Denitrification Filters w/ methanol addition ● Largest Plant in Eastern U.S. Achieving LOT for TN Utilizing Conventional Suspended Growth BNR Process ● Upcoming Expansion to 75 mgd » TN = 2.7 mg/L, TP = 1 mg/L ● Calibrated BioWin Model Used to Evaluate/ Optimize Expansion 49
  • 50. Neuse River – 4-stage w/ denitrification filters Typical Operating Parameters 50
  • 51. Neuse River - Operation and Performance ● Most TN Removal in BNR Basins ● Filters “Trimming” ± 1 mg/L (~ 5 mg/L Methanol Dose) ● Annual Average Effluent TN = 2.4 mg/L (2004 - 2008) S E a n d F in a l E fflu e n t N itr o g e n C o n c e n tr a tio n s 6 ● 2007 Annual Average Effluent TN = 1.96 mg/L Concentration (mg/L) 5 4 3 2 1 EFF TN SE TN 3 0 p e r. M o v . A v g . (E F F T N ) 3 0 p e r. M o v . A v g . (S E T N ) Sep-07 Jul-07 May-07 Mar-07 Jan-07 Nov-06 Sep-06 Jul-06 May-06 Mar-06 Jan-06 Nov-05 Sep-05 Jul-05 May-05 Mar-05 Jan-05 Nov-04 Sep-04 Jul-04 May-04 Mar-04 51 Jan-04 0
  • 52. High Point, NC – 26 mgd, 5-stage process mgd, 5- 52
  • 53. 53 EFF TN No alum or ferric 10/29/2008 7/31/2008 5/2/2008 2/2/2008 11/4/2007 8/6/2007 5/8/2007 2/7/2007 11/9/2006 8/11/2006 5/13/2006 2/12/2006 11/14/2005 20 8/16/2005 5/18/2005 2/17/2005 11/19/2004 8/21/2004 5/23/2004 2/23/2004 11/25/2003 8/27/2003 5/29/2003 2/28/2003 11/30/2002 9/1/2002 EFF Total Nitrogen (mg/L) High Point Performance 22 Average Eff TN 1/07 to 12/08 = 3.3 mg/L 18 16 14 12 No supplemental carbon 10 8 6 4 2 0 30 per. Mov. Avg. (EFF TN) Avg TP = 0.18 mg/L Biologically
  • 54. Major Recycle Impacts ● Solids handling recycle streams » Filtrate, centrate, gravity thickener overflow ● Frequency of return Parameters Plant Recycle Loads (lbs/day) Contribution From Plant Recycles (%) BOD 43,600 2,830 6.5 TSS 39,300 6,590 17 TKN 54 Plant Influent Loads (lbs/day) 5,700 1,620 29 TP 1,280 680 53
  • 56. Florida vs. Mass Estuary Nitrogen Challenge ● FL - Existing Ocean Outfalls and Septic Tanks ● Cape – Mostly Septic Tanks ● Both – High Level Nitrogen Treatment / Recharge 56
  • 57. Historically, South Florida’s sole source supply (the Biscayne Aquifer), was fiercely protected Effluent Reuse Class I Deep Injection Wells 57 Two Key issues for FDEP: ● Alternate Water Supply Resource ● Environmental enhancement (Nitrogen)
  • 58. Existing Supply Limited for Utilities C.E.R.P No New Water for the Public 58
  • 59. Recent Legislation – Ocean Outfall Ban ● Outfall shut down due to nitrogen – Coral Reefs ● Achieve significant TN & TP reductions by 2018 ● “Reuse” 60% of outfall flow by 2025 ● After 2025, outfall for wet weather back-up, w/ nutrient reductions 59
  • 60. Legislated Water Reuse Requirements Lake Okeechobee 7.7 MGD 6.2 MGD 22.4 MGD 24.1 MGD 48.6 MGD 68.9 MGD Total = 178 MGD 60 South Central Regional Boca Raton Broward Co. North Hollywood Miami-Dade North Miami-Dade Central District
  • 61. Recharging Groundwater is Essentially a Surface Water Discharge – nitrogen concerns County / Local Issues 61
  • 63. Miami South District Water Reclamation Plant ● 1st indirect potable reuse project in Florida ● Recharge drinking water aquifer with 23 mgd of highly treated wastewater ● Addressing pharmaceuticals and pathogens with regulators and public ● MF, RO, UV-AOP ● Ultra-pure drinking water quality 63
  • 65. Advanced Oxidation Processes (AOPs) High dosage UV w/ H2O2 UV ~ 500 mj/cm2 H2O2 ~ 1-3 ppm UV – TiO2 Ozone 65
  • 66. Hydroxyl Radical (OH°) is a very strong oxidant! OXIDIZING SPECIES RELATIVE OXIDATION POTENTIAL (V) Hydroxyl Radical 2.05 Ozone 1.52 Hydrogen Peroxide 1.31 Permanganate 1.24 Chlorine Dioxide 1.15 Chlorine 1.00 Data from Metcalf & Eddy, 2003 66 Increasing ability to degrade pollutants
  • 67. Miami Dade South District WRP Miami-Dade County Miami- 67
  • 68. Example of the complexities Moat Drainage Canal Regional Canal Proposed Biscayne Wells 68 Note: Locations are conceptual. Intended for discussion purposes only
  • 69. Biscayne National Park is Environmentally Sensitive 69
  • 70. Groundwater Recharge Criteria Miami Dade County Florida State Standard TOC -- 3 mg/l Total Suspended Solids (TSS) -- 5 mg/l Total Nitrogen (TN) -- 10 mg/L Ammonia 2.8 mg/l 0.5 mg/l -- Total Phosphorus (TP) .003 mg/l -- Yes No Parameter Emerging Contaminants 70
  • 73. WWTP Located Near Canal That Could Recharge the Biscayne Aquifer Plantation WWTF East Holloway Canal East Wellfields Central Wellfields 73
  • 74. Pilot Goals ● Demonstrate technology can meet water quality » TN » TP ● Unregulated Parameters » Microconstituents » Toxicity » Algal growth potential » Hormonal impacts 74
  • 76. Nutrient Control ● What is the technology necessary to meet the stringent TN & TP limits? ● Biological vs Chemical nutrient removal ● Are RO membranes necessary? 76
  • 77. Aquatic Organism Impact ● Whole effluent toxicity (WET) tests ● Is the RO permeate toxic? ● Will the effluent cause any hormonal impacts? 77
  • 78. Microconstituents ● Which microconstituents are in your wastewater? ● What technology will most effectively remove them? ● Are microconstituents really a concern at these concentrations (ng/L)? 78
  • 79. Recharge Modeling ● Does your point of discharge “offset” your withdrawal impacts? ● Can you get a 1/1 credit? ● What happens during the wet season? 79
  • 80. Sustainability ● Is this really sustainable? ● Water Supply vs Carbon Footprint? 80
  • 81. Public Outreach ● How do you change the “Sewer to Tap” mentality? ● How do you involve the public early in the project? 81
  • 82. Costs ● Capital cost ● Energy costs 82
  • 84. Broward County Canal Recharge Effluent Limits Parameter Effluent Limit TN < 1.5 mg/L TP < 0.02 mg/L Nitrate < 10 mg/L Ammonia TSS < 5.0 mg/L CBOD5 < 10.0 mg/L BOD 84 < 0.02 mg/L < 5.0 mg/L
  • 88. Plantation AWT MBR Scheme MBR Pilot 88 RO/UV Pilot Trailer
  • 89. Total nitrogen removal of MBR and RO Pilot Units 89
  • 90. Total phosphorus removal of MBR and RO Pilot Units 90
  • 92. Plantation AWT Conventional Treatment Scheme Denitrification Filter Pilot 92 UF/RO/UV Pilot Trailer
  • 93. Total nitrogen removal of Deep Bed Filter and RO Pilot Units 93
  • 94. Total phosphorus removal of Deep Bed Filter and RO Pilot Units 94
  • 95. Conclusions – Nutrient Removal ● Both pilots met stringent TN & TP limits ● RO membranes are necessary to meet TP limit ● Membranes alone (UF/RO) with no chemical addition met TN & TP limits 95
  • 97. What are Microconstituents? ● Pharmaceutically Active Compounds (PhAC) » Ethynyl Estradiol » Sulfamethaxazole ● Personal Care Products (PCP) Ethynyl Estradiol » Triclosan » Toiletries, cosmetics, fragrances ● Endocrine Disrupting Compounds (EDC) » Bisphenol-a » Atrazine » DEET 97 DEET Triclosan
  • 98. Concentration (ng/l) Microconstituents – RO Influent Concentrations 98
  • 99. Concentration (ng/l) Microconstituents – Most were removed by RO membranes 99
  • 101. Is the RO permeate toxic? ● RO permeate is too clean » RO re-stabilization/re-mineralization » Added salts and minerals ● How would this work full scale? » Dilution » Mixing zone 101
  • 102. Does RO Pre-treatment Preaffect toxicity? ● RO Pre-treatment » Antiscalant » Chloramines ● Pilot Results Fatheaded Minnow 102 Water Flea
  • 103. Summary ● The pilot demonstrated to meet stringent nutrient limits at different test conditions. ● RO membranes are necessary for surface water discharge due to stringent TP limits. ● Almost all microconstituents were removed by RO system. ● RO permeate could be toxic re-stabilization/remineralization is necessary. ● The observed toxicity to aquatic organisms was likely caused by chloramines. Other forms of RO pretreatment should be evaluated. 103
  • 105. University of Connecticut Reuse Project 105
  • 106. This is a Spotlight Project 106
  • 107. Potential Uses of Reclaimed Wastewater Reuse Facility ► ▼ WWTP ◄ Power Plant 107 ◄ Irrigation Sites ►
  • 109. UCONN Reclaimed Water Facility University of Connecticut – Reclaimed Water Facility Location Storrs, CT Capacity 1.0 mgd Technology Microfiltration + UV Disinfection + Chloramination Application • Cooling Tower Make-Up Water • Boiler Feed Water (post RO treatment) • Irrigation Unique Challenges 109 • Corrosion & Scaling Control for Cooling Towers
  • 110. MF System Design Criteria Parameter Type Pressurized System Rated Capacity 1 mgd No. of MF Units 3 No. of Membrane Modules per Unit 32 Membrane Type 0.1 micron PVDF Specific Design Flux 39 gfd Minimum Recovery Percent 110 Value 91%
  • 111. UV System Design Criteria Parameter Type LPHO System Rated Capacity 1 mgd No. of UV Systems 2+1 UV Design Dose 80 mJ/cm2 UV Transmittance ≥ 65% at 254 nm Effluent Turbidity ≤ 0.2 NTU (95% of the time) Effluent Total Coliform Max. 2.2/100 mL (7 day geometric mean) Suspended Solids Max. 111 Value 5 mg/L
  • 112. Sustainability Features ● Replaces as much as 40% of water supply at times ● Reclaimed water reservoir used as a heating source ● Stormwater capture and blending with wastewater ● Solar electricity 112
  • 115. Summary and Conclusions ● Nitrogen control programs are growing ● Very low nitrogen requires significant energy and $ ● Range of treatment options ● Good experiences and resources in other states to draw upon 115