An industry update on nitrogen removal programs across the United States. Presented by Rick Cisterna, Senior Associate with Hazen and Sawyer during the Buzzards Bay Coalition's 2011 Decision Makers Workshop series. Learn more at www.savebuzzardsbay.org/DecisionMakers
Industry update on nitrogen removal programs across the United States: What does it mean for New England?
1. Industry Update on Nitrogen Removal
Programs Across the United States:
What Does it Mean for New England?
March 3rd, 2011
Richard H. Cisterna, P.E.
Cisterna, P.E.
1
2. Outline
1
Water Industry Sustainability
2
National Perspective - Nitrogen and Hypoxia
3
Massachusetts Estuaries
Nitrogen Treatment Technology Overview
4
5
Conventional and Advanced
Case Studies
6
2
Summary and Conclusions
11. Long Island Sound Nitrogen Control Program
● In 1998, CT, NY, and EPA agreed to reduce
human sources of N by 58.5% by 2014. A
TMDL was developed and approved by EPA
in 2001.
11
18. Mass Nitrogen Reduction Program Goals
» Reduce ‘N’ to estuaries
» Consider centralized and decentralized
approaches
» Highly treat wastewater to new
Massachusetts DEP Standards
» Strategically recharge reclaimed water
18
20. Mass. DEP: Groundwater Discharge Program
(314 CMR 5.00)
Requirements
Meet secondary treatment effluent limits:
» Nitrate as Nitrogen < 10 mg/L
» Total Nitrogen
< 10 mg/L
» Fecal Coliform
< 200 colonies per 100 mL
All Discharges
Discharges within
Zone II or IWPA
Effluent shall be filtered to meet:
» TSS
» Turbidity
» TOC
Discharges within
Zone II or IWPA
and 2 year Travel
Time
< 10 mg/L
< 5 NTU
< 3 mg/L
Effluent shall be oxidized, filtered, disinfected and coagulated
to meet:
» TSS
» Turbidity
» BOD
< 5 mg/L
< 2 NTU
< 10 mg/L
» TOC
< 1 mg/L
» Fecal Coliform
= avg. of zero colonies per 100 mL over a
continuous 7 day sampling period; no single
sample shall exceed 14 colonies per 100 mL
= 5 Log Inactivation and/or Removal
or
20
Direct Injection
(into saturated
zone)
» Virus
Disinfection shall not be waived.
Coagulation may be waived if meet turbidity requirement with
filtration alone.
26. BNR Process Configurations – 5-stage
Typical 5-stage BNR Process – Lower TN limit
Carbon
Secondary
Clarifier
Wastewater
Anaerobic Primary
Anoxic
Aerobic Secondary
Anoxic
BNR
Aeration Tank
Secondary
Effluent
Reaeration
WAS
TN ~ 3 to 4 mg/L
26
27. 3+ Stage with Denitrification Filters
TN < 3 mg/L
Acetate
Methanol
Secondary
Clarifier
Wastewater
Anaerobic Anoxic
Aerobic
BNR
Aeration Tank
WAS
27
Granular
Media
Filter
Secondary
Effluent
28. Denitrification Filters
● Nitrified secondary effluent sent to filtration
● Filter media used to grow an attached biomass that
will denitrify the secondary effluent
● Supplemental carbon addition
● Good solids removal + denite – 2 gpm/ft2
28
30. Integrated Fixed Film Activated Sludge
(IFAS)
● Media held in Aeration Basins to provide
attached growth for Nitrifying biomass
● Typical Floating and Fixed IFAS Media
» Kaldnes (plastic)
» Linpor (sponge)
» Ringlace (cord)
30
30
31. IFAS in Nutrient Removal
ANA
ANOX AEROBIC
•Higher capacity in same
volume
•“Modular” phasing
•Improved wet weather
stability
31
ANOX
32. TZ Osborne WRF – Pilot Layout
RAS
To Final
Clarifier No. 7
Primary
Effluent
IFAS
Cell 1
~ 35% fill (AK-K3)
3 distinct zones
32
IFAS
Cell 2
IFAS
Cell 3
Screens for each cell
Isolation / throttle air
valve for each cell
33. IFAS Pilot Results / Lessons Learned
● Effective nitrification in
approximately half the
aerobic volume
● Dynamic microbial
population
● Higher air usage
● Screen headloss higher than
expected
● Foam handling a must
● Influent screening must be
sized correctly (i.e. opening
size)
33
Biomass on Media (gTSS/m2 of media surface)
30
25
20
15
10
5
0
04/01/08
06/13/08
08/25/08
11/06/08
01/18/09
04/01/09
Date
Cell D Biomass
Cell E Biomass
Cell F Biomass
42. Glycerin
● Typically byproduct of
biodiesel production
● Benefits
» Faster kinetics
● Drawbacks
» Potential for product
inconsistencies with
waste products
» Viscous in cold weather
» Specialist population not
required
● Products
» Brenntag
» Unicarb-DN
» BioCarb DN (Denite-1)
» MicroC-Glycerin
» Waste products
42
43. Alternative Carbon Testing
Parameter
NRWWTP
HCWRF
Size (mgd)
Feed point
Basins fed
carbon
Control
(if
applicable)
75
75
One
All
Substrate
43
PWWTP
SDWRF
NDWRF
7.5
Second anoxic zone
All
20
20
One
4 out of 5
One parallel Full-scale
Full-scale One parallel One parallel
basin that
evaluation, evaluation,
basin that
basin that
was fed
therefore no therefore no was not fed was not fed
methanol
control
control
carbon
carbon
Glycerin
Sugar water
Glycerin
Glycerin
Glycerin
and glycerin
45. Parkway Full-Scale Pilot Data
Full■ No Acclimation Period Required
Full Scale Pilot Data
1/26/2008
1/19/2008
1/12/2008
45
Effluent NOx
Effluent TN
Brenntag Glycerin
7 per. Mov. Avg. (Effluent NOx)
7 per. Mov. Avg. (Effluent TN)
Carbon dose, gal/day
0
1/5/2008
0
12/29/2007
20
12/22/2007
1
12/15/2007
40
12/8/2007
2
12/1/2007
60
11/24/2007
3
11/17/2007
80
11/10/2007
4
11/3/2007
100
10/27/2007
120
5
Concentration (mg/L)
6
46. Cell
1
Cell 2
Cell 3
3848-047
Primary
Anoxic/
Aerobic Zone
Cell 4
Cell 5
Secondary
Anoxic/
Aerobic Zone
Aerobic Zone
Cell 6
Cell 7
Cell 8
R
eAeration
Zone
Prim
ary
A
noxic/
Anaerobic Zone
Anaerobic
Zone
RA
S
Ferm
entation
Henrico VA
Cell 9
Cell 10
Cell 11
Cell 12
Cell 13
NRCY
RAS
M istributionC
LD
hannel
PED
istributionChannel
RA
SPipeline
BNR Tank 8
NRCY
RAS
BNR Tank 7
NRCY
RAS
BNR Tank 6
NRCY
RAS
To
Secondary
Clarifier
No. 8
BNR Tank 5
ML Distribution Channel
RAS/WAS
Pump Station
RAS
46
To
Secondary
Clarifier
No. 7
47. Henrico County WRF Plant Effluent Nitrogen
Profile vs. Substrate Feed Rate
● Sugar water and glycerin both effective.
47
51. Neuse River - Operation and Performance
● Most TN Removal in BNR Basins
● Filters “Trimming” ± 1 mg/L (~ 5 mg/L Methanol Dose)
● Annual Average Effluent TN = 2.4 mg/L (2004 - 2008)
S E a n d F in a l E fflu e n t N itr o g e n C o n c e n tr a tio n s
6
● 2007 Annual Average Effluent TN = 1.96 mg/L
Concentration (mg/L)
5
4
3
2
1
EFF TN
SE TN
3 0 p e r. M o v . A v g . (E F F T N )
3 0 p e r. M o v . A v g . (S E T N )
Sep-07
Jul-07
May-07
Mar-07
Jan-07
Nov-06
Sep-06
Jul-06
May-06
Mar-06
Jan-06
Nov-05
Sep-05
Jul-05
May-05
Mar-05
Jan-05
Nov-04
Sep-04
Jul-04
May-04
Mar-04
51
Jan-04
0
56. Florida vs. Mass Estuary Nitrogen Challenge
● FL - Existing Ocean Outfalls and Septic Tanks
● Cape – Mostly Septic Tanks
● Both – High Level Nitrogen Treatment / Recharge
56
57. Historically, South Florida’s sole source supply
(the Biscayne Aquifer), was fiercely protected
Effluent
Reuse
Class I
Deep Injection Wells
57
Two Key issues for FDEP:
● Alternate Water Supply
Resource
● Environmental
enhancement (Nitrogen)
59. Recent Legislation – Ocean Outfall Ban
● Outfall shut down due to nitrogen – Coral Reefs
● Achieve significant TN & TP reductions by 2018
● “Reuse” 60% of outfall flow by 2025
● After 2025, outfall for wet weather back-up, w/
nutrient reductions
59
60. Legislated Water Reuse Requirements
Lake
Okeechobee
7.7 MGD
6.2 MGD
22.4 MGD
24.1 MGD
48.6 MGD
68.9 MGD
Total = 178 MGD
60
South Central Regional
Boca Raton
Broward Co. North
Hollywood
Miami-Dade North
Miami-Dade Central District
61. Recharging Groundwater is Essentially a Surface
Water Discharge – nitrogen concerns
County / Local Issues
61
63. Miami South District
Water Reclamation Plant
● 1st indirect potable reuse project in Florida
● Recharge drinking water aquifer with 23 mgd of
highly treated wastewater
● Addressing pharmaceuticals and pathogens with
regulators and public
● MF, RO, UV-AOP
● Ultra-pure drinking
water quality
63
68. Example of the complexities
Moat
Drainage Canal
Regional Canal
Proposed
Biscayne Wells
68
Note: Locations are conceptual. Intended for discussion purposes only
76. Nutrient Control
● What is the
technology
necessary to meet
the stringent TN &
TP limits?
● Biological vs
Chemical nutrient
removal
● Are RO
membranes
necessary?
76
77. Aquatic Organism Impact
● Whole effluent
toxicity (WET)
tests
● Is the RO
permeate toxic?
● Will the effluent
cause any
hormonal
impacts?
77
79. Recharge Modeling
● Does your
point of
discharge “offset” your
withdrawal
impacts?
● Can you get a
1/1 credit?
● What happens
during the wet
season?
79
95. Conclusions – Nutrient Removal
● Both pilots met stringent TN & TP limits
● RO membranes are necessary to meet TP limit
● Membranes alone (UF/RO) with no chemical
addition met TN & TP limits
95
101. Is the RO permeate toxic?
● RO permeate is too clean
» RO re-stabilization/re-mineralization
» Added salts and minerals
● How would this work full scale?
» Dilution
» Mixing zone
101
102. Does RO Pre-treatment
Preaffect toxicity?
● RO Pre-treatment
» Antiscalant
» Chloramines
● Pilot Results
Fatheaded Minnow
102
Water Flea
103. Summary
● The pilot demonstrated to meet stringent nutrient
limits at different test conditions.
● RO membranes are necessary for surface water
discharge due to stringent TP limits.
● Almost all microconstituents were removed by
RO system.
● RO permeate could be toxic re-stabilization/remineralization is necessary.
● The observed toxicity to aquatic organisms was
likely caused by chloramines. Other forms of RO
pretreatment should be evaluated.
103
109. UCONN Reclaimed Water Facility
University of Connecticut
– Reclaimed Water Facility
Location
Storrs, CT
Capacity
1.0 mgd
Technology
Microfiltration +
UV Disinfection +
Chloramination
Application
• Cooling Tower
Make-Up Water
• Boiler Feed Water
(post RO treatment)
• Irrigation
Unique
Challenges
109
• Corrosion &
Scaling Control for
Cooling Towers
110. MF System Design Criteria
Parameter
Type
Pressurized
System Rated Capacity
1 mgd
No. of MF Units
3
No. of Membrane Modules per Unit
32
Membrane Type
0.1 micron PVDF
Specific Design Flux
39 gfd
Minimum Recovery Percent
110
Value
91%
111. UV System Design Criteria
Parameter
Type
LPHO
System Rated Capacity
1 mgd
No. of UV Systems
2+1
UV Design Dose
80 mJ/cm2
UV Transmittance
≥ 65% at 254 nm
Effluent Turbidity
≤ 0.2 NTU (95% of the time)
Effluent Total Coliform Max.
2.2/100 mL (7 day geometric mean)
Suspended Solids Max.
111
Value
5 mg/L
112. Sustainability Features
● Replaces as much as
40% of water supply at
times
● Reclaimed water
reservoir used as a
heating source
● Stormwater capture and
blending with wastewater
● Solar electricity
112
115. Summary and Conclusions
● Nitrogen control programs are growing
● Very low nitrogen requires significant energy and $
● Range of treatment options
● Good experiences and resources in other states to
draw upon
115