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Heat Treatment
Heat Treatment 
The controlled heating & 
cooling of metals for the 
purpose of altering their 
properties
Heat Treatment 
It is used in manufacturing, 
providing simple and low-cost 
means of obtaining 
desired properties
Processing Heat Treatments 
thermal processes designed to 
increase strength-preparing 
materials for fabrication
which includes: 
improving machining 
characteristics 
 reducing forming forces and 
energy consumption 
 restoring ductility for further 
deformation
Equilibrium Diagram as Aid 
to Heat Treatment 
 It indicates the temperatures 
that must be attained to achieve 
a desired product and change 
that will occur upon subsequent 
cooling
Simplified Iron-carbon diagram
Processing 
Heat Treatments 
for Steel
Annealing 
 a number of process 
heating operations
Annealing 
reducing hardness 
 removing residual stresses 
 improving toughness 
 restoring ductility 
 altering mechanical , physical 
magnetic properties
Full Annealing 
Hypoeutectoid steels are heated to 
30-60 °C above the A3 to convert to 
homogeneous single-phase 
austenite of uniform composition 
and temperature then slowly cooled 
to below A1 temperature
Full Annealing 
it is time consuming 
require considerable energy to 
maintain the elevated temperature 
Gen. Rule: 1hr at temperature/inch 
of thickness of largest section
Normalizing 
metal is heated to 60°C (100°F) 
above the A3 or Acm, soaked 
to obtain uniform austenite, 
then removed and cooled 
in still air
Process Anneal 
metal is heated below A1, 
held long enough 
to achieve softening, 
then cooled in air
Advantages of Process Anneal 
cheaper 
more rapid 
tends to produce less scaling
Stress-Relief Anneal 
employed to remove residual 
stresses in large steel castings 
and welded structures
Stress-Relief Anneal 
 parts are heated below A1 
(550-660°C;1000-1200°F), 
held for period of time, 
then slowly cooled
Spheroidization 
employed when high-carbon 
steels must be prepared for 
machining and forming 
required for above 0.6% carbon
Graphical Summary
Heat Treatments 
for 
Nonferrous Metals
Purpose for Nonferrous Metals 
to be heat-treated: 
obtaining uniform structure 
providing stress relief 
bringing about recrystallization
6 Major Mechanisms: 
Solid Solution Hardening 
Strain Hardening 
Grain Size Refinement 
Precipitation Hardening 
Dispersion Hardening 
Phase Transformation 
Next
Solid Solution Hardening 
a base metal dissolves other atoms 
in solid solution either as 
substantial solutions 
or as interstitial solutions 
Back
Strain Hardening 
increases strength by plastic 
deformation under 
cold-working conditions 
Back
Grain Size Refinement 
 used to increase strength, 
except at elevated temperatures 
where failure is by grain-boundary 
diffusion-controlled creep 
mechanism 
Back
Precipitation/Age Hardening 
is a method whereby strength 
is obtained from a nonequilibrium 
structure produced by a three step 
( solution treat-quench and age) 
heat treatment 
Back
Dispersion Hardening 
strength is obtained from 
distinct second-phase particles 
in a base matrix 
Back
Phase Transformations 
strengthening involves alloys 
w/c can be heated to form a 
single high-temperature phase, 
transformed to one or more 
low-temperature phase upon 
cooling 
Back
Strengthening Heat Treatments 
for Nonferrous Metals 
Aging - a continuous process 
which begins by the clustering 
of solute atoms on distinct 
planes of the parent lattice
Precipitation-hardening materials 
can be classified: 
Naturally Aging - the req. diffusion 
at unstable to the stable 2-phase 
structure at room temperature 
Artificially Aging - require elevated 
temperature
Silver- Copper Equilibrium Diagram
Enlargement of Copper
Aids to understanding the 
nonequilibrium processes 
Isothermal transformation (IT) or 
time-temperature-transformation 
(T-T-T) diagram
Bainite 
Electron microscopy maybe 
required for to resolve the carbides 
in the resulting structure 
Martensite 
Exceptionally strong, hard & brittle
Martensite
Tempering 
Subsequent cooling required to 
restore some desired degree of 
toughness at the expense of a 
decrease in strength & hardness
Continuous Cooling Transformation 
(C-C-T) Diagram 
These diagrams are used to 
represent which types of phase 
changes will occur in a material 
as it is cooled at different rates.
Jominy Test for Hardenability 
Used to assist understanding of 
nonequilibrium heat treatment
Hardness - a mechanical 
property related to strength 
and is strong function of the 
carbon content of a metal
Hardenability - a measure of the 
depth to which full hardness can 
be attained under a normal 
hardening cycle and is related 
primarily to amounts and types 
of alloying elements.
Adding alloy to steel 
The primary reason for adding 
alloy elements to commercial 
steel is to increase the 
hardenability , not to improve 
the strength properties
Quench Media 
Stages of quenching 
First Stage (Vapor Jacket Stage) 
Second Stage of Quenching 
Third Stage
Water 
is fairly good quenching 
medium because of its high 
heat of vaporization. 
 is cheap, but the bubbles may 
cause soft spots in metal
Brine (Salt) 
 more severe quenching 
medium than water because 
salt creates bubbles , forcing a 
more rapid transition through 
the vapor jacket stage
The Role of Design 
in the Heat Treatment 
of Steel
Design Details & 
Material Selection 
Proper consideration of it leads: 
 more simple, 
 more economical 
 more reliable products
Undesirable Design Features 
Nonuniform sections or 
thickness 
Sharp Interior Corners 
Sharp Exterior Corners
Residual Stresses 
are often-complex results of 
the various dimensional 
changes that occur during 
heat treatment
Austempering 
The process called if the piece 
is held at this temperature 
long enough, the austenite will 
transform to bainite.
Martempering/Marquenching 
The process called if the piece is 
stabilized and then slowly 
cooled through the martensite 
transformation
Ausforming 
 a treatment used to strengthen 
metals and improve its wear 
properties
Surface Steel Hardening 
Selective Heating of the Surface 
Altered Surface Chemistry 
Deposition of Additional Layer
Selective Heating Techniques 
Selective Heating 
Flame Hardening 
Induction Heating 
Laser beam hardening 
Electron beam hardening
Altered Surface Chemistry 
Pack Carburizing 
Gas Carburizing 
Liquid Carburizing/Cyaniding 
Nitriding 
Ionitriding
Heat Treatment Equipment 
Batch Furnaces 
Continuous Furnaces
Box-Type Furnace
Car-Bottom Box-Type Furnace
Vertical Pit Furnace
Bell-Type Pit Furnace
Elevator-Type Furnace
Continuous Furnace
Thank You! 
Sario , Pamela May 
Reporter

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Heat Treatment Guide: Processes, Diagrams & Techniques for Metals