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RADIOMETRIC METHODS FOR
AGE DETERMINATION
CONTENTS
1. Introduction
2. Characteristics
3. Radiometric dating
4. Uranium-Lead method
5. Potassium-Argon method
6. Rubidium-strontium method
7. Carbon Dating
8. Conclusion
INTRODUCTION
• The spontaneous disintegration of a heavy
nuclei with the emission of certain harmful
radiations is called RADIOACTIVITY.
CHARACTERISTICS
• Excess or lacking of neutrons, relative to the
protons, affects the stability of the nucleus.
• Heavy nuclei are generally unstable(83-92).
• Rate of disintegration of radioactive sample at any
instant of time is directly proportional to the
number of atoms present in the sample at that
instant of time- LAW OF RADIOACTIVE DECAY.
dN/dt = -λN
• The time during which half the original number of
atoms disintegrate – HALF LIFE
T= 0.693/λ
RADIOMETRIC DATING
• Technique used to date materials such as rocks by
observing the abundance of naturally occurring
radioactive isotope and it’s decay products.
RADIOMETRIC DATING METHODS
1. URANIUM-LEAD
2. POTASSIUM ARGON
3. RUBIDIUM STRONTIUM
4. CARBON DATING
URANIUM – LEAD DATING METHOD
• Uranium- Lead dating is one of the oldest and if
done properly one of the most accurate.
• Uranium comes as two common isotopes; U235 and
U238.
• Both are unstable and radioactive, shedding nuclear
particles in a cascade that doesn't stop until they
become lead (Pb).
• The two cascades are different—U235becomes
Pb207(half life-704 million years) and U238
becomes Pb206 (half life- 4.47 billion years).
• Lead atoms created by uranium decay are trapped
in the crystal and build up in concentration with
time; helping us in dating.
• The favourite mineral among U-Pb daters is zircon
(ZrSiO4), for several good reasons.
• Some zircons are obviously disturbed and can be
ignored, while other cases are harder to judge. In
these cases, the concordia diagram is a valuable
tool.
• Uranium- lead dating works only for metamorphic
and igneous rocks.
POTASSIUM ARGON METHOD
• The potassium-argon (K-Ar) isotopic dating method
is especially useful for determining the age of lavas.
• Potassium has one radioactive isotope (40K).
• Potassium-40 decays with a half-life of 1250 million
years.
• What simplifies things is that potassium is a reactive
metal and argon is an inert gas.
• The mineral Sanidine, the high-temperature form of
Potassium Feldspar, is the most desirable.
• Meteoric and volcanic rocks have been analysed by
this method.
RUBIDIUM- STRONTIUM METHOD
• The utility of Rubidium Strontium isotope system
results from the fact that 87Rb (one of the isotopes
of Rubidium) decays to 87Sr with a half-life of 49
billion years.
• The method is applicable to very old rocks because
the transformation is extremely slow: the half-life,
or time required for half the initial quantity of
rubidium-87 to disappear; is approximately 50
billion years.
• It is used to date igneous and metamorphic rocks.
CARBON DATING
• Carbon dating is a variety of radioactive dating;
applicable only to matter which was once living.
• Neutron produced by cosmic ray bombardment
produces radioactive isotope Carbon-14
• Carbon-14 decays with a half-life of about 5730
years by the emission of an electron, disintegrating
to nitrogen 14.
• Carbon dating only works on fossils that used to be
alive. You can not carbon date a rock or
sedimentary layer.
Parent Isotope and
mode of Decay
Daughter
isotope
Half life
(m.y)
Geological age
range
Occurrence and useful geological
materials
U-238, alpha & beta Pb-206 4,510 older than
about 10 m.y
Accessory minerals, e.g. zircon and
sphene, in igneous and metamorphic
rocks
U-235, alpha & beta Pb-207 713 common igneous and metamorphic
whole rocks. Many have sufficient U
and Pb for age determination
Th-232, alpha & beta Pb-208 13,900 U & Th minerals. Rare and restricted
to uncommon geological
environments.
K-40, electron capture
and beta
Ar-40
Ca-40
11,850
1,470
older than
about 0.1 m.y
Many common rock forming
minerals, e.g.biotite, muscovite,
sanidine, hbl, glauconite, basic
igneous whole rocks, slates
Ru-87, beta Sr-87 50,000 older than
about 10 m.y
Most K-minerals contain sufficient Rb
for age work, e.g. biotite, muscovite,
k-felds, glauconite, Many common
igneous and metamorphic rocks,
some sedimentary whole rocks, e.g.
shales, yeild time of diagenesis
Sm-147, alpha Nd-143 106,000 older than
about 10 m.y
Mafic and ultramafic igneous rocks
CONCLUSION
• Radiometric methods are one of the most
effective tools in age determination.
• They are even used to date fossils.
• Radiometric methods other than the ones
listed above are: samarium-147 to neodyium-
143, cosmogenic nuclide dating and so on.
REFERENCE
• Harry Y Mc Sween, Steven M.Richardson and Maria
E Uhle(2009). Geochemistry, PVT LTD, New Delhi,
pp 290-298.
• John V Walther(2010). Essentials of Geochemistry,
Jones and Barhett, New Delhi,pp 383-400
• Brian Mason, Carleton B. Moore(1982). Principles
of Geochemistry, John Wiley and Sons, pp 198-208
• C.S. Pichmuthu (1985), Archaean Geology, Oxford &
IBH pub.Co. p.125
• http://creation.mobi/radiometric-dating-age-of-
earth
• http://geology.about.com/od/geotime_dating/a/ur
aniumlead.htm
Radiometric methods for age determination

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Radiometric methods for age determination

  • 2. CONTENTS 1. Introduction 2. Characteristics 3. Radiometric dating 4. Uranium-Lead method 5. Potassium-Argon method 6. Rubidium-strontium method 7. Carbon Dating 8. Conclusion
  • 3. INTRODUCTION • The spontaneous disintegration of a heavy nuclei with the emission of certain harmful radiations is called RADIOACTIVITY.
  • 4. CHARACTERISTICS • Excess or lacking of neutrons, relative to the protons, affects the stability of the nucleus. • Heavy nuclei are generally unstable(83-92). • Rate of disintegration of radioactive sample at any instant of time is directly proportional to the number of atoms present in the sample at that instant of time- LAW OF RADIOACTIVE DECAY. dN/dt = -λN • The time during which half the original number of atoms disintegrate – HALF LIFE T= 0.693/λ
  • 5. RADIOMETRIC DATING • Technique used to date materials such as rocks by observing the abundance of naturally occurring radioactive isotope and it’s decay products. RADIOMETRIC DATING METHODS 1. URANIUM-LEAD 2. POTASSIUM ARGON 3. RUBIDIUM STRONTIUM 4. CARBON DATING
  • 6. URANIUM – LEAD DATING METHOD • Uranium- Lead dating is one of the oldest and if done properly one of the most accurate. • Uranium comes as two common isotopes; U235 and U238. • Both are unstable and radioactive, shedding nuclear particles in a cascade that doesn't stop until they become lead (Pb). • The two cascades are different—U235becomes Pb207(half life-704 million years) and U238 becomes Pb206 (half life- 4.47 billion years).
  • 7. • Lead atoms created by uranium decay are trapped in the crystal and build up in concentration with time; helping us in dating. • The favourite mineral among U-Pb daters is zircon (ZrSiO4), for several good reasons. • Some zircons are obviously disturbed and can be ignored, while other cases are harder to judge. In these cases, the concordia diagram is a valuable tool. • Uranium- lead dating works only for metamorphic and igneous rocks.
  • 8. POTASSIUM ARGON METHOD • The potassium-argon (K-Ar) isotopic dating method is especially useful for determining the age of lavas. • Potassium has one radioactive isotope (40K). • Potassium-40 decays with a half-life of 1250 million years. • What simplifies things is that potassium is a reactive metal and argon is an inert gas. • The mineral Sanidine, the high-temperature form of Potassium Feldspar, is the most desirable. • Meteoric and volcanic rocks have been analysed by this method.
  • 9. RUBIDIUM- STRONTIUM METHOD • The utility of Rubidium Strontium isotope system results from the fact that 87Rb (one of the isotopes of Rubidium) decays to 87Sr with a half-life of 49 billion years. • The method is applicable to very old rocks because the transformation is extremely slow: the half-life, or time required for half the initial quantity of rubidium-87 to disappear; is approximately 50 billion years. • It is used to date igneous and metamorphic rocks.
  • 10. CARBON DATING • Carbon dating is a variety of radioactive dating; applicable only to matter which was once living. • Neutron produced by cosmic ray bombardment produces radioactive isotope Carbon-14 • Carbon-14 decays with a half-life of about 5730 years by the emission of an electron, disintegrating to nitrogen 14. • Carbon dating only works on fossils that used to be alive. You can not carbon date a rock or sedimentary layer.
  • 11. Parent Isotope and mode of Decay Daughter isotope Half life (m.y) Geological age range Occurrence and useful geological materials U-238, alpha & beta Pb-206 4,510 older than about 10 m.y Accessory minerals, e.g. zircon and sphene, in igneous and metamorphic rocks U-235, alpha & beta Pb-207 713 common igneous and metamorphic whole rocks. Many have sufficient U and Pb for age determination Th-232, alpha & beta Pb-208 13,900 U & Th minerals. Rare and restricted to uncommon geological environments. K-40, electron capture and beta Ar-40 Ca-40 11,850 1,470 older than about 0.1 m.y Many common rock forming minerals, e.g.biotite, muscovite, sanidine, hbl, glauconite, basic igneous whole rocks, slates Ru-87, beta Sr-87 50,000 older than about 10 m.y Most K-minerals contain sufficient Rb for age work, e.g. biotite, muscovite, k-felds, glauconite, Many common igneous and metamorphic rocks, some sedimentary whole rocks, e.g. shales, yeild time of diagenesis Sm-147, alpha Nd-143 106,000 older than about 10 m.y Mafic and ultramafic igneous rocks
  • 12. CONCLUSION • Radiometric methods are one of the most effective tools in age determination. • They are even used to date fossils. • Radiometric methods other than the ones listed above are: samarium-147 to neodyium- 143, cosmogenic nuclide dating and so on.
  • 13. REFERENCE • Harry Y Mc Sween, Steven M.Richardson and Maria E Uhle(2009). Geochemistry, PVT LTD, New Delhi, pp 290-298. • John V Walther(2010). Essentials of Geochemistry, Jones and Barhett, New Delhi,pp 383-400 • Brian Mason, Carleton B. Moore(1982). Principles of Geochemistry, John Wiley and Sons, pp 198-208 • C.S. Pichmuthu (1985), Archaean Geology, Oxford & IBH pub.Co. p.125 • http://creation.mobi/radiometric-dating-age-of- earth • http://geology.about.com/od/geotime_dating/a/ur aniumlead.htm