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Low Global Warming Replacements for HCFCs in Stationary Air Conditioning Equipment. Mark W. Spatz, Global Leader Refrigerant Technology, Honeywell Refrigerants
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Low Global Warming Platform ,[object Object],[object Object]
HFO Blends for Stationary Applications N Series (A1) L Series (A2L)  L-41  GWP <500 R-410A  GWP=2088 L-YF  GWP = 4 L-ZE  GWP = 6 N-13  GWP ~600 HFC-134a GWP=1430 L-20+  GWP <350 N-20  GWP ~1000 HCFC-22 GWP=1810 L-40  GWP~200-300 N-40  GWP~1300 (retrofit)  N-20  GWP~1000 (new equip) R-404A  GWP=3922 Lowest GWP Option  (Mildly Flammable)  Reduced GWP Option  (Non-flammable)   Current Product
HFO-1234yf Flammability Properties ,[object Object],[object Object],Difficult to ignite HFO-1234yf due to high Minimum Ignition Energy  Lower Flame Limit, g/m 3 Minimum Ignition Energy, mJ Methane R-152a Acetylene Propane Iso-Butane Gasoline HFO-1234yf R-32 Ammonia 1243zf Increasing Flammability > 5000 times more energy to ignite!
HFO-1234yf Flammability Properties ,[object Object],[object Object],HFO-1234yf will be classified in Class 2L (Low Burning Velocity) Burning Velocity, cm/s Heat of Combustion, MJ/kg Increasing Impact R152a Ammonia R32 HFO-1234yf R134a methane propane butane ASHRAE Class 3 ASHRAE Class 2 Class 2L gasoline
Allowable Charges: Equivalent Basis ,[object Object],[object Object],Stochiometric composition of 1157g will produce less than 3kPa of pressure rise
Replacing HCFC-22 in Air Conditioning Systems L-41 /  HFC32 HCFC 22 CO 2 HFC 410A HFC 407C Operating Pressures System redesign necessary if using refrigerants with higher operating pressures Non-flammable GWP = 2088 Properties enable cost-effective efficient system Non-flammable  GWP=1824 Can utilize R-22 design Non-ozone Depleting Low GWP Highly flammable  GWP<20 Mildly flammable  GWP<350  Utilize R22 Designs Very high pressure major design changes needed Poor efficiency GWP = 1  Mildly flammable  GWP = 675 (R32)  GWP < 500 (L41) R410A Performance R32 - high discharge T Hydro Carbons HFO Blend  L-20
R-22 (R-410A) Replacements – A/C & Heat Pumps ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Test Condition DB( º C) WB(ºC) DB(ºC) WB(ºC) AHRI Std. A 26.7 19 35 24 AHRI Std. B 26.7 19 27.8 18 AHRI Std. C 26.7 14 27.8 - AHRI Std. MOC 26.7 19 46.1 24 Operating Conditions (Cooling Mode) Indoor Ambient Outdoor Ambient
R-22 Reversible Heat Pump: Cooling Results ,[object Object],[object Object],[object Object]
R410A Reversible Heat Pump: Cooling Results ,[object Object],[object Object]
A/C for Hot Climates There are Viable Options for Stationary A/C Systems Operating in Hot Regions
Concluding Remarks ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
DISCLAIMER Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, expressed or implied. Information provided herein does not relieve the user from the responsibility of carrying out its own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained. Statements or suggestions concerning the use of materials and processes are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe on any patents. The user should not assume that all toxicity data and safety measures are indicated herein or that other measures may not be required. Thank you! Questions?

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Low GWP HCFC Replacements for Stationary ACTITLE Honeywell Research on HCFC Alternatives for Buildings

  • 1. Low Global Warming Replacements for HCFCs in Stationary Air Conditioning Equipment. Mark W. Spatz, Global Leader Refrigerant Technology, Honeywell Refrigerants
  • 2.
  • 3. HFO Blends for Stationary Applications N Series (A1) L Series (A2L) L-41 GWP <500 R-410A GWP=2088 L-YF GWP = 4 L-ZE GWP = 6 N-13 GWP ~600 HFC-134a GWP=1430 L-20+ GWP <350 N-20 GWP ~1000 HCFC-22 GWP=1810 L-40 GWP~200-300 N-40 GWP~1300 (retrofit) N-20 GWP~1000 (new equip) R-404A GWP=3922 Lowest GWP Option (Mildly Flammable) Reduced GWP Option (Non-flammable) Current Product
  • 4.
  • 5.
  • 6.
  • 7. Replacing HCFC-22 in Air Conditioning Systems L-41 / HFC32 HCFC 22 CO 2 HFC 410A HFC 407C Operating Pressures System redesign necessary if using refrigerants with higher operating pressures Non-flammable GWP = 2088 Properties enable cost-effective efficient system Non-flammable GWP=1824 Can utilize R-22 design Non-ozone Depleting Low GWP Highly flammable GWP<20 Mildly flammable GWP<350 Utilize R22 Designs Very high pressure major design changes needed Poor efficiency GWP = 1 Mildly flammable GWP = 675 (R32) GWP < 500 (L41) R410A Performance R32 - high discharge T Hydro Carbons HFO Blend L-20
  • 8.
  • 9.
  • 10.
  • 11. A/C for Hot Climates There are Viable Options for Stationary A/C Systems Operating in Hot Regions
  • 12.
  • 13. DISCLAIMER Although all statements and information contained herein are believed to be accurate and reliable, they are presented without guarantee or warranty of any kind, expressed or implied. Information provided herein does not relieve the user from the responsibility of carrying out its own tests and experiments, and the user assumes all risks and liability for use of the information and results obtained. Statements or suggestions concerning the use of materials and processes are made without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe on any patents. The user should not assume that all toxicity data and safety measures are indicated herein or that other measures may not be required. Thank you! Questions?