SlideShare uma empresa Scribd logo
1 de 8
Baixar para ler offline
Laboratory Strength of Glass Ionomer
and Zinc Phosphate Cements
Andree Piwowarczyk, Dr med dent,1
Peter Ottl, Dr med dent,1
and
Hans-Christoph Lauer, Dr med dent2
Purpose: The present in vitro study examined 3 mechanical properties, namely compressive,
flexural, and diametral tensile strength, of various commercially available cements and core
materials as a function of time after mixing.
Materials and Methods: The examined materials were 2 cermet cements (Ketac Silver [ESPE,
Seefeld, Germany] and Chelon Silver [ESPE]), 1 metal-reinforced glass ionomer cement (Miracle
Mix [GC Dental Industrial Corp, Tokyo, Japan]), 2 conventional glass ionomer cements (Ketac Bond
[ESPE] and Ketac Cem [ESPE]), 1 standard cure zinc phosphate cement (Harvard Cement [Richter
and Hoffmann, Berlin, Germany]), and 1 zinc phosphate cement with the addition of 30% silver
amalgam alloy powder (Harvard Cement 70% with Dispersalloy 30% [Richter and Hoffmann/
Johnson and Johnson, East Windsor, NJ]). Properties were measured using a universal testing
machine at 15 minutes, 1 hour, and 24 hours after first mixing.
Results: Compressive strengths varied widely between the 3 times of measurement from 5.8 ؎
6.6 MPa for Ketac Cem to 144.3 ؎ 10.2 MPa for Ketac Silver. Twenty-four hours after mixing, the
Bonferroni test showed significant (p < .01) differences between Ketac Silver and all other
materials tested. Diametral tensile strengths ranged widely from 4.4 ؎ 0.9 MPa for Ketac Cem to
11.5 ؎ 2.2 MPa for Chelon Silver. At 15 minutes, 1 hour, and 24 hours after first mixing, the analysis
of variance did not show any significant differences between Ketac Silver, Chelon Silver, and
Miracle Mix. The 3-point flexural strength of Ketac Silver showed, at 15 minutes with 13.5 ؎ 3.9
MPa and at 24 hours with 27.2 ؎ 7.4 MPa, the highest values.
Conclusions: Setting time influences the mechanical properties of the materials tested in this
study. Ketac Silver, a glass ionomer cement reinforced with sintered glass-silver particles, showed
the highest mechanical properties of the examined materials.
J Prosthodont 2001;10:140-147. Copyright © 2001 by The American College of Prosthodontists.
INDEX WORDS: core restoration, mechanical properties, compressive strength, flexural
strength, diametral tensile strength
FIXED PROSTHODONTIC restorations often
require the placement of foundation restora-
tions to establish retentive and resistance forms to
the teeth used as prosthesis retainers. These resto-
rations will ideally possess sufficient mechanical
strength, retention to the hard dental tissues, and a
high degree of biocompatibility.1
Glass ionomer cements2,3 have been used as core
build-up materials. They provide mechanical and
chemical adhesion to the hard dental tissues that is
on the order of one fifth to one third of that ob-
tained with composite resins using the acid-etch
technique.2 The reported results differ on the basis
of brand of material4 and conditioning techniques.5
Metal-reinforced glass ionomer cements, known as
cermet cements, are a mixture of glass and metal
powder6 sintered to high density. This material sets
to form a cement via an acid-base reaction.7 By
sintering metal particles into the glass phase, it is
possible to improve the material’s abrasion,8,9 and
to yield a modest increase in diametral tensile
strength.10
The objective of this study was to determine and
compare the mechanical properties of various ce-
ments used as core build-up materials relative to
time after first mixing. The parameters examined
were compressive strength, flexural strength, and
diametral tensile strength at times of 15 minutes, 1
hour, and 24 hours.
From Department of Prosthetic Dentistry, School of Dentistry, Johann
Wolfgang Goethe University, Frankfurt, Germany.
1
Assistant Professor.
2
Professor and Director.
Accepted June 25, 2001.
Correspondence to: Dr. A. Piwowarczyk, Department of Pros-
thetic Dentistry, School of Dentistry, Johann Wolfgang Goethe Uni-
versity, Theodor-Stern-Kai 7, D-60590 Frankfurt, Germany. E-mail:
piwowarczyk@t-online.de
Copyright © 2001 by The American College of Prosthodontists
1059-941X/01/1003-0003$35.00/0
doi:10.1053/jpro.2001.27338
140 Journal of Prosthodontics, Vol 10, No 3 (September), 2001: pp 140-147
Materials and Methods
This study evaluated 2 cermet cements (Ketac Silver
[ESPE, Seefeld, Germany] and Chelon Silver [ESPE]), 1
metal-reinforced glass ionomer cement (Miracle Mix
[GC Dental Industrial Corp, Tokyo, Japan]), 2 conven-
tional glass ionomer cements (Ketac Bond [ESPE] and
Ketac Cem [ESPE]), 1 standard cure zinc phosphate
cement (Harvard Cement [Richter and Hoffmann, Ber-
lin, Germany]), and 1 zinc phosphate cement with the
addition of 30% silver amalgam alloy powder (Harvard
Cement 70% with Dispersalloy 30% [Richter and Hoff-
mann/Johnson and Johnson, East Windsor, NJ]) under
compressive, tensile, and flexural forces (Table 1).
Powder was weighed using an analytical balance (Ϯ1
mg) following the manufacturer’s recommendation,
while the liquid volume suggested by the manufacturer
was established using a measuring pipette with an accu-
racy of Ϯ0.03 mL. One material, Ketac Silver, was sup-
plied in premeasured capsules. For this material, the
manufacturer’s recommendation of a trituration time of
10 seconds was used for the Capmix (ESPE) amalgam-
ator. To measure the compressive and tensile strengths,
specimens were prepared in cylindrical Teflon molds
(Figs 1 and 2) to the dimensions of 6 and 8 mm diameter
and 12 and 4 mm height, respectively, as dictated by the
British Standards Institute Specification 6039.11 The
specification BS 6039 refers to the manufacturer’s rec-
ommendations concerning the mixing process along with
the need to fill the molds within 2 minutes of the initia-
tion of mixing.
Specimens used to determine flexural strength were
produced in brass molds 25 ϫ 2 ϫ 2 mm in size that had
been insulated with polytetrafluoroethylene spray (DIN
13922/EN 24049).12 The molds were placed in an incu-
bator (Heraeus Kulzer, Hanau, Germany) at 37.0 Ϯ
1.0°C and at 95% to 100% relative humidity 3 minutes
after mixing. Specimens were removed from the mold
within 60 minutes of testing. Specimens for the 24-hour
measurements were stored in the incubator submerged
in distilled water until examined. The dimensions of the
specimens were checked with a micrometer (Mauser,
Figure 1. Precision mold and specimen for determining
the compressive strength (6 ϫ 12 mm).
Table 1. Core Materials and Manufacturers
Material Classification Manufacturer
Mixing
Process
Powder/Liquid
Ratio
Ketac Silver Cermet cement Espe, Seefeld, Germany Mechanical
Chelon Silver Cermet cement Espe, Seefeld, Germany Manual 3.8:1
Miracle Mix Metal-reinforced glass
ionomer cement
GC Dental Industrial
Corporation, Tokyo, Japan
Manual 5.0:1
Ketac Bond Conventional glass
ionomer cement
Espe, Seefeld, Germany Manual 3.4:1
Ketac Cem Conventional glass
ionomer cement
Espe, Seefeld, Germany Manual 3.4:1
Harvard Cement Zinc phosphate cement Richter & Hoffmann, Berlin,
Germany
Manual 2.5:1
Harvard Cement 70%/
Dispersalloy 30%
Zinc phosphate cement
with admixture
amalgam alloy
powder
Richter & Hoffmann, Berlin,
Germany/Johnson &
Johnson, East Windsor, NJ
Manual 2.5:1
Figure 2. Precision mold and specimen for determining
the diametral tensile strength (4 ϫ 8 mm).
141September 2001, Volume 10, Number 3
Nu¨rnberg, Germany; precision: 0.01 mm). Testing was
performed at 23.0 Ϯ 1.0°C and 50% Ϯ 5% relative hu-
midity. A Zwick 1435 Universal testing machine (Zwick,
Ulm, Germany) was used at a crosshead speed of 1
mm/min to test compressive and diametral tensile
strengths (Fig 3). Specimens were loaded until fracture
at a constant crosshead speed of 1 mm/min (BS 6039).11
Measurements for the 3-point flexural strength test (Fig
4) were performed at a constant crosshead speed of 1
mm/min (DIN 13922/EN 24049). Flexural, compressive,
and diametral tensile strengths were assessed at 15 min-
utes, 1 hour, and 24 hours after first mixing. Ten mea-
surements each were made for each material and for
each of the 3 parameters examined.
Statistical data analysis was performed by one-way
analysis of variance with regard to the time factor and by
2-sided t tests with regard to the compressive, flexural,
and diametral tensile strength variables. The level of
significance was fixed at p Յ .05 for significant differ-
ences. The Bonferroni test was used for post-hoc analysis
of variance comparing multiple means.
Results
Compressive Strength
At the earliest testing period of 15 minutes after
mixing, mean compressive strength values ranged
from 35.8 Ϯ 6.6 MPa for Ketac Cem to 74.9 Ϯ 7.2
MPa for Harvard zinc phosphate cement with ad-
mixture of silver amalgam alloy powder (Fig 5).
Compressive tests at 1 hour showed increased com-
pressive strength for all materials. Metal-reinforced
glass ionomer cements Ketac Silver and Chelon
Silver increased by 40.1% and 47.8%, respectively.
The lowest value was found for the glass ionomer
cement Ketac Cem with 64.2 Ϯ 7.3 MPa after 1
hour. At 24 hours, the compressive strength values
showed further increases to 144.3 Ϯ 10.2 MPa by
Ketac Silver, followed by Chelon Silver and Miracle
Mix with values of 119.2 Ϯ 17.8 MPa and 111.4 Ϯ
13.2 MPa, Harvard cement with 95.7 Ϯ 19.1 MPa,
and the admixture of Harvard cement with amal-
gam alloy powder with 91.5 Ϯ 15.0 MPa. The
Bonferonni test identified statistically significant
differences among groups concerning the times
of measurement (Table 2).
Diametral Tensile Strength
Diametral tensile strength means and standard
deviations are displayed in Fig 6. At 15 minutes, the
highest value of 7.8 Ϯ 1.0 MPa was obtained with
the combination of Harvard cement and amalgam
alloy powder; conventional glass ionomer cements
(Ketac Bond, Ketac Cem) were measured at 5.3 Ϯ
0.7 MPa and 4.4 Ϯ 0.9 MPa. At 1 hour, results for
the tested materials ranged from 6.3 Ϯ 1.0 MPa
(Ketac Cem) to 8.5 Ϯ 1.9 MPa (Miracle Mix). At 24
hours, Chelon Silver at 11.5 Ϯ 2.2 MPa, Ketac
Silver at 11.2 Ϯ 1.6 MPa, and Miracle Mix at 10.7 Ϯ
1.5 MPa showed the highest values. Between 1 and
24 hours after first mixing, Chelon Silver, Ketac
Silver, Miracle Mix, and Ketac Cem showed a sig-
nificant (p Յ .01) increase in diametral tensile
strength. In addition to the 3 times of measure-
Figure 3. Testing procedure for determining the diame-
tral tensile strength.
Figure 4. Testing procedure for determining the flex-
ural strength.
142 Laboratory Strength of Cements ● Piwowarczyk, Ottl, and Lauer
ment, the analysis of variance again identified sig-
nificant differences among the materials (Table 3).
Three-point Flexural Strength
Figure 7 illustrates the 3-point flexural strength
means and standard deviations. At 15 minutes after
first mixing, Harvard cement with amalgam alloy
powder at 16.2 Ϯ 1.4 MPa, Harvard cement at
14.5 Ϯ 1.7 MPa, and Ketac Silver at 13.5 Ϯ 3.9 MPa
yielded the highest values. At 15 minutes, Ketac
Cem showed the value of 4.7 Ϯ 1.7 MPa. During
the first hour, the flexural strength value for Mir-
acle Mix increased by 87.3% to 17.7 Ϯ 4.3 MPa. The
corresponding values for Chelon Silver and Ketac
Silver were 15.9 Ϯ 5.0 MPa and 15.0 Ϯ 4.6 MPa.
Twenty-four hours after first mixing, Ketac Silver,
at 27.2 Ϯ 7.4 MPa, yielded the highest values of all
the cements examined, while also showing the
greatest increase in strength (81.0%) over the
1-hour value. The other materials showed results
ranging from 9.6 Ϯ 4.6 MPa for Ketac Bond to
24.8 Ϯ 8.0 MPa for Chelon Silver (Fig 7). The
analysis of variance showed that Ketac Silver and
Chelon Silver differed significantly from Miracle
Mix (p Յ .01), Ketac Cem (p Յ .01), Ketac Bond
(p Յ .01), Harvard cement (p Յ .01), and Harvard
cement with amalgam alloy powder (p Յ .05). As a
result of the Bonferonni test at p Յ .05, the vertical
lines in Table 4 bracket statistically equivalent
groups.
Discussion
In designing this study, the decision was made to
make evaluations on standardized molds. This al-
lowed the testing to conform to the British Stan-
Figure 5. Compressive
strength (BS 6039) of various
core restoration materials
(0.25, 1, and 24 hours after
first mixing; n ϭ 10 measure-
ments each per material and
time). KS, Ketac Silver; CS,
Chelon Silver; MM, Miracle
Mix; KB, Ketac Bond; KC,
Ketac Cem; HZ, Harvard ce-
ment; HA, Harvard cement
with amalgam alloy powder.
Table 2. Compressive Strength (BS 6039) of Various Core Restoration Materials (0.25, 1, and 24 Hours After First
Mixing; n ϭ 10 Measurements Each per Material and Time)
Material
0.25 h 1 h 24 h
x (MPa) x (MPa) x (MPa)
Ketac Silver 66.0 Ϯ 3.5 92.5 Ϯ 9.5 144.3 Ϯ 10.2
Chelon Silver 55.1 Ϯ 2.6 81.5 Ϯ 5.9 119.2 Ϯ 17.8
Miracle Mix 40.7 Ϯ 4.1 77.6 Ϯ 6.1 111.4 Ϯ 13.2
Ketac Bond 37.7 Ϯ 4.0 66.2 Ϯ 6.7 84.1 Ϯ 18.3
Ketac Cem 35.8 Ϯ 6.6 64.2 Ϯ 7.3 80.1 Ϯ 201
Harvard cement 72.9 Ϯ 5.9 84.0 Ϯ 13.3 95.7 Ϯ 19.1
Harvard cement 70%/
amalgam alloy powder
(Dispersalloy) 30% 74.9 Ϯ 7.2 86.9 Ϯ 11.4 91.5 Ϯ 15.0
Note. The vertical bars in respective lines to the right of the points of measurement indicate groups that do not significantly differ as
measured by the Bonferroni test (p Յ .05).
Abbreviations: x, arithmetic mean; s, standard deviation.
143September 2001, Volume 10, Number 3
dards Institute Specification 6039.11 The alternative
use of extracted teeth brought with it the variability
associated with differences in dimensions, degree of
calcification, water content, and the potential for
pre-existing hard tissue defects.13-15 Although the
latter approach may allow simpler interpretation of
clinical expectations, it eliminates standardization
and complicates meaningful comparisons.
Considerable differences in compressive, flex-
ural, and diametral tensile strength were seen
among the tested materials. All 3 of the recognized
tests showed a similar ranking order for the mate-
rials (Figs 5, 6, and 7). Under the conditions of this
study, Ketac Silver presented the highest values of
compressive and flexural strengths at 24 hours of
all the cements examined. This material showed
statistically significant differences (p Յ .05) in test-
ing compressive strength at all times of measure-
ment.
Between 1 and 24 hours, Ketac Silver showed a
significant (p Յ .01) increase in strength within all
the 3 testing parameters. Previous reports showed
that the setting reaction of glass ionomer cements
is complex, requiring 24 hours for maturation.7,16,17
This is in contrast to the zinc phosphate materials,
Harvard cement, and Harvard cement with added
amalgam alloy, which showed less increase in
strength over time.
The data in this report failed to show a consis-
tent relationship between the method of mixing
(manual or mechanical) and strength properties.
Strict adherence to the prescribed mixing ratio is
Figure 6. Diametral tensile
strength (BS 6039) of various
core restoration materials
(0.25, 1, and 24 hours after
first mixing; n ϭ 10 measure-
ments each per material and
time). KS, Ketac Silver; CS,
Chelon Silver; MM, Miracle
Mix; KB, Ketac Bond; KC,
Ketac Cem; HZ, Harvard ce-
ment; HA, Harvard cement
with amalgam alloy powder.
Table 3. Diametral Tensile Strength (BS 6039) of Various Core Restoration Materials (0.25, 1, and 24 Hours After
First Mixing; n ϭ 10 Measurements Each per Material and Time)
Material
0.25 h 1 h 24 h
x (MPa) s (MPa) x (MPa) s (MPa) x (MPa) s (MPa)
Ketac Silver 6.5 1.5 8.1 1.5 11.2 1.6
Chelon Silver 7.2 1.6 8.2 1.4 11.5 2.2
Miracle Mix 7.2 1.0 8.5 1.9 10.7 1.5
Ketac Bond 5.3 0.7 6.9 1.2 7.4 1.2
Ketac Cem 4.4 0.9 6.3 1.0 7.5 1.3
Harvard cement 6.9 0.9 7.4 1.1 7.9 1.7
Harvard cement 70%/
amalgam alloy powder
(Dispersalloy) 30% 7.8 1.0 8.3 1.1 9.2 1.8
Note. The vertical bars in respective lines to the right of the points of measurement indicate groups that do not significantly differ as
measured by the Bonferroni test (p Յ .05).
Abbreviations: x, arithmetic mean; s, standard deviation.
144 Laboratory Strength of Cements ● Piwowarczyk, Ottl, and Lauer
said to be especially important for the successful
use of glass ionomer cements. Negative influences
on strength, solubility, and surface structure as a
result of having too little powder have been cited in
the literature. Conversely, with too high of a pow-
der-to-liquid ratio, a reduction in setting time and
bond strength has been described.18,19 The manu-
ally mixed product Chelon Silver, chemically iden-
tical to Ketac Silver, has a lower compressive
strength at 15 minutes (p Յ .01), 1 hour (p Յ .05),
and 24 hours (p Յ .01), but Chelon Silver and
Ketac Silver showed no significant differences in
flexural and diametral tensile strengths over these
time periods (p Յ .05).
The present study showed significantly (p Յ .05)
lower values for the glass ionomer cements Ketac
Cem and Ketac Bond concerning compressive, flex-
ural, and diametral tensile strengths at all times of
measurement, compared with the cermet cements,
Ketac Silver and Chelon Silver. The data reported
by Chung10 showed higher diametral tensile
strength values for metal-reinforced materials,
Ketac Silver and Miracle Mix, compared with the
glass ionomer cement, Fuji II (GC Dental Indus-
trial Corp). Cermet cements were intended to pos-
sess higher flexural strength than glass ionomer
cements.20 Walls and coworkers21 showed an in-
crease in compressive strength and compressive
fatigue limit for cermet-type materials compared
with the strength of a conventional glass ionomer
cement from the same manufacturer. In contrast to
the above-mentioned studies, Cho et al22 docu-
mented that silver-reinforced glass ionomer cement
Ketac Silver did not improve the compressive and
diametral tensile strength in comparison with the
conventional glass ionomer cement, Ketac Fil
Figure 7. Three-point flex-
ural strength (DIN 13922/EN
24049) of various core resto-
ration materials (0.25, 1, and
24 hours after first mixing;
n ϭ 10 measurements each
per material and time). KS,
Ketac Silver; CS, Chelon Sil-
ver; MM, Miracle Mix; KB,
Ketac Bond; KC, Ketac
Cem; HZ, Harvard cement;
HA, Harvard cement with
amalgam alloy powder.
Table 4. Three-point Flexural Strength (DIN 13922/EN 24049) of Various Core Restoration Materials (0.25, 1, and
24 Hours After First Mixing; n ϭ 10 Measurements Each per Material and Time)
Material
0.25 h 1 h 24 h
x (MPa) s (MPa) x (MPa) s (MPa) x (MPa) s (MPa)
Ketac Silver 13.5 3.9 15.0 4.6 27.2 7.4
Chelon Silver 11.8 4.1 15.9 5.0 24.8 8.0
Miracle Mix 9.5 1.1 17.7 4.3 18.5 1.9
Ketac Bond 8.4 3.2 7.3 4.4 9.6 4.6
Ketac Cem 4.7 1.7 8.2 3.4 11.6 5.6
Harvard cement 14.5 1.7 17.7 2.9 20.3 1.6
Harvard cement 70%/
amalgam alloy powder
(Dispersalloy) 30% 16.2 1.4 18.8 1.3 22.0 1.6
Note. The vertical bars in respective lines to the right of the points of measurement indicate groups that do not significantly differ as
measured by the Bonferroni test (p Յ .05).
Abbreviations: x, arithmetic mean; s, standard deviation.
145September 2001, Volume 10, Number 3
(ESPE). The work of Williams et al23 did not show
any significant reduction in compressive and diame-
tral tensile strengths for the glass ionomer ce-
ments, Chelon Fil (ESPE) and Fuji II (GC Dental
Industrial Corp), compared with reinforced mate-
rials, Chelon Silver and Miracle Mix. Peutzfeldt24
reported a similar flexural strength of Ketac Silver
and Miracle Mix to 5 conventional glass ionomer
cements.
In the present study, Miracle Mix, a metal-
reinforced, nonsintered glass ionomer cement,
showed a marked increase in compressive, tensile,
and flexural strengths during the first hour after
first mixing. At 24 hours, Miracle Mix was inferior
to the cermet cements Ketac Silver (p Յ .01) and
Chelon Silver (p Յ .05) in flexural strength. After 7
days, Peutzfeldt24 found, in the 3-point flexural
strength tests with specimens of 10 ϫ 2 ϫ 2 mm, a
flexural strength of 13 Ϯ 2 MPa for Miracle Mix
and 29 Ϯ 13 MPa for Ketac Silver. Nakajima et al25
showed no significant differences in 3-point flexural
strength tests on Miracle Mix glass ionomer ce-
ments (23.0 Ϯ 3.1 MPa) and Ketac Silver (22.6 Ϯ
10.4 MPa) when tested at 24 hours after storage
in 100% humidity at 37°C. When measuring com-
pressive strengths (American Dental Association
[ADA] specification #66), values of 132.1 Ϯ 13.7
MPa and 121.9 Ϯ 12.7 MPa for Miracle Mix and
Ketac Silver, respectively, were shown.
Cohen et al26 examined the diametral tensile
strength and compressive strength (ADA specifica-
tion #27) of titanium-reinforced composite resins,
Ti-Core (Essential Dental Systems, Hackensack,
NJ) and Flexi-Flow Cem (Essential Dental Sys-
tems), compared with commercially available core
build-up materials and cements. All specimens had
been stored at 100% humidity for 24 hours. The
glass ionomer cements Ketac Silver, Miracle Mix,
and Ketac Cem yielded 60.1% to 80.8% lower values
than titanium-reinforced composite resins. Of the
3 glass ionomer cements tested, Ketac Silver
achieved the highest values with regard to diame-
tral tensile strength and compressive strength at
12.5 Ϯ 2.2 MPa and 115.1 Ϯ 16.0 MPa, respectively.
The present study showed that after 24 hours,
zinc phosphate cement, with and without the ad-
mixture of silver amalgam alloy powder, is stronger
than conventional glass ionomer cements and
weaker than cermet cements under compressive,
tensile, and flexural forces. The cement strength is
almost linearly dependent on the powder:liquid ra-
tio.27 For zinc phosphate cement, Abraham28 deter-
mined an increasing compressive strength and de-
clining solubility by increasing the powder-to-liquid
ratio. On a graphic curve, this results in a rise to a
maximum value and subsequently a decline in re-
lation to the compressive strength. Smith29 con-
cluded that the compressive and tensile strengths
of properly mixed zinc phosphate cement are ade-
quate to resist masticatory stress.
The reported results concerning the mechanical
properties of cements are broad and variable. In
particular, measurements of strength are depen-
dent on the method of specimen preparation, the
operator, and labor variability.30 In addition to me-
chanical properties, other factors such as pulp com-
patibility,31-33 allergic potential,34-36 and expansion
caused by water absorption37-39 should be consid-
ered when choosing a material for a foundation
restoration. To confirm the results of laboratory
studies, longitudinal clinical trials should be con-
ducted to establish the most important predictors
of clinical success for core materials.
Conclusions
1. Compressive strength, flexural strength, and
diametral tensile strength varied among the
tested materials.
2. Under the conditions of this study, 24 hours after
first mixing, cermet cements were stronger than
metal-reinforced glass ionomer cement, conven-
tional glass ionomer cements, and zinc phos-
phate cement without and with the addition of
silver amalgam alloy powder.
3. The compressive strength of Chelon Silver was
significantly lower than the chemically identical
capsule product Ketac Silver at the 3 times of
measurement.
Acknowledgment
The authors would like to thank the Institute for Medical
Information Processing, Biometry, and Epidemiology (di-
rector: Professor K. U¨berla) of the University of Munich
for its support in performing the statistical analysis of the
data.
References
1. Paul SJ, Scha¨rer P: Plastische Aufbauten in der Kronen- und
Bru¨ckenprothetik. [Plastic build-ups in crown and bridge
prosthodontics.] Quintessenz 1996;47:1519-1531
2. Hickel R, Kunzelmann K-H: Glasionomer- und Kompomer-
fu¨llung [Glass ionomer and compomer restorations], in Hei-
146 Laboratory Strength of Cements ● Piwowarczyk, Ottl, and Lauer
demann D (ed): Kariologie und Fu¨llungstherapie. Praxis
der Zahnheilkunde (ed 4). Mu¨nchen, Germany, Urban &
Schwarzenberg, 1999, pp 154-176
3. Hickel R: Moderne Fu¨llungswerkstoffe. [Modern restorative
materials.] Dtsch Zahna¨rztl Z 1997;52:572-585
4. Lin A, McIntyre NS, Davidson RD: Studies on the adhesion
of glass-ionomer cements to dentin. J Dent Res 1992;71:
1836-1841
5. Powis DR, Follerås T, Merson SA, et al: Improved adhesion
of a glass ionomer cement to dentin and enamel. J Dent Res
1982;61:1416-1422
6. McLean JW, Gasser O: Glass-cermet cements. Quintes-
sence Int 1985;16:333-343
7. Wilson AD, McLean JW: Glass-ionomer cement. Chicago,
IL, Quintessence Publishing, 1988
8. McKinney JE, Antonucci JM, Rupp NW: Wear and micro-
hardness of a silver-sintered glass-ionomer cement. J Dent
Res 1988;67:831-835
9. Moore BK, Swartz ML, Phillips RW: Abrasion resistance of
metal reinforced glass ionomer cements. J Dent Res 1985;
64:371 (abstr 1766)
10. Chung KH: The properties of metal-reinforced glass iono-
mer materials. J Oral Rehabil 1993;20:79-87
11. British Standards Institution: Specification for dental glass
ionomer cements. BS 6039, 1981
12. DIN Deutsches Institut fu¨r Normung e.V, DIN-Taschen-
buch 267: Zahnheilkunde-Werkstoffe: Normen, Gesetze,
Richtlinien. [Dental Materials: Standards, Laws, Direc-
tives.] Berlin, Germany, Beuth, 1997, pp 105-116
13. Kantor ME, Pines MS: A comparative study of restorative
techniques for pulpless teeth. J Prosthet Dent 1977;38:405-
412
14. Mc Donald AV, King PA, Setchell DJ: An in vitro study to
compare impact fracture resistance of intact root-treated
teeth. Int Endod J 1990;23:304-312
15. Trope M, Maltz DO, Tronstad L: Resistance to fracture of
restored endodontically treated teeth. Endod Dent Trauma-
tol 1985;1:108-111
16. Smith DC: Composition and characteristics of glass ionomer
cements. J Am Dent Assoc 1990;120:20-22
17. Nicholson JW: Chemistry of glass-ionomer cements: A re-
view. Biomaterials 1998;19:485-494
18. Kullmann W: Glasionomer-Zemente—Physikalisch-tech-
nische Eigenschaften in Abha¨ngigkeit von der Verarbeitung.
[Glass ionomer cements—Physical-technical characteristics
as a function of the processing.] Dtsch Zahna¨rztl Z 1986;41:
751-754
19. Mount GJ, Makinson OF: Glass-ionomer restorative ce-
ments: Clinical implications of the setting reaction. Oper
Dent 1982;7:134-141
20. McLean JW: Cermet cements. J Am Dent Assoc 1990;120:
43-47
21. Walls AWG, Adamson J, McCabe JF, et al: The properties of
a glass polyalkenoate (ionomer) cement incorporating sin-
tered metallic particles. Dent Mater 1987;3:113-116
22. Cho GC, Kaneko LM, Donovan TE, et al: Diametral and
compressive strength of dental core materials. J Prosthet
Dent 1999;82:272-276
23. Williams JA, Billington RW, Pearson GJ: The compar-
ative strengths of commercial glass-ionomer cements
with and without metal additions. Br Dent J 1992;172:
279-282
24. Peutzfeldt A: Compomers and glass ionomers: Bond
strength to dentin and mechanical properties. Am J Dent
1996;9:259-263
25. Nakajima H, Watkins JH, Arita K, et al: Mechanical prop-
erties of glass ionomers under static and dynamic loading.
Dent Mater 1996;12:30-37
26. Cohen BI, Deutsch AS, Condos S, et al: Compressive and
diametral tensile strength of titanium-reinforced compos-
ites. J Esthet Dent 1992;4:50-55
27. Bruce WL, Stevens L: Strength properties of three zinc
phosphate cements mixed to two different consistencies.
Aust Dent J 1989;34:132-135
28. Abraham B: Untersuchung von vier Zinkphosphatzementen
auf Druckfestigkeit und Lo¨slichkeit nach der FDI-Spezifika-
tion Nr. 6 bei verschiedenem Pulver-Flu¨ssigkeits-Verha¨ltnis.
[Study of four zinc phosphate cements for compression
strength and solubility according to the FDI specification
No. 6 with different powder-liquid ratio.] Thesis, Berlin,
1973
29. Smith DC: Dental cements. Current status and future pros-
pects. Dent Clin North Am 1983;27:763-792
30. McCabe JF, Watts DC, Wilson HJ, et al: An investigation of
test house variability in the mechanical testing of material
and statistical treatment of results. J Dent Res 1990;18:
90-97
31. Hume WR, Mount GJ: In vitro studies on the potential for
pulpal cytotoxicity of glass-ionomer cements. J Dent Res
1988;67:915-918
32. Schmalz G, Thonemann B, Riedel M, et al: Biological and
clinical investigations of a glass ionomer base material. Dent
Mater 1994;10:304-313
33. Schmalz G: The biocompatibility of non-amalgam dental
filling materials. Eur J Oral Sci 1998;106:696-706
34. Geurtsen W: Substances released from dental resin compos-
ites and glass ionomer cements. Eur J Oral Sci 1998;106:
687-695
35. Arenholt-Bindslev D: Composites and Compomers. 1st
In-
ternational ESPE Dental Symposium, Mu¨nchen, Germany,
September 28, 1998
36. Arenholt-Bindslev D: Environmental aspects of dental filling
materials. Eur J Oral Sci 1998;106:713-720
37. Cooley RL, Robbins JW, Barnwell S: Dimensional stability of
glass ionomer used as a core material. J Prosthet Dent
1990;64:651-653
38. Small IC, Watson TF, Chadwick AV, et al: Water
sorption in resin-modified glass-ionomer cements: An
in vitro comparison with other materials. Biomaterials
1998;19:545-550
39. Cattani-Lorente MA, Dupuis V, Moya F, et al: Comparative
study of the physical properties of a polyacid-modified com-
posite resin and a resin-modified glass ionomer cement.
Dent Mater 1999;15:21-32
147September 2001, Volume 10, Number 3

Mais conteúdo relacionado

Mais procurados

Experimental study of ancient admixture and natural fibre in concrete
Experimental study of ancient admixture and natural fibre in concreteExperimental study of ancient admixture and natural fibre in concrete
Experimental study of ancient admixture and natural fibre in concreteeSAT Journals
 
IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...
IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...
IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...IRJET Journal
 
Experimental Study of Strength Parameters of Hybrid Fibre Reinforced C...
Experimental Study of  Strength  Parameters  of   Hybrid  Fibre  Reinforced C...Experimental Study of  Strength  Parameters  of   Hybrid  Fibre  Reinforced C...
Experimental Study of Strength Parameters of Hybrid Fibre Reinforced C...IRJET Journal
 
Preparation and Characterization of Rubber Composites using Sawdust as Filler
Preparation and Characterization of Rubber Composites using Sawdust as FillerPreparation and Characterization of Rubber Composites using Sawdust as Filler
Preparation and Characterization of Rubber Composites using Sawdust as Fillerijtsrd
 
Tensile properties of unidirectional glass/epoxy composites at different orie...
Tensile properties of unidirectional glass/epoxy composites at different orie...Tensile properties of unidirectional glass/epoxy composites at different orie...
Tensile properties of unidirectional glass/epoxy composites at different orie...IJERA Editor
 
Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...
Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...
Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...IJERA Editor
 
Changes in Structural Features of Al-12Si-3Cu Alloy Due to Age Hardening
Changes in Structural Features of Al-12Si-3Cu Alloy Due to Age HardeningChanges in Structural Features of Al-12Si-3Cu Alloy Due to Age Hardening
Changes in Structural Features of Al-12Si-3Cu Alloy Due to Age HardeningIRJET Journal
 
IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...
IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...
IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...IRJET Journal
 
Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...eSAT Journals
 
EFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETE
EFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETEEFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETE
EFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETEIAEME Publication
 
IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...
IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...
IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...IRJET Journal
 
Comparison of rebound numbers for m20 concrete with silica fume
Comparison of rebound numbers for m20 concrete with silica fumeComparison of rebound numbers for m20 concrete with silica fume
Comparison of rebound numbers for m20 concrete with silica fumeeSAT Publishing House
 
Improving impact and mechanical properties of gap graded concrete
Improving impact and mechanical properties of gap graded concreteImproving impact and mechanical properties of gap graded concrete
Improving impact and mechanical properties of gap graded concreteIAEME Publication
 
IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...
IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...
IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...IRJET Journal
 
STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...
STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...
STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...IAEME Publication
 
IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...
IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...
IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...IRJET Journal
 

Mais procurados (19)

Experimental study of ancient admixture and natural fibre in concrete
Experimental study of ancient admixture and natural fibre in concreteExperimental study of ancient admixture and natural fibre in concrete
Experimental study of ancient admixture and natural fibre in concrete
 
Ijmet 10 01_052
Ijmet 10 01_052Ijmet 10 01_052
Ijmet 10 01_052
 
IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...
IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...
IRJET-Expremental Analysis of Ternary Blended Concrete by using Partial Repla...
 
Experimental Study of Strength Parameters of Hybrid Fibre Reinforced C...
Experimental Study of  Strength  Parameters  of   Hybrid  Fibre  Reinforced C...Experimental Study of  Strength  Parameters  of   Hybrid  Fibre  Reinforced C...
Experimental Study of Strength Parameters of Hybrid Fibre Reinforced C...
 
Preparation and Characterization of Rubber Composites using Sawdust as Filler
Preparation and Characterization of Rubber Composites using Sawdust as FillerPreparation and Characterization of Rubber Composites using Sawdust as Filler
Preparation and Characterization of Rubber Composites using Sawdust as Filler
 
Tensile properties of unidirectional glass/epoxy composites at different orie...
Tensile properties of unidirectional glass/epoxy composites at different orie...Tensile properties of unidirectional glass/epoxy composites at different orie...
Tensile properties of unidirectional glass/epoxy composites at different orie...
 
Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...
Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...
Effect of Coarse Aggregate Size on the Compressive Strength and the Flexural ...
 
Changes in Structural Features of Al-12Si-3Cu Alloy Due to Age Hardening
Changes in Structural Features of Al-12Si-3Cu Alloy Due to Age HardeningChanges in Structural Features of Al-12Si-3Cu Alloy Due to Age Hardening
Changes in Structural Features of Al-12Si-3Cu Alloy Due to Age Hardening
 
IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...
IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...
IRJET- Strength and Durability Properties of High Volume Fly Ash Concrete for...
 
Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...Investigation on the behaviour of alfa composite in pre and post heat treated...
Investigation on the behaviour of alfa composite in pre and post heat treated...
 
A02110105
A02110105A02110105
A02110105
 
EFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETE
EFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETEEFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETE
EFFECT OF ACTIVATOR RATIO ON STRENGTH PROPERTIES OF GEOPOLYMER CONCRETE
 
IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...
IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...
IRJET- Experimental Investigation of Self Compacting and Self Curing Concrete...
 
Comparison of rebound numbers for m20 concrete with silica fume
Comparison of rebound numbers for m20 concrete with silica fumeComparison of rebound numbers for m20 concrete with silica fume
Comparison of rebound numbers for m20 concrete with silica fume
 
Improving impact and mechanical properties of gap graded concrete
Improving impact and mechanical properties of gap graded concreteImproving impact and mechanical properties of gap graded concrete
Improving impact and mechanical properties of gap graded concrete
 
IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...
IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...
IRJET - Flexural Behaviour of Reinforced Concrete with Polypropylene and Crim...
 
STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...
STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...
STRENGTH CHARACTERIZATION OF GLASSCARON HYBRID REINFORCEMENTS - AN EXPERIMENT...
 
S4805118123
S4805118123S4805118123
S4805118123
 
IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...
IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...
IRJET- Comparative Study on the Strength Parameters of Concrete Made using Na...
 

Destaque

Secrets of success
Secrets of successSecrets of success
Secrets of successAdeel Javaid
 
مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...
مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...
مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...احتكار التميز
 
Event stolica общее
Event stolica общееEvent stolica общее
Event stolica общееphenix-ra
 
Role of amm
Role of ammRole of amm
Role of ammRaad-Ali
 
مؤسسة احتكار التميز لمنتجات التجميل
مؤسسة احتكار التميز لمنتجات التجميلمؤسسة احتكار التميز لمنتجات التجميل
مؤسسة احتكار التميز لمنتجات التجميلاحتكار التميز
 
Physiognomy in classification of individuals with lateral preference in masti...
Physiognomy in classification of individuals with lateral preference in masti...Physiognomy in classification of individuals with lateral preference in masti...
Physiognomy in classification of individuals with lateral preference in masti...Jinny Shaw
 
Cybersecurity threat assessment manual
Cybersecurity threat assessment manualCybersecurity threat assessment manual
Cybersecurity threat assessment manualAdeel Javaid
 

Destaque (10)

Secrets of success
Secrets of successSecrets of success
Secrets of success
 
مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...
مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...
مؤسسة احتكار التميز لمنتجات التجميل - مستحضرات التجميل - العناية بالبشرة - تب...
 
post and core
post and corepost and core
post and core
 
Event stolica общее
Event stolica общееEvent stolica общее
Event stolica общее
 
Role of amm
Role of ammRole of amm
Role of amm
 
مؤسسة احتكار التميز لمنتجات التجميل
مؤسسة احتكار التميز لمنتجات التجميلمؤسسة احتكار التميز لمنتجات التجميل
مؤسسة احتكار التميز لمنتجات التجميل
 
LA
LALA
LA
 
Physiognomy in classification of individuals with lateral preference in masti...
Physiognomy in classification of individuals with lateral preference in masti...Physiognomy in classification of individuals with lateral preference in masti...
Physiognomy in classification of individuals with lateral preference in masti...
 
radiology
radiologyradiology
radiology
 
Cybersecurity threat assessment manual
Cybersecurity threat assessment manualCybersecurity threat assessment manual
Cybersecurity threat assessment manual
 

Semelhante a article

Flexural strengthofveneeringceramicsforzirconia
Flexural strengthofveneeringceramicsforzirconiaFlexural strengthofveneeringceramicsforzirconia
Flexural strengthofveneeringceramicsforzirconiaThapanee Srichumpong
 
The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder Tre...
The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder  Tre...The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder  Tre...
The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder Tre...University of Mosul, College of Dentistry,
 
Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)
Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)
Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)IOSR Journals
 
silver nanoparticles relation on properties of silicone elastomer
silver nanoparticles relation on properties of silicone elastomersilver nanoparticles relation on properties of silicone elastomer
silver nanoparticles relation on properties of silicone elastomerdellasain
 
An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...
An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...
An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...IRJET Journal
 
Experimental Study on Strength of Concrete with Addition of Chopped Glass Fiber
Experimental Study on Strength of Concrete with Addition of Chopped Glass FiberExperimental Study on Strength of Concrete with Addition of Chopped Glass Fiber
Experimental Study on Strength of Concrete with Addition of Chopped Glass FiberIRJET Journal
 
12_Mahmoud_Rev6 (1)
12_Mahmoud_Rev6 (1)12_Mahmoud_Rev6 (1)
12_Mahmoud_Rev6 (1)Amr Hussien
 
Effect of Heat Treatment on Corrosion Behavior of Spring Steels
Effect of Heat Treatment on Corrosion Behavior of Spring SteelsEffect of Heat Treatment on Corrosion Behavior of Spring Steels
Effect of Heat Treatment on Corrosion Behavior of Spring SteelsEditor IJCATR
 
Fric wear1904011semenovkor
Fric wear1904011semenovkorFric wear1904011semenovkor
Fric wear1904011semenovkorM Muhajirin
 
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...IRJET Journal
 
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...IRJET Journal
 
IRJET- Effect on Strength of Steel Fiber Reinforced Concrete with Variati...
IRJET-  	  Effect on Strength of Steel Fiber Reinforced Concrete with Variati...IRJET-  	  Effect on Strength of Steel Fiber Reinforced Concrete with Variati...
IRJET- Effect on Strength of Steel Fiber Reinforced Concrete with Variati...IRJET Journal
 
Basic principles in impression making 3
Basic principles in impression making  3Basic principles in impression making  3
Basic principles in impression making 3Prosth Ozone
 
journel clubs in prosthodontics
journel clubs in prosthodonticsjournel clubs in prosthodontics
journel clubs in prosthodonticsdellasain
 
Experimental Investigation on Mechanical Properties of Self-healing Concrete ...
Experimental Investigation on Mechanical Properties of Self-healing Concrete ...Experimental Investigation on Mechanical Properties of Self-healing Concrete ...
Experimental Investigation on Mechanical Properties of Self-healing Concrete ...IRJET Journal
 
Paper id 27201418
Paper id 27201418Paper id 27201418
Paper id 27201418IJRAT
 

Semelhante a article (20)

Flexural strengthofveneeringceramicsforzirconia
Flexural strengthofveneeringceramicsforzirconiaFlexural strengthofveneeringceramicsforzirconia
Flexural strengthofveneeringceramicsforzirconia
 
The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder Tre...
The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder  Tre...The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder  Tre...
The Evaluation of Certain Properties of Polymethyl – Methacrylate Powder Tre...
 
Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)
Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)
Performance of Self Compacting High Strength Fiber Reinforced Concrete (SCHSFRC)
 
silver nanoparticles relation on properties of silicone elastomer
silver nanoparticles relation on properties of silicone elastomersilver nanoparticles relation on properties of silicone elastomer
silver nanoparticles relation on properties of silicone elastomer
 
An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...
An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...
An Experimental Investigation on Steel Fiber Reinforced Concrete with Partial...
 
Firing cycle
Firing cycleFiring cycle
Firing cycle
 
Experimental Study on Strength of Concrete with Addition of Chopped Glass Fiber
Experimental Study on Strength of Concrete with Addition of Chopped Glass FiberExperimental Study on Strength of Concrete with Addition of Chopped Glass Fiber
Experimental Study on Strength of Concrete with Addition of Chopped Glass Fiber
 
12_Mahmoud_Rev6 (1)
12_Mahmoud_Rev6 (1)12_Mahmoud_Rev6 (1)
12_Mahmoud_Rev6 (1)
 
Effect of Heat Treatment on Corrosion Behavior of Spring Steels
Effect of Heat Treatment on Corrosion Behavior of Spring SteelsEffect of Heat Treatment on Corrosion Behavior of Spring Steels
Effect of Heat Treatment on Corrosion Behavior of Spring Steels
 
Fric wear1904011semenovkor
Fric wear1904011semenovkorFric wear1904011semenovkor
Fric wear1904011semenovkor
 
Puplish report 2
Puplish report 2Puplish report 2
Puplish report 2
 
26 write-up
26 write-up26 write-up
26 write-up
 
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...
 
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...IRJET-  	  Utilization & Effects of Crown Caps on Strength Properties of Conc...
IRJET- Utilization & Effects of Crown Caps on Strength Properties of Conc...
 
IRJET- Effect on Strength of Steel Fiber Reinforced Concrete with Variati...
IRJET-  	  Effect on Strength of Steel Fiber Reinforced Concrete with Variati...IRJET-  	  Effect on Strength of Steel Fiber Reinforced Concrete with Variati...
IRJET- Effect on Strength of Steel Fiber Reinforced Concrete with Variati...
 
Basic principles in impression making 3
Basic principles in impression making  3Basic principles in impression making  3
Basic principles in impression making 3
 
journel clubs in prosthodontics
journel clubs in prosthodonticsjournel clubs in prosthodontics
journel clubs in prosthodontics
 
Experimental Investigation on Mechanical Properties of Self-healing Concrete ...
Experimental Investigation on Mechanical Properties of Self-healing Concrete ...Experimental Investigation on Mechanical Properties of Self-healing Concrete ...
Experimental Investigation on Mechanical Properties of Self-healing Concrete ...
 
Paper id 27201418
Paper id 27201418Paper id 27201418
Paper id 27201418
 
Flexural Behaviour of Steel Fibers Reinforced High Strength Self Compacting C...
Flexural Behaviour of Steel Fibers Reinforced High Strength Self Compacting C...Flexural Behaviour of Steel Fibers Reinforced High Strength Self Compacting C...
Flexural Behaviour of Steel Fibers Reinforced High Strength Self Compacting C...
 

Último

The Next Things To Immediately Do About Mating Press
The Next Things To Immediately Do About Mating PressThe Next Things To Immediately Do About Mating Press
The Next Things To Immediately Do About Mating Pressmatingpress170
 
Jumark Morit Diezmo- Career portfolio- BPED 3A
Jumark Morit Diezmo- Career portfolio- BPED 3AJumark Morit Diezmo- Career portfolio- BPED 3A
Jumark Morit Diezmo- Career portfolio- BPED 3Ajumarkdiezmo1
 
办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一
办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一
办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一A SSS
 
Introduction to phyton , important topic
Introduction to phyton , important topicIntroduction to phyton , important topic
Introduction to phyton , important topicakpgenious67
 
原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量
原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量
原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量sehgh15heh
 
Escort Service Andheri WhatsApp:+91-9833363713
Escort Service Andheri WhatsApp:+91-9833363713Escort Service Andheri WhatsApp:+91-9833363713
Escort Service Andheri WhatsApp:+91-9833363713Riya Pathan
 
格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档
格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档
格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档208367051
 
办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一
办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一
办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一A SSS
 
Nathan_Baughman_Resume_copywriter_and_editor
Nathan_Baughman_Resume_copywriter_and_editorNathan_Baughman_Resume_copywriter_and_editor
Nathan_Baughman_Resume_copywriter_and_editorNathanBaughman3
 
定制英国克兰菲尔德大学毕业证成绩单原版一比一
定制英国克兰菲尔德大学毕业证成绩单原版一比一定制英国克兰菲尔德大学毕业证成绩单原版一比一
定制英国克兰菲尔德大学毕业证成绩单原版一比一z zzz
 
8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCR
8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCR8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCR
8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCRdollysharma2066
 
Spanish Classes Online In India With Tutor At Affordable Price
Spanish Classes Online In India With Tutor At Affordable PriceSpanish Classes Online In India With Tutor At Affordable Price
Spanish Classes Online In India With Tutor At Affordable PriceFluent Fast Academy
 
Unlock Your Creative Potential: 7 Skills for Content Creator Evolution
Unlock Your Creative Potential: 7 Skills for Content Creator EvolutionUnlock Your Creative Potential: 7 Skills for Content Creator Evolution
Unlock Your Creative Potential: 7 Skills for Content Creator EvolutionRhazes Ghaisan
 
美国SU学位证,雪城大学毕业证书1:1制作
美国SU学位证,雪城大学毕业证书1:1制作美国SU学位证,雪城大学毕业证书1:1制作
美国SU学位证,雪城大学毕业证书1:1制作ss846v0c
 
AICTE PPT slide of Engineering college kr pete
AICTE PPT slide of Engineering college kr peteAICTE PPT slide of Engineering college kr pete
AICTE PPT slide of Engineering college kr peteshivubhavv
 
原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证
原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证
原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证diploma001
 
LinkedIn Strategic Guidelines April 2024
LinkedIn Strategic Guidelines April 2024LinkedIn Strategic Guidelines April 2024
LinkedIn Strategic Guidelines April 2024Bruce Bennett
 
Digital Marketing Training Institute in Mohali, India
Digital Marketing Training Institute in Mohali, IndiaDigital Marketing Training Institute in Mohali, India
Digital Marketing Training Institute in Mohali, IndiaDigital Discovery Institute
 
Application deck- Cyril Caudroy-2024.pdf
Application deck- Cyril Caudroy-2024.pdfApplication deck- Cyril Caudroy-2024.pdf
Application deck- Cyril Caudroy-2024.pdfCyril CAUDROY
 

Último (20)

The Next Things To Immediately Do About Mating Press
The Next Things To Immediately Do About Mating PressThe Next Things To Immediately Do About Mating Press
The Next Things To Immediately Do About Mating Press
 
Jumark Morit Diezmo- Career portfolio- BPED 3A
Jumark Morit Diezmo- Career portfolio- BPED 3AJumark Morit Diezmo- Career portfolio- BPED 3A
Jumark Morit Diezmo- Career portfolio- BPED 3A
 
办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一
办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一
办理学位证(UoM证书)北安普顿大学毕业证成绩单原版一比一
 
Introduction to phyton , important topic
Introduction to phyton , important topicIntroduction to phyton , important topic
Introduction to phyton , important topic
 
Students with Oppositional Defiant Disorder
Students with Oppositional Defiant DisorderStudents with Oppositional Defiant Disorder
Students with Oppositional Defiant Disorder
 
原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量
原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量
原版定制copy澳洲查尔斯达尔文大学毕业证CDU毕业证成绩单留信学历认证保障质量
 
Escort Service Andheri WhatsApp:+91-9833363713
Escort Service Andheri WhatsApp:+91-9833363713Escort Service Andheri WhatsApp:+91-9833363713
Escort Service Andheri WhatsApp:+91-9833363713
 
格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档
格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档
格里菲斯大学毕业证(Griffith毕业证)#文凭成绩单#真实留信学历认证永久存档
 
办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一
办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一
办理学位证(Massey证书)新西兰梅西大学毕业证成绩单原版一比一
 
Nathan_Baughman_Resume_copywriter_and_editor
Nathan_Baughman_Resume_copywriter_and_editorNathan_Baughman_Resume_copywriter_and_editor
Nathan_Baughman_Resume_copywriter_and_editor
 
定制英国克兰菲尔德大学毕业证成绩单原版一比一
定制英国克兰菲尔德大学毕业证成绩单原版一比一定制英国克兰菲尔德大学毕业证成绩单原版一比一
定制英国克兰菲尔德大学毕业证成绩单原版一比一
 
8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCR
8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCR8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCR
8377877756 Full Enjoy @24/7 Call Girls in Pitampura Delhi NCR
 
Spanish Classes Online In India With Tutor At Affordable Price
Spanish Classes Online In India With Tutor At Affordable PriceSpanish Classes Online In India With Tutor At Affordable Price
Spanish Classes Online In India With Tutor At Affordable Price
 
Unlock Your Creative Potential: 7 Skills for Content Creator Evolution
Unlock Your Creative Potential: 7 Skills for Content Creator EvolutionUnlock Your Creative Potential: 7 Skills for Content Creator Evolution
Unlock Your Creative Potential: 7 Skills for Content Creator Evolution
 
美国SU学位证,雪城大学毕业证书1:1制作
美国SU学位证,雪城大学毕业证书1:1制作美国SU学位证,雪城大学毕业证书1:1制作
美国SU学位证,雪城大学毕业证书1:1制作
 
AICTE PPT slide of Engineering college kr pete
AICTE PPT slide of Engineering college kr peteAICTE PPT slide of Engineering college kr pete
AICTE PPT slide of Engineering college kr pete
 
原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证
原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证
原版定制卡尔加里大学毕业证(UC毕业证)留信学历认证
 
LinkedIn Strategic Guidelines April 2024
LinkedIn Strategic Guidelines April 2024LinkedIn Strategic Guidelines April 2024
LinkedIn Strategic Guidelines April 2024
 
Digital Marketing Training Institute in Mohali, India
Digital Marketing Training Institute in Mohali, IndiaDigital Marketing Training Institute in Mohali, India
Digital Marketing Training Institute in Mohali, India
 
Application deck- Cyril Caudroy-2024.pdf
Application deck- Cyril Caudroy-2024.pdfApplication deck- Cyril Caudroy-2024.pdf
Application deck- Cyril Caudroy-2024.pdf
 

article

  • 1. Laboratory Strength of Glass Ionomer and Zinc Phosphate Cements Andree Piwowarczyk, Dr med dent,1 Peter Ottl, Dr med dent,1 and Hans-Christoph Lauer, Dr med dent2 Purpose: The present in vitro study examined 3 mechanical properties, namely compressive, flexural, and diametral tensile strength, of various commercially available cements and core materials as a function of time after mixing. Materials and Methods: The examined materials were 2 cermet cements (Ketac Silver [ESPE, Seefeld, Germany] and Chelon Silver [ESPE]), 1 metal-reinforced glass ionomer cement (Miracle Mix [GC Dental Industrial Corp, Tokyo, Japan]), 2 conventional glass ionomer cements (Ketac Bond [ESPE] and Ketac Cem [ESPE]), 1 standard cure zinc phosphate cement (Harvard Cement [Richter and Hoffmann, Berlin, Germany]), and 1 zinc phosphate cement with the addition of 30% silver amalgam alloy powder (Harvard Cement 70% with Dispersalloy 30% [Richter and Hoffmann/ Johnson and Johnson, East Windsor, NJ]). Properties were measured using a universal testing machine at 15 minutes, 1 hour, and 24 hours after first mixing. Results: Compressive strengths varied widely between the 3 times of measurement from 5.8 ؎ 6.6 MPa for Ketac Cem to 144.3 ؎ 10.2 MPa for Ketac Silver. Twenty-four hours after mixing, the Bonferroni test showed significant (p < .01) differences between Ketac Silver and all other materials tested. Diametral tensile strengths ranged widely from 4.4 ؎ 0.9 MPa for Ketac Cem to 11.5 ؎ 2.2 MPa for Chelon Silver. At 15 minutes, 1 hour, and 24 hours after first mixing, the analysis of variance did not show any significant differences between Ketac Silver, Chelon Silver, and Miracle Mix. The 3-point flexural strength of Ketac Silver showed, at 15 minutes with 13.5 ؎ 3.9 MPa and at 24 hours with 27.2 ؎ 7.4 MPa, the highest values. Conclusions: Setting time influences the mechanical properties of the materials tested in this study. Ketac Silver, a glass ionomer cement reinforced with sintered glass-silver particles, showed the highest mechanical properties of the examined materials. J Prosthodont 2001;10:140-147. Copyright © 2001 by The American College of Prosthodontists. INDEX WORDS: core restoration, mechanical properties, compressive strength, flexural strength, diametral tensile strength FIXED PROSTHODONTIC restorations often require the placement of foundation restora- tions to establish retentive and resistance forms to the teeth used as prosthesis retainers. These resto- rations will ideally possess sufficient mechanical strength, retention to the hard dental tissues, and a high degree of biocompatibility.1 Glass ionomer cements2,3 have been used as core build-up materials. They provide mechanical and chemical adhesion to the hard dental tissues that is on the order of one fifth to one third of that ob- tained with composite resins using the acid-etch technique.2 The reported results differ on the basis of brand of material4 and conditioning techniques.5 Metal-reinforced glass ionomer cements, known as cermet cements, are a mixture of glass and metal powder6 sintered to high density. This material sets to form a cement via an acid-base reaction.7 By sintering metal particles into the glass phase, it is possible to improve the material’s abrasion,8,9 and to yield a modest increase in diametral tensile strength.10 The objective of this study was to determine and compare the mechanical properties of various ce- ments used as core build-up materials relative to time after first mixing. The parameters examined were compressive strength, flexural strength, and diametral tensile strength at times of 15 minutes, 1 hour, and 24 hours. From Department of Prosthetic Dentistry, School of Dentistry, Johann Wolfgang Goethe University, Frankfurt, Germany. 1 Assistant Professor. 2 Professor and Director. Accepted June 25, 2001. Correspondence to: Dr. A. Piwowarczyk, Department of Pros- thetic Dentistry, School of Dentistry, Johann Wolfgang Goethe Uni- versity, Theodor-Stern-Kai 7, D-60590 Frankfurt, Germany. E-mail: piwowarczyk@t-online.de Copyright © 2001 by The American College of Prosthodontists 1059-941X/01/1003-0003$35.00/0 doi:10.1053/jpro.2001.27338 140 Journal of Prosthodontics, Vol 10, No 3 (September), 2001: pp 140-147
  • 2. Materials and Methods This study evaluated 2 cermet cements (Ketac Silver [ESPE, Seefeld, Germany] and Chelon Silver [ESPE]), 1 metal-reinforced glass ionomer cement (Miracle Mix [GC Dental Industrial Corp, Tokyo, Japan]), 2 conven- tional glass ionomer cements (Ketac Bond [ESPE] and Ketac Cem [ESPE]), 1 standard cure zinc phosphate cement (Harvard Cement [Richter and Hoffmann, Ber- lin, Germany]), and 1 zinc phosphate cement with the addition of 30% silver amalgam alloy powder (Harvard Cement 70% with Dispersalloy 30% [Richter and Hoff- mann/Johnson and Johnson, East Windsor, NJ]) under compressive, tensile, and flexural forces (Table 1). Powder was weighed using an analytical balance (Ϯ1 mg) following the manufacturer’s recommendation, while the liquid volume suggested by the manufacturer was established using a measuring pipette with an accu- racy of Ϯ0.03 mL. One material, Ketac Silver, was sup- plied in premeasured capsules. For this material, the manufacturer’s recommendation of a trituration time of 10 seconds was used for the Capmix (ESPE) amalgam- ator. To measure the compressive and tensile strengths, specimens were prepared in cylindrical Teflon molds (Figs 1 and 2) to the dimensions of 6 and 8 mm diameter and 12 and 4 mm height, respectively, as dictated by the British Standards Institute Specification 6039.11 The specification BS 6039 refers to the manufacturer’s rec- ommendations concerning the mixing process along with the need to fill the molds within 2 minutes of the initia- tion of mixing. Specimens used to determine flexural strength were produced in brass molds 25 ϫ 2 ϫ 2 mm in size that had been insulated with polytetrafluoroethylene spray (DIN 13922/EN 24049).12 The molds were placed in an incu- bator (Heraeus Kulzer, Hanau, Germany) at 37.0 Ϯ 1.0°C and at 95% to 100% relative humidity 3 minutes after mixing. Specimens were removed from the mold within 60 minutes of testing. Specimens for the 24-hour measurements were stored in the incubator submerged in distilled water until examined. The dimensions of the specimens were checked with a micrometer (Mauser, Figure 1. Precision mold and specimen for determining the compressive strength (6 ϫ 12 mm). Table 1. Core Materials and Manufacturers Material Classification Manufacturer Mixing Process Powder/Liquid Ratio Ketac Silver Cermet cement Espe, Seefeld, Germany Mechanical Chelon Silver Cermet cement Espe, Seefeld, Germany Manual 3.8:1 Miracle Mix Metal-reinforced glass ionomer cement GC Dental Industrial Corporation, Tokyo, Japan Manual 5.0:1 Ketac Bond Conventional glass ionomer cement Espe, Seefeld, Germany Manual 3.4:1 Ketac Cem Conventional glass ionomer cement Espe, Seefeld, Germany Manual 3.4:1 Harvard Cement Zinc phosphate cement Richter & Hoffmann, Berlin, Germany Manual 2.5:1 Harvard Cement 70%/ Dispersalloy 30% Zinc phosphate cement with admixture amalgam alloy powder Richter & Hoffmann, Berlin, Germany/Johnson & Johnson, East Windsor, NJ Manual 2.5:1 Figure 2. Precision mold and specimen for determining the diametral tensile strength (4 ϫ 8 mm). 141September 2001, Volume 10, Number 3
  • 3. Nu¨rnberg, Germany; precision: 0.01 mm). Testing was performed at 23.0 Ϯ 1.0°C and 50% Ϯ 5% relative hu- midity. A Zwick 1435 Universal testing machine (Zwick, Ulm, Germany) was used at a crosshead speed of 1 mm/min to test compressive and diametral tensile strengths (Fig 3). Specimens were loaded until fracture at a constant crosshead speed of 1 mm/min (BS 6039).11 Measurements for the 3-point flexural strength test (Fig 4) were performed at a constant crosshead speed of 1 mm/min (DIN 13922/EN 24049). Flexural, compressive, and diametral tensile strengths were assessed at 15 min- utes, 1 hour, and 24 hours after first mixing. Ten mea- surements each were made for each material and for each of the 3 parameters examined. Statistical data analysis was performed by one-way analysis of variance with regard to the time factor and by 2-sided t tests with regard to the compressive, flexural, and diametral tensile strength variables. The level of significance was fixed at p Յ .05 for significant differ- ences. The Bonferroni test was used for post-hoc analysis of variance comparing multiple means. Results Compressive Strength At the earliest testing period of 15 minutes after mixing, mean compressive strength values ranged from 35.8 Ϯ 6.6 MPa for Ketac Cem to 74.9 Ϯ 7.2 MPa for Harvard zinc phosphate cement with ad- mixture of silver amalgam alloy powder (Fig 5). Compressive tests at 1 hour showed increased com- pressive strength for all materials. Metal-reinforced glass ionomer cements Ketac Silver and Chelon Silver increased by 40.1% and 47.8%, respectively. The lowest value was found for the glass ionomer cement Ketac Cem with 64.2 Ϯ 7.3 MPa after 1 hour. At 24 hours, the compressive strength values showed further increases to 144.3 Ϯ 10.2 MPa by Ketac Silver, followed by Chelon Silver and Miracle Mix with values of 119.2 Ϯ 17.8 MPa and 111.4 Ϯ 13.2 MPa, Harvard cement with 95.7 Ϯ 19.1 MPa, and the admixture of Harvard cement with amal- gam alloy powder with 91.5 Ϯ 15.0 MPa. The Bonferonni test identified statistically significant differences among groups concerning the times of measurement (Table 2). Diametral Tensile Strength Diametral tensile strength means and standard deviations are displayed in Fig 6. At 15 minutes, the highest value of 7.8 Ϯ 1.0 MPa was obtained with the combination of Harvard cement and amalgam alloy powder; conventional glass ionomer cements (Ketac Bond, Ketac Cem) were measured at 5.3 Ϯ 0.7 MPa and 4.4 Ϯ 0.9 MPa. At 1 hour, results for the tested materials ranged from 6.3 Ϯ 1.0 MPa (Ketac Cem) to 8.5 Ϯ 1.9 MPa (Miracle Mix). At 24 hours, Chelon Silver at 11.5 Ϯ 2.2 MPa, Ketac Silver at 11.2 Ϯ 1.6 MPa, and Miracle Mix at 10.7 Ϯ 1.5 MPa showed the highest values. Between 1 and 24 hours after first mixing, Chelon Silver, Ketac Silver, Miracle Mix, and Ketac Cem showed a sig- nificant (p Յ .01) increase in diametral tensile strength. In addition to the 3 times of measure- Figure 3. Testing procedure for determining the diame- tral tensile strength. Figure 4. Testing procedure for determining the flex- ural strength. 142 Laboratory Strength of Cements ● Piwowarczyk, Ottl, and Lauer
  • 4. ment, the analysis of variance again identified sig- nificant differences among the materials (Table 3). Three-point Flexural Strength Figure 7 illustrates the 3-point flexural strength means and standard deviations. At 15 minutes after first mixing, Harvard cement with amalgam alloy powder at 16.2 Ϯ 1.4 MPa, Harvard cement at 14.5 Ϯ 1.7 MPa, and Ketac Silver at 13.5 Ϯ 3.9 MPa yielded the highest values. At 15 minutes, Ketac Cem showed the value of 4.7 Ϯ 1.7 MPa. During the first hour, the flexural strength value for Mir- acle Mix increased by 87.3% to 17.7 Ϯ 4.3 MPa. The corresponding values for Chelon Silver and Ketac Silver were 15.9 Ϯ 5.0 MPa and 15.0 Ϯ 4.6 MPa. Twenty-four hours after first mixing, Ketac Silver, at 27.2 Ϯ 7.4 MPa, yielded the highest values of all the cements examined, while also showing the greatest increase in strength (81.0%) over the 1-hour value. The other materials showed results ranging from 9.6 Ϯ 4.6 MPa for Ketac Bond to 24.8 Ϯ 8.0 MPa for Chelon Silver (Fig 7). The analysis of variance showed that Ketac Silver and Chelon Silver differed significantly from Miracle Mix (p Յ .01), Ketac Cem (p Յ .01), Ketac Bond (p Յ .01), Harvard cement (p Յ .01), and Harvard cement with amalgam alloy powder (p Յ .05). As a result of the Bonferonni test at p Յ .05, the vertical lines in Table 4 bracket statistically equivalent groups. Discussion In designing this study, the decision was made to make evaluations on standardized molds. This al- lowed the testing to conform to the British Stan- Figure 5. Compressive strength (BS 6039) of various core restoration materials (0.25, 1, and 24 hours after first mixing; n ϭ 10 measure- ments each per material and time). KS, Ketac Silver; CS, Chelon Silver; MM, Miracle Mix; KB, Ketac Bond; KC, Ketac Cem; HZ, Harvard ce- ment; HA, Harvard cement with amalgam alloy powder. Table 2. Compressive Strength (BS 6039) of Various Core Restoration Materials (0.25, 1, and 24 Hours After First Mixing; n ϭ 10 Measurements Each per Material and Time) Material 0.25 h 1 h 24 h x (MPa) x (MPa) x (MPa) Ketac Silver 66.0 Ϯ 3.5 92.5 Ϯ 9.5 144.3 Ϯ 10.2 Chelon Silver 55.1 Ϯ 2.6 81.5 Ϯ 5.9 119.2 Ϯ 17.8 Miracle Mix 40.7 Ϯ 4.1 77.6 Ϯ 6.1 111.4 Ϯ 13.2 Ketac Bond 37.7 Ϯ 4.0 66.2 Ϯ 6.7 84.1 Ϯ 18.3 Ketac Cem 35.8 Ϯ 6.6 64.2 Ϯ 7.3 80.1 Ϯ 201 Harvard cement 72.9 Ϯ 5.9 84.0 Ϯ 13.3 95.7 Ϯ 19.1 Harvard cement 70%/ amalgam alloy powder (Dispersalloy) 30% 74.9 Ϯ 7.2 86.9 Ϯ 11.4 91.5 Ϯ 15.0 Note. The vertical bars in respective lines to the right of the points of measurement indicate groups that do not significantly differ as measured by the Bonferroni test (p Յ .05). Abbreviations: x, arithmetic mean; s, standard deviation. 143September 2001, Volume 10, Number 3
  • 5. dards Institute Specification 6039.11 The alternative use of extracted teeth brought with it the variability associated with differences in dimensions, degree of calcification, water content, and the potential for pre-existing hard tissue defects.13-15 Although the latter approach may allow simpler interpretation of clinical expectations, it eliminates standardization and complicates meaningful comparisons. Considerable differences in compressive, flex- ural, and diametral tensile strength were seen among the tested materials. All 3 of the recognized tests showed a similar ranking order for the mate- rials (Figs 5, 6, and 7). Under the conditions of this study, Ketac Silver presented the highest values of compressive and flexural strengths at 24 hours of all the cements examined. This material showed statistically significant differences (p Յ .05) in test- ing compressive strength at all times of measure- ment. Between 1 and 24 hours, Ketac Silver showed a significant (p Յ .01) increase in strength within all the 3 testing parameters. Previous reports showed that the setting reaction of glass ionomer cements is complex, requiring 24 hours for maturation.7,16,17 This is in contrast to the zinc phosphate materials, Harvard cement, and Harvard cement with added amalgam alloy, which showed less increase in strength over time. The data in this report failed to show a consis- tent relationship between the method of mixing (manual or mechanical) and strength properties. Strict adherence to the prescribed mixing ratio is Figure 6. Diametral tensile strength (BS 6039) of various core restoration materials (0.25, 1, and 24 hours after first mixing; n ϭ 10 measure- ments each per material and time). KS, Ketac Silver; CS, Chelon Silver; MM, Miracle Mix; KB, Ketac Bond; KC, Ketac Cem; HZ, Harvard ce- ment; HA, Harvard cement with amalgam alloy powder. Table 3. Diametral Tensile Strength (BS 6039) of Various Core Restoration Materials (0.25, 1, and 24 Hours After First Mixing; n ϭ 10 Measurements Each per Material and Time) Material 0.25 h 1 h 24 h x (MPa) s (MPa) x (MPa) s (MPa) x (MPa) s (MPa) Ketac Silver 6.5 1.5 8.1 1.5 11.2 1.6 Chelon Silver 7.2 1.6 8.2 1.4 11.5 2.2 Miracle Mix 7.2 1.0 8.5 1.9 10.7 1.5 Ketac Bond 5.3 0.7 6.9 1.2 7.4 1.2 Ketac Cem 4.4 0.9 6.3 1.0 7.5 1.3 Harvard cement 6.9 0.9 7.4 1.1 7.9 1.7 Harvard cement 70%/ amalgam alloy powder (Dispersalloy) 30% 7.8 1.0 8.3 1.1 9.2 1.8 Note. The vertical bars in respective lines to the right of the points of measurement indicate groups that do not significantly differ as measured by the Bonferroni test (p Յ .05). Abbreviations: x, arithmetic mean; s, standard deviation. 144 Laboratory Strength of Cements ● Piwowarczyk, Ottl, and Lauer
  • 6. said to be especially important for the successful use of glass ionomer cements. Negative influences on strength, solubility, and surface structure as a result of having too little powder have been cited in the literature. Conversely, with too high of a pow- der-to-liquid ratio, a reduction in setting time and bond strength has been described.18,19 The manu- ally mixed product Chelon Silver, chemically iden- tical to Ketac Silver, has a lower compressive strength at 15 minutes (p Յ .01), 1 hour (p Յ .05), and 24 hours (p Յ .01), but Chelon Silver and Ketac Silver showed no significant differences in flexural and diametral tensile strengths over these time periods (p Յ .05). The present study showed significantly (p Յ .05) lower values for the glass ionomer cements Ketac Cem and Ketac Bond concerning compressive, flex- ural, and diametral tensile strengths at all times of measurement, compared with the cermet cements, Ketac Silver and Chelon Silver. The data reported by Chung10 showed higher diametral tensile strength values for metal-reinforced materials, Ketac Silver and Miracle Mix, compared with the glass ionomer cement, Fuji II (GC Dental Indus- trial Corp). Cermet cements were intended to pos- sess higher flexural strength than glass ionomer cements.20 Walls and coworkers21 showed an in- crease in compressive strength and compressive fatigue limit for cermet-type materials compared with the strength of a conventional glass ionomer cement from the same manufacturer. In contrast to the above-mentioned studies, Cho et al22 docu- mented that silver-reinforced glass ionomer cement Ketac Silver did not improve the compressive and diametral tensile strength in comparison with the conventional glass ionomer cement, Ketac Fil Figure 7. Three-point flex- ural strength (DIN 13922/EN 24049) of various core resto- ration materials (0.25, 1, and 24 hours after first mixing; n ϭ 10 measurements each per material and time). KS, Ketac Silver; CS, Chelon Sil- ver; MM, Miracle Mix; KB, Ketac Bond; KC, Ketac Cem; HZ, Harvard cement; HA, Harvard cement with amalgam alloy powder. Table 4. Three-point Flexural Strength (DIN 13922/EN 24049) of Various Core Restoration Materials (0.25, 1, and 24 Hours After First Mixing; n ϭ 10 Measurements Each per Material and Time) Material 0.25 h 1 h 24 h x (MPa) s (MPa) x (MPa) s (MPa) x (MPa) s (MPa) Ketac Silver 13.5 3.9 15.0 4.6 27.2 7.4 Chelon Silver 11.8 4.1 15.9 5.0 24.8 8.0 Miracle Mix 9.5 1.1 17.7 4.3 18.5 1.9 Ketac Bond 8.4 3.2 7.3 4.4 9.6 4.6 Ketac Cem 4.7 1.7 8.2 3.4 11.6 5.6 Harvard cement 14.5 1.7 17.7 2.9 20.3 1.6 Harvard cement 70%/ amalgam alloy powder (Dispersalloy) 30% 16.2 1.4 18.8 1.3 22.0 1.6 Note. The vertical bars in respective lines to the right of the points of measurement indicate groups that do not significantly differ as measured by the Bonferroni test (p Յ .05). Abbreviations: x, arithmetic mean; s, standard deviation. 145September 2001, Volume 10, Number 3
  • 7. (ESPE). The work of Williams et al23 did not show any significant reduction in compressive and diame- tral tensile strengths for the glass ionomer ce- ments, Chelon Fil (ESPE) and Fuji II (GC Dental Industrial Corp), compared with reinforced mate- rials, Chelon Silver and Miracle Mix. Peutzfeldt24 reported a similar flexural strength of Ketac Silver and Miracle Mix to 5 conventional glass ionomer cements. In the present study, Miracle Mix, a metal- reinforced, nonsintered glass ionomer cement, showed a marked increase in compressive, tensile, and flexural strengths during the first hour after first mixing. At 24 hours, Miracle Mix was inferior to the cermet cements Ketac Silver (p Յ .01) and Chelon Silver (p Յ .05) in flexural strength. After 7 days, Peutzfeldt24 found, in the 3-point flexural strength tests with specimens of 10 ϫ 2 ϫ 2 mm, a flexural strength of 13 Ϯ 2 MPa for Miracle Mix and 29 Ϯ 13 MPa for Ketac Silver. Nakajima et al25 showed no significant differences in 3-point flexural strength tests on Miracle Mix glass ionomer ce- ments (23.0 Ϯ 3.1 MPa) and Ketac Silver (22.6 Ϯ 10.4 MPa) when tested at 24 hours after storage in 100% humidity at 37°C. When measuring com- pressive strengths (American Dental Association [ADA] specification #66), values of 132.1 Ϯ 13.7 MPa and 121.9 Ϯ 12.7 MPa for Miracle Mix and Ketac Silver, respectively, were shown. Cohen et al26 examined the diametral tensile strength and compressive strength (ADA specifica- tion #27) of titanium-reinforced composite resins, Ti-Core (Essential Dental Systems, Hackensack, NJ) and Flexi-Flow Cem (Essential Dental Sys- tems), compared with commercially available core build-up materials and cements. All specimens had been stored at 100% humidity for 24 hours. The glass ionomer cements Ketac Silver, Miracle Mix, and Ketac Cem yielded 60.1% to 80.8% lower values than titanium-reinforced composite resins. Of the 3 glass ionomer cements tested, Ketac Silver achieved the highest values with regard to diame- tral tensile strength and compressive strength at 12.5 Ϯ 2.2 MPa and 115.1 Ϯ 16.0 MPa, respectively. The present study showed that after 24 hours, zinc phosphate cement, with and without the ad- mixture of silver amalgam alloy powder, is stronger than conventional glass ionomer cements and weaker than cermet cements under compressive, tensile, and flexural forces. The cement strength is almost linearly dependent on the powder:liquid ra- tio.27 For zinc phosphate cement, Abraham28 deter- mined an increasing compressive strength and de- clining solubility by increasing the powder-to-liquid ratio. On a graphic curve, this results in a rise to a maximum value and subsequently a decline in re- lation to the compressive strength. Smith29 con- cluded that the compressive and tensile strengths of properly mixed zinc phosphate cement are ade- quate to resist masticatory stress. The reported results concerning the mechanical properties of cements are broad and variable. In particular, measurements of strength are depen- dent on the method of specimen preparation, the operator, and labor variability.30 In addition to me- chanical properties, other factors such as pulp com- patibility,31-33 allergic potential,34-36 and expansion caused by water absorption37-39 should be consid- ered when choosing a material for a foundation restoration. To confirm the results of laboratory studies, longitudinal clinical trials should be con- ducted to establish the most important predictors of clinical success for core materials. Conclusions 1. Compressive strength, flexural strength, and diametral tensile strength varied among the tested materials. 2. Under the conditions of this study, 24 hours after first mixing, cermet cements were stronger than metal-reinforced glass ionomer cement, conven- tional glass ionomer cements, and zinc phos- phate cement without and with the addition of silver amalgam alloy powder. 3. The compressive strength of Chelon Silver was significantly lower than the chemically identical capsule product Ketac Silver at the 3 times of measurement. Acknowledgment The authors would like to thank the Institute for Medical Information Processing, Biometry, and Epidemiology (di- rector: Professor K. U¨berla) of the University of Munich for its support in performing the statistical analysis of the data. References 1. Paul SJ, Scha¨rer P: Plastische Aufbauten in der Kronen- und Bru¨ckenprothetik. [Plastic build-ups in crown and bridge prosthodontics.] Quintessenz 1996;47:1519-1531 2. Hickel R, Kunzelmann K-H: Glasionomer- und Kompomer- fu¨llung [Glass ionomer and compomer restorations], in Hei- 146 Laboratory Strength of Cements ● Piwowarczyk, Ottl, and Lauer
  • 8. demann D (ed): Kariologie und Fu¨llungstherapie. Praxis der Zahnheilkunde (ed 4). Mu¨nchen, Germany, Urban & Schwarzenberg, 1999, pp 154-176 3. Hickel R: Moderne Fu¨llungswerkstoffe. [Modern restorative materials.] Dtsch Zahna¨rztl Z 1997;52:572-585 4. Lin A, McIntyre NS, Davidson RD: Studies on the adhesion of glass-ionomer cements to dentin. J Dent Res 1992;71: 1836-1841 5. Powis DR, Follerås T, Merson SA, et al: Improved adhesion of a glass ionomer cement to dentin and enamel. J Dent Res 1982;61:1416-1422 6. McLean JW, Gasser O: Glass-cermet cements. Quintes- sence Int 1985;16:333-343 7. Wilson AD, McLean JW: Glass-ionomer cement. Chicago, IL, Quintessence Publishing, 1988 8. McKinney JE, Antonucci JM, Rupp NW: Wear and micro- hardness of a silver-sintered glass-ionomer cement. J Dent Res 1988;67:831-835 9. Moore BK, Swartz ML, Phillips RW: Abrasion resistance of metal reinforced glass ionomer cements. J Dent Res 1985; 64:371 (abstr 1766) 10. Chung KH: The properties of metal-reinforced glass iono- mer materials. J Oral Rehabil 1993;20:79-87 11. British Standards Institution: Specification for dental glass ionomer cements. BS 6039, 1981 12. DIN Deutsches Institut fu¨r Normung e.V, DIN-Taschen- buch 267: Zahnheilkunde-Werkstoffe: Normen, Gesetze, Richtlinien. [Dental Materials: Standards, Laws, Direc- tives.] Berlin, Germany, Beuth, 1997, pp 105-116 13. Kantor ME, Pines MS: A comparative study of restorative techniques for pulpless teeth. J Prosthet Dent 1977;38:405- 412 14. Mc Donald AV, King PA, Setchell DJ: An in vitro study to compare impact fracture resistance of intact root-treated teeth. Int Endod J 1990;23:304-312 15. Trope M, Maltz DO, Tronstad L: Resistance to fracture of restored endodontically treated teeth. Endod Dent Trauma- tol 1985;1:108-111 16. Smith DC: Composition and characteristics of glass ionomer cements. J Am Dent Assoc 1990;120:20-22 17. Nicholson JW: Chemistry of glass-ionomer cements: A re- view. Biomaterials 1998;19:485-494 18. Kullmann W: Glasionomer-Zemente—Physikalisch-tech- nische Eigenschaften in Abha¨ngigkeit von der Verarbeitung. [Glass ionomer cements—Physical-technical characteristics as a function of the processing.] Dtsch Zahna¨rztl Z 1986;41: 751-754 19. Mount GJ, Makinson OF: Glass-ionomer restorative ce- ments: Clinical implications of the setting reaction. Oper Dent 1982;7:134-141 20. McLean JW: Cermet cements. J Am Dent Assoc 1990;120: 43-47 21. Walls AWG, Adamson J, McCabe JF, et al: The properties of a glass polyalkenoate (ionomer) cement incorporating sin- tered metallic particles. Dent Mater 1987;3:113-116 22. Cho GC, Kaneko LM, Donovan TE, et al: Diametral and compressive strength of dental core materials. J Prosthet Dent 1999;82:272-276 23. Williams JA, Billington RW, Pearson GJ: The compar- ative strengths of commercial glass-ionomer cements with and without metal additions. Br Dent J 1992;172: 279-282 24. Peutzfeldt A: Compomers and glass ionomers: Bond strength to dentin and mechanical properties. Am J Dent 1996;9:259-263 25. Nakajima H, Watkins JH, Arita K, et al: Mechanical prop- erties of glass ionomers under static and dynamic loading. Dent Mater 1996;12:30-37 26. Cohen BI, Deutsch AS, Condos S, et al: Compressive and diametral tensile strength of titanium-reinforced compos- ites. J Esthet Dent 1992;4:50-55 27. Bruce WL, Stevens L: Strength properties of three zinc phosphate cements mixed to two different consistencies. Aust Dent J 1989;34:132-135 28. Abraham B: Untersuchung von vier Zinkphosphatzementen auf Druckfestigkeit und Lo¨slichkeit nach der FDI-Spezifika- tion Nr. 6 bei verschiedenem Pulver-Flu¨ssigkeits-Verha¨ltnis. [Study of four zinc phosphate cements for compression strength and solubility according to the FDI specification No. 6 with different powder-liquid ratio.] Thesis, Berlin, 1973 29. Smith DC: Dental cements. Current status and future pros- pects. Dent Clin North Am 1983;27:763-792 30. McCabe JF, Watts DC, Wilson HJ, et al: An investigation of test house variability in the mechanical testing of material and statistical treatment of results. J Dent Res 1990;18: 90-97 31. Hume WR, Mount GJ: In vitro studies on the potential for pulpal cytotoxicity of glass-ionomer cements. J Dent Res 1988;67:915-918 32. Schmalz G, Thonemann B, Riedel M, et al: Biological and clinical investigations of a glass ionomer base material. Dent Mater 1994;10:304-313 33. Schmalz G: The biocompatibility of non-amalgam dental filling materials. Eur J Oral Sci 1998;106:696-706 34. Geurtsen W: Substances released from dental resin compos- ites and glass ionomer cements. Eur J Oral Sci 1998;106: 687-695 35. Arenholt-Bindslev D: Composites and Compomers. 1st In- ternational ESPE Dental Symposium, Mu¨nchen, Germany, September 28, 1998 36. Arenholt-Bindslev D: Environmental aspects of dental filling materials. Eur J Oral Sci 1998;106:713-720 37. Cooley RL, Robbins JW, Barnwell S: Dimensional stability of glass ionomer used as a core material. J Prosthet Dent 1990;64:651-653 38. Small IC, Watson TF, Chadwick AV, et al: Water sorption in resin-modified glass-ionomer cements: An in vitro comparison with other materials. Biomaterials 1998;19:545-550 39. Cattani-Lorente MA, Dupuis V, Moya F, et al: Comparative study of the physical properties of a polyacid-modified com- posite resin and a resin-modified glass ionomer cement. Dent Mater 1999;15:21-32 147September 2001, Volume 10, Number 3