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Standard Practices  of  Handling, Storage  and    Transportation of   Cl2 Tonners/Cylinders BY H. S. SEHGAL DGM (PRODUCTION)
OVERVIEW ,[object Object],[object Object],[object Object],[object Object]
Conti… ,[object Object],[object Object],[object Object]
Introduction   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Common Industrial Gases ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Main Causes of Accidents ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Main Hazards ,[object Object],[object Object],[object Object],[object Object],[object Object]
Flammable Gases ,[object Object],[object Object],[object Object],[object Object],[object Object]
Non-Flammable Gases ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Poison Gases ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
NEVER trust a color of a compressed gas cylinder.  NEVER assume cylinder content ALWAYS check the label! Compressed gases Identification
Handling Liquefied Compressed Gas-Chlorine ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
CONT… ,[object Object],[object Object],[object Object]
DESIGN FACTORS OF TONER/CYLINDER FOR TOXIC GAS  {CHLORINE} 2 MM 2 MM CORROSION ALLOWANCE D.P. TEST SHALL BE CARRIED OUT FOR JOINT BETWEEN VALVE AND HEMISPHEREIOD. D.P. TEST SHALL BE CARRIED OUT FOR JOINT BETWEEN VALVE AND HEMISPHEREIOD. DYE PENETRATION TEST 0.95  0.95  JOINT EFFICIENCY  100% ON ALL BUTT WELDS BEARING PARTS. 100% ON ALL BUTT WELDS BEARING PARTS. RADIOGRAPHY AMBINET (65 DEG. C.) AMBINET (65 DEG. C.) DESIGN TEMP 35 KGF/CM2 (MIN) 35 KGF/CM2 (MIN) HY. TEST PRESSURE 19.9 KGF/CM2 19.9 KGF/CM2 DESIGN PRESSURE IS-7681-1975/IS-3196 IS 2825/ASME SECTION VIII DIV I /PD 5500 DESIGN CODE CYLINDER TONNER SPECIFICATION
CONT… PUNCHING DETAIL ON FOOTRING AND HEMISHERE OF TONER (VALVE SIDE) M.O.C. OF VALVES VALVE/PLUGS PAINTING LIQUID CAPACITY STRESS RELIEVING  WATER CAPACITY PNEUMETIC TEST PRESSURE SPECIFICATION SR. NO.  : T.WT.  : W.C.  : H.T.  : AL,SI, BRONZE WITH MONEL SPINDEL AS PER IS-3224 MFGD. GOLDEN YELLOW COLOR ALL OVER AFTER PRIMER PAINTING OF PRIMER IS:356. 900 KGS(MIN) YES 780 LTRS 11 KGF/CM2 (MIN) TONNER SR. NO.  : T.WT.  : W.C.  : H.T.  : AL,SI, BRONZE WITH MONEL SPINDEL AS PER IS-3224 MFGD. GOLDEN YELLOW COLOR ALL OVER AFTER PRIMER PAINTING OF PRIMER IS:356. 100 KGS(MIN) YES 88 LTRS 11 KGF/CM2 (MIN) CYLINDER
CONT… 2 MM 2 MM CORROSION ALLOWANCE CYLINDER TONNER SPECIFICATION 1.19 70 KGS 6 MM BUREAU OF INDIAN STANDARD/ LLYOD CCE-NAGPUR 1.19 620 KGS 12 MM BUREAU OF INDIAN STANDARD/ LLYOD CCE-NAGPUR FILLING RATIO TARE WEIGHT NOMINAL WALL THICKNESS INSPECTION  APPROVAL SA 516 GR 60/70 SA 516 GR 60/70 MATERIAL OF CONSTRUCTION  AS PER STANDARD DESIGN AS PER STANDARD DESIGN COVER HOOD 368 MM 316 MM 988 MM 784 MM 760 MM 2085+_ 12 MM O.D. I.D. L.
CONT… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
CONT… ,[object Object],[object Object],[object Object],[object Object],[object Object]
STORAGE PRACTICES FOR TONNERS AND CYLINDERS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
 
 
 
 
 
ASSOCIATED OPERATIONAL PRACTICES ,[object Object],[object Object],[object Object],[object Object],[object Object],b. Checking/ recording of receipt tonners  ,[object Object],a. Unloading of cylinders from truck
PREPARATION OF   TONNERS/CYLINDERS ,[object Object],[object Object],[object Object],d. Internal  inspection with 12 volt supply ,[object Object],c. Checking of valves/spindle/plugs ,[object Object],b. For Cl2 gas  ,[object Object],[object Object],[object Object],[object Object],a. Physical checking
Conti… ,[object Object],[object Object],[object Object],f. Preparation for empty tonners ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],e. Hydro test for overdue tonners
FILLING OF   TONNERS/CYLINDERS  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Conti… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
DESPATCH OF FILLED   TONNERS/CYLINDERS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
QUALITATIVE CHECK ,[object Object],[object Object],[object Object],[object Object]
INTENSIVE TRAINING PROGRAMME ,[object Object],[object Object],[object Object],[object Object]
EMERGENCY & EMERGENCY MANAGEMENT ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Conti… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
GLOBAL MODE OF CHLORINE   TRANSPORTATION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
GLOBAL TRANSPORTATION SCENARIO Worldwide other modes of Transportation are also being used like thro’ Barges on Water for more than 6000 kms distance in Columbia, Chile & for very short distances, Pipelines 1200 Road (100%) 51 India 1000 200 Rail (67%) Road (33%) 6 Europe 600 300 Rail (30%) Road (70%) 10 Japan 4000 (Brazil) 1500 (Chile) Road Rail (75%) 66 South America 1000 Rail (90%) Road (6%) 35 North America Max. Distance Covered  (Kms) Mode of Transport Quantity of Cl2 Transported  (% of Production) Country
 
STATUS OF INDIAN CHLORINE INDUSTRY ,[object Object],[object Object],[object Object],[object Object],[object Object]
CHECK POINTS FOR TRANSPORTATION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
SAFETY PRACTICES OF TRANSPORTATION- MANUFACTURER ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SAFETY PRACTICES OF TRANSPORTATION- TRANSPORTER ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Control Measures In Case Of Chlorine Leakage During Transportation   ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
TRANSPORT  PRACTICES  IN OTHER COUNTRIES ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
BENEFITS OF BULK TRANSPOTATION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
 
Straps & logistic rail for securing cylinders
Load bars & logistic rail for securing cylinders
Palletizing cylinders
Ground level loading & unloading cylinders
Ton container blocking
Front bulkhead reinforcement for ton containers
C clamp on two end ton containers of truck load
Telescopic boom mounted on ton container trailer
Ton container lock-down devices
PRACTICES OF CHLORINE WITHDRAWL AT CUSTOMER END ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
 
Withdrawal rate of Chlorine ( Room Temp. – Threshold temp.) * withdrawal factor withdrawal factor for Tonner = 8/ Cylinder= 1   Threshold temp. is the temp. where minimum required gas pressure  is reached   Temp. Deg. C Tonner (900 Kg.) Cylinder (67 Kg.) Day Hr. Per Day Per Hr. 4 45 1.87 4.08 0.17 10 110 4.58 9.50 0.39 15 130 5.41 16.10 0.67 20 254 10.58 21.54 0.90 27 315 13.12 20.12 1.17
REGULATORY REQUIREMENTS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Important precautions  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Remember   ,[object Object],[object Object],[object Object],[object Object]
Activities for which Licenses is required ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Other requirement under the Regulations: ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
Condition for no licence for filling and possession   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Examination and testing of Chlorine tonners and bullets ,[object Object],[object Object],[object Object]
[object Object],[object Object]
Important Additional Conditions of  licenses   ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Notice of accidents ,[object Object],[object Object],[object Object],[object Object]
Provisions under Factories Act 1984 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Provisions under Manufacture, Storage & Import of Hazardous Chemicals Rules – 1989 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Provisions under Chemical Accidents (Emergency Planning, Preparedness and Response) Rules, 1996 ,[object Object],[object Object],[object Object],[object Object],[object Object]
Provisions under Central Motor Vehicle Rules 1989 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
EMERGENCY HANDLING FROM POSSIBLE LEAKAGE POINTS OF TONNER  Close the valve -      Provide O/L brass seal nut. -      Provide additional valve with  Clamp. -      Use emergency kit Sr. No. Particular Problem Action  1 Gland leakage - Gland nut loose Tighten the gland nut with suitable spanner 2 Chlorine valve passing Pitting on the spindle seat - Pitting on valve seat -  3 Chlorine valve damage - Valve broken - Use emergency kit to control leakage 4 Leakage from tonner surface - Pin hole on the surface - Use emergency kit to control leakage 5 Leakage from blind plug - Thread damaged - Use emergency kit to control leakage 6 Leakage from O/L of the Cl2 Valve - Thread damaged - Pin hole in the outlet nozzle - Gasket not properly fitted - Dosing line leakage - Close valve - Rotate Tonner to 180 deg., Use 2 nd  valve - Replace gasket   - Replace the dosing line
 
LIQUID CHLORINE SPILLAGE AND CONTROL ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
CHLORINE ABSORPTION SYSTEM ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
FIRST AID FOR CHLORINE EXPOSURE ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Cont… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
LIQUID CHLORINE STORAGE  ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
SAFETY CONTROLS ON BULLETS ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Containment system in case of toxic release at tank area ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Contd… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
MATERIALS OF CONSTRUCTION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
PIPING DESIGN/MAINTENANCE ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
REFERENCE FOR SAFE OPERATION OF CL2 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Contd… ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
LEARNING AND SHARING INCIDENT REPORT ,[object Object],[object Object],[object Object]
Incident of Chlorine Off-Site Emergency at Bhiwandi Municipal Corp on 23rd & 24th July 2010 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Incident of Chlorine Leakage at Mumbai Port Trust (MBPT) on 14th July, 2010 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]
Incident of Hydrochloric Acid Leakage  due to damage of the HCL Tanker Valve ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Incident of Chlorine Gas Leakage from Tonner during Transportation On 5th September 2010 at  Village Chhattar on Rajkot-Morbi Highway (Gujarat) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
3.  Incident due to storage of incompatible material ,[object Object],[object Object]
Tank Failure in one Chlor-Alkali Plant, On June 7, 2010 In Thailand ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Incident of Hydrochloric Acid Leakage due to product spillage ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
CONCLUSION ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
 
 

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Standard practices r9

  • 1. Standard Practices of Handling, Storage and Transportation of Cl2 Tonners/Cylinders BY H. S. SEHGAL DGM (PRODUCTION)
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  • 11. NEVER trust a color of a compressed gas cylinder. NEVER assume cylinder content ALWAYS check the label! Compressed gases Identification
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  • 14. DESIGN FACTORS OF TONER/CYLINDER FOR TOXIC GAS {CHLORINE} 2 MM 2 MM CORROSION ALLOWANCE D.P. TEST SHALL BE CARRIED OUT FOR JOINT BETWEEN VALVE AND HEMISPHEREIOD. D.P. TEST SHALL BE CARRIED OUT FOR JOINT BETWEEN VALVE AND HEMISPHEREIOD. DYE PENETRATION TEST 0.95 0.95 JOINT EFFICIENCY 100% ON ALL BUTT WELDS BEARING PARTS. 100% ON ALL BUTT WELDS BEARING PARTS. RADIOGRAPHY AMBINET (65 DEG. C.) AMBINET (65 DEG. C.) DESIGN TEMP 35 KGF/CM2 (MIN) 35 KGF/CM2 (MIN) HY. TEST PRESSURE 19.9 KGF/CM2 19.9 KGF/CM2 DESIGN PRESSURE IS-7681-1975/IS-3196 IS 2825/ASME SECTION VIII DIV I /PD 5500 DESIGN CODE CYLINDER TONNER SPECIFICATION
  • 15. CONT… PUNCHING DETAIL ON FOOTRING AND HEMISHERE OF TONER (VALVE SIDE) M.O.C. OF VALVES VALVE/PLUGS PAINTING LIQUID CAPACITY STRESS RELIEVING WATER CAPACITY PNEUMETIC TEST PRESSURE SPECIFICATION SR. NO. : T.WT. : W.C. : H.T. : AL,SI, BRONZE WITH MONEL SPINDEL AS PER IS-3224 MFGD. GOLDEN YELLOW COLOR ALL OVER AFTER PRIMER PAINTING OF PRIMER IS:356. 900 KGS(MIN) YES 780 LTRS 11 KGF/CM2 (MIN) TONNER SR. NO. : T.WT. : W.C. : H.T. : AL,SI, BRONZE WITH MONEL SPINDEL AS PER IS-3224 MFGD. GOLDEN YELLOW COLOR ALL OVER AFTER PRIMER PAINTING OF PRIMER IS:356. 100 KGS(MIN) YES 88 LTRS 11 KGF/CM2 (MIN) CYLINDER
  • 16. CONT… 2 MM 2 MM CORROSION ALLOWANCE CYLINDER TONNER SPECIFICATION 1.19 70 KGS 6 MM BUREAU OF INDIAN STANDARD/ LLYOD CCE-NAGPUR 1.19 620 KGS 12 MM BUREAU OF INDIAN STANDARD/ LLYOD CCE-NAGPUR FILLING RATIO TARE WEIGHT NOMINAL WALL THICKNESS INSPECTION APPROVAL SA 516 GR 60/70 SA 516 GR 60/70 MATERIAL OF CONSTRUCTION AS PER STANDARD DESIGN AS PER STANDARD DESIGN COVER HOOD 368 MM 316 MM 988 MM 784 MM 760 MM 2085+_ 12 MM O.D. I.D. L.
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  • 39. GLOBAL TRANSPORTATION SCENARIO Worldwide other modes of Transportation are also being used like thro’ Barges on Water for more than 6000 kms distance in Columbia, Chile & for very short distances, Pipelines 1200 Road (100%) 51 India 1000 200 Rail (67%) Road (33%) 6 Europe 600 300 Rail (30%) Road (70%) 10 Japan 4000 (Brazil) 1500 (Chile) Road Rail (75%) 66 South America 1000 Rail (90%) Road (6%) 35 North America Max. Distance Covered (Kms) Mode of Transport Quantity of Cl2 Transported (% of Production) Country
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  • 58. Straps & logistic rail for securing cylinders
  • 59. Load bars & logistic rail for securing cylinders
  • 61. Ground level loading & unloading cylinders
  • 63. Front bulkhead reinforcement for ton containers
  • 64. C clamp on two end ton containers of truck load
  • 65. Telescopic boom mounted on ton container trailer
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  • 72. Withdrawal rate of Chlorine ( Room Temp. – Threshold temp.) * withdrawal factor withdrawal factor for Tonner = 8/ Cylinder= 1 Threshold temp. is the temp. where minimum required gas pressure is reached Temp. Deg. C Tonner (900 Kg.) Cylinder (67 Kg.) Day Hr. Per Day Per Hr. 4 45 1.87 4.08 0.17 10 110 4.58 9.50 0.39 15 130 5.41 16.10 0.67 20 254 10.58 21.54 0.90 27 315 13.12 20.12 1.17
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  • 88. EMERGENCY HANDLING FROM POSSIBLE LEAKAGE POINTS OF TONNER Close the valve -      Provide O/L brass seal nut. -      Provide additional valve with Clamp. -      Use emergency kit Sr. No. Particular Problem Action 1 Gland leakage - Gland nut loose Tighten the gland nut with suitable spanner 2 Chlorine valve passing Pitting on the spindle seat - Pitting on valve seat -  3 Chlorine valve damage - Valve broken - Use emergency kit to control leakage 4 Leakage from tonner surface - Pin hole on the surface - Use emergency kit to control leakage 5 Leakage from blind plug - Thread damaged - Use emergency kit to control leakage 6 Leakage from O/L of the Cl2 Valve - Thread damaged - Pin hole in the outlet nozzle - Gasket not properly fitted - Dosing line leakage - Close valve - Rotate Tonner to 180 deg., Use 2 nd valve - Replace gasket   - Replace the dosing line
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