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Demonstration Project Design 
Edward Steadman, University of North Dakota Energy & Environmental 
Research Center 
Advanced Workshop for CO2 Storage 
August 26-27, 2014 
DF IPN ESIA Ticomán Auditorium 
SUPPORTED BY:
Integrated fossil energy solutions 
Advanced Combustion 
 Gasification 
 Turbines 
 Supercritical CO2 
 Direct Power Extraction 
Efficiencies > 45% 
i Capital Cost by 50% 
$10 - $40/tonne CO2 Captured 
Near-zero GHGs 
Near-zero criteria pollutants 
Near-zero water usage 
Advanced CO CO2 Storage 2 Capture 
and Compression 
 Solvents 
 Sorbents 
 Membranes 
 Hybrid 
 Process Intensification 
 Cryogenic Capture 
SUPPORTED BY: 
 Pressurized 
 O2 membrane 
 Chemical looping 
 USC Materials 
 Carbon Utilization (EOR) 
 Infrastructure (RCSPs) 
 Geological Storage 
 Monitoring, Verification and 
Accounting 
Advanced Energy Systems 
5 MWE Oxycombustion Pilot Advanced Turbines 
Courtesy of Darren Mollot, DOE
SUPPORTED BY:
U.S. Department of Energy carbon sequestration programs 
CORE R&D Infrastructure Global Collaborations 
Precombustion Capture Regional Carbon 
SUPPORTED BY: 
Sequestration 
Partnerships 
International 
Demonstration Projects 
Monitoring, Verification 
and Accounting 
Geologic 
Characterization 
Carbon Sequestration 
Leadership Forum 
Geologic Storage Small-scale Field 
Trials 
Worldwide CCS Projects 
Database 
Risk Framework Large-scale Field 
Trials 
North American Carbon 
Atlas Partnership 
CO2 Utilization Knowledge Sharing US-China Clean Energy 
Research Center
The U.S. Programs aim to create a bridge to affordable CCS 
technology 
SUPPORTED BY:
NETL Carbon Sequestration Program goals 
To accomplish widespread CCS deployment, four program goals have 
been established: 
(1)Develop technologies that can separate, capture, transport, and store 
CO2 using either direct or indirect systems that result in a less than 10 
percent increase in the cost of energy by 2015; 
(2)Develop technologies that will support industries’ ability to predict CO2 
storage capacity in geologic formations to within ±30 percent by 2015; 
(3)Develop technologies to demonstrate that 99 percent of injected CO2 
remains in the injection zones by 2015; 
(4)Complete Best Practices Manuals (BPMs) for site selection, 
characterization, site operations, and closure practices by 2020. 
SUPPORTED BY:
REGIONAL CARBON SEQUESTRATION 
PARTNERSHIPS 
SUPPORTED BY:
SUPPORTED BY: 
Sources 
927 stationary sources 
Total CO2 emissions: 
≈ 562 million tons/yr 
• 9% of U.S. and Canada 
population 
• 8% of U.S. and Canada gross 
domestic product (GDP) 
• 12% of U.S. and Canada 
anthropogenic CO2
PCOR PARTNERSHIP REGION STORAGE 
OPPORTUNITIES 
SUPPORTED BY: 
Oil Fields 
6000+ fields evaluated. 
Fields in the Williston, Powder River, 
Denver–Julesberg, and Alberta 
Basins were evaluated. 
Great Potential in Both Oilfield and 
Saline Formations 
• Enormous carbon dioxide (CO2) storage 
potential in the best oil fields alone! 
• In the top 160 fields, over 3 Bbbl of 
incremental recovery potential. 
• With the potential to incidentally store over 
1 Bt of CO2. 
• Multiple saline formations in the Alberta, 
Williston, Powder River, and Denver– 
Julesberg Basins.
Regional Carbon Sequestration Partnerships (RCSP) 
• Competitive bids by strong regional research and development 
collaborations made up of universities, industry, national 
laboratories, state agencies. 
• Three phases to provide: 
• Characterization – assessment of regional sources and 
storage sites 
• Validation – small scale projects to test storage formations 
with high potential 
• Development – large-scale injection tests (>1 million tons). 
• Long-term funding over 10 years starting 2003, expected to 
continue to 2020. 
SUPPORTED BY:
NATCARB 
• The National Carbon Sequestration Database and Geographic Information 
System (NATCARB) is a geographic information system (GIS)-based tool 
developed to provide a view of carbon capture and storage (CCS) potential. 
• Interactive, public web access 
• Data and tools include: 
• CO2 stationary sources 
• Potential geologic CO2 storage formations 
• Infrastructure 
• Analytical tools (pipeline measurement, storage resource estimation, 
cost estimation, etc.) required for addressing CCS deployment 
• Distributed computing solutions link the RCSPs and other publically 
accessible repositories of CCS-relevant data . 
SUPPORTED BY:
Example of maps generated from NATCARB of basins, 
saline, and oil and gas storage resources 
Basins Oil and 
SUPPORTED BY: 
Gas 
Saline
Major CCS demonstration projects (as of 2013) 
Project locations & cost share 
SUPPORTED BY: 
CCPI 
ICCS Area 1 
FutureGen 2.0 
Southern Company 
Kemper County IGCC Project 
IGCC-Transport Gasifier 
w/Carbon Capture 
~$2.0B – Total CCPI project 
$270M – DOE 
EOR – ~3M MTPY 2014 start 
NRG 
W.A. Parish Generating Station 
Post Combustion CO2 Capture 
$775 M (est.) – Total 
$167M – DOE 
EOR – ~1.4M MTPY 2016 start 
Summit TX Clean Energy 
Commercial Demo of 
Advanced 
IGCC w/ Full Carbon Capture 
~$1.7B – Total 
$450M – DOE 
EOR – ~2.2M MTPY 2017 
start 
HECA 
Commercial Demo of 
Advanced 
IGCC w/ Full Carbon Capture 
~$4B – Total, $408M – DOE 
EOR – ~2.6M MTPY 2019 
start 
Leucadia Energy 
CO2 Capture from Methanol/H2 
Plant 
EOR in TX & LA Oilfields 
$436M - Total, $261M – DOE 
EOR – ~4.5M MTPY 2017 start 
Air Products and Chemicals, Inc. 
CO2 Capture from Steam Methane Reformers 
EOR in Eastern TX Oilfields 
$431M – Total, $284M – DOE 
EOR – ~0.93M MTPY 2012 start 
FutureGen 2.0 
Large-scale Testing of Oxy- 
Combustion w/ CO2 Capture and 
Sequestration in Saline Formation 
Project: ~$1.77B – Total; ~$1.05B 
– DOE 
SALINE – ~1M MTPY 2017 start 
Archer Daniels Midland 
CO2 Capture from Ethanol Plant 
CO2 Stored in Saline Reservoir 
$208M – Total, $141M – DOE 
SALINE – ~0.9M MTPY 2014 
start 
Courtesy of Darren Mollot, DOE
Key goals of large-scale projects 
• Demonstrate adequate injectivity and available capacity at near-commercial scale by 
injecting CO2 over an extended period of time. 
• Verify storage permanence by validating that CO2 will be contained in the target 
formations; develop technologies and protocols to quantify potential releases and that the 
projects do not adversely impact underground sources of drinking water (USDWs) or 
cause CO2 to be released to the atmosphere. 
• Determine the areal extent of the CO2 plume and potential release pathways by 
monitoring the areal extent and vertical migration of the CO2 during and after project 
completion and develop methodologies to determine the presence of release pathways 
such that the proposed mitigation strategy can sustain a near-zero release. 
• Develop risk assessment strategies by identifying risk parameters, probability and 
potential impact of occurrence, and mitigation strategies. 
• Engage in public outreach and education about CCS. 
• Develop information that supports the development of an effective regulatory and legal 
framework for the safe, long-term injection and geologic CO2 storage in the regions that 
the projects are developed. 
SUPPORTED BY:
SUPPORTED BY: 
END.

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Demonstration Project Design for CO2 Storage

  • 1. Demonstration Project Design Edward Steadman, University of North Dakota Energy & Environmental Research Center Advanced Workshop for CO2 Storage August 26-27, 2014 DF IPN ESIA Ticomán Auditorium SUPPORTED BY:
  • 2. Integrated fossil energy solutions Advanced Combustion  Gasification  Turbines  Supercritical CO2  Direct Power Extraction Efficiencies > 45% i Capital Cost by 50% $10 - $40/tonne CO2 Captured Near-zero GHGs Near-zero criteria pollutants Near-zero water usage Advanced CO CO2 Storage 2 Capture and Compression  Solvents  Sorbents  Membranes  Hybrid  Process Intensification  Cryogenic Capture SUPPORTED BY:  Pressurized  O2 membrane  Chemical looping  USC Materials  Carbon Utilization (EOR)  Infrastructure (RCSPs)  Geological Storage  Monitoring, Verification and Accounting Advanced Energy Systems 5 MWE Oxycombustion Pilot Advanced Turbines Courtesy of Darren Mollot, DOE
  • 4. U.S. Department of Energy carbon sequestration programs CORE R&D Infrastructure Global Collaborations Precombustion Capture Regional Carbon SUPPORTED BY: Sequestration Partnerships International Demonstration Projects Monitoring, Verification and Accounting Geologic Characterization Carbon Sequestration Leadership Forum Geologic Storage Small-scale Field Trials Worldwide CCS Projects Database Risk Framework Large-scale Field Trials North American Carbon Atlas Partnership CO2 Utilization Knowledge Sharing US-China Clean Energy Research Center
  • 5. The U.S. Programs aim to create a bridge to affordable CCS technology SUPPORTED BY:
  • 6. NETL Carbon Sequestration Program goals To accomplish widespread CCS deployment, four program goals have been established: (1)Develop technologies that can separate, capture, transport, and store CO2 using either direct or indirect systems that result in a less than 10 percent increase in the cost of energy by 2015; (2)Develop technologies that will support industries’ ability to predict CO2 storage capacity in geologic formations to within ±30 percent by 2015; (3)Develop technologies to demonstrate that 99 percent of injected CO2 remains in the injection zones by 2015; (4)Complete Best Practices Manuals (BPMs) for site selection, characterization, site operations, and closure practices by 2020. SUPPORTED BY:
  • 7. REGIONAL CARBON SEQUESTRATION PARTNERSHIPS SUPPORTED BY:
  • 8. SUPPORTED BY: Sources 927 stationary sources Total CO2 emissions: ≈ 562 million tons/yr • 9% of U.S. and Canada population • 8% of U.S. and Canada gross domestic product (GDP) • 12% of U.S. and Canada anthropogenic CO2
  • 9. PCOR PARTNERSHIP REGION STORAGE OPPORTUNITIES SUPPORTED BY: Oil Fields 6000+ fields evaluated. Fields in the Williston, Powder River, Denver–Julesberg, and Alberta Basins were evaluated. Great Potential in Both Oilfield and Saline Formations • Enormous carbon dioxide (CO2) storage potential in the best oil fields alone! • In the top 160 fields, over 3 Bbbl of incremental recovery potential. • With the potential to incidentally store over 1 Bt of CO2. • Multiple saline formations in the Alberta, Williston, Powder River, and Denver– Julesberg Basins.
  • 10. Regional Carbon Sequestration Partnerships (RCSP) • Competitive bids by strong regional research and development collaborations made up of universities, industry, national laboratories, state agencies. • Three phases to provide: • Characterization – assessment of regional sources and storage sites • Validation – small scale projects to test storage formations with high potential • Development – large-scale injection tests (>1 million tons). • Long-term funding over 10 years starting 2003, expected to continue to 2020. SUPPORTED BY:
  • 11. NATCARB • The National Carbon Sequestration Database and Geographic Information System (NATCARB) is a geographic information system (GIS)-based tool developed to provide a view of carbon capture and storage (CCS) potential. • Interactive, public web access • Data and tools include: • CO2 stationary sources • Potential geologic CO2 storage formations • Infrastructure • Analytical tools (pipeline measurement, storage resource estimation, cost estimation, etc.) required for addressing CCS deployment • Distributed computing solutions link the RCSPs and other publically accessible repositories of CCS-relevant data . SUPPORTED BY:
  • 12. Example of maps generated from NATCARB of basins, saline, and oil and gas storage resources Basins Oil and SUPPORTED BY: Gas Saline
  • 13. Major CCS demonstration projects (as of 2013) Project locations & cost share SUPPORTED BY: CCPI ICCS Area 1 FutureGen 2.0 Southern Company Kemper County IGCC Project IGCC-Transport Gasifier w/Carbon Capture ~$2.0B – Total CCPI project $270M – DOE EOR – ~3M MTPY 2014 start NRG W.A. Parish Generating Station Post Combustion CO2 Capture $775 M (est.) – Total $167M – DOE EOR – ~1.4M MTPY 2016 start Summit TX Clean Energy Commercial Demo of Advanced IGCC w/ Full Carbon Capture ~$1.7B – Total $450M – DOE EOR – ~2.2M MTPY 2017 start HECA Commercial Demo of Advanced IGCC w/ Full Carbon Capture ~$4B – Total, $408M – DOE EOR – ~2.6M MTPY 2019 start Leucadia Energy CO2 Capture from Methanol/H2 Plant EOR in TX & LA Oilfields $436M - Total, $261M – DOE EOR – ~4.5M MTPY 2017 start Air Products and Chemicals, Inc. CO2 Capture from Steam Methane Reformers EOR in Eastern TX Oilfields $431M – Total, $284M – DOE EOR – ~0.93M MTPY 2012 start FutureGen 2.0 Large-scale Testing of Oxy- Combustion w/ CO2 Capture and Sequestration in Saline Formation Project: ~$1.77B – Total; ~$1.05B – DOE SALINE – ~1M MTPY 2017 start Archer Daniels Midland CO2 Capture from Ethanol Plant CO2 Stored in Saline Reservoir $208M – Total, $141M – DOE SALINE – ~0.9M MTPY 2014 start Courtesy of Darren Mollot, DOE
  • 14. Key goals of large-scale projects • Demonstrate adequate injectivity and available capacity at near-commercial scale by injecting CO2 over an extended period of time. • Verify storage permanence by validating that CO2 will be contained in the target formations; develop technologies and protocols to quantify potential releases and that the projects do not adversely impact underground sources of drinking water (USDWs) or cause CO2 to be released to the atmosphere. • Determine the areal extent of the CO2 plume and potential release pathways by monitoring the areal extent and vertical migration of the CO2 during and after project completion and develop methodologies to determine the presence of release pathways such that the proposed mitigation strategy can sustain a near-zero release. • Develop risk assessment strategies by identifying risk parameters, probability and potential impact of occurrence, and mitigation strategies. • Engage in public outreach and education about CCS. • Develop information that supports the development of an effective regulatory and legal framework for the safe, long-term injection and geologic CO2 storage in the regions that the projects are developed. SUPPORTED BY:

Editor's Notes

  1. Databases from characterization phase used to populate NATCARB