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MOISTURE

MECHILLE JANE R. WONG
                MS EST
   Water is essential to life on earth.
Polarity of Water
• In a water molecule two hydrogen atoms form
  single polar covalent bonds with an oxygen
  atom. Gives water more structure than other
  liquids
   – Because oxygen is more electronegative, the region
     around oxygen has a partial negative charge.
   – The region near the two hydrogen atoms has a
     partial positive charge.
• A water molecule is a polar molecule with
  opposite ends of the molecule with opposite
  charges.
• Water has a variety of unusual properties
  because of attractions between these polar
  molecules.
      – The slightly negative regions of one molecule are
        attracted to the slightly positive regions of nearby
        molecules, forming a hydrogen bond.
      – Each water molecule
        can form hydrogen
        bonds with up to
        four neighbors.



                                               Fig. 3.1
Copyright © 2002 Pearson Education, Inc., publishing as Benjamin Cummings
HYDROGEN BONDS
• Hold water molecules        • Extraordinary Properties
  together                      that are a result of hydrogen
• Each water molecule can       bonds.
                                 – Cohesive behavior
  form a maximum of 4
                                 – Resists changes in
  hydrogen bonds
                                   temperature
• The hydrogen bonds             – High heat of vaporization
  joining water molecules        – Expands when it freezes
  are weak, about 1/20th as      – Versatile solvent
  strong as covalent bonds.
• They form, break, and
  reform with great
  frequency
Organisms Depend on Cohesion
         Hydrogen bonds hold the substance
       together, a phenomenon called cohesion
• Cohesion is responsible for the
  transport of the water column in
  plants
• Cohesion among water molecules
  plays a key role in the transport of
  water against gravity in plants
• Adhesion, clinging
  of one substance to
  another, contributes
  too, as water adheres
  to the wall of the
  vessels.
• Surface tension, a measure of the force
  necessary to stretch or break the surface of a
  liquid, is related to cohesion.
      – Water has a greater surface tension than most other
          liquids because hydrogen bonds among surface
          water molecules resist stretching or breaking the
          surface.
      – Water behaves as if
          covered by an invisible
          film.
      – Some animals can stand,
          walk, or run on water
          without breaking the
                                                                    Fig. 3.3
          surface.
Copyright © 2002 Pearson Education, Inc., publishing as Benjamin Cummings
Specific Heat is the amount of heat that must be
    absorbed or lost for one gram of a substance to
             change its temperature by 1oC.
Three-fourths of the earth is covered
by water. The water serves as a
large heat sink responsible for:
1.Prevention of temperature
fluctuations that are outside the
range suitable for life.
2.Coastal areas having a mild
climate
3.A stable marine environment
Moderates Temperatures on Earth
Water stabilizes air temperatures by absorbing heat from
warmer air and releasing heat to cooler air.
Water can absorb or release relatively large amounts of heat
with only a slight change in its own temperature.

 Celsius Scale at Sea Level      • What is kinetic energy?
                                 • Heat?
100oC    Water boils
                                 • Temperature?
37oC     Human body              • Calorie?
         temperature
                                 • What is the difference
23oC     Room temperature          in cal and Cal?
0oC      Water freezes
                                 • What is specific heat?
Evaporative Cooling
    • The cooling of a
      surface occurs when
      the liquid evaporates
    • This is responsible for:
       – Moderating earth’s
         climate
       – Stabilizes
         temperature in
         aquatic ecosystems
       – Preventing organisms
         from overheating
Density of Water
   • Most dense at 4oC
   • Contracts until 4oC
   • Expands from 4oC to
     0oC

The density of water:
1.Prevents water from freezing from the bottom up.
2.Ice forms on the surface first—the freezing of the
water releases heat to the water below creating
insulation.
3.Makes transition between season less abrupt.
– When water reaches 0oC, water becomes locked into
      a crystalline lattice with each molecule bonded to to
      the maximum of four partners.
    – As ice starts to melt, some of the hydrogen bonds
      break and some water molecules can slip closer
      together than they can while in the ice state.
    – Ice is about 10% less dense than water at 4oC.




    Fig. 3.5
Copyright © 2002 Pearson Education, Inc., publishing as Benjamin Cummings
Solvent for Life
• Solution
  – Solute
  – solvent
• Aqueous solution
• Hydrophilic
  – Ionic compounds
    dissolve in water
  – Polar molecules
    (generally) are water
    soluble
• Hydrophobic
  – Nonpolar compounds
   The Three forms of Water.

 Solids: When water becomes very cold
  and freezes it will change from a liquid to
  a solid. It has a definite form and shape.
 Liquids: When water takes the shape of
  its container it is in a liquid form.
 Gases: When water is seen in a vapor
  form and has no definite size or shape it
  is in a gas form.

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Moisture

  • 2. Water is essential to life on earth.
  • 3.
  • 4. Polarity of Water • In a water molecule two hydrogen atoms form single polar covalent bonds with an oxygen atom. Gives water more structure than other liquids – Because oxygen is more electronegative, the region around oxygen has a partial negative charge. – The region near the two hydrogen atoms has a partial positive charge. • A water molecule is a polar molecule with opposite ends of the molecule with opposite charges.
  • 5. • Water has a variety of unusual properties because of attractions between these polar molecules. – The slightly negative regions of one molecule are attracted to the slightly positive regions of nearby molecules, forming a hydrogen bond. – Each water molecule can form hydrogen bonds with up to four neighbors. Fig. 3.1 Copyright © 2002 Pearson Education, Inc., publishing as Benjamin Cummings
  • 6. HYDROGEN BONDS • Hold water molecules • Extraordinary Properties together that are a result of hydrogen • Each water molecule can bonds. – Cohesive behavior form a maximum of 4 – Resists changes in hydrogen bonds temperature • The hydrogen bonds – High heat of vaporization joining water molecules – Expands when it freezes are weak, about 1/20th as – Versatile solvent strong as covalent bonds. • They form, break, and reform with great frequency
  • 7. Organisms Depend on Cohesion Hydrogen bonds hold the substance together, a phenomenon called cohesion • Cohesion is responsible for the transport of the water column in plants • Cohesion among water molecules plays a key role in the transport of water against gravity in plants • Adhesion, clinging of one substance to another, contributes too, as water adheres to the wall of the vessels.
  • 8. • Surface tension, a measure of the force necessary to stretch or break the surface of a liquid, is related to cohesion. – Water has a greater surface tension than most other liquids because hydrogen bonds among surface water molecules resist stretching or breaking the surface. – Water behaves as if covered by an invisible film. – Some animals can stand, walk, or run on water without breaking the Fig. 3.3 surface. Copyright © 2002 Pearson Education, Inc., publishing as Benjamin Cummings
  • 9. Specific Heat is the amount of heat that must be absorbed or lost for one gram of a substance to change its temperature by 1oC. Three-fourths of the earth is covered by water. The water serves as a large heat sink responsible for: 1.Prevention of temperature fluctuations that are outside the range suitable for life. 2.Coastal areas having a mild climate 3.A stable marine environment
  • 10. Moderates Temperatures on Earth Water stabilizes air temperatures by absorbing heat from warmer air and releasing heat to cooler air. Water can absorb or release relatively large amounts of heat with only a slight change in its own temperature. Celsius Scale at Sea Level • What is kinetic energy? • Heat? 100oC Water boils • Temperature? 37oC Human body • Calorie? temperature • What is the difference 23oC Room temperature in cal and Cal? 0oC Water freezes • What is specific heat?
  • 11. Evaporative Cooling • The cooling of a surface occurs when the liquid evaporates • This is responsible for: – Moderating earth’s climate – Stabilizes temperature in aquatic ecosystems – Preventing organisms from overheating
  • 12. Density of Water • Most dense at 4oC • Contracts until 4oC • Expands from 4oC to 0oC The density of water: 1.Prevents water from freezing from the bottom up. 2.Ice forms on the surface first—the freezing of the water releases heat to the water below creating insulation. 3.Makes transition between season less abrupt.
  • 13. – When water reaches 0oC, water becomes locked into a crystalline lattice with each molecule bonded to to the maximum of four partners. – As ice starts to melt, some of the hydrogen bonds break and some water molecules can slip closer together than they can while in the ice state. – Ice is about 10% less dense than water at 4oC. Fig. 3.5 Copyright © 2002 Pearson Education, Inc., publishing as Benjamin Cummings
  • 14. Solvent for Life • Solution – Solute – solvent • Aqueous solution • Hydrophilic – Ionic compounds dissolve in water – Polar molecules (generally) are water soluble • Hydrophobic – Nonpolar compounds
  • 15.
  • 16.
  • 17. The Three forms of Water.  Solids: When water becomes very cold and freezes it will change from a liquid to a solid. It has a definite form and shape.  Liquids: When water takes the shape of its container it is in a liquid form.  Gases: When water is seen in a vapor form and has no definite size or shape it is in a gas form.